TY  - JOUR
AU  - Savić, Veljko
AU  - Dojčinović, Marina
AU  - Topalović, Vladimir
AU  - Cvijović-Alagić, Ivana
AU  - Stojanović, Jovica
AU  - Matijašević, Srđan
AU  - Grujić, Snežana
PY  - 2024
UR  - https://ritnms.itnms.ac.rs/handle/123456789/1233
AB  - The incombustible portion of coal that remains after burning is known as bottom or fly ash, and it has a detrimental influence on the environment. One of the possible alternatives for reducing the amount of ash deposited in landfills might be the production of useful glass-ceramic from vitrified fly ash. Glass-ceramic was synthesized using fly ash from the thermal power plant "Nikola Tesla" and fluxing additives. Sinter-crystallization of the parent glass resulted in glass ceramics. The glass was created by melting a combination of coal fly ash (CFA), Na2CO3, and CaCO3 at T= 1500 °C and quenching the melt in the air. Glass powders were sintered at temperatures 850 and 900 °C. The resulting glass-ceramics were characterized microstructurally, physically, and mechanically. The cavitation erosion of samples was evaluated. The cavitation rate was 0.015 mg/min for the sample sintered at 850 °C, and 0.0053 mg/min for the sample sintered at 900 °C. The leaching of heavy metals in glass-ceramic samples was determined using the Toxicity Characteristic Leaching Procedure. A low concentration of heavy metals in the leaching solution showed that heavy metals were successfully incorporated in the glass matrix and that obtained glass-ceramics are ecologically safe for usage. Both samples exhibit good resistance to cavitation erosion, suggesting their potential as possible replacements for structural ceramics commonly employed components of hydraulic machinery.
PB  - Springer Nature
T2  - International Journal of Environmental Science and Technology
T1  - The effect of sintering temperature on cavitation erosion in glass-ceramics based on coal fly ash
EP  - 6074
IS  - 7
SP  - 6065
VL  - 21
DO  - 10.1007/s13762-023-05411-9
ER  - 

@article{
author = "Savić, Veljko and Dojčinović, Marina and Topalović, Vladimir and Cvijović-Alagić, Ivana and Stojanović, Jovica and Matijašević, Srđan and Grujić, Snežana",
year = "2024",
abstract = "The incombustible portion of coal that remains after burning is known as bottom or fly ash, and it has a detrimental influence on the environment. One of the possible alternatives for reducing the amount of ash deposited in landfills might be the production of useful glass-ceramic from vitrified fly ash. Glass-ceramic was synthesized using fly ash from the thermal power plant "Nikola Tesla" and fluxing additives. Sinter-crystallization of the parent glass resulted in glass ceramics. The glass was created by melting a combination of coal fly ash (CFA), Na2CO3, and CaCO3 at T= 1500 °C and quenching the melt in the air. Glass powders were sintered at temperatures 850 and 900 °C. The resulting glass-ceramics were characterized microstructurally, physically, and mechanically. The cavitation erosion of samples was evaluated. The cavitation rate was 0.015 mg/min for the sample sintered at 850 °C, and 0.0053 mg/min for the sample sintered at 900 °C. The leaching of heavy metals in glass-ceramic samples was determined using the Toxicity Characteristic Leaching Procedure. A low concentration of heavy metals in the leaching solution showed that heavy metals were successfully incorporated in the glass matrix and that obtained glass-ceramics are ecologically safe for usage. Both samples exhibit good resistance to cavitation erosion, suggesting their potential as possible replacements for structural ceramics commonly employed components of hydraulic machinery.",
publisher = "Springer Nature",
journal = "International Journal of Environmental Science and Technology",
title = "The effect of sintering temperature on cavitation erosion in glass-ceramics based on coal fly ash",
pages = "6074-6065",
number = "7",
volume = "21",
doi = "10.1007/s13762-023-05411-9"
}

Savić, V., Dojčinović, M., Topalović, V., Cvijović-Alagić, I., Stojanović, J., Matijašević, S.,& Grujić, S.. (2024). The effect of sintering temperature on cavitation erosion in glass-ceramics based on coal fly ash. in International Journal of Environmental Science and Technology
Springer Nature., 21(7), 6065-6074.
https://doi.org/10.1007/s13762-023-05411-9

Savić V, Dojčinović M, Topalović V, Cvijović-Alagić I, Stojanović J, Matijašević S, Grujić S. The effect of sintering temperature on cavitation erosion in glass-ceramics based on coal fly ash. in International Journal of Environmental Science and Technology. 2024;21(7):6065-6074.
doi:10.1007/s13762-023-05411-9 .

Savić, Veljko, Dojčinović, Marina, Topalović, Vladimir, Cvijović-Alagić, Ivana, Stojanović, Jovica, Matijašević, Srđan, Grujić, Snežana, "The effect of sintering temperature on cavitation erosion in glass-ceramics based on coal fly ash" in International Journal of Environmental Science and Technology, 21, no. 7 (2024):6065-6074,
https://doi.org/10.1007/s13762-023-05411-9 . .

TY  - JOUR
AU  - Đorđević, Nataša
AU  - Matijašević, Srđan
AU  - Mihajlović, Slavica
AU  - Stojanović, Jovica
AU  - Radulović, Aleksandra
AU  - Savić, Ljiljana
PY  - 2023
UR  - https://ritnms.itnms.ac.rs/handle/123456789/1207
AB  - The glass was prepared by the standard melt-quenching technique. The crystallization of powder glass from the system Li2O-Al2O3-GeO2-P2O5 was studied. The investigations were performed under non-isothermal and isothermal conditions using the AAS, DTA, XRD and FTIR methods. The aim of this research was to study the ease of glass formation, crystallization and crystal structure of obtained phases. The results showed that the glass crystallizes by primary crystallization. LiGe2(PO4)3 was formed as the primary phase, until detectable traces of GeO2 were formed as secondary. The influence of particle size of the glass powder samples in the range 0-1 mm on the temperature of the DTA crystallization peak, Tp, the peak height (T)p and the parameter Tp2/(T)p was studied. It was demonstrated that for the particle size in the range of 0.05-0.35 mm surface and volume crystallization were significant, while the particle size >0.35 mm according to the volume crystallization was dominant.
PB  - Belgrade : Association for ETRAN Society
T2  - Science of Sintering
T1  - The effect of particle size on the crystallization LiGe2(PO4)3  phase from glass
DO  - 10.2298/SOS231111064D
ER  - 

@article{
author = "Đorđević, Nataša and Matijašević, Srđan and Mihajlović, Slavica and Stojanović, Jovica and Radulović, Aleksandra and Savić, Ljiljana",
year = "2023",
abstract = "The glass was prepared by the standard melt-quenching technique. The crystallization of powder glass from the system Li2O-Al2O3-GeO2-P2O5 was studied. The investigations were performed under non-isothermal and isothermal conditions using the AAS, DTA, XRD and FTIR methods. The aim of this research was to study the ease of glass formation, crystallization and crystal structure of obtained phases. The results showed that the glass crystallizes by primary crystallization. LiGe2(PO4)3 was formed as the primary phase, until detectable traces of GeO2 were formed as secondary. The influence of particle size of the glass powder samples in the range 0-1 mm on the temperature of the DTA crystallization peak, Tp, the peak height (T)p and the parameter Tp2/(T)p was studied. It was demonstrated that for the particle size in the range of 0.05-0.35 mm surface and volume crystallization were significant, while the particle size >0.35 mm according to the volume crystallization was dominant.",
publisher = "Belgrade : Association for ETRAN Society",
journal = "Science of Sintering",
title = "The effect of particle size on the crystallization LiGe2(PO4)3  phase from glass",
doi = "10.2298/SOS231111064D"
}

Đorđević, N., Matijašević, S., Mihajlović, S., Stojanović, J., Radulović, A.,& Savić, L.. (2023). The effect of particle size on the crystallization LiGe2(PO4)3  phase from glass. in Science of Sintering
Belgrade : Association for ETRAN Society..
https://doi.org/10.2298/SOS231111064D

Đorđević N, Matijašević S, Mihajlović S, Stojanović J, Radulović A, Savić L. The effect of particle size on the crystallization LiGe2(PO4)3  phase from glass. in Science of Sintering. 2023;.
doi:10.2298/SOS231111064D .

Đorđević, Nataša, Matijašević, Srđan, Mihajlović, Slavica, Stojanović, Jovica, Radulović, Aleksandra, Savić, Ljiljana, "The effect of particle size on the crystallization LiGe2(PO4)3  phase from glass" in Science of Sintering (2023),
https://doi.org/10.2298/SOS231111064D . .

TY  - JOUR
AU  - Matijašević, Srđan
AU  - Topalović, Vladimir
AU  - Savić, Veljko
AU  - Labus, Nebojša
AU  - Nikolić, Jelena
AU  - Zildžović, Snežana
AU  - Grujić, Snežana
PY  - 2023
UR  - https://ritnms.itnms.ac.rs/handle/123456789/1221
AB  - The crystal growth rate of LiGe2(PO4)3 phase from lithium germanium-phosphate glass was studied. The glass have been homogenized using the previously established 
temperature-time conditions, which make it possible to remove volatile substances from the glass melt. The atomic absorption spectrophotometry (AAS) was used to determine the 
chemical content of the obtained glass and scanning electron microscope (SEM) were used to reveal the isothermal process of crystal growth. The crystal growth rates were determined 
experimentally and theoretically.
PB  - Belgrade : Association for ETRAN Society
T2  - Science of Sintering
T1  - The Crystal Growth of NASICON Phase from the Lithium Germanium Phosphate Glass
EP  - 547
IS  - 4
SP  - 539
VL  - 55
DO  - 10.2298/SOS220809022M
ER  - 

@article{
author = "Matijašević, Srđan and Topalović, Vladimir and Savić, Veljko and Labus, Nebojša and Nikolić, Jelena and Zildžović, Snežana and Grujić, Snežana",
year = "2023",
abstract = "The crystal growth rate of LiGe2(PO4)3 phase from lithium germanium-phosphate glass was studied. The glass have been homogenized using the previously established 
temperature-time conditions, which make it possible to remove volatile substances from the glass melt. The atomic absorption spectrophotometry (AAS) was used to determine the 
chemical content of the obtained glass and scanning electron microscope (SEM) were used to reveal the isothermal process of crystal growth. The crystal growth rates were determined 
experimentally and theoretically.",
publisher = "Belgrade : Association for ETRAN Society",
journal = "Science of Sintering",
title = "The Crystal Growth of NASICON Phase from the Lithium Germanium Phosphate Glass",
pages = "547-539",
number = "4",
volume = "55",
doi = "10.2298/SOS220809022M"
}

Matijašević, S., Topalović, V., Savić, V., Labus, N., Nikolić, J., Zildžović, S.,& Grujić, S.. (2023). The Crystal Growth of NASICON Phase from the Lithium Germanium Phosphate Glass. in Science of Sintering
Belgrade : Association for ETRAN Society., 55(4), 539-547.
https://doi.org/10.2298/SOS220809022M

Matijašević S, Topalović V, Savić V, Labus N, Nikolić J, Zildžović S, Grujić S. The Crystal Growth of NASICON Phase from the Lithium Germanium Phosphate Glass. in Science of Sintering. 2023;55(4):539-547.
doi:10.2298/SOS220809022M .

Matijašević, Srđan, Topalović, Vladimir, Savić, Veljko, Labus, Nebojša, Nikolić, Jelena, Zildžović, Snežana, Grujić, Snežana, "The Crystal Growth of NASICON Phase from the Lithium Germanium Phosphate Glass" in Science of Sintering, 55, no. 4 (2023):539-547,
https://doi.org/10.2298/SOS220809022M . .

TY  - CONF
AU  - Đorđević, Nataša
AU  - Vlahović, Milica
AU  - Mihajlović, Slavica
AU  - Vušović, Nenad
AU  - Matijašević, Srđan
PY  - 2023
UR  - https://ritnms.itnms.ac.rs/handle/123456789/1180
AB  - Mechanical activation of materials leads to qualitative changes in material structure. These changes can include the accumulation of energy in the form of weakening bonds in the crystal, disruption of the crystal lattice, agglomeration, and in some cases even the synthesis of a completely new substance. In this study, anhydrous sodium carbonate was mechanically activated for 28 minutes in a vibro mill at a frequency of 3000 oscillations per minute. After activation, the changes occurring in the activated material were monitored. The samples were placed in the atmosphere of air at room conditions for 31 days (relaxation period). It was observed that during the relaxation period moisture and carbon dioxide were absorbed by the activated sodium carbonate in form of hemisorption, forming sodium bicarbonate. The transformation mechanism was monitored by Fourier-transform infrared (FTIR) spectroscopy as a function of relaxation time. Characteristic groups were monitored: CO32-, HCO3- and OH-.
PB  - Belgrade : Union of Mechanical and Electrotechnical Engineers and Technicians of Serbia (SMEITS)
PB  - Belgrade : Society for Renewable Electrical Power Sources
C3  - 11th International Conference on Renewable Electrical Power Sources (ICREPS 2023)
T1  - Spectroscopy analysis of activated sodium carbonate
EP  - 413
SP  - 409
ER  - 

@conference{
author = "Đorđević, Nataša and Vlahović, Milica and Mihajlović, Slavica and Vušović, Nenad and Matijašević, Srđan",
year = "2023",
abstract = "Mechanical activation of materials leads to qualitative changes in material structure. These changes can include the accumulation of energy in the form of weakening bonds in the crystal, disruption of the crystal lattice, agglomeration, and in some cases even the synthesis of a completely new substance. In this study, anhydrous sodium carbonate was mechanically activated for 28 minutes in a vibro mill at a frequency of 3000 oscillations per minute. After activation, the changes occurring in the activated material were monitored. The samples were placed in the atmosphere of air at room conditions for 31 days (relaxation period). It was observed that during the relaxation period moisture and carbon dioxide were absorbed by the activated sodium carbonate in form of hemisorption, forming sodium bicarbonate. The transformation mechanism was monitored by Fourier-transform infrared (FTIR) spectroscopy as a function of relaxation time. Characteristic groups were monitored: CO32-, HCO3- and OH-.",
publisher = "Belgrade : Union of Mechanical and Electrotechnical Engineers and Technicians of Serbia (SMEITS), Belgrade : Society for Renewable Electrical Power Sources",
journal = "11th International Conference on Renewable Electrical Power Sources (ICREPS 2023)",
title = "Spectroscopy analysis of activated sodium carbonate",
pages = "413-409"
}

Đorđević, N., Vlahović, M., Mihajlović, S., Vušović, N.,& Matijašević, S.. (2023). Spectroscopy analysis of activated sodium carbonate. in 11th International Conference on Renewable Electrical Power Sources (ICREPS 2023)
Belgrade : Union of Mechanical and Electrotechnical Engineers and Technicians of Serbia (SMEITS)., 409-413.

Đorđević N, Vlahović M, Mihajlović S, Vušović N, Matijašević S. Spectroscopy analysis of activated sodium carbonate. in 11th International Conference on Renewable Electrical Power Sources (ICREPS 2023). 2023;:409-413..

Đorđević, Nataša, Vlahović, Milica, Mihajlović, Slavica, Vušović, Nenad, Matijašević, Srđan, "Spectroscopy analysis of activated sodium carbonate" in 11th International Conference on Renewable Electrical Power Sources (ICREPS 2023) (2023):409-413.

TY  - JOUR
AU  - Labus, Nebojsa
AU  - Krstić, Jugoslav
AU  - Matijašević, Srđan
AU  - Pavlović, Vladimir
PY  - 2023
UR  - https://ritnms.itnms.ac.rs/handle/123456789/743
AB  - Powder mixture consisted of ZnO, Mn2O3 (MnCO3) and Fe2O3 blended powders, was found laminating during compaction. Polyvinyl alcohol (PVA) and a combination of PVA with polyethylene glycol (PEG) added as a plasticizer, were introduced as polymer binders to improve the compaction of oxide mixtures. It has been done by forming a suspension of oxide mixture and varying the polymer solution concentration and composition. By evaporating the solvent, new materials were obtained, which consist of oxide particles bound via polymer. In such a manner obtained hybrid materials were characterized with attenuated total reflection Fourier transformed infrared (ATR-FTIR) spectroscopy, differential thermal analysis (DTA) and transmission electron microscopy (TEM). The oxide polymer material was compacted at 200 MPa and the expansion of this compact during heating was monitored in temperature range up to 550ºC with dilatometer. It was found that PVA forms graft polymer with PEG and specific interaction with oxide particles surface was revealed.
AB  - Смеша прахова састављена од ZnO, Mn2O3 (MnCO3) и Fe2O3 комбинације
прахова је показивала ламинацију током пресовања. Поливинил алкохол (PVA) и
комбинација PVA са полиетилен гликолом (PEG) који је додат као пластификатор, су
уведени као полимерно везиво за пресовање оксидних прахова. Везиво је уведено тако
што је формирана суспензија смеше различитих оксида прахова у полимерном
раствору. Концентрације полимера и састави су варирани. Уклањањем растварача
добијени су нови материјали који се састоје од честица оксида повезаних полимерима.
Ови хибридни материјали окарактерисани су методама ометене тоталне рефлексије
фурије трансформисане инфрацрвене спектроскопије (ATR-FTIR) као и
диференцијалне термичке анализе (DTA). Микроструктура је посматрана
трансмисоном електронском микроскопијом (TEM). Оксид-полимер материјали су
пресовани на притиску од 200 MPa и ширење испреска током грејања је праћено у температурском опсегу од собне до 550ºC употребом дилатометра. Нађено је да PVA
формира графт полимер са PEG и да постоји специфична интеракција полимера са
површином честица оксида.
PB  - Belgrade : Association for ETRAN Society
T2  - Science of Sintering
T1  - Oxide Powder Mixture with Poly-vinyl Alcohol (PVA) and added Polyethylene Glycol (PEG) as Plasticizer
EP  - 2023
SP  - 189
VL  - 55
DO  - 10.2298/SOS220828005L
ER  - 

@article{
author = "Labus, Nebojsa and Krstić, Jugoslav and Matijašević, Srđan and Pavlović, Vladimir",
year = "2023",
abstract = "Powder mixture consisted of ZnO, Mn2O3 (MnCO3) and Fe2O3 blended powders, was found laminating during compaction. Polyvinyl alcohol (PVA) and a combination of PVA with polyethylene glycol (PEG) added as a plasticizer, were introduced as polymer binders to improve the compaction of oxide mixtures. It has been done by forming a suspension of oxide mixture and varying the polymer solution concentration and composition. By evaporating the solvent, new materials were obtained, which consist of oxide particles bound via polymer. In such a manner obtained hybrid materials were characterized with attenuated total reflection Fourier transformed infrared (ATR-FTIR) spectroscopy, differential thermal analysis (DTA) and transmission electron microscopy (TEM). The oxide polymer material was compacted at 200 MPa and the expansion of this compact during heating was monitored in temperature range up to 550ºC with dilatometer. It was found that PVA forms graft polymer with PEG and specific interaction with oxide particles surface was revealed., Смеша прахова састављена од ZnO, Mn2O3 (MnCO3) и Fe2O3 комбинације
прахова је показивала ламинацију током пресовања. Поливинил алкохол (PVA) и
комбинација PVA са полиетилен гликолом (PEG) који је додат као пластификатор, су
уведени као полимерно везиво за пресовање оксидних прахова. Везиво је уведено тако
што је формирана суспензија смеше различитих оксида прахова у полимерном
раствору. Концентрације полимера и састави су варирани. Уклањањем растварача
добијени су нови материјали који се састоје од честица оксида повезаних полимерима.
Ови хибридни материјали окарактерисани су методама ометене тоталне рефлексије
фурије трансформисане инфрацрвене спектроскопије (ATR-FTIR) као и
диференцијалне термичке анализе (DTA). Микроструктура је посматрана
трансмисоном електронском микроскопијом (TEM). Оксид-полимер материјали су
пресовани на притиску од 200 MPa и ширење испреска током грејања је праћено у температурском опсегу од собне до 550ºC употребом дилатометра. Нађено је да PVA
формира графт полимер са PEG и да постоји специфична интеракција полимера са
површином честица оксида.",
publisher = "Belgrade : Association for ETRAN Society",
journal = "Science of Sintering",
title = "Oxide Powder Mixture with Poly-vinyl Alcohol (PVA) and added Polyethylene Glycol (PEG) as Plasticizer",
pages = "2023-189",
volume = "55",
doi = "10.2298/SOS220828005L"
}

Labus, N., Krstić, J., Matijašević, S.,& Pavlović, V.. (2023). Oxide Powder Mixture with Poly-vinyl Alcohol (PVA) and added Polyethylene Glycol (PEG) as Plasticizer. in Science of Sintering
Belgrade : Association for ETRAN Society., 55, 189-2023.
https://doi.org/10.2298/SOS220828005L

Labus N, Krstić J, Matijašević S, Pavlović V. Oxide Powder Mixture with Poly-vinyl Alcohol (PVA) and added Polyethylene Glycol (PEG) as Plasticizer. in Science of Sintering. 2023;55:189-2023.
doi:10.2298/SOS220828005L .

Labus, Nebojsa, Krstić, Jugoslav, Matijašević, Srđan, Pavlović, Vladimir, "Oxide Powder Mixture with Poly-vinyl Alcohol (PVA) and added Polyethylene Glycol (PEG) as Plasticizer" in Science of Sintering, 55 (2023):189-2023,
https://doi.org/10.2298/SOS220828005L . .

TY  - CONF
AU  - Nikolić, Jelena
AU  - Topalović, Vladimir
AU  - Đošić, Marija
AU  - Savić, Veljko
AU  - Obradović, Milena
AU  - Matijašević, Srđan
AU  - Grujić, Snežana
PY  - 2023
UR  - https://ritnms.itnms.ac.rs/handle/123456789/792
AB  - This paper shows the dissolution behavior of polyphosphate glass in demineralized water and 2% citric acid solution at temperatures: 15, 20, 30, 37 and 50 °C. The influence of the solvent type on the diffusion coefficients of the modifying cations, under static conditions, is also presented. The diffusion coefficients, determined from concentration profiles of the modifying cations, are calculated to be in the range of 0.27 to 350x10-14 m2/h for dissolution in demineralized water, and in the range of 3.6 to 148x10-12 m2/h for the dissolution in 2% citric acid solution. The values of activation energy of cations diffusion in demineralized water are in the range from 68.32 to 105.41 kJ/mol, while for 2% citric acid solution they are in the range from 39.28 to 55.34 kJ/mol.
PB  - Belgrade : Association of Metallurgical Engineers of Serbia
C3  - 5th Metallurgical & Materials Engineering Congress of South-East Europe
T1  - Dissolution  of polyphosphate glass: Impact of pH on diffusion coefficients of modifying cations at low temperatures
EP  - 236
SP  - 231
ER  - 

@conference{
author = "Nikolić, Jelena and Topalović, Vladimir and Đošić, Marija and Savić, Veljko and Obradović, Milena and Matijašević, Srđan and Grujić, Snežana",
year = "2023",
abstract = "This paper shows the dissolution behavior of polyphosphate glass in demineralized water and 2% citric acid solution at temperatures: 15, 20, 30, 37 and 50 °C. The influence of the solvent type on the diffusion coefficients of the modifying cations, under static conditions, is also presented. The diffusion coefficients, determined from concentration profiles of the modifying cations, are calculated to be in the range of 0.27 to 350x10-14 m2/h for dissolution in demineralized water, and in the range of 3.6 to 148x10-12 m2/h for the dissolution in 2% citric acid solution. The values of activation energy of cations diffusion in demineralized water are in the range from 68.32 to 105.41 kJ/mol, while for 2% citric acid solution they are in the range from 39.28 to 55.34 kJ/mol.",
publisher = "Belgrade : Association of Metallurgical Engineers of Serbia",
journal = "5th Metallurgical & Materials Engineering Congress of South-East Europe",
title = "Dissolution  of polyphosphate glass: Impact of pH on diffusion coefficients of modifying cations at low temperatures",
pages = "236-231"
}

Nikolić, J., Topalović, V., Đošić, M., Savić, V., Obradović, M., Matijašević, S.,& Grujić, S.. (2023). Dissolution  of polyphosphate glass: Impact of pH on diffusion coefficients of modifying cations at low temperatures. in 5th Metallurgical & Materials Engineering Congress of South-East Europe
Belgrade : Association of Metallurgical Engineers of Serbia., 231-236.

Nikolić J, Topalović V, Đošić M, Savić V, Obradović M, Matijašević S, Grujić S. Dissolution  of polyphosphate glass: Impact of pH on diffusion coefficients of modifying cations at low temperatures. in 5th Metallurgical & Materials Engineering Congress of South-East Europe. 2023;:231-236..

Nikolić, Jelena, Topalović, Vladimir, Đošić, Marija, Savić, Veljko, Obradović, Milena, Matijašević, Srđan, Grujić, Snežana, "Dissolution  of polyphosphate glass: Impact of pH on diffusion coefficients of modifying cations at low temperatures" in 5th Metallurgical & Materials Engineering Congress of South-East Europe (2023):231-236.

TY  - JOUR
AU  - Topalović, Vladimir
AU  - Nikolić, Jelena
AU  - Matijašević, Srđan
AU  - Stojanović, Jovica
AU  - Karamanov, Alexander
AU  - Grujić, Snežana
AU  - Jevtić, Sanja
PY  - 2023
UR  - https://ritnms.itnms.ac.rs/handle/123456789/650
AB  - The goal of this research is to investigate the effect of SrO and La2O3 addition on the crystallization characteristics and sintering behavior of polyphosphate glasses. Differential scanning calorimetry (DSC), hot stage microscopy (HSM), X-ray diffraction (XRD), and scanning electron microscopy (SEM) methods were used to investigate the crystallization and sintering behaviors of glasses. The addition of SrO and La2O3 (1 or 5%), at the expense of phosphate mole fraction in polyphosphate bioactive glass, raises the characteristic temperature of glasses, and resistance to crystallization. Furthermore, the temperature of maximal shrinkage increases with the addition of SrO and La2O3. Surface crystallization is the dominant mechanism of crystallization in all samples. All glasses show complex crystallization leading to the formation of several crystalline phases. Sintered phosphate glass-ceramic containing bioactive beta-CaP2O6, alpha-Ca-3(PO4)(2,) and beta-Ca-3(PO4)(2) phases were successfully prepared.
PB  - Dordrecht : Springer
T2  - Journal of Thermal Analysis and Calorimetry
T1  - The effect of SrO and La2O3 addition on the crystallization characteristics and sintering behavior of distinct polyphosphate glasses
EP  - 732
EP  - 
IS  - 3
SP  - 721
VL  - 148
DO  - 10.1007/s10973-022-11777-8
UR  - conv_958
ER  - 

@article{
author = "Topalović, Vladimir and Nikolić, Jelena and Matijašević, Srđan and Stojanović, Jovica and Karamanov, Alexander and Grujić, Snežana and Jevtić, Sanja",
year = "2023",
abstract = "The goal of this research is to investigate the effect of SrO and La2O3 addition on the crystallization characteristics and sintering behavior of polyphosphate glasses. Differential scanning calorimetry (DSC), hot stage microscopy (HSM), X-ray diffraction (XRD), and scanning electron microscopy (SEM) methods were used to investigate the crystallization and sintering behaviors of glasses. The addition of SrO and La2O3 (1 or 5%), at the expense of phosphate mole fraction in polyphosphate bioactive glass, raises the characteristic temperature of glasses, and resistance to crystallization. Furthermore, the temperature of maximal shrinkage increases with the addition of SrO and La2O3. Surface crystallization is the dominant mechanism of crystallization in all samples. All glasses show complex crystallization leading to the formation of several crystalline phases. Sintered phosphate glass-ceramic containing bioactive beta-CaP2O6, alpha-Ca-3(PO4)(2,) and beta-Ca-3(PO4)(2) phases were successfully prepared.",
publisher = "Dordrecht : Springer",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "The effect of SrO and La2O3 addition on the crystallization characteristics and sintering behavior of distinct polyphosphate glasses",
pages = "732--721",
number = "3",
volume = "148",
doi = "10.1007/s10973-022-11777-8",
url = "conv_958"
}

Topalović, V., Nikolić, J., Matijašević, S., Stojanović, J., Karamanov, A., Grujić, S.,& Jevtić, S.. (2023). The effect of SrO and La2O3 addition on the crystallization characteristics and sintering behavior of distinct polyphosphate glasses. in Journal of Thermal Analysis and Calorimetry
Dordrecht : Springer., 148(3), 721-732.
https://doi.org/10.1007/s10973-022-11777-8
conv_958

Topalović V, Nikolić J, Matijašević S, Stojanović J, Karamanov A, Grujić S, Jevtić S. The effect of SrO and La2O3 addition on the crystallization characteristics and sintering behavior of distinct polyphosphate glasses. in Journal of Thermal Analysis and Calorimetry. 2023;148(3):721-732.
doi:10.1007/s10973-022-11777-8
conv_958 .

Topalović, Vladimir, Nikolić, Jelena, Matijašević, Srđan, Stojanović, Jovica, Karamanov, Alexander, Grujić, Snežana, Jevtić, Sanja, "The effect of SrO and La2O3 addition on the crystallization characteristics and sintering behavior of distinct polyphosphate glasses" in Journal of Thermal Analysis and Calorimetry, 148, no. 3 (2023):721-732,
https://doi.org/10.1007/s10973-022-11777-8 .,
conv_958 .

TY  - CONF
AU  - Nikolić, Jelena
AU  - Topalović, Vladimir
AU  - Matijašević, Srđan
AU  - Savić, Veljko
AU  - Đošić, Marija
AU  - Zildžović, Snežana
AU  - Grujić, Snežana
PY  - 2022
UR  - https://ritnms.itnms.ac.rs/handle/123456789/788
AB  - Fosfatna stakla imaju jedinstveno svojstvo da se mogu potpuno rastvoriti u vodenim rastvorima, a brzina rastvaranja može da se kontroliše. Proces rastvaranja stakla počinje razmenom katjona sa površine stakla sa protonima iz rastvora (H+ ili H3O+) i hidratacijom staklene mreže. Početna brzina rastvaranja je osnovna karakteristika rastvaranja stakla. Analiza početnih brzina rastvaranja fosfatnog stakla, koje je dobijeno topljenjem,  pokazuje da su brzine značajno veće u kiseloj sredini u odnosu na brzine rastvaranja u neutralnoj. Granulacija uzorka ima veći uticaj na početne brzine u neutralnoj sredini. Granulacija uzorka ne utiče na vrednost energije aktivacija početnih brzina rastvaranja u obe sredine. U neutralnoj sredini temperatura manje utiče na hidrolizu, a više na difuziju katjona, dok je u kiseloj sredini suprotno.
PB  - Belgrade : Serbian Chemical Society
C3  - 58. Savetovanje Srpskog hemijskog društva/ 58th Meeting of the Serbian Chemical Society
T1  - Ispitivanje uticaja pH i granulacije na početnu brzinu rastvaranja fosfatnog stakla/ Investigation of the influence of pH and granulation on the initial dissolution rate of phosphate glass
EP  - 119
SP  - 119
ER  - 

@conference{
author = "Nikolić, Jelena and Topalović, Vladimir and Matijašević, Srđan and Savić, Veljko and Đošić, Marija and Zildžović, Snežana and Grujić, Snežana",
year = "2022",
abstract = "Fosfatna stakla imaju jedinstveno svojstvo da se mogu potpuno rastvoriti u vodenim rastvorima, a brzina rastvaranja može da se kontroliše. Proces rastvaranja stakla počinje razmenom katjona sa površine stakla sa protonima iz rastvora (H+ ili H3O+) i hidratacijom staklene mreže. Početna brzina rastvaranja je osnovna karakteristika rastvaranja stakla. Analiza početnih brzina rastvaranja fosfatnog stakla, koje je dobijeno topljenjem,  pokazuje da su brzine značajno veće u kiseloj sredini u odnosu na brzine rastvaranja u neutralnoj. Granulacija uzorka ima veći uticaj na početne brzine u neutralnoj sredini. Granulacija uzorka ne utiče na vrednost energije aktivacija početnih brzina rastvaranja u obe sredine. U neutralnoj sredini temperatura manje utiče na hidrolizu, a više na difuziju katjona, dok je u kiseloj sredini suprotno.",
publisher = "Belgrade : Serbian Chemical Society",
journal = "58. Savetovanje Srpskog hemijskog društva/ 58th Meeting of the Serbian Chemical Society",
title = "Ispitivanje uticaja pH i granulacije na početnu brzinu rastvaranja fosfatnog stakla/ Investigation of the influence of pH and granulation on the initial dissolution rate of phosphate glass",
pages = "119-119"
}

Nikolić, J., Topalović, V., Matijašević, S., Savić, V., Đošić, M., Zildžović, S.,& Grujić, S.. (2022). Ispitivanje uticaja pH i granulacije na početnu brzinu rastvaranja fosfatnog stakla/ Investigation of the influence of pH and granulation on the initial dissolution rate of phosphate glass. in 58. Savetovanje Srpskog hemijskog društva/ 58th Meeting of the Serbian Chemical Society
Belgrade : Serbian Chemical Society., 119-119.

Nikolić J, Topalović V, Matijašević S, Savić V, Đošić M, Zildžović S, Grujić S. Ispitivanje uticaja pH i granulacije na početnu brzinu rastvaranja fosfatnog stakla/ Investigation of the influence of pH and granulation on the initial dissolution rate of phosphate glass. in 58. Savetovanje Srpskog hemijskog društva/ 58th Meeting of the Serbian Chemical Society. 2022;:119-119..

Nikolić, Jelena, Topalović, Vladimir, Matijašević, Srđan, Savić, Veljko, Đošić, Marija, Zildžović, Snežana, Grujić, Snežana, "Ispitivanje uticaja pH i granulacije na početnu brzinu rastvaranja fosfatnog stakla/ Investigation of the influence of pH and granulation on the initial dissolution rate of phosphate glass" in 58. Savetovanje Srpskog hemijskog društva/ 58th Meeting of the Serbian Chemical Society (2022):119-119.

TY  - CONF
AU  - Topalović, Vladimir
AU  - Savić, Veljko
AU  - Nikolić, Jelena
AU  - Matijašević, Srđan
AU  - Đošić, Marija
AU  - Zildžović, Snežana
AU  - Grujić, Snežana
PY  - 2022
UR  - https://ritnms.itnms.ac.rs/handle/123456789/787
AB  - Staklokeramički nosači koji oponašaju strukturu kostiju dobijeni su korišćenjem poliuretanske (PU) pene i polifosfatnog stakla u prahu. Osnovno staklo je pripremljeno standardnom tehnikom izlivanja rastopa i njegovog hlađenja na sobnoj temperaturi. Kocke pene su potapane u koloidni rastvor stakla, presovane i osušene. Poliuretanska pena obložena staklenim česticama je termički obrađena i staklo je sinterovano 3 h na 620 ⁰C. Mikrostruktura, morfologija i fazni sastav pripremljenih staklokeramičkih nosača ispitivani su metodama skenirajuće elektronske mikroskopije (SEM) i rendgenske difrakcije (XRD). Dobijeni su 3D porozni staklokeramički nosači koji sadrže bioaktivne kristalne faze β-Ca3(PO4)2 i β-Ca2P2O7. Struktura sinterovanih nosača je veoma porozna, a stubovi između pora su dobro sinterovani. Dobijeni fazni sastav i mikrostruktura nosača ukazuju na mogućnost njihove primene kao bioaktivnih materijala za inženjering koštanih tkiva.
PB  - Belgrade : Serbian Chemical Society
C3  - 58. Savetovanje Srpskog hemijskog društva/ 58th Meeting of the Serbian Chemical Society
T1  - Dobijanje poroznih 3D bioaktivnih staklokeramičkih nosača/Fabrication of porous 3D bioactive phosphate glass-ceramic scaffolds
EP  - 108
SP  - 108
ER  - 

@conference{
author = "Topalović, Vladimir and Savić, Veljko and Nikolić, Jelena and Matijašević, Srđan and Đošić, Marija and Zildžović, Snežana and Grujić, Snežana",
year = "2022",
abstract = "Staklokeramički nosači koji oponašaju strukturu kostiju dobijeni su korišćenjem poliuretanske (PU) pene i polifosfatnog stakla u prahu. Osnovno staklo je pripremljeno standardnom tehnikom izlivanja rastopa i njegovog hlađenja na sobnoj temperaturi. Kocke pene su potapane u koloidni rastvor stakla, presovane i osušene. Poliuretanska pena obložena staklenim česticama je termički obrađena i staklo je sinterovano 3 h na 620 ⁰C. Mikrostruktura, morfologija i fazni sastav pripremljenih staklokeramičkih nosača ispitivani su metodama skenirajuće elektronske mikroskopije (SEM) i rendgenske difrakcije (XRD). Dobijeni su 3D porozni staklokeramički nosači koji sadrže bioaktivne kristalne faze β-Ca3(PO4)2 i β-Ca2P2O7. Struktura sinterovanih nosača je veoma porozna, a stubovi između pora su dobro sinterovani. Dobijeni fazni sastav i mikrostruktura nosača ukazuju na mogućnost njihove primene kao bioaktivnih materijala za inženjering koštanih tkiva.",
publisher = "Belgrade : Serbian Chemical Society",
journal = "58. Savetovanje Srpskog hemijskog društva/ 58th Meeting of the Serbian Chemical Society",
title = "Dobijanje poroznih 3D bioaktivnih staklokeramičkih nosača/Fabrication of porous 3D bioactive phosphate glass-ceramic scaffolds",
pages = "108-108"
}

Topalović, V., Savić, V., Nikolić, J., Matijašević, S., Đošić, M., Zildžović, S.,& Grujić, S.. (2022). Dobijanje poroznih 3D bioaktivnih staklokeramičkih nosača/Fabrication of porous 3D bioactive phosphate glass-ceramic scaffolds. in 58. Savetovanje Srpskog hemijskog društva/ 58th Meeting of the Serbian Chemical Society
Belgrade : Serbian Chemical Society., 108-108.

Topalović V, Savić V, Nikolić J, Matijašević S, Đošić M, Zildžović S, Grujić S. Dobijanje poroznih 3D bioaktivnih staklokeramičkih nosača/Fabrication of porous 3D bioactive phosphate glass-ceramic scaffolds. in 58. Savetovanje Srpskog hemijskog društva/ 58th Meeting of the Serbian Chemical Society. 2022;:108-108..

Topalović, Vladimir, Savić, Veljko, Nikolić, Jelena, Matijašević, Srđan, Đošić, Marija, Zildžović, Snežana, Grujić, Snežana, "Dobijanje poroznih 3D bioaktivnih staklokeramičkih nosača/Fabrication of porous 3D bioactive phosphate glass-ceramic scaffolds" in 58. Savetovanje Srpskog hemijskog društva/ 58th Meeting of the Serbian Chemical Society (2022):108-108.

TY  - CONF
AU  - Labus, Nebojsa
AU  - Marković, Smilja
AU  - Nikolić, Maria Vesna
AU  - Rosić, Milena
AU  - Matijašević, Srđan
PY  - 2022
UR  - https://ritnms.itnms.ac.rs/handle/123456789/742
AB  - Sintering and phase transition are often superimposed at dimensional change diagram recorded during heating. Phase transition kinetic is thus hard to deconvolute due to the superposition of the sintering and phase transition dimensional change phenomena. 
Metastabile perovskite phase ZnTiO3 has transition to stabile spinel Zn2TiO4 which occurs at 945oC with high kinetic rate. Nano powder with 40 nm particle diameter was pressed uniaxially at 200 MPa pressure without binder to form compact that will be consequently sintered. Dimensional change during heating was monitored using dilatometric thermo-mechanical analyzer TMA model SETSYS Evolution. Lever`s rule was used to calculate amount of the emerging phase during phase transition.
The compacted specimens were treated on the non-isothermal schedule up to 1050oC.Sintering phenomenon of the ZnTiO3 nanopowder compact was also recorded up to 900oC with isothermal holding of 25 minutes where phase transition was avoided due to lower temperature and isothermal holding. Second run heating of the obtained sintered specimens were recorded with the heating schedule of non-isothermal heating up to 1050oC.
Kinetic of the phase transition was obtained from dilatograms recorded during sintering and from bulk on the second run heating. Furthermore, phase transition kinetics was obtained by subsequent data subtraction of the sintering curves without phase transition from the dilatation sintering curves containing phase transition.
In such a manner complex kinetics of phenomena such as sintering, linear expansion and phase transition recorded as dimensional change during heating brings the recognition of their mutual interconnected relations. Also application of these mathematical operations on dilatometric data leads to the established procedure for the sintering and phase transition data treatment.
PB  - Belgrade : Association for ETRAN Society
C3  - IX International Conference IcETRAN and LXVI ETRAN Conference
T1  - Sintering and Phase Transition of the ZnTiO3 Nano Powder Dilatometric Data Deconvolution
EP  - 471
SP  - 464
ER  - 

@conference{
author = "Labus, Nebojsa and Marković, Smilja and Nikolić, Maria Vesna and Rosić, Milena and Matijašević, Srđan",
year = "2022",
abstract = "Sintering and phase transition are often superimposed at dimensional change diagram recorded during heating. Phase transition kinetic is thus hard to deconvolute due to the superposition of the sintering and phase transition dimensional change phenomena. 
Metastabile perovskite phase ZnTiO3 has transition to stabile spinel Zn2TiO4 which occurs at 945oC with high kinetic rate. Nano powder with 40 nm particle diameter was pressed uniaxially at 200 MPa pressure without binder to form compact that will be consequently sintered. Dimensional change during heating was monitored using dilatometric thermo-mechanical analyzer TMA model SETSYS Evolution. Lever`s rule was used to calculate amount of the emerging phase during phase transition.
The compacted specimens were treated on the non-isothermal schedule up to 1050oC.Sintering phenomenon of the ZnTiO3 nanopowder compact was also recorded up to 900oC with isothermal holding of 25 minutes where phase transition was avoided due to lower temperature and isothermal holding. Second run heating of the obtained sintered specimens were recorded with the heating schedule of non-isothermal heating up to 1050oC.
Kinetic of the phase transition was obtained from dilatograms recorded during sintering and from bulk on the second run heating. Furthermore, phase transition kinetics was obtained by subsequent data subtraction of the sintering curves without phase transition from the dilatation sintering curves containing phase transition.
In such a manner complex kinetics of phenomena such as sintering, linear expansion and phase transition recorded as dimensional change during heating brings the recognition of their mutual interconnected relations. Also application of these mathematical operations on dilatometric data leads to the established procedure for the sintering and phase transition data treatment.",
publisher = "Belgrade : Association for ETRAN Society",
journal = "IX International Conference IcETRAN and LXVI ETRAN Conference",
title = "Sintering and Phase Transition of the ZnTiO3 Nano Powder Dilatometric Data Deconvolution",
pages = "471-464"
}

Labus, N., Marković, S., Nikolić, M. V., Rosić, M.,& Matijašević, S.. (2022). Sintering and Phase Transition of the ZnTiO3 Nano Powder Dilatometric Data Deconvolution. in IX International Conference IcETRAN and LXVI ETRAN Conference
Belgrade : Association for ETRAN Society., 464-471.

Labus N, Marković S, Nikolić MV, Rosić M, Matijašević S. Sintering and Phase Transition of the ZnTiO3 Nano Powder Dilatometric Data Deconvolution. in IX International Conference IcETRAN and LXVI ETRAN Conference. 2022;:464-471..

Labus, Nebojsa, Marković, Smilja, Nikolić, Maria Vesna, Rosić, Milena, Matijašević, Srđan, "Sintering and Phase Transition of the ZnTiO3 Nano Powder Dilatometric Data Deconvolution" in IX International Conference IcETRAN and LXVI ETRAN Conference (2022):464-471.

TY  - JOUR
AU  - Matijašević, Srđan
AU  - Grujić, Snežana R.
AU  - Nikolić, Jelena
AU  - Topalović, Vladimir
AU  - Savić, Veljko
AU  - Zildžović, Snežana
AU  - Labus, Nebojša
PY  - 2022
UR  - https://ritnms.itnms.ac.rs/handle/123456789/619
AB  - The nucleation process of lithium germanium-phosphate glass was studied to determine the temperature range of nucleation and the temperature of the maximum nucleation rate. The differential thermal analysis (DTA), and scanning electron microscope (SEM) were used to reveal the nonisothermal and isothermal process of nucleation, respectively. The crystallization process occurred at a high homogeneous nucleation rate and the spherulitic crystal growth morphology. Nanostructured samples were obtained.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - The Analysis of the Nucleation Process of the Lithium Germanium Phosphate Glass
EP  - 334
IS  - 3
SP  - 321
VL  - 54
DO  - 10.2298/SOS2203321M
UR  - conv_960
UR  - https://hdl.handle.net/21.15107/rcub_dais_13580
ER  - 

@article{
author = "Matijašević, Srđan and Grujić, Snežana R. and Nikolić, Jelena and Topalović, Vladimir and Savić, Veljko and Zildžović, Snežana and Labus, Nebojša",
year = "2022",
abstract = "The nucleation process of lithium germanium-phosphate glass was studied to determine the temperature range of nucleation and the temperature of the maximum nucleation rate. The differential thermal analysis (DTA), and scanning electron microscope (SEM) were used to reveal the nonisothermal and isothermal process of nucleation, respectively. The crystallization process occurred at a high homogeneous nucleation rate and the spherulitic crystal growth morphology. Nanostructured samples were obtained.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "The Analysis of the Nucleation Process of the Lithium Germanium Phosphate Glass",
pages = "334-321",
number = "3",
volume = "54",
doi = "10.2298/SOS2203321M",
url = "conv_960, https://hdl.handle.net/21.15107/rcub_dais_13580"
}

Matijašević, S., Grujić, S. R., Nikolić, J., Topalović, V., Savić, V., Zildžović, S.,& Labus, N.. (2022). The Analysis of the Nucleation Process of the Lithium Germanium Phosphate Glass. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 54(3), 321-334.
https://doi.org/10.2298/SOS2203321M
conv_960

Matijašević S, Grujić SR, Nikolić J, Topalović V, Savić V, Zildžović S, Labus N. The Analysis of the Nucleation Process of the Lithium Germanium Phosphate Glass. in Science of Sintering. 2022;54(3):321-334.
doi:10.2298/SOS2203321M
conv_960 .

Matijašević, Srđan, Grujić, Snežana R., Nikolić, Jelena, Topalović, Vladimir, Savić, Veljko, Zildžović, Snežana, Labus, Nebojša, "The Analysis of the Nucleation Process of the Lithium Germanium Phosphate Glass" in Science of Sintering, 54, no. 3 (2022):321-334,
https://doi.org/10.2298/SOS2203321M .,
conv_960 .

TY  - JOUR
AU  - Savić, Veljko
AU  - Topalović, Vladimir
AU  - Matijašević, Srđan
AU  - Nikolić, Jelena
AU  - Grujić, Snežana
AU  - Zildžović, Snežana
AU  - Radulović, Aleksandra
PY  - 2021
UR  - https://ritnms.itnms.ac.rs/handle/123456789/597
AB  - In this study, the glass-composite was prepared using glass cullet and waste foundry sand as raw materials. The powder technology route was employed. The mixtures containing 10-50 wt% of the sand were sintered at T = 750 degrees C for t =1h. XRD and DTA analyses were performed. The chemical durability of the resulting glass-composite was determined by leaching test in HCl, H2SO4, NaOH and distilled water at T = 95 degrees C for t =1h. It was shown that the sintering process carried out without the crystallization of the glass matrix. The lowest chemical durability was determined in alkali solution of glasscomposite.
PB  - Savez inženjera metalurgije Srbije, Beograd
T2  - Metallurgical & Materials Engineering
T1  - Chemical durability of sintered glass-composite prepared from glass cullet and waste foundry sand
EP  - 113
IS  - 1
SP  - 105
VL  - 27
DO  - 10.30544/477
UR  - conv_906
ER  - 

@article{
author = "Savić, Veljko and Topalović, Vladimir and Matijašević, Srđan and Nikolić, Jelena and Grujić, Snežana and Zildžović, Snežana and Radulović, Aleksandra",
year = "2021",
abstract = "In this study, the glass-composite was prepared using glass cullet and waste foundry sand as raw materials. The powder technology route was employed. The mixtures containing 10-50 wt% of the sand were sintered at T = 750 degrees C for t =1h. XRD and DTA analyses were performed. The chemical durability of the resulting glass-composite was determined by leaching test in HCl, H2SO4, NaOH and distilled water at T = 95 degrees C for t =1h. It was shown that the sintering process carried out without the crystallization of the glass matrix. The lowest chemical durability was determined in alkali solution of glasscomposite.",
publisher = "Savez inženjera metalurgije Srbije, Beograd",
journal = "Metallurgical & Materials Engineering",
title = "Chemical durability of sintered glass-composite prepared from glass cullet and waste foundry sand",
pages = "113-105",
number = "1",
volume = "27",
doi = "10.30544/477",
url = "conv_906"
}

Savić, V., Topalović, V., Matijašević, S., Nikolić, J., Grujić, S., Zildžović, S.,& Radulović, A.. (2021). Chemical durability of sintered glass-composite prepared from glass cullet and waste foundry sand. in Metallurgical & Materials Engineering
Savez inženjera metalurgije Srbije, Beograd., 27(1), 105-113.
https://doi.org/10.30544/477
conv_906

Savić V, Topalović V, Matijašević S, Nikolić J, Grujić S, Zildžović S, Radulović A. Chemical durability of sintered glass-composite prepared from glass cullet and waste foundry sand. in Metallurgical & Materials Engineering. 2021;27(1):105-113.
doi:10.30544/477
conv_906 .

Savić, Veljko, Topalović, Vladimir, Matijašević, Srđan, Nikolić, Jelena, Grujić, Snežana, Zildžović, Snežana, Radulović, Aleksandra, "Chemical durability of sintered glass-composite prepared from glass cullet and waste foundry sand" in Metallurgical & Materials Engineering, 27, no. 1 (2021):105-113,
https://doi.org/10.30544/477 .,
conv_906 .

TY  - JOUR
AU  - Smiljanić, Sonja
AU  - Grujić, Snežana R.
AU  - Matijašević, Srđan
AU  - Stojanović, Jovica
AU  - Nikolić, Jelena
AU  - Savić, Veljko
AU  - Popović, Daniela Z.
PY  - 2021
UR  - https://ritnms.itnms.ac.rs/handle/123456789/588
AB  - The crystal growth rate of La(2)SrB(10)O(19)in an undercooled melt of stoichiometric composition was studied. The crystallization of the bulk samples was performed in a single-stage regime under isothermal conditions at the selected temperatures for the different time periods. The surface crystallization was observed and in all crystallized samples, the La(2)SrB(10)O(19)crystalline phase was identified. Based on the dependence of the crystalline layer thickness on treatment time at selected temperature, crystal growth rate was obtained. The crystal growth rates were from 1.65 x 10(-8)to 2.77 x 10(-7)m s(-1)in the temperature interval (700-780 degrees C). The experimental values were compared to the calculated values using theoretical model of the crystal growth. The experimental growth rate followed the same trend as the calculated growth rate, but the experimental values were higher than the calculated.
PB  - Springer, Dordrecht
T2  - Journal of Thermal Analysis and Calorimetry
T1  - Crystal growth of La(2)SrB(10)O(19)from undercooled melt
EP  - 1576
IS  - 4
SP  - 1569
VL  - 146
DO  - 10.1007/s10973-020-10122-1
UR  - conv_886
ER  - 

@article{
author = "Smiljanić, Sonja and Grujić, Snežana R. and Matijašević, Srđan and Stojanović, Jovica and Nikolić, Jelena and Savić, Veljko and Popović, Daniela Z.",
year = "2021",
abstract = "The crystal growth rate of La(2)SrB(10)O(19)in an undercooled melt of stoichiometric composition was studied. The crystallization of the bulk samples was performed in a single-stage regime under isothermal conditions at the selected temperatures for the different time periods. The surface crystallization was observed and in all crystallized samples, the La(2)SrB(10)O(19)crystalline phase was identified. Based on the dependence of the crystalline layer thickness on treatment time at selected temperature, crystal growth rate was obtained. The crystal growth rates were from 1.65 x 10(-8)to 2.77 x 10(-7)m s(-1)in the temperature interval (700-780 degrees C). The experimental values were compared to the calculated values using theoretical model of the crystal growth. The experimental growth rate followed the same trend as the calculated growth rate, but the experimental values were higher than the calculated.",
publisher = "Springer, Dordrecht",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "Crystal growth of La(2)SrB(10)O(19)from undercooled melt",
pages = "1576-1569",
number = "4",
volume = "146",
doi = "10.1007/s10973-020-10122-1",
url = "conv_886"
}

Smiljanić, S., Grujić, S. R., Matijašević, S., Stojanović, J., Nikolić, J., Savić, V.,& Popović, D. Z.. (2021). Crystal growth of La(2)SrB(10)O(19)from undercooled melt. in Journal of Thermal Analysis and Calorimetry
Springer, Dordrecht., 146(4), 1569-1576.
https://doi.org/10.1007/s10973-020-10122-1
conv_886

Smiljanić S, Grujić SR, Matijašević S, Stojanović J, Nikolić J, Savić V, Popović DZ. Crystal growth of La(2)SrB(10)O(19)from undercooled melt. in Journal of Thermal Analysis and Calorimetry. 2021;146(4):1569-1576.
doi:10.1007/s10973-020-10122-1
conv_886 .

Smiljanić, Sonja, Grujić, Snežana R., Matijašević, Srđan, Stojanović, Jovica, Nikolić, Jelena, Savić, Veljko, Popović, Daniela Z., "Crystal growth of La(2)SrB(10)O(19)from undercooled melt" in Journal of Thermal Analysis and Calorimetry, 146, no. 4 (2021):1569-1576,
https://doi.org/10.1007/s10973-020-10122-1 .,
conv_886 .

TY  - JOUR
AU  - Matijašević, Srđan
AU  - Topalović, Vladimir
AU  - Grujić, Snežana R.
AU  - Savić, Veljko
AU  - Nikolić, Jelena
AU  - Labus, Nebojša
AU  - Zildžović, Snežana
PY  - 2021
UR  - https://ritnms.itnms.ac.rs/handle/123456789/576
AB  - The selected lithium germanium-phosphate glass was prepared by a conventional melt-quenching technique. The XRD method was employed to confirm the glass was obtained and to reveal crystalline phases during heat treatment. The dilatometry (DIL), differential thermal analysis (DTA), and differential scanning calorimetry (DSC) were used to determine the characteristic temperatures and enthalpies of crystallization and melting of the crystalline phase. The DTA and DIL were used to obtain the viscosity curves by applying the VogelFulcher-Tammann (VFT) equation.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - The Thermophysical Properties of Primary Phase in Lithium Germanium Phosphate Glass
EP  - 310
IS  - 3
SP  - 301
VL  - 53
DO  - 10.2298/SOS2103301M
UR  - conv_926
ER  - 

@article{
author = "Matijašević, Srđan and Topalović, Vladimir and Grujić, Snežana R. and Savić, Veljko and Nikolić, Jelena and Labus, Nebojša and Zildžović, Snežana",
year = "2021",
abstract = "The selected lithium germanium-phosphate glass was prepared by a conventional melt-quenching technique. The XRD method was employed to confirm the glass was obtained and to reveal crystalline phases during heat treatment. The dilatometry (DIL), differential thermal analysis (DTA), and differential scanning calorimetry (DSC) were used to determine the characteristic temperatures and enthalpies of crystallization and melting of the crystalline phase. The DTA and DIL were used to obtain the viscosity curves by applying the VogelFulcher-Tammann (VFT) equation.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "The Thermophysical Properties of Primary Phase in Lithium Germanium Phosphate Glass",
pages = "310-301",
number = "3",
volume = "53",
doi = "10.2298/SOS2103301M",
url = "conv_926"
}

Matijašević, S., Topalović, V., Grujić, S. R., Savić, V., Nikolić, J., Labus, N.,& Zildžović, S.. (2021). The Thermophysical Properties of Primary Phase in Lithium Germanium Phosphate Glass. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 53(3), 301-310.
https://doi.org/10.2298/SOS2103301M
conv_926

Matijašević S, Topalović V, Grujić SR, Savić V, Nikolić J, Labus N, Zildžović S. The Thermophysical Properties of Primary Phase in Lithium Germanium Phosphate Glass. in Science of Sintering. 2021;53(3):301-310.
doi:10.2298/SOS2103301M
conv_926 .

Matijašević, Srđan, Topalović, Vladimir, Grujić, Snežana R., Savić, Veljko, Nikolić, Jelena, Labus, Nebojša, Zildžović, Snežana, "The Thermophysical Properties of Primary Phase in Lithium Germanium Phosphate Glass" in Science of Sintering, 53, no. 3 (2021):301-310,
https://doi.org/10.2298/SOS2103301M .,
conv_926 .

TY  - JOUR
AU  - Karamanov, Alexander
AU  - Smiljanić, Sonja
AU  - Karamanova, Emilia
AU  - Matijašević, Srđan
AU  - Nikolić, Jelena
AU  - Savić, Veljko
AU  - Grujić, Snežana
PY  - 2020
UR  - https://ritnms.itnms.ac.rs/handle/123456789/528
AB  - Sintering, crystallization and foaming of nano glass powders with composition La2O3 center dot SrO center dot 5B(2)O(3) were studied by hot stage microscopy (HSM) and simultaneous thermal analysis (DTA-TG) under non-isothermal regime at 10 degrees C/min and by optical contactless dilatometer under isothermal conditions at 700 degrees C up to 10 hours for different times. After the thermal treatments, specimens were characterized by gas pycnometry, X-ray Powder Diffraction (XRD) and Field Emission Scanning Electron Microscopes (FE-SEM). The results demonstrate that the densification completed before the crystallization process, thus forming well sintered samples. Then, during the phase formation gas is released, which leads to foaming process. After holding of 160 minutes at 700 degrees C the degree of crystallization reached about 0.8 and the foaming stopped. The obtained sample had high closed porosity and quite intriguing structure composed of two fairly different crystal arrangements. The first was "sponge-like", while the second was denser and consisted of "sheets", 10-30 nm thick. The subsequent holding led to re-crystallization, formation of larger denser zones that reached even 10-15 mu m and an increase in open porosity. These results highlight that in the case of sinter crystallization of nano powders, some intriguing features can be expected.
PB  - Elsevier, Amsterdam
T2  - Journal of Non-Crystalline Solids
T1  - Sintering, crystallization and foaming of La2O3 center dot SrO center dot 5B(2)O(3) glass powders: effect of the holding time
VL  - 544
DO  - 10.1016/j.jnoncrysol.2020.120168
UR  - conv_885
ER  - 

@article{
author = "Karamanov, Alexander and Smiljanić, Sonja and Karamanova, Emilia and Matijašević, Srđan and Nikolić, Jelena and Savić, Veljko and Grujić, Snežana",
year = "2020",
abstract = "Sintering, crystallization and foaming of nano glass powders with composition La2O3 center dot SrO center dot 5B(2)O(3) were studied by hot stage microscopy (HSM) and simultaneous thermal analysis (DTA-TG) under non-isothermal regime at 10 degrees C/min and by optical contactless dilatometer under isothermal conditions at 700 degrees C up to 10 hours for different times. After the thermal treatments, specimens were characterized by gas pycnometry, X-ray Powder Diffraction (XRD) and Field Emission Scanning Electron Microscopes (FE-SEM). The results demonstrate that the densification completed before the crystallization process, thus forming well sintered samples. Then, during the phase formation gas is released, which leads to foaming process. After holding of 160 minutes at 700 degrees C the degree of crystallization reached about 0.8 and the foaming stopped. The obtained sample had high closed porosity and quite intriguing structure composed of two fairly different crystal arrangements. The first was "sponge-like", while the second was denser and consisted of "sheets", 10-30 nm thick. The subsequent holding led to re-crystallization, formation of larger denser zones that reached even 10-15 mu m and an increase in open porosity. These results highlight that in the case of sinter crystallization of nano powders, some intriguing features can be expected.",
publisher = "Elsevier, Amsterdam",
journal = "Journal of Non-Crystalline Solids",
title = "Sintering, crystallization and foaming of La2O3 center dot SrO center dot 5B(2)O(3) glass powders: effect of the holding time",
volume = "544",
doi = "10.1016/j.jnoncrysol.2020.120168",
url = "conv_885"
}

Karamanov, A., Smiljanić, S., Karamanova, E., Matijašević, S., Nikolić, J., Savić, V.,& Grujić, S.. (2020). Sintering, crystallization and foaming of La2O3 center dot SrO center dot 5B(2)O(3) glass powders: effect of the holding time. in Journal of Non-Crystalline Solids
Elsevier, Amsterdam., 544.
https://doi.org/10.1016/j.jnoncrysol.2020.120168
conv_885

Karamanov A, Smiljanić S, Karamanova E, Matijašević S, Nikolić J, Savić V, Grujić S. Sintering, crystallization and foaming of La2O3 center dot SrO center dot 5B(2)O(3) glass powders: effect of the holding time. in Journal of Non-Crystalline Solids. 2020;544.
doi:10.1016/j.jnoncrysol.2020.120168
conv_885 .

Karamanov, Alexander, Smiljanić, Sonja, Karamanova, Emilia, Matijašević, Srđan, Nikolić, Jelena, Savić, Veljko, Grujić, Snežana, "Sintering, crystallization and foaming of La2O3 center dot SrO center dot 5B(2)O(3) glass powders: effect of the holding time" in Journal of Non-Crystalline Solids, 544 (2020),
https://doi.org/10.1016/j.jnoncrysol.2020.120168 .,
conv_885 .

TY  - JOUR
AU  - Stojanović, Jovica
AU  - Smiljanić, Sonja
AU  - Grujić, Snežana R.
AU  - Vulić, Predrag J.
AU  - Matijašević, Srđan
AU  - Nikolić, Jelena
AU  - Savić, Veljko
PY  - 2019
UR  - https://ritnms.itnms.ac.rs/handle/123456789/513
AB  - The crystal structure of new lanthanum strontium borate glass-ceramics was refined by the Rietveld method. The results showed that La2SrB10O19 has the monoclinic crystal structure, space group C2 (No. 5) with a = 11.1170(6), b = 6.5667(3), c = 9.2363(3) angstrom,beta = 91.481 degrees, V = 674.04(7) angstrom(3), two formula units per unit-cell, and density 3.830 g cm(-3). The main building units of the crystal structure are BO4 tetrahedra and BO3 triangles. Clusters composed of [B5O12] form an infinite double layer running perpendicular to the c-axis. Lanthanum atoms, situated in [B5O12](n) layers, are coordinated with 10 oxygen atom in a form of LaO10 polyhedra, while Sr atoms, located between [B5O12](n) layers, are coordinated with 8 oxygen atoms in a form of SrO8 polyhedra. Microstructural measurements contain both crystallite domain sizes and microstrain calculations obtained by the Warren Averbach and the simplified integral-breadth methods.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - Structure and Microstructure Characterization of the La2SrB10O19 Glass-ceramics
EP  - 399
IS  - 4
SP  - 389
VL  - 51
DO  - 10.2298/SOS1904389S
UR  - conv_873
ER  - 

@article{
author = "Stojanović, Jovica and Smiljanić, Sonja and Grujić, Snežana R. and Vulić, Predrag J. and Matijašević, Srđan and Nikolić, Jelena and Savić, Veljko",
year = "2019",
abstract = "The crystal structure of new lanthanum strontium borate glass-ceramics was refined by the Rietveld method. The results showed that La2SrB10O19 has the monoclinic crystal structure, space group C2 (No. 5) with a = 11.1170(6), b = 6.5667(3), c = 9.2363(3) angstrom,beta = 91.481 degrees, V = 674.04(7) angstrom(3), two formula units per unit-cell, and density 3.830 g cm(-3). The main building units of the crystal structure are BO4 tetrahedra and BO3 triangles. Clusters composed of [B5O12] form an infinite double layer running perpendicular to the c-axis. Lanthanum atoms, situated in [B5O12](n) layers, are coordinated with 10 oxygen atom in a form of LaO10 polyhedra, while Sr atoms, located between [B5O12](n) layers, are coordinated with 8 oxygen atoms in a form of SrO8 polyhedra. Microstructural measurements contain both crystallite domain sizes and microstrain calculations obtained by the Warren Averbach and the simplified integral-breadth methods.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "Structure and Microstructure Characterization of the La2SrB10O19 Glass-ceramics",
pages = "399-389",
number = "4",
volume = "51",
doi = "10.2298/SOS1904389S",
url = "conv_873"
}

Stojanović, J., Smiljanić, S., Grujić, S. R., Vulić, P. J., Matijašević, S., Nikolić, J.,& Savić, V.. (2019). Structure and Microstructure Characterization of the La2SrB10O19 Glass-ceramics. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 51(4), 389-399.
https://doi.org/10.2298/SOS1904389S
conv_873

Stojanović J, Smiljanić S, Grujić SR, Vulić PJ, Matijašević S, Nikolić J, Savić V. Structure and Microstructure Characterization of the La2SrB10O19 Glass-ceramics. in Science of Sintering. 2019;51(4):389-399.
doi:10.2298/SOS1904389S
conv_873 .

Stojanović, Jovica, Smiljanić, Sonja, Grujić, Snežana R., Vulić, Predrag J., Matijašević, Srđan, Nikolić, Jelena, Savić, Veljko, "Structure and Microstructure Characterization of the La2SrB10O19 Glass-ceramics" in Science of Sintering, 51, no. 4 (2019):389-399,
https://doi.org/10.2298/SOS1904389S .,
conv_873 .

TY  - JOUR
AU  - Vujošević, Ana
AU  - Matijašević, Srđan
AU  - Smiljanić, Sonja
AU  - Nikolić, Jelena
AU  - Zečević, Bogoljub
AU  - Topalović, Vladimir
AU  - Savić, Veljko
PY  - 2019
UR  - https://ritnms.itnms.ac.rs/handle/123456789/495
AB  - Polifosfatno staklo, u kome je molski odnos (M2O + MO)/P2O5 >1, koje sadrži i mikroelemente Zn2+, Mn2+, Fe3+ i Cu2+, korišćeno je u supstratu za proizvodnju rasada cveća i povrća. Eksperimenti su izvedeni u stakleniku na Poljoprivrednom fakultetu u Beogradu i u laboratorijama ITNMS. Ispitivano je ponašanje polifosfatnog stakla prilikom rastvaranja u dejonizovanoj vodi i 2% rastvoru limunske kiseline na temperaturama od 20, 30, 37 i 50 °C. Ispitan je uticaj vremena rastvaranja na normalizovani gubitak mase (fm) i normalizovane koncentracije jona (fi). Određene su i konstante brzina rastvaranja(kw-dejonizovana voda, kc -2% rastvor limunske kiseline). Vrednosti kc su veće od vrednosti za kw, što potvrđuje uticaj rastvarača i temperature na proces rastvaranja. Rezultati su pokazali pozitivan efekat polifosfatnog stakla na rast i kvalitet ispitivanih biljaka. Primenjena doza polifosfatnog stakla od 1 gl-1 pokazala je najbolji efekat na rast ispitivanih biljaka-rasada.
AB  - Due to the dissolution properties the phosphate glasses can be promising materials for the development of new ecologically safe fertilizers. The complex polyphosphate glass with a molar ratio (M2O + MO)/P2O5 >1 and addition of microelements Zn2+, Mn2+, Fe3+ and Cu2+ were used in substrate for production of flower and vegetables seedlings. Dissolution tests were conducted in deionized water and 2% citric acid. The effects of the reaction time on the normalized glass mass loss (fm) and the normalized concentrations of the ions (fi) at 20, 30, 37 and 50°C were determined. Dissolution rate constants (kw - deionized water, kc -2% citric acid) were also determined (kw-0.0028-0.0094 gm-2, kc-0.029-0.011 gm-2). Values of kc were higher than those of kw, which confirms a significant effect of solvent type and temperature on the dissolution kinetics of glass. The experiments with plants (one vegetable and one flower) showed that the addition of phosphate glass caused an increase in yield and quality of plants. The applied dose of polyphosphate glass of 1gl-1 showed the best effect on the growth of the examined plant seedlings.
PB  - Inženjersko društvo za koroziju, Beograd
T2  - Zaštita materijala
T1  - Efekat primene polifosfatnog stakla u supstratima za gajenje cveća i povrća
T1  - Polyphosphate glass as fertilizer for plant seedlings
EP  - 104
IS  - 1
SP  - 96
VL  - 60
DO  - 10.5937/zasmat1901096V
UR  - conv_159
ER  - 

@article{
author = "Vujošević, Ana and Matijašević, Srđan and Smiljanić, Sonja and Nikolić, Jelena and Zečević, Bogoljub and Topalović, Vladimir and Savić, Veljko",
year = "2019",
abstract = "Polifosfatno staklo, u kome je molski odnos (M2O + MO)/P2O5 >1, koje sadrži i mikroelemente Zn2+, Mn2+, Fe3+ i Cu2+, korišćeno je u supstratu za proizvodnju rasada cveća i povrća. Eksperimenti su izvedeni u stakleniku na Poljoprivrednom fakultetu u Beogradu i u laboratorijama ITNMS. Ispitivano je ponašanje polifosfatnog stakla prilikom rastvaranja u dejonizovanoj vodi i 2% rastvoru limunske kiseline na temperaturama od 20, 30, 37 i 50 °C. Ispitan je uticaj vremena rastvaranja na normalizovani gubitak mase (fm) i normalizovane koncentracije jona (fi). Određene su i konstante brzina rastvaranja(kw-dejonizovana voda, kc -2% rastvor limunske kiseline). Vrednosti kc su veće od vrednosti za kw, što potvrđuje uticaj rastvarača i temperature na proces rastvaranja. Rezultati su pokazali pozitivan efekat polifosfatnog stakla na rast i kvalitet ispitivanih biljaka. Primenjena doza polifosfatnog stakla od 1 gl-1 pokazala je najbolji efekat na rast ispitivanih biljaka-rasada., Due to the dissolution properties the phosphate glasses can be promising materials for the development of new ecologically safe fertilizers. The complex polyphosphate glass with a molar ratio (M2O + MO)/P2O5 >1 and addition of microelements Zn2+, Mn2+, Fe3+ and Cu2+ were used in substrate for production of flower and vegetables seedlings. Dissolution tests were conducted in deionized water and 2% citric acid. The effects of the reaction time on the normalized glass mass loss (fm) and the normalized concentrations of the ions (fi) at 20, 30, 37 and 50°C were determined. Dissolution rate constants (kw - deionized water, kc -2% citric acid) were also determined (kw-0.0028-0.0094 gm-2, kc-0.029-0.011 gm-2). Values of kc were higher than those of kw, which confirms a significant effect of solvent type and temperature on the dissolution kinetics of glass. The experiments with plants (one vegetable and one flower) showed that the addition of phosphate glass caused an increase in yield and quality of plants. The applied dose of polyphosphate glass of 1gl-1 showed the best effect on the growth of the examined plant seedlings.",
publisher = "Inženjersko društvo za koroziju, Beograd",
journal = "Zaštita materijala",
title = "Efekat primene polifosfatnog stakla u supstratima za gajenje cveća i povrća, Polyphosphate glass as fertilizer for plant seedlings",
pages = "104-96",
number = "1",
volume = "60",
doi = "10.5937/zasmat1901096V",
url = "conv_159"
}

Vujošević, A., Matijašević, S., Smiljanić, S., Nikolić, J., Zečević, B., Topalović, V.,& Savić, V.. (2019). Efekat primene polifosfatnog stakla u supstratima za gajenje cveća i povrća. in Zaštita materijala
Inženjersko društvo za koroziju, Beograd., 60(1), 96-104.
https://doi.org/10.5937/zasmat1901096V
conv_159

Vujošević A, Matijašević S, Smiljanić S, Nikolić J, Zečević B, Topalović V, Savić V. Efekat primene polifosfatnog stakla u supstratima za gajenje cveća i povrća. in Zaštita materijala. 2019;60(1):96-104.
doi:10.5937/zasmat1901096V
conv_159 .

Vujošević, Ana, Matijašević, Srđan, Smiljanić, Sonja, Nikolić, Jelena, Zečević, Bogoljub, Topalović, Vladimir, Savić, Veljko, "Efekat primene polifosfatnog stakla u supstratima za gajenje cveća i povrća" in Zaštita materijala, 60, no. 1 (2019):96-104,
https://doi.org/10.5937/zasmat1901096V .,
conv_159 .

TY  - CONF
AU  - Topalović, Vladimir
AU  - Matijašević, Srđan
AU  - Nikolić, Jelena
AU  - Đošić, Marija
AU  - Savić, Veljko
AU  - Smiljanić, Sonja
AU  - Grujić, Snežana
PY  - 2019
UR  - https://ritnms.itnms.ac.rs/handle/123456789/791
AB  - Because their potential biomedical application, different types of phosphate based glasses were studied and evaluated for drug delivery applications and bone tissue engineering. The addition of lanthanum to modified apatite was found to improve its biocompatibility and lower the cytotoxicity against osteoblast. In this paper, glass-ceramic with the composition 42P2O5·40CaO·5La2O3·10Na2O·3TiO2 (mol %) was obtained by standard melt-quenching method. The raw materials used for glass synthesis were reagent grade (NH4)2HPO4, Na2CO3, CaCO3, La2CO3 and TiO2. Powder X-ray diffraction analysis confirmed the quenched melt to be vitreous. To examine the glass crystallization non-isothermal crystallization was studied using DTA. Samples were crystalized at the appropriate temperature according to the DTA analysis. The XRD technique was used to identify the phase composition of the crystallized bulk glass samples. XRD analysis of the powdered sample showed that during sintering the glass particles crystallized and the crystalline phases determined were: α-Ca2P2O7, β-Ca2P2O7, Ca10Na(PO4)7, LaP5O14, β-NaTiOPO4, Ca2P2O7∙4H2O, Ca(PO3)2, β-Ca3(PO4)2, Ca3(PO4)2, γ-Ca(PO3)2, NaCa(PO3)3. For α-Ca2P2O7, β-Ca3(PO4)2 and β-Ca2P2O7, the bioactivity, i.e. the ability to promote the formation of apatite (HAP) layer after reaction with the surrounding body fluid has been reported. The obtained phase composition of the glass-ceramic indicated its possible application as a bioactive material for  bone tissue engineering.
PB  - Belgrade : Association of Metallurgical Engineers of Serbia
C3  - 4th Metallurgical & Materials Engineering Congress of South-East Europe MME SEE 2019
T1  - Characterization of lanthanum-doped phosphate glass
EP  - 34
SP  - 34
ER  - 

@conference{
author = "Topalović, Vladimir and Matijašević, Srđan and Nikolić, Jelena and Đošić, Marija and Savić, Veljko and Smiljanić, Sonja and Grujić, Snežana",
year = "2019",
abstract = "Because their potential biomedical application, different types of phosphate based glasses were studied and evaluated for drug delivery applications and bone tissue engineering. The addition of lanthanum to modified apatite was found to improve its biocompatibility and lower the cytotoxicity against osteoblast. In this paper, glass-ceramic with the composition 42P2O5·40CaO·5La2O3·10Na2O·3TiO2 (mol %) was obtained by standard melt-quenching method. The raw materials used for glass synthesis were reagent grade (NH4)2HPO4, Na2CO3, CaCO3, La2CO3 and TiO2. Powder X-ray diffraction analysis confirmed the quenched melt to be vitreous. To examine the glass crystallization non-isothermal crystallization was studied using DTA. Samples were crystalized at the appropriate temperature according to the DTA analysis. The XRD technique was used to identify the phase composition of the crystallized bulk glass samples. XRD analysis of the powdered sample showed that during sintering the glass particles crystallized and the crystalline phases determined were: α-Ca2P2O7, β-Ca2P2O7, Ca10Na(PO4)7, LaP5O14, β-NaTiOPO4, Ca2P2O7∙4H2O, Ca(PO3)2, β-Ca3(PO4)2, Ca3(PO4)2, γ-Ca(PO3)2, NaCa(PO3)3. For α-Ca2P2O7, β-Ca3(PO4)2 and β-Ca2P2O7, the bioactivity, i.e. the ability to promote the formation of apatite (HAP) layer after reaction with the surrounding body fluid has been reported. The obtained phase composition of the glass-ceramic indicated its possible application as a bioactive material for  bone tissue engineering.",
publisher = "Belgrade : Association of Metallurgical Engineers of Serbia",
journal = "4th Metallurgical & Materials Engineering Congress of South-East Europe MME SEE 2019",
title = "Characterization of lanthanum-doped phosphate glass",
pages = "34-34"
}

Topalović, V., Matijašević, S., Nikolić, J., Đošić, M., Savić, V., Smiljanić, S.,& Grujić, S.. (2019). Characterization of lanthanum-doped phosphate glass. in 4th Metallurgical & Materials Engineering Congress of South-East Europe MME SEE 2019
Belgrade : Association of Metallurgical Engineers of Serbia., 34-34.

Topalović V, Matijašević S, Nikolić J, Đošić M, Savić V, Smiljanić S, Grujić S. Characterization of lanthanum-doped phosphate glass. in 4th Metallurgical & Materials Engineering Congress of South-East Europe MME SEE 2019. 2019;:34-34..

Topalović, Vladimir, Matijašević, Srđan, Nikolić, Jelena, Đošić, Marija, Savić, Veljko, Smiljanić, Sonja, Grujić, Snežana, "Characterization of lanthanum-doped phosphate glass" in 4th Metallurgical & Materials Engineering Congress of South-East Europe MME SEE 2019 (2019):34-34.

TY  - CONF
AU  - Savić, Veljko
AU  - Matijašević, Srđan
AU  - Topalović, Vladimir
AU  - Smiljanić, Sonja
AU  - Nikolić, Jelena
AU  - Zildžović, Snežana
AU  - Grujić, Snežana
PY  - 2019
UR  - https://ritnms.itnms.ac.rs/handle/123456789/790
AB  - Copper mine tailings is one of the most used secondary raw materials. The most common use is in cement industry and as filler in road construction. The area of secondary raw materials utilization offering the greatest potential is in the development of glass-ceramic compositions, where the waste is melted to form a glass, fabricated using conventional glass forming techniques, and subsequently nucleated and devitrified in a controlled manner through heat treatment. The resultant, partially crystallized material offers improved strength, chemical and abrasion resistance. Copper mine tailings was mixed with 30% glass cullets and melted in electric furnace BLF 17/3 at T=1450 °C during t=0.5 h. The obtained glass sample was black, without visible residual gas bubbles. X-ray powder diffraction (XRD) analysis confirmed the quenched melt to be amorphous. DTA and HSM analysis was performed on the previously prepared glass powder. The glass powder samples were pressed in pellets and sintered in an electric furnace at the temperature of 1040 °C for 2h and a glass- ceramics was obtained. Applications for these glass-ceramic materials would include structural products, pipe or pipeliners to transport abrasive or corrosive fluids, alkali-resistant fibers to replace asbestos in concrete products, and use as a matrix material in which radioactive wastes could be chemically incorporated in a stable, nonleachable, solid form.
PB  - Belgrade : Association of Metallurgical Engineers of Serbia
C3  - 4th Metallurgical & Materials Engineering Congress of South-East Europe MME SEE 2019
T1  - Glass-ceramics obtained from copper mine tailings and glass cullets
EP  - 33
SP  - 33
ER  - 

@conference{
author = "Savić, Veljko and Matijašević, Srđan and Topalović, Vladimir and Smiljanić, Sonja and Nikolić, Jelena and Zildžović, Snežana and Grujić, Snežana",
year = "2019",
abstract = "Copper mine tailings is one of the most used secondary raw materials. The most common use is in cement industry and as filler in road construction. The area of secondary raw materials utilization offering the greatest potential is in the development of glass-ceramic compositions, where the waste is melted to form a glass, fabricated using conventional glass forming techniques, and subsequently nucleated and devitrified in a controlled manner through heat treatment. The resultant, partially crystallized material offers improved strength, chemical and abrasion resistance. Copper mine tailings was mixed with 30% glass cullets and melted in electric furnace BLF 17/3 at T=1450 °C during t=0.5 h. The obtained glass sample was black, without visible residual gas bubbles. X-ray powder diffraction (XRD) analysis confirmed the quenched melt to be amorphous. DTA and HSM analysis was performed on the previously prepared glass powder. The glass powder samples were pressed in pellets and sintered in an electric furnace at the temperature of 1040 °C for 2h and a glass- ceramics was obtained. Applications for these glass-ceramic materials would include structural products, pipe or pipeliners to transport abrasive or corrosive fluids, alkali-resistant fibers to replace asbestos in concrete products, and use as a matrix material in which radioactive wastes could be chemically incorporated in a stable, nonleachable, solid form.",
publisher = "Belgrade : Association of Metallurgical Engineers of Serbia",
journal = "4th Metallurgical & Materials Engineering Congress of South-East Europe MME SEE 2019",
title = "Glass-ceramics obtained from copper mine tailings and glass cullets",
pages = "33-33"
}

Savić, V., Matijašević, S., Topalović, V., Smiljanić, S., Nikolić, J., Zildžović, S.,& Grujić, S.. (2019). Glass-ceramics obtained from copper mine tailings and glass cullets. in 4th Metallurgical & Materials Engineering Congress of South-East Europe MME SEE 2019
Belgrade : Association of Metallurgical Engineers of Serbia., 33-33.

Savić V, Matijašević S, Topalović V, Smiljanić S, Nikolić J, Zildžović S, Grujić S. Glass-ceramics obtained from copper mine tailings and glass cullets. in 4th Metallurgical & Materials Engineering Congress of South-East Europe MME SEE 2019. 2019;:33-33..

Savić, Veljko, Matijašević, Srđan, Topalović, Vladimir, Smiljanić, Sonja, Nikolić, Jelena, Zildžović, Snežana, Grujić, Snežana, "Glass-ceramics obtained from copper mine tailings and glass cullets" in 4th Metallurgical & Materials Engineering Congress of South-East Europe MME SEE 2019 (2019):33-33.

TY  - JOUR
AU  - Smiljanić, Sonja
AU  - Karamanova, Emilia
AU  - Grujić, Snežana
AU  - Rogan, Jelena
AU  - Stojanović, Jovica
AU  - Matijašević, Srđan
AU  - Karamanov, Alexander
PY  - 2018
UR  - https://ritnms.itnms.ac.rs/handle/123456789/474
AB  - The peculiarities of sinter-crystallization of La2O3 center dot SrO center dot 5B(2)O(3) fine glass powder (below 1 mu m) are investigated and discussed. The sintering was studied by contactless optical dilatometry and porosity measurements. The crystallization process was evaluated by differential scanning calorimetry (DSC) and the crystalline phase formation was analyzed by X-ray diffraction (XRD). Finally the microstructures of the samples sintered at different temperatures were observed by field emission scanning electron microscope (FESEM). The specific aim of this study was to highlight the influence of sintering temperature and heating rate on the densification process and the final structure of glass-ceramic samples. It was shown that zero water adsorption and minimum closed porosity of similar to 3% were obtained at heating rate of 2 degrees C/min and at about 1 h holding at 690 degrees C. The temperature increase accelerated intense foaming process that resulted in formation of total porosity of 35-45%. It was also demonstrated that the foaming depended on the heating rate: the higher the heating rate - the more intensive was the bloating. The observed foaming process was related to intensive crystallization and re-crystallization of La2O3 center dot SrO center dot 5B(2)O(3) crystal phase. The phase formation processes entirely completed after 30-60 min at 730-740 degrees C with the formation of intriguing and unusual crystal structures.
PB  - Elsevier Science Bv, Amsterdam
T2  - Journal of Non-Crystalline Solids
T1  - Sintering, crystallization and foaming of La2O3 center dot SrO center dot 5B(2)O(3) glass powders - effect of the holding temperature and the heating rate
EP  - 382
SP  - 375
VL  - 481
DO  - 10.1016/j.jnoncrysol.2017.11.009
UR  - conv_816
ER  - 

@article{
author = "Smiljanić, Sonja and Karamanova, Emilia and Grujić, Snežana and Rogan, Jelena and Stojanović, Jovica and Matijašević, Srđan and Karamanov, Alexander",
year = "2018",
abstract = "The peculiarities of sinter-crystallization of La2O3 center dot SrO center dot 5B(2)O(3) fine glass powder (below 1 mu m) are investigated and discussed. The sintering was studied by contactless optical dilatometry and porosity measurements. The crystallization process was evaluated by differential scanning calorimetry (DSC) and the crystalline phase formation was analyzed by X-ray diffraction (XRD). Finally the microstructures of the samples sintered at different temperatures were observed by field emission scanning electron microscope (FESEM). The specific aim of this study was to highlight the influence of sintering temperature and heating rate on the densification process and the final structure of glass-ceramic samples. It was shown that zero water adsorption and minimum closed porosity of similar to 3% were obtained at heating rate of 2 degrees C/min and at about 1 h holding at 690 degrees C. The temperature increase accelerated intense foaming process that resulted in formation of total porosity of 35-45%. It was also demonstrated that the foaming depended on the heating rate: the higher the heating rate - the more intensive was the bloating. The observed foaming process was related to intensive crystallization and re-crystallization of La2O3 center dot SrO center dot 5B(2)O(3) crystal phase. The phase formation processes entirely completed after 30-60 min at 730-740 degrees C with the formation of intriguing and unusual crystal structures.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Journal of Non-Crystalline Solids",
title = "Sintering, crystallization and foaming of La2O3 center dot SrO center dot 5B(2)O(3) glass powders - effect of the holding temperature and the heating rate",
pages = "382-375",
volume = "481",
doi = "10.1016/j.jnoncrysol.2017.11.009",
url = "conv_816"
}

Smiljanić, S., Karamanova, E., Grujić, S., Rogan, J., Stojanović, J., Matijašević, S.,& Karamanov, A.. (2018). Sintering, crystallization and foaming of La2O3 center dot SrO center dot 5B(2)O(3) glass powders - effect of the holding temperature and the heating rate. in Journal of Non-Crystalline Solids
Elsevier Science Bv, Amsterdam., 481, 375-382.
https://doi.org/10.1016/j.jnoncrysol.2017.11.009
conv_816

Smiljanić S, Karamanova E, Grujić S, Rogan J, Stojanović J, Matijašević S, Karamanov A. Sintering, crystallization and foaming of La2O3 center dot SrO center dot 5B(2)O(3) glass powders - effect of the holding temperature and the heating rate. in Journal of Non-Crystalline Solids. 2018;481:375-382.
doi:10.1016/j.jnoncrysol.2017.11.009
conv_816 .

Smiljanić, Sonja, Karamanova, Emilia, Grujić, Snežana, Rogan, Jelena, Stojanović, Jovica, Matijašević, Srđan, Karamanov, Alexander, "Sintering, crystallization and foaming of La2O3 center dot SrO center dot 5B(2)O(3) glass powders - effect of the holding temperature and the heating rate" in Journal of Non-Crystalline Solids, 481 (2018):375-382,
https://doi.org/10.1016/j.jnoncrysol.2017.11.009 .,
conv_816 .

TY  - JOUR
AU  - Matijašević, Srđan
AU  - Grujić, Snežana R.
AU  - Topalović, Vladimir
AU  - Nikolić, Jelena
AU  - Smiljanić, Sonja
AU  - Labus, Nebojša
AU  - Savić, Veljko
PY  - 2018
UR  - https://ritnms.itnms.ac.rs/handle/123456789/472
AB  - Crystallization kinetics of 22.5Li(2)O center dot 10Al(2)O(3)center dot 30GeO(2)center dot 37.5P(2)O(5) (mol%) glass was studied under non-isothermal condition using the differential thermal analysis (DTA). The study was performed by using the first crystallization peak temperature (T-p1) which belongs to the precipitation of LiGe2(PO4)(3) phase in the glass. The activation energy of glass crystallization (E-a) was determined using different isokinetic methods. The dependence of E-a on the degree of glass-crystal transformation (alpha) was studied using model-free isoconversional linear integral KAS (Kissinger-Akahira-Sunose) and FWO (Flynn-Wall-Ozawa) methods. It was shown that the E-a varies with a and hence with temperature and consequently the glass/crystal transformation can be described as a complex process involving different mechanisms of nucleation and growth.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - Non-Isothermal Crystallization of Lithium Germanophosphate Glass Studied by Different Kinetic Methods
EP  - 203
IS  - 2
SP  - 193
VL  - 50
DO  - 10.2298/SOS1802193M
UR  - conv_837
ER  - 

@article{
author = "Matijašević, Srđan and Grujić, Snežana R. and Topalović, Vladimir and Nikolić, Jelena and Smiljanić, Sonja and Labus, Nebojša and Savić, Veljko",
year = "2018",
abstract = "Crystallization kinetics of 22.5Li(2)O center dot 10Al(2)O(3)center dot 30GeO(2)center dot 37.5P(2)O(5) (mol%) glass was studied under non-isothermal condition using the differential thermal analysis (DTA). The study was performed by using the first crystallization peak temperature (T-p1) which belongs to the precipitation of LiGe2(PO4)(3) phase in the glass. The activation energy of glass crystallization (E-a) was determined using different isokinetic methods. The dependence of E-a on the degree of glass-crystal transformation (alpha) was studied using model-free isoconversional linear integral KAS (Kissinger-Akahira-Sunose) and FWO (Flynn-Wall-Ozawa) methods. It was shown that the E-a varies with a and hence with temperature and consequently the glass/crystal transformation can be described as a complex process involving different mechanisms of nucleation and growth.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "Non-Isothermal Crystallization of Lithium Germanophosphate Glass Studied by Different Kinetic Methods",
pages = "203-193",
number = "2",
volume = "50",
doi = "10.2298/SOS1802193M",
url = "conv_837"
}

Matijašević, S., Grujić, S. R., Topalović, V., Nikolić, J., Smiljanić, S., Labus, N.,& Savić, V.. (2018). Non-Isothermal Crystallization of Lithium Germanophosphate Glass Studied by Different Kinetic Methods. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 50(2), 193-203.
https://doi.org/10.2298/SOS1802193M
conv_837

Matijašević S, Grujić SR, Topalović V, Nikolić J, Smiljanić S, Labus N, Savić V. Non-Isothermal Crystallization of Lithium Germanophosphate Glass Studied by Different Kinetic Methods. in Science of Sintering. 2018;50(2):193-203.
doi:10.2298/SOS1802193M
conv_837 .

Matijašević, Srđan, Grujić, Snežana R., Topalović, Vladimir, Nikolić, Jelena, Smiljanić, Sonja, Labus, Nebojša, Savić, Veljko, "Non-Isothermal Crystallization of Lithium Germanophosphate Glass Studied by Different Kinetic Methods" in Science of Sintering, 50, no. 2 (2018):193-203,
https://doi.org/10.2298/SOS1802193M .,
conv_837 .

TY  - CONF
AU  - Savić, Veljko
AU  - Matijašević, Srđan
AU  - Topalović, Vladimir
AU  - Zildžović, Snežana
AU  - Smiljanić, Sonja
AU  - Grujić, Snežana
PY  - 2018
UR  - https://ritnms.itnms.ac.rs/handle/123456789/745
AB  - The nucleation of powder glass from the system Li2O-Al2O3-GeO2-P2O5 was studied. The investigations were performed under non-isothermal conditions using the  DTA method. The field of nucleation is determined. It was observed that there is possibility of simultaneous nucleation and crystal growth in glass. Dependence (Tp-1)max of Tn is linear for studied glass system.
PB  - Bor : Mining and Metallurgy Institute Bor
C3  - 50th International October Conference on Mining and Metallurgy-IOCMM 2018
T1  - Non-isothermal analysis of nucleation the Li2O-GeO2-Al2O3-P2O5 glass
EP  - 222
SP  - 219
ER  - 

@conference{
author = "Savić, Veljko and Matijašević, Srđan and Topalović, Vladimir and Zildžović, Snežana and Smiljanić, Sonja and Grujić, Snežana",
year = "2018",
abstract = "The nucleation of powder glass from the system Li2O-Al2O3-GeO2-P2O5 was studied. The investigations were performed under non-isothermal conditions using the  DTA method. The field of nucleation is determined. It was observed that there is possibility of simultaneous nucleation and crystal growth in glass. Dependence (Tp-1)max of Tn is linear for studied glass system.",
publisher = "Bor : Mining and Metallurgy Institute Bor",
journal = "50th International October Conference on Mining and Metallurgy-IOCMM 2018",
title = "Non-isothermal analysis of nucleation the Li2O-GeO2-Al2O3-P2O5 glass",
pages = "222-219"
}

Savić, V., Matijašević, S., Topalović, V., Zildžović, S., Smiljanić, S.,& Grujić, S.. (2018). Non-isothermal analysis of nucleation the Li2O-GeO2-Al2O3-P2O5 glass. in 50th International October Conference on Mining and Metallurgy-IOCMM 2018
Bor : Mining and Metallurgy Institute Bor., 219-222.

Savić V, Matijašević S, Topalović V, Zildžović S, Smiljanić S, Grujić S. Non-isothermal analysis of nucleation the Li2O-GeO2-Al2O3-P2O5 glass. in 50th International October Conference on Mining and Metallurgy-IOCMM 2018. 2018;:219-222..

Savić, Veljko, Matijašević, Srđan, Topalović, Vladimir, Zildžović, Snežana, Smiljanić, Sonja, Grujić, Snežana, "Non-isothermal analysis of nucleation the Li2O-GeO2-Al2O3-P2O5 glass" in 50th International October Conference on Mining and Metallurgy-IOCMM 2018 (2018):219-222.

TY  - JOUR
AU  - Nikolić, Jelena
AU  - Tosić, Mihajlo B.
AU  - Grujić, Snežana R.
AU  - Živanović, Vladimir D.
AU  - Đošić, Marija
AU  - Matijašević, Srđan
AU  - Smiljanić, Sonja
PY  - 2017
UR  - https://ritnms.itnms.ac.rs/handle/123456789/448
AB  - In this work, the dissolution behavior of a polyphosphate glass, with the composition 45P(2)O(5) center dot 3SiO(2) center dot 25K(2)O center dot 15CaO center dot 10MgO center dot ZnO center dot MnO (mol %), in simulated body fluid (SBF) at a temperature of 37 degrees C for different times was studied. Two powder sizes of the glass (granulation: 0.1-0.3 and 0.3-0.65 mm) and the bulk glass were investigated. The dissolution experiments were conducted under stationary conditions. Changes in the normalized mass release, normalized concentration of ions, pH values, and surface morphology were determined as a function of the dissolution time. The initial rates of glass powder dissolution and leaching of ions, as well as the diffusion coefficient of cations and the releasing rate of ions, during the hydrolysis process of glass were determined. It was shown that the investigated phosphate glass dissolves in SBF incongruently, with neither precipitation nor the formation of newly potentially toxic compounds, in a dissolution period 720 h.
PB  - Srpsko hemijsko društvo, Beograd
T2  - Journal of the Serbian Chemical Society
T1  - Dissolution behavior of a polyphosphate glass in simulated body fluid
EP  - 342
IS  - 3
SP  - 329
VL  - 82
DO  - 10.2298/JSC161031009N
UR  - conv_792
ER  - 

@article{
author = "Nikolić, Jelena and Tosić, Mihajlo B. and Grujić, Snežana R. and Živanović, Vladimir D. and Đošić, Marija and Matijašević, Srđan and Smiljanić, Sonja",
year = "2017",
abstract = "In this work, the dissolution behavior of a polyphosphate glass, with the composition 45P(2)O(5) center dot 3SiO(2) center dot 25K(2)O center dot 15CaO center dot 10MgO center dot ZnO center dot MnO (mol %), in simulated body fluid (SBF) at a temperature of 37 degrees C for different times was studied. Two powder sizes of the glass (granulation: 0.1-0.3 and 0.3-0.65 mm) and the bulk glass were investigated. The dissolution experiments were conducted under stationary conditions. Changes in the normalized mass release, normalized concentration of ions, pH values, and surface morphology were determined as a function of the dissolution time. The initial rates of glass powder dissolution and leaching of ions, as well as the diffusion coefficient of cations and the releasing rate of ions, during the hydrolysis process of glass were determined. It was shown that the investigated phosphate glass dissolves in SBF incongruently, with neither precipitation nor the formation of newly potentially toxic compounds, in a dissolution period 720 h.",
publisher = "Srpsko hemijsko društvo, Beograd",
journal = "Journal of the Serbian Chemical Society",
title = "Dissolution behavior of a polyphosphate glass in simulated body fluid",
pages = "342-329",
number = "3",
volume = "82",
doi = "10.2298/JSC161031009N",
url = "conv_792"
}

Nikolić, J., Tosić, M. B., Grujić, S. R., Živanović, V. D., Đošić, M., Matijašević, S.,& Smiljanić, S.. (2017). Dissolution behavior of a polyphosphate glass in simulated body fluid. in Journal of the Serbian Chemical Society
Srpsko hemijsko društvo, Beograd., 82(3), 329-342.
https://doi.org/10.2298/JSC161031009N
conv_792

Nikolić J, Tosić MB, Grujić SR, Živanović VD, Đošić M, Matijašević S, Smiljanić S. Dissolution behavior of a polyphosphate glass in simulated body fluid. in Journal of the Serbian Chemical Society. 2017;82(3):329-342.
doi:10.2298/JSC161031009N
conv_792 .

Nikolić, Jelena, Tosić, Mihajlo B., Grujić, Snežana R., Živanović, Vladimir D., Đošić, Marija, Matijašević, Srđan, Smiljanić, Sonja, "Dissolution behavior of a polyphosphate glass in simulated body fluid" in Journal of the Serbian Chemical Society, 82, no. 3 (2017):329-342,
https://doi.org/10.2298/JSC161031009N .,
conv_792 .

TY  - JOUR
AU  - Topalović, Vladimir
AU  - Grujić, Snežana R.
AU  - Živanović, Vladimir D.
AU  - Matijašević, Srđan
AU  - Nikolić, Jelena
AU  - Stojanović, Jovica
AU  - Smiljanić, Sonja
PY  - 2017
UR  - https://ritnms.itnms.ac.rs/handle/123456789/437
AB  - Melt-quenching method was employed for obtaining a glass-ceramic with the following composition 42P(2)O(5). 40CaO.5SrO.10Na(2)O.3TiO(2) (mol%) glass. The crystallization and sintering behavior of glass have been studied by using DTA, HSM, XRD, FTIR and SEM methods. It was determined that the surface and volume crystallization mechanisms act simultaneously in bulk glass samples. The comparison of DTA and HSM data revealed that the sintering and crystallization processes are independent. The sintered calcium phosphate glass ceramic which contained bioactive beta-Ca-3(PO4)(2) and beta-Ca2P2O7 phases was successfully prepared. It was determined that during crystallization the primary phase in the precipitate was beta-Ca(PO3)(2). Other phases appearing in the resulting glass-ceramic were: alpha-Ca2P2O7, gamma-Ca2PO7, Ca4P6O19 and CaHPO4(H2O)(2). Crystalline phases containing Sr and Ti were not detected. SEM analysis of the glass-ceramic microstructure revealed surface crystallization of glass particles and plate-like morphology of crystal growth. The result of the in vitro bioactivity showed that no apatite layer was formed on the surface of the as-prepared glass-ceramic samples after immersion in the simulated body fluid (SBF).
PB  - Elsevier Sci Ltd, Oxford
T2  - Ceramics International
T1  - Bioactive glass-ceramics prepared by powder sintering and crystallization of polyphosphate glass containing strontium
EP  - 12069
IS  - 15
SP  - 12061
VL  - 43
DO  - 10.1016/j.ceramint.2017.06.061
UR  - conv_803
ER  - 

@article{
author = "Topalović, Vladimir and Grujić, Snežana R. and Živanović, Vladimir D. and Matijašević, Srđan and Nikolić, Jelena and Stojanović, Jovica and Smiljanić, Sonja",
year = "2017",
abstract = "Melt-quenching method was employed for obtaining a glass-ceramic with the following composition 42P(2)O(5). 40CaO.5SrO.10Na(2)O.3TiO(2) (mol%) glass. The crystallization and sintering behavior of glass have been studied by using DTA, HSM, XRD, FTIR and SEM methods. It was determined that the surface and volume crystallization mechanisms act simultaneously in bulk glass samples. The comparison of DTA and HSM data revealed that the sintering and crystallization processes are independent. The sintered calcium phosphate glass ceramic which contained bioactive beta-Ca-3(PO4)(2) and beta-Ca2P2O7 phases was successfully prepared. It was determined that during crystallization the primary phase in the precipitate was beta-Ca(PO3)(2). Other phases appearing in the resulting glass-ceramic were: alpha-Ca2P2O7, gamma-Ca2PO7, Ca4P6O19 and CaHPO4(H2O)(2). Crystalline phases containing Sr and Ti were not detected. SEM analysis of the glass-ceramic microstructure revealed surface crystallization of glass particles and plate-like morphology of crystal growth. The result of the in vitro bioactivity showed that no apatite layer was formed on the surface of the as-prepared glass-ceramic samples after immersion in the simulated body fluid (SBF).",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Ceramics International",
title = "Bioactive glass-ceramics prepared by powder sintering and crystallization of polyphosphate glass containing strontium",
pages = "12069-12061",
number = "15",
volume = "43",
doi = "10.1016/j.ceramint.2017.06.061",
url = "conv_803"
}

Topalović, V., Grujić, S. R., Živanović, V. D., Matijašević, S., Nikolić, J., Stojanović, J.,& Smiljanić, S.. (2017). Bioactive glass-ceramics prepared by powder sintering and crystallization of polyphosphate glass containing strontium. in Ceramics International
Elsevier Sci Ltd, Oxford., 43(15), 12061-12069.
https://doi.org/10.1016/j.ceramint.2017.06.061
conv_803

Topalović V, Grujić SR, Živanović VD, Matijašević S, Nikolić J, Stojanović J, Smiljanić S. Bioactive glass-ceramics prepared by powder sintering and crystallization of polyphosphate glass containing strontium. in Ceramics International. 2017;43(15):12061-12069.
doi:10.1016/j.ceramint.2017.06.061
conv_803 .

Topalović, Vladimir, Grujić, Snežana R., Živanović, Vladimir D., Matijašević, Srđan, Nikolić, Jelena, Stojanović, Jovica, Smiljanić, Sonja, "Bioactive glass-ceramics prepared by powder sintering and crystallization of polyphosphate glass containing strontium" in Ceramics International, 43, no. 15 (2017):12061-12069,
https://doi.org/10.1016/j.ceramint.2017.06.061 .,
conv_803 .

TY  - CONF
AU  - Savić, Veljko
AU  - Matijašević, Srđan
AU  - Grujić, Snežana
AU  - Topalović, Vladimir
AU  - Smiljanić, Sonja
AU  - Nikolić, Jelena
AU  - Zildžović, Snežana
PY  - 2017
UR  - https://ritnms.itnms.ac.rs/handle/123456789/789
AB  - Lithium based solid electrolytes are mainly useful for utilization in high energy density batteries, supercapacitors, sensors, displays and electrochemical devices. They generally crystallize in rhombohedral R3-c(167) space group related to open structures and the monovalent Li+ cation can easily migrate in lattice with low activation energy. These materials are usually obtained by powder sintering route and the crystallization of these glasses. The studies of crystallization of Li2O–Al2O3–GeO2–P2O5 glasses showed that one of dominant crystal phase precipitated in glass matrix is NASICON - type LiGe2(PO4)3 crystals. It was detected that this glass crystallizes by the volume crystallization mechanism. The enthalpy of crystallization ΔHcryst= -48.36 kJmol-1 was determined. The density of the crystalline phase was ρ=3.52 gcm-3 and molar volume Vm = 121.09 ·10-6 m3. The ionic conductivity of the test phase which be-longs to the solid solutions is about 6.2· 10−6 Scm-1 at room temperature.
It may be considered that the structure of this glass consists of GeO6 octahedra and PO4 tetrahedra. The basic unit of this glass consists of two GeO6 octahedra and PO4 tetrahedra corresponding to [Ge2(PO4)]. Each GeO6 octahedron is connected to three PO4 tetrahedra, each of which is linked to four GeO6 octahedra.
These units in turn are connected to form `ribbons` along the c-axis and the ribbons are joined together along the a-and b-axis by PO4 tetrahedra. This structure results in cavities where lithium ions reside and in bottlenecks in which they pass through.
PB  - Belgrade : Association of Metallurgical Engineers of Serbia
C3  - Metallurgical & Materials Engineering Congress of South-East Europe MME SEE 2017
T1  - Ion conductive glass-ceramics in the system Li2O·Al2O3·GeO2·P2O5
EP  - 46
SP  - 46
ER  - 

@conference{
author = "Savić, Veljko and Matijašević, Srđan and Grujić, Snežana and Topalović, Vladimir and Smiljanić, Sonja and Nikolić, Jelena and Zildžović, Snežana",
year = "2017",
abstract = "Lithium based solid electrolytes are mainly useful for utilization in high energy density batteries, supercapacitors, sensors, displays and electrochemical devices. They generally crystallize in rhombohedral R3-c(167) space group related to open structures and the monovalent Li+ cation can easily migrate in lattice with low activation energy. These materials are usually obtained by powder sintering route and the crystallization of these glasses. The studies of crystallization of Li2O–Al2O3–GeO2–P2O5 glasses showed that one of dominant crystal phase precipitated in glass matrix is NASICON - type LiGe2(PO4)3 crystals. It was detected that this glass crystallizes by the volume crystallization mechanism. The enthalpy of crystallization ΔHcryst= -48.36 kJmol-1 was determined. The density of the crystalline phase was ρ=3.52 gcm-3 and molar volume Vm = 121.09 ·10-6 m3. The ionic conductivity of the test phase which be-longs to the solid solutions is about 6.2· 10−6 Scm-1 at room temperature.
It may be considered that the structure of this glass consists of GeO6 octahedra and PO4 tetrahedra. The basic unit of this glass consists of two GeO6 octahedra and PO4 tetrahedra corresponding to [Ge2(PO4)]. Each GeO6 octahedron is connected to three PO4 tetrahedra, each of which is linked to four GeO6 octahedra.
These units in turn are connected to form `ribbons` along the c-axis and the ribbons are joined together along the a-and b-axis by PO4 tetrahedra. This structure results in cavities where lithium ions reside and in bottlenecks in which they pass through.",
publisher = "Belgrade : Association of Metallurgical Engineers of Serbia",
journal = "Metallurgical & Materials Engineering Congress of South-East Europe MME SEE 2017",
title = "Ion conductive glass-ceramics in the system Li2O·Al2O3·GeO2·P2O5",
pages = "46-46"
}

Savić, V., Matijašević, S., Grujić, S., Topalović, V., Smiljanić, S., Nikolić, J.,& Zildžović, S.. (2017). Ion conductive glass-ceramics in the system Li2O·Al2O3·GeO2·P2O5. in Metallurgical & Materials Engineering Congress of South-East Europe MME SEE 2017
Belgrade : Association of Metallurgical Engineers of Serbia., 46-46.

Savić V, Matijašević S, Grujić S, Topalović V, Smiljanić S, Nikolić J, Zildžović S. Ion conductive glass-ceramics in the system Li2O·Al2O3·GeO2·P2O5. in Metallurgical & Materials Engineering Congress of South-East Europe MME SEE 2017. 2017;:46-46..

Savić, Veljko, Matijašević, Srđan, Grujić, Snežana, Topalović, Vladimir, Smiljanić, Sonja, Nikolić, Jelena, Zildžović, Snežana, "Ion conductive glass-ceramics in the system Li2O·Al2O3·GeO2·P2O5" in Metallurgical & Materials Engineering Congress of South-East Europe MME SEE 2017 (2017):46-46.