Directed synthesis, structure and properties of multifunctional materials

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Directed synthesis, structure and properties of multifunctional materials (en)
Усмерена синтеза, структура и својства мултифункционалних материјала (sr)
Usmerena sinteza, struktura i svojstva multifunkcionalnih materijala (sr_RS)
Authors

Publications

Effects of mechanical-activation and TiO2 addition on the behavior of two-step sintered steatite ceramics

Terzić, Anja; Obradović, Nina; Kosanović, Darko; Stojanović, Jovica; Đorđević, Antonije; Andrić, Ljubiša; Pavlović, Vladimir B.

(Elsevier Sci Ltd, Oxford, 2019)

TY  - JOUR
AU  - Terzić, Anja
AU  - Obradović, Nina
AU  - Kosanović, Darko
AU  - Stojanović, Jovica
AU  - Đorđević, Antonije
AU  - Andrić, Ljubiša
AU  - Pavlović, Vladimir B.
PY  - 2019
UR  - https://ritnms.itnms.ac.rs/handle/123456789/519
AB  - Steatite, as ceramic with composition predominantly resting on magnesium silicate, was produced from economic resources - talc, aluminosilicate clays, and either BaCO3 or feldspar as flux. Titanium dioxide was a doping agent. Four steatite mixtures were mechanically activated in a planetary ball mill for 30, 45 or 60 min, prior to the thermal treatment. Two-step sintering with initial phase set at 1350 degrees C and holding period conducted at 1250 degrees C was applied to initiate diffusion and prevent grain growth. Thereby, a high density ceramic material with low-porous submicron structure was acquired. The effects of TiO2 addition on densification, microstructure, and dielectric characteristics of steatites were monitored. The thermal stability of green mixtures was tested by differential thermal and thermogravimetric analyses. Changes in crystallinity and mineral phase composition were observed by the X-ray diffraction technique. Microstructural visualization with spatial arrangements of individual chemical elements on surface of the sintered ceramics was acquired by scanning electron microscopy accompanied with EDS mapping. In order to test the possibility of employment of the obtained steatites in insulation materials, electrical measurements were conducted by recording variations of the dielectric constant and loss tangent as a function of alternations in the mix-design and the mechanical activation period.
PB  - Elsevier Sci Ltd, Oxford
T2  - Ceramics International
T1  - Effects of mechanical-activation and TiO2 addition on the behavior of two-step sintered steatite ceramics
EP  - 3022
IS  - 3
SP  - 3013
VL  - 45
DO  - 10.1016/j.ceramint.2018.10.120
UR  - conv_842
ER  - 
@article{
author = "Terzić, Anja and Obradović, Nina and Kosanović, Darko and Stojanović, Jovica and Đorđević, Antonije and Andrić, Ljubiša and Pavlović, Vladimir B.",
year = "2019",
abstract = "Steatite, as ceramic with composition predominantly resting on magnesium silicate, was produced from economic resources - talc, aluminosilicate clays, and either BaCO3 or feldspar as flux. Titanium dioxide was a doping agent. Four steatite mixtures were mechanically activated in a planetary ball mill for 30, 45 or 60 min, prior to the thermal treatment. Two-step sintering with initial phase set at 1350 degrees C and holding period conducted at 1250 degrees C was applied to initiate diffusion and prevent grain growth. Thereby, a high density ceramic material with low-porous submicron structure was acquired. The effects of TiO2 addition on densification, microstructure, and dielectric characteristics of steatites were monitored. The thermal stability of green mixtures was tested by differential thermal and thermogravimetric analyses. Changes in crystallinity and mineral phase composition were observed by the X-ray diffraction technique. Microstructural visualization with spatial arrangements of individual chemical elements on surface of the sintered ceramics was acquired by scanning electron microscopy accompanied with EDS mapping. In order to test the possibility of employment of the obtained steatites in insulation materials, electrical measurements were conducted by recording variations of the dielectric constant and loss tangent as a function of alternations in the mix-design and the mechanical activation period.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Ceramics International",
title = "Effects of mechanical-activation and TiO2 addition on the behavior of two-step sintered steatite ceramics",
pages = "3022-3013",
number = "3",
volume = "45",
doi = "10.1016/j.ceramint.2018.10.120",
url = "conv_842"
}
Terzić, A., Obradović, N., Kosanović, D., Stojanović, J., Đorđević, A., Andrić, L.,& Pavlović, V. B.. (2019). Effects of mechanical-activation and TiO2 addition on the behavior of two-step sintered steatite ceramics. in Ceramics International
Elsevier Sci Ltd, Oxford., 45(3), 3013-3022.
https://doi.org/10.1016/j.ceramint.2018.10.120
conv_842
Terzić A, Obradović N, Kosanović D, Stojanović J, Đorđević A, Andrić L, Pavlović VB. Effects of mechanical-activation and TiO2 addition on the behavior of two-step sintered steatite ceramics. in Ceramics International. 2019;45(3):3013-3022.
doi:10.1016/j.ceramint.2018.10.120
conv_842 .
Terzić, Anja, Obradović, Nina, Kosanović, Darko, Stojanović, Jovica, Đorđević, Antonije, Andrić, Ljubiša, Pavlović, Vladimir B., "Effects of mechanical-activation and TiO2 addition on the behavior of two-step sintered steatite ceramics" in Ceramics International, 45, no. 3 (2019):3013-3022,
https://doi.org/10.1016/j.ceramint.2018.10.120 .,
conv_842 .
1
2
2

Thermal and Mechanical Behavior of Composite Mortars Containing Natural Sorptive Clays and Fly Ash

Terzić, Anja; Pezo, Lato; Milicić, Ljiljana; Mijatović, Nevenka; Radojević, Zagorka; Radulović, Dragan; Andrić, Ljubiša

(Međunarodni Institut za nauku o sinterovanju, Beograd, 2019)

TY  - JOUR
AU  - Terzić, Anja
AU  - Pezo, Lato
AU  - Milicić, Ljiljana
AU  - Mijatović, Nevenka
AU  - Radojević, Zagorka
AU  - Radulović, Dragan
AU  - Andrić, Ljubiša
PY  - 2019
UR  - https://ritnms.itnms.ac.rs/handle/123456789/503
AB  - Mineral additives are extensively applied as cement replacement materials in both construction concrete and mortar. Fly ash is one of the most commonly utilized additives which improve Theological properties, as well as thermal and mechanical behavior of mortar, and as such it has been widely investigated. This industrial byproduct comprises heavy metals in its composition; therefore further research is needed to optimize its effective dosage. Moreover, certain sorptive clays, such as natural zeolite and bentonite, can prevent migration of toxic elements from fly ash by immobilizing them in their structure. Ten experimental mortars are prepared with Portland cement, river sand and addition of fly ash, zeolite and/or bentonite in accordance with chemometric experimental design rules. The aim of the study was to investigate the effect of mineral additives on thermal and mechanical performances of mortar. Thermal characteristics were monitored via dilatometric analysis and DTA method. Principal component analysis was used on the results of physico-mechanical testing (workability, bulk density, water absorption, shrinkage, compressive and flexural strength) to enable the divisions of the observed samples into groups in the factor space. The performance of Artificial Neural Network was compared with the experimental data in order to develop rapid and accurate method for prediction of mechanical parameters of mortar. The ANN model showed high overall prediction accuracy (r(2) = 0.989, during training cycle). The test results indicate that incorporation of the mineral additives gave cost effective mortars with sufficiently good properties. However, tools of analytical modeling highlighted mortar with zeolite and fly ash as the optimal composition regarding its mechanical performance.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - Thermal and Mechanical Behavior of Composite Mortars Containing Natural Sorptive Clays and Fly Ash
EP  - 56
IS  - 1
SP  - 39
VL  - 51
DO  - 10.2298/SOS1901039T
UR  - conv_865
ER  - 
@article{
author = "Terzić, Anja and Pezo, Lato and Milicić, Ljiljana and Mijatović, Nevenka and Radojević, Zagorka and Radulović, Dragan and Andrić, Ljubiša",
year = "2019",
abstract = "Mineral additives are extensively applied as cement replacement materials in both construction concrete and mortar. Fly ash is one of the most commonly utilized additives which improve Theological properties, as well as thermal and mechanical behavior of mortar, and as such it has been widely investigated. This industrial byproduct comprises heavy metals in its composition; therefore further research is needed to optimize its effective dosage. Moreover, certain sorptive clays, such as natural zeolite and bentonite, can prevent migration of toxic elements from fly ash by immobilizing them in their structure. Ten experimental mortars are prepared with Portland cement, river sand and addition of fly ash, zeolite and/or bentonite in accordance with chemometric experimental design rules. The aim of the study was to investigate the effect of mineral additives on thermal and mechanical performances of mortar. Thermal characteristics were monitored via dilatometric analysis and DTA method. Principal component analysis was used on the results of physico-mechanical testing (workability, bulk density, water absorption, shrinkage, compressive and flexural strength) to enable the divisions of the observed samples into groups in the factor space. The performance of Artificial Neural Network was compared with the experimental data in order to develop rapid and accurate method for prediction of mechanical parameters of mortar. The ANN model showed high overall prediction accuracy (r(2) = 0.989, during training cycle). The test results indicate that incorporation of the mineral additives gave cost effective mortars with sufficiently good properties. However, tools of analytical modeling highlighted mortar with zeolite and fly ash as the optimal composition regarding its mechanical performance.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "Thermal and Mechanical Behavior of Composite Mortars Containing Natural Sorptive Clays and Fly Ash",
pages = "56-39",
number = "1",
volume = "51",
doi = "10.2298/SOS1901039T",
url = "conv_865"
}
Terzić, A., Pezo, L., Milicić, L., Mijatović, N., Radojević, Z., Radulović, D.,& Andrić, L.. (2019). Thermal and Mechanical Behavior of Composite Mortars Containing Natural Sorptive Clays and Fly Ash. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 51(1), 39-56.
https://doi.org/10.2298/SOS1901039T
conv_865
Terzić A, Pezo L, Milicić L, Mijatović N, Radojević Z, Radulović D, Andrić L. Thermal and Mechanical Behavior of Composite Mortars Containing Natural Sorptive Clays and Fly Ash. in Science of Sintering. 2019;51(1):39-56.
doi:10.2298/SOS1901039T
conv_865 .
Terzić, Anja, Pezo, Lato, Milicić, Ljiljana, Mijatović, Nevenka, Radojević, Zagorka, Radulović, Dragan, Andrić, Ljubiša, "Thermal and Mechanical Behavior of Composite Mortars Containing Natural Sorptive Clays and Fly Ash" in Science of Sintering, 51, no. 1 (2019):39-56,
https://doi.org/10.2298/SOS1901039T .,
conv_865 .
3
8
9

Kinetics of thermally activated processes in cordierite-based ceramics

Obradović, Nina; Blagojević, Vladimir; Filipović, Suzana; Đorđević, Nataša; Kosanović, Darko; Marković, Smilja; Kachlik, Martin; Maca, Karel; Pavlović, Vladimir

(Springer, Dordrecht, 2019)

TY  - JOUR
AU  - Obradović, Nina
AU  - Blagojević, Vladimir
AU  - Filipović, Suzana
AU  - Đorđević, Nataša
AU  - Kosanović, Darko
AU  - Marković, Smilja
AU  - Kachlik, Martin
AU  - Maca, Karel
AU  - Pavlović, Vladimir
PY  - 2019
UR  - https://ritnms.itnms.ac.rs/handle/123456789/501
AB  - Thermally activated processes in cordierite-based ceramics were investigated to determine the effect of the mechanical activation and the addition of TeO2 on kinetic and thermodynamic parameters of these processes. Using a combination of dilatometry and DTA measurements in the 100-1400 degrees C temperature range, it was established that both the mechanical activation and the addition of TeO2 have a significant effect on processes in cordierite-based ceramics. A combination of 5 mass% addition of TeO2 and mechanical activation for 40 min reduced the sintering temperature of cordierite ceramics to around 1100 degrees C. In addition, the analysis of DTA measurements of mechanically activated samples indicates that the mechanical activation leads to intensification of the cordierite formation through an increase in concentration of surface defects and an increase in grain contact surface in the initial powder.
PB  - Springer, Dordrecht
T2  - Journal of Thermal Analysis and Calorimetry
T1  - Kinetics of thermally activated processes in cordierite-based ceramics
EP  - 2998
IS  - 5
SP  - 2989
VL  - 138
DO  - 10.1007/s10973-018-7924-1
UR  - https://hdl.handle.net/21.15107/rcub_dais_7048
UR  - conv_867
ER  - 
@article{
author = "Obradović, Nina and Blagojević, Vladimir and Filipović, Suzana and Đorđević, Nataša and Kosanović, Darko and Marković, Smilja and Kachlik, Martin and Maca, Karel and Pavlović, Vladimir",
year = "2019",
abstract = "Thermally activated processes in cordierite-based ceramics were investigated to determine the effect of the mechanical activation and the addition of TeO2 on kinetic and thermodynamic parameters of these processes. Using a combination of dilatometry and DTA measurements in the 100-1400 degrees C temperature range, it was established that both the mechanical activation and the addition of TeO2 have a significant effect on processes in cordierite-based ceramics. A combination of 5 mass% addition of TeO2 and mechanical activation for 40 min reduced the sintering temperature of cordierite ceramics to around 1100 degrees C. In addition, the analysis of DTA measurements of mechanically activated samples indicates that the mechanical activation leads to intensification of the cordierite formation through an increase in concentration of surface defects and an increase in grain contact surface in the initial powder.",
publisher = "Springer, Dordrecht",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "Kinetics of thermally activated processes in cordierite-based ceramics",
pages = "2998-2989",
number = "5",
volume = "138",
doi = "10.1007/s10973-018-7924-1",
url = "https://hdl.handle.net/21.15107/rcub_dais_7048, conv_867"
}
Obradović, N., Blagojević, V., Filipović, S., Đorđević, N., Kosanović, D., Marković, S., Kachlik, M., Maca, K.,& Pavlović, V.. (2019). Kinetics of thermally activated processes in cordierite-based ceramics. in Journal of Thermal Analysis and Calorimetry
Springer, Dordrecht., 138(5), 2989-2998.
https://doi.org/10.1007/s10973-018-7924-1
https://hdl.handle.net/21.15107/rcub_dais_7048
Obradović N, Blagojević V, Filipović S, Đorđević N, Kosanović D, Marković S, Kachlik M, Maca K, Pavlović V. Kinetics of thermally activated processes in cordierite-based ceramics. in Journal of Thermal Analysis and Calorimetry. 2019;138(5):2989-2998.
doi:10.1007/s10973-018-7924-1
https://hdl.handle.net/21.15107/rcub_dais_7048 .
Obradović, Nina, Blagojević, Vladimir, Filipović, Suzana, Đorđević, Nataša, Kosanović, Darko, Marković, Smilja, Kachlik, Martin, Maca, Karel, Pavlović, Vladimir, "Kinetics of thermally activated processes in cordierite-based ceramics" in Journal of Thermal Analysis and Calorimetry, 138, no. 5 (2019):2989-2998,
https://doi.org/10.1007/s10973-018-7924-1 .,
https://hdl.handle.net/21.15107/rcub_dais_7048 .
7
1
4

Primena modifikovanih tanina u antikorozionim alkidnim premazima

Milošević, Milena D.; Daničić, Dunja D.; Kovačina, Jovanka N.; Bugarčić, Mladen; Rusmirović, Jelena D.; Kovacević, Tihomir; Marinković, Aleksandar D.

(Inženjersko društvo za koroziju, Beograd, 2019)

TY  - JOUR
AU  - Milošević, Milena D.
AU  - Daničić, Dunja D.
AU  - Kovačina, Jovanka N.
AU  - Bugarčić, Mladen
AU  - Rusmirović, Jelena D.
AU  - Kovacević, Tihomir
AU  - Marinković, Aleksandar D.
PY  - 2019
UR  - https://ritnms.itnms.ac.rs/handle/123456789/499
AB  - U ovom radu prikazana je sinteza antikorozionih aditiva na bazi hemijski modifikovanog tanina i njihova primena u alkidnim premazima u cilju poboljšanja antikorozionih svojstava. Prikazane su dve metode modifikacije tanina: direktna modifikacija tanina primenom amonijum-hidroksida, amonijum-hidroksid/amonijum-hlorid pufera ili dietilentriamina (DETA); i dvostepena modifikacija tanina koja u prvom stupnju uključuje modifikaciju epihlorhidrinom sa ciljem da se dobije tannin sa epoksi terminiranim funkcionalnim grupama, ET, i modifikaciju ET tanina sa heteroaromatičnim aminima ili masnim kiselinama izolovanim iz lanenog ulja (LFA) u drugom stupnju. Sintetisani antikorozioni aditivi su okarakterisani primenom ATR-FTIR, 1H i 13C NMR spektroskopija, i elementalnom analizom. Sadržaj epoksi, amino, hidroksilnih i karboksilnih grupa i vrednost jodnog broja sintetisanih aditiva određen je prema standardnim metodama. Alkidni premazi koji sadrže antikorozione aditive na bazi modifikovanog tanina ispitani su prema standardnoj SRPS EN ISO 4628 metodi. Antikorozivni alkidni premazi na bazi modfikovanih tanina pokazali su poboljšane antikorozione karakteristike i adheziju u poređenju sa alkidnim premazom na bazi cink-fosfata. Alkidni premazi koji sadrže dvostepeno modifikovani tanin sa LFA i 2-amino-5-merkapto-1,3,4-tiadiazolom pokazali su najbolje antikorozione karakteristike.
AB  - The study of the synthesis of anticorrosive inhibitors, based on chemically modified tannins, and their use in alkyd based coatings to improve anticorrosive properties is presented in this work. Two methods of tannin modification were applied: direct method using ammonium hydroxide, ammonium hydroxide/ammonium chloride buffer or diethylenetriamine (DETA); and a two-step method including tannin modification with epichlorohydrin (ECH) in first step to produce epoxy modified tannin, ET, and further modification with heteroaromatic amines or linseed oil fatty acids (LFA) in second step. The obtained anticorrosive additives were characterized using ATR-FTIR, 1H and 13C NMR spectroscopies and elemental analysis. Epoxy, amino, hydroxyl, acid and iodine values of the synthesized inhibitors were determined according to standard methods. The prepared alkyd coating with tannin inhibitors was tested according to standard SRPS EN ISO 4628 method. Anticorrosive coating containing modified tannin based additive showed increased anticorrosive properties, good adhesion and coverage comparing to the coating with zinc phosphate additive. The alkyd coating films based on ET-LFA and ET modified with 2-amino-5-mercapto-1,3,4-thiadiazole showed best anticorrosive results.
PB  - Inženjersko društvo za koroziju, Beograd
T2  - Zaštita materijala
T1  - Primena modifikovanih tanina u antikorozionim alkidnim premazima
T1  - Modified tannins for alkyd based anticorrosive coatings
EP  - 95
IS  - 1
SP  - 81
VL  - 60
DO  - 10.5937/zasmat1901081M
UR  - conv_158
ER  - 
@article{
author = "Milošević, Milena D. and Daničić, Dunja D. and Kovačina, Jovanka N. and Bugarčić, Mladen and Rusmirović, Jelena D. and Kovacević, Tihomir and Marinković, Aleksandar D.",
year = "2019",
abstract = "U ovom radu prikazana je sinteza antikorozionih aditiva na bazi hemijski modifikovanog tanina i njihova primena u alkidnim premazima u cilju poboljšanja antikorozionih svojstava. Prikazane su dve metode modifikacije tanina: direktna modifikacija tanina primenom amonijum-hidroksida, amonijum-hidroksid/amonijum-hlorid pufera ili dietilentriamina (DETA); i dvostepena modifikacija tanina koja u prvom stupnju uključuje modifikaciju epihlorhidrinom sa ciljem da se dobije tannin sa epoksi terminiranim funkcionalnim grupama, ET, i modifikaciju ET tanina sa heteroaromatičnim aminima ili masnim kiselinama izolovanim iz lanenog ulja (LFA) u drugom stupnju. Sintetisani antikorozioni aditivi su okarakterisani primenom ATR-FTIR, 1H i 13C NMR spektroskopija, i elementalnom analizom. Sadržaj epoksi, amino, hidroksilnih i karboksilnih grupa i vrednost jodnog broja sintetisanih aditiva određen je prema standardnim metodama. Alkidni premazi koji sadrže antikorozione aditive na bazi modifikovanog tanina ispitani su prema standardnoj SRPS EN ISO 4628 metodi. Antikorozivni alkidni premazi na bazi modfikovanih tanina pokazali su poboljšane antikorozione karakteristike i adheziju u poređenju sa alkidnim premazom na bazi cink-fosfata. Alkidni premazi koji sadrže dvostepeno modifikovani tanin sa LFA i 2-amino-5-merkapto-1,3,4-tiadiazolom pokazali su najbolje antikorozione karakteristike., The study of the synthesis of anticorrosive inhibitors, based on chemically modified tannins, and their use in alkyd based coatings to improve anticorrosive properties is presented in this work. Two methods of tannin modification were applied: direct method using ammonium hydroxide, ammonium hydroxide/ammonium chloride buffer or diethylenetriamine (DETA); and a two-step method including tannin modification with epichlorohydrin (ECH) in first step to produce epoxy modified tannin, ET, and further modification with heteroaromatic amines or linseed oil fatty acids (LFA) in second step. The obtained anticorrosive additives were characterized using ATR-FTIR, 1H and 13C NMR spectroscopies and elemental analysis. Epoxy, amino, hydroxyl, acid and iodine values of the synthesized inhibitors were determined according to standard methods. The prepared alkyd coating with tannin inhibitors was tested according to standard SRPS EN ISO 4628 method. Anticorrosive coating containing modified tannin based additive showed increased anticorrosive properties, good adhesion and coverage comparing to the coating with zinc phosphate additive. The alkyd coating films based on ET-LFA and ET modified with 2-amino-5-mercapto-1,3,4-thiadiazole showed best anticorrosive results.",
publisher = "Inženjersko društvo za koroziju, Beograd",
journal = "Zaštita materijala",
title = "Primena modifikovanih tanina u antikorozionim alkidnim premazima, Modified tannins for alkyd based anticorrosive coatings",
pages = "95-81",
number = "1",
volume = "60",
doi = "10.5937/zasmat1901081M",
url = "conv_158"
}
Milošević, M. D., Daničić, D. D., Kovačina, J. N., Bugarčić, M., Rusmirović, J. D., Kovacević, T.,& Marinković, A. D.. (2019). Primena modifikovanih tanina u antikorozionim alkidnim premazima. in Zaštita materijala
Inženjersko društvo za koroziju, Beograd., 60(1), 81-95.
https://doi.org/10.5937/zasmat1901081M
conv_158
Milošević MD, Daničić DD, Kovačina JN, Bugarčić M, Rusmirović JD, Kovacević T, Marinković AD. Primena modifikovanih tanina u antikorozionim alkidnim premazima. in Zaštita materijala. 2019;60(1):81-95.
doi:10.5937/zasmat1901081M
conv_158 .
Milošević, Milena D., Daničić, Dunja D., Kovačina, Jovanka N., Bugarčić, Mladen, Rusmirović, Jelena D., Kovacević, Tihomir, Marinković, Aleksandar D., "Primena modifikovanih tanina u antikorozionim alkidnim premazima" in Zaštita materijala, 60, no. 1 (2019):81-95,
https://doi.org/10.5937/zasmat1901081M .,
conv_158 .
2
2

The effect of alternations in mineral additives (zeolite, bentonite, fly ash) on physico-chemical behavior of Portland cement based binders

Terzić, Anja; Pezo, Lato; Mijatović, Nevenka; Stojanović, Jovica; Kragović, Milan; Milicić, Ljiljana; Andrić, Ljubiša

(Elsevier Sci Ltd, Oxford, 2018)

TY  - JOUR
AU  - Terzić, Anja
AU  - Pezo, Lato
AU  - Mijatović, Nevenka
AU  - Stojanović, Jovica
AU  - Kragović, Milan
AU  - Milicić, Ljiljana
AU  - Andrić, Ljubiša
PY  - 2018
UR  - https://ritnms.itnms.ac.rs/handle/123456789/469
AB  - Instrumental analyses accompanied by analytical modeling tools were employed to assess physico-chemical changes induced by variations in chemical composition of cementitious composites, i.e. mortar binders. Coal combustion ash was utilized as pozzolanic mineral additive. The binders' mix-design was supplemented with sorptive clays to prevent migration of toxic elements from fly ash. The experiment was established on the premise of clay's ion-exchanging ability. Ten binders comprising cement CEM I 42.5 and fly ash, zeolite and/or bentonite additions were prepared in accordance with chemometric experimental design rules. Chemical composition was determined via XRF method. The changes in mineral phases and crystallinity were traced by X-ray diffraction. Hydration mechanisms and thermal behavior were investigated via DTA/TGA. The chemical bonds were identified by FTIR. Morphology of hardened samples was detected by SEM. Mathematical tools employed data sets of instrumental analyses to form a clear differentiation between binders and to assess changes caused by adoption of mineral additives in the mix designs. Sorptive clays showed pozzolanic behavior, thereby causing no incapacitation to the cement hydration mechanism, and classifying as a possible economical resources which can be used in production technology of construction materials to redeem environmental pollution issues of building industry.
PB  - Elsevier Sci Ltd, Oxford
T2  - Construction and Building Materials
T1  - The effect of alternations in mineral additives (zeolite, bentonite, fly ash) on physico-chemical behavior of Portland cement based binders
EP  - 210
SP  - 199
VL  - 180
DO  - 10.1016/j.conbuildmat.2018.06.007
UR  - conv_829
ER  - 
@article{
author = "Terzić, Anja and Pezo, Lato and Mijatović, Nevenka and Stojanović, Jovica and Kragović, Milan and Milicić, Ljiljana and Andrić, Ljubiša",
year = "2018",
abstract = "Instrumental analyses accompanied by analytical modeling tools were employed to assess physico-chemical changes induced by variations in chemical composition of cementitious composites, i.e. mortar binders. Coal combustion ash was utilized as pozzolanic mineral additive. The binders' mix-design was supplemented with sorptive clays to prevent migration of toxic elements from fly ash. The experiment was established on the premise of clay's ion-exchanging ability. Ten binders comprising cement CEM I 42.5 and fly ash, zeolite and/or bentonite additions were prepared in accordance with chemometric experimental design rules. Chemical composition was determined via XRF method. The changes in mineral phases and crystallinity were traced by X-ray diffraction. Hydration mechanisms and thermal behavior were investigated via DTA/TGA. The chemical bonds were identified by FTIR. Morphology of hardened samples was detected by SEM. Mathematical tools employed data sets of instrumental analyses to form a clear differentiation between binders and to assess changes caused by adoption of mineral additives in the mix designs. Sorptive clays showed pozzolanic behavior, thereby causing no incapacitation to the cement hydration mechanism, and classifying as a possible economical resources which can be used in production technology of construction materials to redeem environmental pollution issues of building industry.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Construction and Building Materials",
title = "The effect of alternations in mineral additives (zeolite, bentonite, fly ash) on physico-chemical behavior of Portland cement based binders",
pages = "210-199",
volume = "180",
doi = "10.1016/j.conbuildmat.2018.06.007",
url = "conv_829"
}
Terzić, A., Pezo, L., Mijatović, N., Stojanović, J., Kragović, M., Milicić, L.,& Andrić, L.. (2018). The effect of alternations in mineral additives (zeolite, bentonite, fly ash) on physico-chemical behavior of Portland cement based binders. in Construction and Building Materials
Elsevier Sci Ltd, Oxford., 180, 199-210.
https://doi.org/10.1016/j.conbuildmat.2018.06.007
conv_829
Terzić A, Pezo L, Mijatović N, Stojanović J, Kragović M, Milicić L, Andrić L. The effect of alternations in mineral additives (zeolite, bentonite, fly ash) on physico-chemical behavior of Portland cement based binders. in Construction and Building Materials. 2018;180:199-210.
doi:10.1016/j.conbuildmat.2018.06.007
conv_829 .
Terzić, Anja, Pezo, Lato, Mijatović, Nevenka, Stojanović, Jovica, Kragović, Milan, Milicić, Ljiljana, Andrić, Ljubiša, "The effect of alternations in mineral additives (zeolite, bentonite, fly ash) on physico-chemical behavior of Portland cement based binders" in Construction and Building Materials, 180 (2018):199-210,
https://doi.org/10.1016/j.conbuildmat.2018.06.007 .,
conv_829 .
34
22
37

Microstructure and Phase Composition Of Steatite Ceramics Sintered by Traditional and Spark Plasma Sintering

Terzić, Anja; Obradović, Nina; Pouchly, Vaclav; Stojanović, Jovica; Maca, Karel; Pavlović, Vladimir B.

(Međunarodni Institut za nauku o sinterovanju, Beograd, 2018)

TY  - JOUR
AU  - Terzić, Anja
AU  - Obradović, Nina
AU  - Pouchly, Vaclav
AU  - Stojanović, Jovica
AU  - Maca, Karel
AU  - Pavlović, Vladimir B.
PY  - 2018
UR  - https://ritnms.itnms.ac.rs/handle/123456789/460
AB  - The influence of the sintering method on the mineral phase transformations and development of the crystalline microstructure of steatite ceramics was investigated. The steatite samples were fabricated from talc and bentonite as low-cost raw materials. Feldspar and barium carbonate, as fluxing agents, were altered in the steatite composition. Dilatometric analysis was applied in the monitoring of the dimensional changes and thereby densification of steatite during the traditional sintering (TS) procedure up to 1200 degrees C. Spark plasma sintering (SPS) method was used under the following sintering conditions: 100 degrees C/min heating rate, uniaxial pressure of 50 MPa; sintering temperature 800 degrees C/1 min or 1000 degrees C/2 min. Crystallinity changes and mineral phase transition during sintering were observed by X-ray diffraction technique. Microstructural visualization of the samples and the spatial arrangements of individual chemical elements were achieved via scanning electron microscopy equipped with the EDS mapping. It was found that SPS sintering facilitated all microstructural changes during high temperature treatment and shifted them to lower temperatures. SPS treatment conducted at 1000 degrees C resulted in maximum densification of the steatite powder compacts and the formation stabilized protoenstatite structure.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - Microstructure and Phase Composition Of Steatite Ceramics Sintered by Traditional and Spark Plasma Sintering
EP  - 312
IS  - 3
SP  - 299
VL  - 50
DO  - 10.2298/SOS1803299T
UR  - conv_838
ER  - 
@article{
author = "Terzić, Anja and Obradović, Nina and Pouchly, Vaclav and Stojanović, Jovica and Maca, Karel and Pavlović, Vladimir B.",
year = "2018",
abstract = "The influence of the sintering method on the mineral phase transformations and development of the crystalline microstructure of steatite ceramics was investigated. The steatite samples were fabricated from talc and bentonite as low-cost raw materials. Feldspar and barium carbonate, as fluxing agents, were altered in the steatite composition. Dilatometric analysis was applied in the monitoring of the dimensional changes and thereby densification of steatite during the traditional sintering (TS) procedure up to 1200 degrees C. Spark plasma sintering (SPS) method was used under the following sintering conditions: 100 degrees C/min heating rate, uniaxial pressure of 50 MPa; sintering temperature 800 degrees C/1 min or 1000 degrees C/2 min. Crystallinity changes and mineral phase transition during sintering were observed by X-ray diffraction technique. Microstructural visualization of the samples and the spatial arrangements of individual chemical elements were achieved via scanning electron microscopy equipped with the EDS mapping. It was found that SPS sintering facilitated all microstructural changes during high temperature treatment and shifted them to lower temperatures. SPS treatment conducted at 1000 degrees C resulted in maximum densification of the steatite powder compacts and the formation stabilized protoenstatite structure.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "Microstructure and Phase Composition Of Steatite Ceramics Sintered by Traditional and Spark Plasma Sintering",
pages = "312-299",
number = "3",
volume = "50",
doi = "10.2298/SOS1803299T",
url = "conv_838"
}
Terzić, A., Obradović, N., Pouchly, V., Stojanović, J., Maca, K.,& Pavlović, V. B.. (2018). Microstructure and Phase Composition Of Steatite Ceramics Sintered by Traditional and Spark Plasma Sintering. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 50(3), 299-312.
https://doi.org/10.2298/SOS1803299T
conv_838
Terzić A, Obradović N, Pouchly V, Stojanović J, Maca K, Pavlović VB. Microstructure and Phase Composition Of Steatite Ceramics Sintered by Traditional and Spark Plasma Sintering. in Science of Sintering. 2018;50(3):299-312.
doi:10.2298/SOS1803299T
conv_838 .
Terzić, Anja, Obradović, Nina, Pouchly, Vaclav, Stojanović, Jovica, Maca, Karel, Pavlović, Vladimir B., "Microstructure and Phase Composition Of Steatite Ceramics Sintered by Traditional and Spark Plasma Sintering" in Science of Sintering, 50, no. 3 (2018):299-312,
https://doi.org/10.2298/SOS1803299T .,
conv_838 .
6
3
5

Effects of different sintering routes on the properties of steatite-based ceramics

Terzić, Anja; Obradović, Nina; Pouchly, Vaclav; Maca, Karel; Radulović, Dragan; Andrić, Ljubiša

(Bor : University of Belgrade, Technical Faculty in Bor, 2017)

TY  - CONF
AU  - Terzić, Anja
AU  - Obradović, Nina
AU  - Pouchly, Vaclav
AU  - Maca, Karel
AU  - Radulović, Dragan
AU  - Andrić, Ljubiša
PY  - 2017
UR  - https://ritnms.itnms.ac.rs/handle/123456789/1031
AB  - This study provided insights into relations between sintering mechanism and behavior of two types of steatite-based ceramics. Experimental steatite samples were synthesized from low-cost natural raw materials. The sintering was conducted via dilatometer and SPS method. The thermally induced changes in the steatites and its properties were monitored by instrumental analyses: mineral phase transition was investigated via XRD, and the thermal stability was observed using DTA. The investigation highlighted the optimal combinations of the raw materials for production of the steatite ceramics for advanced electrical engineering applications.
PB  - Bor : University of Belgrade, Technical Faculty in Bor
C3  - 49th International October Conference on Mining and Metallurgy
T1  - Effects of different sintering routes on the properties of steatite-based ceramics
EP  - 197
SP  - 194
ER  - 
@conference{
author = "Terzić, Anja and Obradović, Nina and Pouchly, Vaclav and Maca, Karel and Radulović, Dragan and Andrić, Ljubiša",
year = "2017",
abstract = "This study provided insights into relations between sintering mechanism and behavior of two types of steatite-based ceramics. Experimental steatite samples were synthesized from low-cost natural raw materials. The sintering was conducted via dilatometer and SPS method. The thermally induced changes in the steatites and its properties were monitored by instrumental analyses: mineral phase transition was investigated via XRD, and the thermal stability was observed using DTA. The investigation highlighted the optimal combinations of the raw materials for production of the steatite ceramics for advanced electrical engineering applications.",
publisher = "Bor : University of Belgrade, Technical Faculty in Bor",
journal = "49th International October Conference on Mining and Metallurgy",
title = "Effects of different sintering routes on the properties of steatite-based ceramics",
pages = "197-194"
}
Terzić, A., Obradović, N., Pouchly, V., Maca, K., Radulović, D.,& Andrić, L.. (2017). Effects of different sintering routes on the properties of steatite-based ceramics. in 49th International October Conference on Mining and Metallurgy
Bor : University of Belgrade, Technical Faculty in Bor., 194-197.
Terzić A, Obradović N, Pouchly V, Maca K, Radulović D, Andrić L. Effects of different sintering routes on the properties of steatite-based ceramics. in 49th International October Conference on Mining and Metallurgy. 2017;:194-197..
Terzić, Anja, Obradović, Nina, Pouchly, Vaclav, Maca, Karel, Radulović, Dragan, Andrić, Ljubiša, "Effects of different sintering routes on the properties of steatite-based ceramics" in 49th International October Conference on Mining and Metallurgy (2017):194-197.

The construction and ceramics industry waste gypsum valorization possibilities

Radulović, Dragan; Terzić, Anja; Andrić, Ljubiša

(Paris : Atlantis Press, 2017)

TY  - CHAP
AU  - Radulović, Dragan
AU  - Terzić, Anja
AU  - Andrić, Ljubiša
PY  - 2017
UR  - https://ritnms.itnms.ac.rs/handle/123456789/1087
AB  - The construction work and ceramic materials industry debris is an important source of waste that ends up unused and disposed on municipal solid waste landfills. Besides concrete and clay based materials, gypsum waste is one of the larger contributors to the building and industry byproducts production chain. The possibilities of waste gypsum revitalization and reutilization in the ceramic industry and civil engineering are investigated in this paper. The gypsum in its dihydrate form is used for moulds in the production of ceramic cast materials. The interest in recovering gypsum waste is increasing as the demand for sustainable production grows. Before secondary gypsum is reapplied, its properties and the recycling process have to be technically and environmentally evaluated. By recy- cling gypsum waste, natural gypsum deposits are being preserved. Furthermore, large percentage of this byproduct achieves its reutilization potential. In this con- text, this paper investigates physical properties, the chemical composition and the thermal behavior of the waste gypsum. The goal is to assess the feasibility of using waste gypsum and to evaluate the viability of the recycling process. The results indicate that the reutilization of gypsum waste might provide a viable substitute for clay in the ceramics industry. Reapplication of the revitalized secondary gypsum is approved from both economical and environmental aspect.
PB  - Paris : Atlantis Press
T2  - IV Advanced Ceramics and Applications Conference
T1  - The construction and ceramics industry waste gypsum valorization possibilities
EP  - 491
SP  - 475
DO  - 10.2991/978-94-6239-213-7
ER  - 
@inbook{
author = "Radulović, Dragan and Terzić, Anja and Andrić, Ljubiša",
year = "2017",
abstract = "The construction work and ceramic materials industry debris is an important source of waste that ends up unused and disposed on municipal solid waste landfills. Besides concrete and clay based materials, gypsum waste is one of the larger contributors to the building and industry byproducts production chain. The possibilities of waste gypsum revitalization and reutilization in the ceramic industry and civil engineering are investigated in this paper. The gypsum in its dihydrate form is used for moulds in the production of ceramic cast materials. The interest in recovering gypsum waste is increasing as the demand for sustainable production grows. Before secondary gypsum is reapplied, its properties and the recycling process have to be technically and environmentally evaluated. By recy- cling gypsum waste, natural gypsum deposits are being preserved. Furthermore, large percentage of this byproduct achieves its reutilization potential. In this con- text, this paper investigates physical properties, the chemical composition and the thermal behavior of the waste gypsum. The goal is to assess the feasibility of using waste gypsum and to evaluate the viability of the recycling process. The results indicate that the reutilization of gypsum waste might provide a viable substitute for clay in the ceramics industry. Reapplication of the revitalized secondary gypsum is approved from both economical and environmental aspect.",
publisher = "Paris : Atlantis Press",
journal = "IV Advanced Ceramics and Applications Conference",
booktitle = "The construction and ceramics industry waste gypsum valorization possibilities",
pages = "491-475",
doi = "10.2991/978-94-6239-213-7"
}
Radulović, D., Terzić, A.,& Andrić, L.. (2017). The construction and ceramics industry waste gypsum valorization possibilities. in IV Advanced Ceramics and Applications Conference
Paris : Atlantis Press., 475-491.
https://doi.org/10.2991/978-94-6239-213-7
Radulović D, Terzić A, Andrić L. The construction and ceramics industry waste gypsum valorization possibilities. in IV Advanced Ceramics and Applications Conference. 2017;:475-491.
doi:10.2991/978-94-6239-213-7 .
Radulović, Dragan, Terzić, Anja, Andrić, Ljubiša, "The construction and ceramics industry waste gypsum valorization possibilities" in IV Advanced Ceramics and Applications Conference (2017):475-491,
https://doi.org/10.2991/978-94-6239-213-7 . .
10

A Kinetic Study of Limestone Dry Micronization in an Ultra-Centrifugal Mill with Peripheral Comminuting Path

Radulović, Dragan; Božović, Darko; Terzić, Anja; Trumić, M. S.; Simić, Vladimir; Andrić, Ljubiša

(Goller Verlag Gmbh, Baden Baden, 2017)

TY  - JOUR
AU  - Radulović, Dragan
AU  - Božović, Darko
AU  - Terzić, Anja
AU  - Trumić, M. S.
AU  - Simić, Vladimir
AU  - Andrić, Ljubiša
PY  - 2017
UR  - https://ritnms.itnms.ac.rs/handle/123456789/440
AB  - Because of its physico-mechanical and physico-chemical characteristics, fine-ground (i.e. micronized) limestone is widely applied in the production of new materials. Limestone can be used as a filler, coating and/or powder in ceramic composites. The effect of its fine micronization depends on the type of equipment used and on the disintegration process. In this study, the emphasis was placed on investigation of the kinetics of the dry micronization milling of limestone in a state-of-the-art ultra-centrifugal mill with a peripheral comminuting path. The efficiency of the ultra-centrifugal mill with a peripheral comminuting path was determined based on a detailed investigation of the limestone dry micronization, which satisfied all the requirements for technological parameters as well as for micronized product parameters. On the basis of the investigation of these parameters and theory of dry micronization conducted in a state-of-the-art mill with use of advanced instrumental techniques for determination and observation of the most significant physical and chemical characteristics, a kinetics model was developed to serve as the basis for quick and effective determination of micronization quality and efficiency. In this paper, the results of grinding in a Retsch ZM-1 ultra-centrifugal mill were analyzed in order to optimize and automate the process of ultrafine micronization.
PB  - Goller Verlag Gmbh, Baden Baden
T2  - Journal of Ceramic Science and Technology
T1  - A Kinetic Study of Limestone Dry Micronization in an Ultra-Centrifugal Mill with Peripheral Comminuting Path
EP  - 304
IS  - 2
SP  - 295
VL  - 8
DO  - 10.4416/JCST2017-00022
UR  - conv_799
ER  - 
@article{
author = "Radulović, Dragan and Božović, Darko and Terzić, Anja and Trumić, M. S. and Simić, Vladimir and Andrić, Ljubiša",
year = "2017",
abstract = "Because of its physico-mechanical and physico-chemical characteristics, fine-ground (i.e. micronized) limestone is widely applied in the production of new materials. Limestone can be used as a filler, coating and/or powder in ceramic composites. The effect of its fine micronization depends on the type of equipment used and on the disintegration process. In this study, the emphasis was placed on investigation of the kinetics of the dry micronization milling of limestone in a state-of-the-art ultra-centrifugal mill with a peripheral comminuting path. The efficiency of the ultra-centrifugal mill with a peripheral comminuting path was determined based on a detailed investigation of the limestone dry micronization, which satisfied all the requirements for technological parameters as well as for micronized product parameters. On the basis of the investigation of these parameters and theory of dry micronization conducted in a state-of-the-art mill with use of advanced instrumental techniques for determination and observation of the most significant physical and chemical characteristics, a kinetics model was developed to serve as the basis for quick and effective determination of micronization quality and efficiency. In this paper, the results of grinding in a Retsch ZM-1 ultra-centrifugal mill were analyzed in order to optimize and automate the process of ultrafine micronization.",
publisher = "Goller Verlag Gmbh, Baden Baden",
journal = "Journal of Ceramic Science and Technology",
title = "A Kinetic Study of Limestone Dry Micronization in an Ultra-Centrifugal Mill with Peripheral Comminuting Path",
pages = "304-295",
number = "2",
volume = "8",
doi = "10.4416/JCST2017-00022",
url = "conv_799"
}
Radulović, D., Božović, D., Terzić, A., Trumić, M. S., Simić, V.,& Andrić, L.. (2017). A Kinetic Study of Limestone Dry Micronization in an Ultra-Centrifugal Mill with Peripheral Comminuting Path. in Journal of Ceramic Science and Technology
Goller Verlag Gmbh, Baden Baden., 8(2), 295-304.
https://doi.org/10.4416/JCST2017-00022
conv_799
Radulović D, Božović D, Terzić A, Trumić MS, Simić V, Andrić L. A Kinetic Study of Limestone Dry Micronization in an Ultra-Centrifugal Mill with Peripheral Comminuting Path. in Journal of Ceramic Science and Technology. 2017;8(2):295-304.
doi:10.4416/JCST2017-00022
conv_799 .
Radulović, Dragan, Božović, Darko, Terzić, Anja, Trumić, M. S., Simić, Vladimir, Andrić, Ljubiša, "A Kinetic Study of Limestone Dry Micronization in an Ultra-Centrifugal Mill with Peripheral Comminuting Path" in Journal of Ceramic Science and Technology, 8, no. 2 (2017):295-304,
https://doi.org/10.4416/JCST2017-00022 .,
conv_799 .

The Chemometric Study of Limestone Physico-chemical Properties and Thermal Behavior for Application in Construction Composites

Radulović, Dragan; Terzić, Anja; Pezo, Lato; Andrić, Ljubiša; Grigorova, Irena

(Međunarodni Institut za nauku o sinterovanju, Beograd, 2017)

TY  - JOUR
AU  - Radulović, Dragan
AU  - Terzić, Anja
AU  - Pezo, Lato
AU  - Andrić, Ljubiša
AU  - Grigorova, Irena
PY  - 2017
UR  - https://ritnms.itnms.ac.rs/handle/123456789/435
AB  - The limestone, as an economically sustainable and easily available basic raw material, is frequently utilized in the building industry for resolving of the environmental protection issues. The limestone is incorporated in a cementitious system either by grinding with cement clinker, or by blending with the binder during concrete production. The employing of powdery limestone as partial cement replacement gives the construction composites with properties comparable to that of conventional concrete. The study of limestone thermal behavior and its chemistry is crucial for the prognosis of the designed composites properties. In this work, the instrumental techniques (atomic emission spectroscopy, differential thermal and thermo-gravimetric analysis, Fourier transform infrared spectroscopy) and the Principal component analysis were employed to discriminate and classify 22 limestone types. The PCA statistical method, as a means of spectra and experimental data fingerprinting, grouped the samples in a multi-dimensional factor space producing four graphical prognosis - one for each instrumental method. DTA/TG peak values varied the most in a short range between 830-870 degrees C, while FTIR spectra showed the highest diversity in the 867-887 cm(-1) and 1237-1647 cm(-1) ranges. This research was governed by an idea to reveal whether it is possible to differentiate various limestone types and to predict the possibility of their employment in construction composites on the basis of the results of instrumental and mathematical analyses.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - The Chemometric Study of Limestone Physico-chemical Properties and Thermal Behavior for Application in Construction Composites
EP  - 261
IS  - 3
SP  - 247
VL  - 49
DO  - 10.2298/SOS1703247R
UR  - conv_807
ER  - 
@article{
author = "Radulović, Dragan and Terzić, Anja and Pezo, Lato and Andrić, Ljubiša and Grigorova, Irena",
year = "2017",
abstract = "The limestone, as an economically sustainable and easily available basic raw material, is frequently utilized in the building industry for resolving of the environmental protection issues. The limestone is incorporated in a cementitious system either by grinding with cement clinker, or by blending with the binder during concrete production. The employing of powdery limestone as partial cement replacement gives the construction composites with properties comparable to that of conventional concrete. The study of limestone thermal behavior and its chemistry is crucial for the prognosis of the designed composites properties. In this work, the instrumental techniques (atomic emission spectroscopy, differential thermal and thermo-gravimetric analysis, Fourier transform infrared spectroscopy) and the Principal component analysis were employed to discriminate and classify 22 limestone types. The PCA statistical method, as a means of spectra and experimental data fingerprinting, grouped the samples in a multi-dimensional factor space producing four graphical prognosis - one for each instrumental method. DTA/TG peak values varied the most in a short range between 830-870 degrees C, while FTIR spectra showed the highest diversity in the 867-887 cm(-1) and 1237-1647 cm(-1) ranges. This research was governed by an idea to reveal whether it is possible to differentiate various limestone types and to predict the possibility of their employment in construction composites on the basis of the results of instrumental and mathematical analyses.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "The Chemometric Study of Limestone Physico-chemical Properties and Thermal Behavior for Application in Construction Composites",
pages = "261-247",
number = "3",
volume = "49",
doi = "10.2298/SOS1703247R",
url = "conv_807"
}
Radulović, D., Terzić, A., Pezo, L., Andrić, L.,& Grigorova, I.. (2017). The Chemometric Study of Limestone Physico-chemical Properties and Thermal Behavior for Application in Construction Composites. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 49(3), 247-261.
https://doi.org/10.2298/SOS1703247R
conv_807
Radulović D, Terzić A, Pezo L, Andrić L, Grigorova I. The Chemometric Study of Limestone Physico-chemical Properties and Thermal Behavior for Application in Construction Composites. in Science of Sintering. 2017;49(3):247-261.
doi:10.2298/SOS1703247R
conv_807 .
Radulović, Dragan, Terzić, Anja, Pezo, Lato, Andrić, Ljubiša, Grigorova, Irena, "The Chemometric Study of Limestone Physico-chemical Properties and Thermal Behavior for Application in Construction Composites" in Science of Sintering, 49, no. 3 (2017):247-261,
https://doi.org/10.2298/SOS1703247R .,
conv_807 .
6
5
7

Influence of different bonding and fluxing agents on the sintering behavior and dielectric properties of steatite ceramic materials

Terzić, Anja; Obradović, Nina; Stojanović, Jovica; Pavlović, Vladimir; Andrić, Ljubiša; Olcan, Dragan; Đorđević, Antonije

(Elsevier Sci Ltd, Oxford, 2017)

TY  - JOUR
AU  - Terzić, Anja
AU  - Obradović, Nina
AU  - Stojanović, Jovica
AU  - Pavlović, Vladimir
AU  - Andrić, Ljubiša
AU  - Olcan, Dragan
AU  - Đorđević, Antonije
PY  - 2017
UR  - https://ritnms.itnms.ac.rs/handle/123456789/432
AB  - The focus of the study was on providing insights into interconnections between sintering and development of the crystalline microstructure, and consequently variations in dielectric behavior of four steatites fabricated from a low-cost raw material, i.e. talc. The changes, induced by the alternations of the binders (bentonite, kaolin clay) and fluxing agents (BaCO3, feldspar), were monitored in the temperature range 1000 degrees to 1250 degrees C in which complete densification and re-crystallization of the investigated structures were accomplished. The critical points in the synthesis of steatite materials were assessed by instrumental analyses. Crystallinity changes and mineral phase transition during sintering were monitored by X-ray diffraction technique. Microstructural visualization of the samples and the spatial arrangements of individual chemical elements were achieved via scanning electron microscopy accompanied with EDS mapping. The thermal stability was observed on the green mixtures using differential thermal and thermo gravimetric analyses. Electrical measurements recorded variations of the dielectric constant (epsilon(r)) and loss tangent (tan delta) as a function of the sintering temperature. The investigation highlighted critical design points, as well as the optimal combinations of the raw materials for production of the steatite ceramics for advanced electrical engineering applications.
PB  - Elsevier Sci Ltd, Oxford
T2  - Ceramics International
T1  - Influence of different bonding and fluxing agents on the sintering behavior and dielectric properties of steatite ceramic materials
EP  - 13275
IS  - 16
SP  - 13264
VL  - 43
DO  - 10.1016/j.ceramint.2017.07.024
UR  - conv_806
ER  - 
@article{
author = "Terzić, Anja and Obradović, Nina and Stojanović, Jovica and Pavlović, Vladimir and Andrić, Ljubiša and Olcan, Dragan and Đorđević, Antonije",
year = "2017",
abstract = "The focus of the study was on providing insights into interconnections between sintering and development of the crystalline microstructure, and consequently variations in dielectric behavior of four steatites fabricated from a low-cost raw material, i.e. talc. The changes, induced by the alternations of the binders (bentonite, kaolin clay) and fluxing agents (BaCO3, feldspar), were monitored in the temperature range 1000 degrees to 1250 degrees C in which complete densification and re-crystallization of the investigated structures were accomplished. The critical points in the synthesis of steatite materials were assessed by instrumental analyses. Crystallinity changes and mineral phase transition during sintering were monitored by X-ray diffraction technique. Microstructural visualization of the samples and the spatial arrangements of individual chemical elements were achieved via scanning electron microscopy accompanied with EDS mapping. The thermal stability was observed on the green mixtures using differential thermal and thermo gravimetric analyses. Electrical measurements recorded variations of the dielectric constant (epsilon(r)) and loss tangent (tan delta) as a function of the sintering temperature. The investigation highlighted critical design points, as well as the optimal combinations of the raw materials for production of the steatite ceramics for advanced electrical engineering applications.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Ceramics International",
title = "Influence of different bonding and fluxing agents on the sintering behavior and dielectric properties of steatite ceramic materials",
pages = "13275-13264",
number = "16",
volume = "43",
doi = "10.1016/j.ceramint.2017.07.024",
url = "conv_806"
}
Terzić, A., Obradović, N., Stojanović, J., Pavlović, V., Andrić, L., Olcan, D.,& Đorđević, A.. (2017). Influence of different bonding and fluxing agents on the sintering behavior and dielectric properties of steatite ceramic materials. in Ceramics International
Elsevier Sci Ltd, Oxford., 43(16), 13264-13275.
https://doi.org/10.1016/j.ceramint.2017.07.024
conv_806
Terzić A, Obradović N, Stojanović J, Pavlović V, Andrić L, Olcan D, Đorđević A. Influence of different bonding and fluxing agents on the sintering behavior and dielectric properties of steatite ceramic materials. in Ceramics International. 2017;43(16):13264-13275.
doi:10.1016/j.ceramint.2017.07.024
conv_806 .
Terzić, Anja, Obradović, Nina, Stojanović, Jovica, Pavlović, Vladimir, Andrić, Ljubiša, Olcan, Dragan, Đorđević, Antonije, "Influence of different bonding and fluxing agents on the sintering behavior and dielectric properties of steatite ceramic materials" in Ceramics International, 43, no. 16 (2017):13264-13275,
https://doi.org/10.1016/j.ceramint.2017.07.024 .,
conv_806 .
10
4
10

Sintering of Fly Ash Based Composites with Zeolite and Bentonite Addition for Application in Construction Materials

Terzić, Anja; Đorđević, Nataša; Mitrić, Miodrag; Marković, Smilja; Đorđević, Katarina; Pavlović, Vladimir B.

(Međunarodni Institut za nauku o sinterovanju, Beograd, 2017)

TY  - JOUR
AU  - Terzić, Anja
AU  - Đorđević, Nataša
AU  - Mitrić, Miodrag
AU  - Marković, Smilja
AU  - Đorđević, Katarina
AU  - Pavlović, Vladimir B.
PY  - 2017
UR  - https://ritnms.itnms.ac.rs/handle/123456789/452
AB  - Due to pozzolanic characteristics, fly ash is commonly used as a cement replacement in construction composites. Addition of natural clays with sorption ability (i.e. zeolite and bentonite) in to the fly ash based construction materials is of both scientific and industrial interest. Namely, due to the application of sorptive clay minerals, it is possible to immobilize toxic heavy metals from the composite structure. The thermal compatibility of fly ash and zeolite, as well as fly ash and bentonite, within the composite was observed during sintering procedure. The starting components were used in 1: 1 ratio and they were applied without additional mechanical treatment. The used compaction pressure for the tablets was 2 t.cm(-2). The sintering process was conducted at 1000 degrees C and 1200 degrees C for two hours in the air atmosphere. The mineralogical phase composition of the non-treated and sintered samples was analyzed using X-ray diffraction method. Scanning electron microscopy was applied in the analysis of the microstructure of starting and sintered samples. The thermal behavior was observed via DTA method. The influence of temperature on the properties of fly ash-zeolite and fly ash-bentonite composites was investigated.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - Sintering of Fly Ash Based Composites with Zeolite and Bentonite Addition for Application in Construction Materials
EP  - 37
IS  - 1
SP  - 23
VL  - 49
DO  - 10.2298/SOS1701023T
UR  - conv_791
ER  - 
@article{
author = "Terzić, Anja and Đorđević, Nataša and Mitrić, Miodrag and Marković, Smilja and Đorđević, Katarina and Pavlović, Vladimir B.",
year = "2017",
abstract = "Due to pozzolanic characteristics, fly ash is commonly used as a cement replacement in construction composites. Addition of natural clays with sorption ability (i.e. zeolite and bentonite) in to the fly ash based construction materials is of both scientific and industrial interest. Namely, due to the application of sorptive clay minerals, it is possible to immobilize toxic heavy metals from the composite structure. The thermal compatibility of fly ash and zeolite, as well as fly ash and bentonite, within the composite was observed during sintering procedure. The starting components were used in 1: 1 ratio and they were applied without additional mechanical treatment. The used compaction pressure for the tablets was 2 t.cm(-2). The sintering process was conducted at 1000 degrees C and 1200 degrees C for two hours in the air atmosphere. The mineralogical phase composition of the non-treated and sintered samples was analyzed using X-ray diffraction method. Scanning electron microscopy was applied in the analysis of the microstructure of starting and sintered samples. The thermal behavior was observed via DTA method. The influence of temperature on the properties of fly ash-zeolite and fly ash-bentonite composites was investigated.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "Sintering of Fly Ash Based Composites with Zeolite and Bentonite Addition for Application in Construction Materials",
pages = "37-23",
number = "1",
volume = "49",
doi = "10.2298/SOS1701023T",
url = "conv_791"
}
Terzić, A., Đorđević, N., Mitrić, M., Marković, S., Đorđević, K.,& Pavlović, V. B.. (2017). Sintering of Fly Ash Based Composites with Zeolite and Bentonite Addition for Application in Construction Materials. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 49(1), 23-37.
https://doi.org/10.2298/SOS1701023T
conv_791
Terzić A, Đorđević N, Mitrić M, Marković S, Đorđević K, Pavlović VB. Sintering of Fly Ash Based Composites with Zeolite and Bentonite Addition for Application in Construction Materials. in Science of Sintering. 2017;49(1):23-37.
doi:10.2298/SOS1701023T
conv_791 .
Terzić, Anja, Đorđević, Nataša, Mitrić, Miodrag, Marković, Smilja, Đorđević, Katarina, Pavlović, Vladimir B., "Sintering of Fly Ash Based Composites with Zeolite and Bentonite Addition for Application in Construction Materials" in Science of Sintering, 49, no. 1 (2017):23-37,
https://doi.org/10.2298/SOS1701023T .,
conv_791 .
5
12
13

The effect of mechano-chemical activation and surface treatment of limestone filler on the properties of construction composites

Terzić, Anja; Radulović, Dragan; Pezo, Lato; Andrić, Ljubiša; Milicić, Ljiljana; Stojanović, Jovica; Grigorova, Irena

(Elsevier Sci Ltd, Oxford, 2017)

TY  - JOUR
AU  - Terzić, Anja
AU  - Radulović, Dragan
AU  - Pezo, Lato
AU  - Andrić, Ljubiša
AU  - Milicić, Ljiljana
AU  - Stojanović, Jovica
AU  - Grigorova, Irena
PY  - 2017
UR  - https://ritnms.itnms.ac.rs/handle/123456789/454
AB  - The effect of the combined actions of milling and hydrophobization procedures applied in construction composites synthesis was investigated. The mortars were prepared with cement (CEM I 42.5) and calcite aggregate complying the standard 1:3 mix ratio. The limestone filler (10 wt%) was added to the mixture upon its mechano-chemical activation in an ultra-centrifugal mill. The activation variables (milling time, rotor velocity, sieve mesh size) were altered to achieve the optimal quality of the powder. The treatment was optimized via chemometric tools. The r(2) values (0.955-0.998) of second order polynomial models accurately predicted the output and the Standard score analysis chose the optimal activation parameters: 4.25 min; 48.58 m/s and 80 gm sieve. The selected filler and all three aggregate fractions were coated with stearic acid via dry procedure. The mortar mixes, prepared with uncoated (M1) and coated (M2) aggregate and filler, were cured for a period of 28 days during which compressive strength and water absorption were monitored. The dimensional changes in mortars were estimated via TMA dilatometer measurements. Thermo-analytical methods (DTA/TGA) were applied in the thermal behavior analysis. Mineralogical and morphological changes in the structure of hardened composite were detected by XRD and SEM, respectively. Limestone aggregate led to lower final compressive strengths in mortar, but it produced an infinitesimally small shrinkage at 1000 degrees C. The hydrophobization via stearic acid initiated the decrease in water absorption and formation of needle-like micro-network that filled structural voids reducing open porosity. The assessment of the effects of limestone utilization as a filler and as an aggregate on the mortar performances confirmed that this novel water-repellent composite is applicable in structural design.
PB  - Elsevier Sci Ltd, Oxford
T2  - Composites Part B-Engineering
T1  - The effect of mechano-chemical activation and surface treatment of limestone filler on the properties of construction composites
EP  - 73
SP  - 61
VL  - 117
DO  - 10.1016/j.compositesb.2017.02.041
UR  - conv_794
ER  - 
@article{
author = "Terzić, Anja and Radulović, Dragan and Pezo, Lato and Andrić, Ljubiša and Milicić, Ljiljana and Stojanović, Jovica and Grigorova, Irena",
year = "2017",
abstract = "The effect of the combined actions of milling and hydrophobization procedures applied in construction composites synthesis was investigated. The mortars were prepared with cement (CEM I 42.5) and calcite aggregate complying the standard 1:3 mix ratio. The limestone filler (10 wt%) was added to the mixture upon its mechano-chemical activation in an ultra-centrifugal mill. The activation variables (milling time, rotor velocity, sieve mesh size) were altered to achieve the optimal quality of the powder. The treatment was optimized via chemometric tools. The r(2) values (0.955-0.998) of second order polynomial models accurately predicted the output and the Standard score analysis chose the optimal activation parameters: 4.25 min; 48.58 m/s and 80 gm sieve. The selected filler and all three aggregate fractions were coated with stearic acid via dry procedure. The mortar mixes, prepared with uncoated (M1) and coated (M2) aggregate and filler, were cured for a period of 28 days during which compressive strength and water absorption were monitored. The dimensional changes in mortars were estimated via TMA dilatometer measurements. Thermo-analytical methods (DTA/TGA) were applied in the thermal behavior analysis. Mineralogical and morphological changes in the structure of hardened composite were detected by XRD and SEM, respectively. Limestone aggregate led to lower final compressive strengths in mortar, but it produced an infinitesimally small shrinkage at 1000 degrees C. The hydrophobization via stearic acid initiated the decrease in water absorption and formation of needle-like micro-network that filled structural voids reducing open porosity. The assessment of the effects of limestone utilization as a filler and as an aggregate on the mortar performances confirmed that this novel water-repellent composite is applicable in structural design.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Composites Part B-Engineering",
title = "The effect of mechano-chemical activation and surface treatment of limestone filler on the properties of construction composites",
pages = "73-61",
volume = "117",
doi = "10.1016/j.compositesb.2017.02.041",
url = "conv_794"
}
Terzić, A., Radulović, D., Pezo, L., Andrić, L., Milicić, L., Stojanović, J.,& Grigorova, I.. (2017). The effect of mechano-chemical activation and surface treatment of limestone filler on the properties of construction composites. in Composites Part B-Engineering
Elsevier Sci Ltd, Oxford., 117, 61-73.
https://doi.org/10.1016/j.compositesb.2017.02.041
conv_794
Terzić A, Radulović D, Pezo L, Andrić L, Milicić L, Stojanović J, Grigorova I. The effect of mechano-chemical activation and surface treatment of limestone filler on the properties of construction composites. in Composites Part B-Engineering. 2017;117:61-73.
doi:10.1016/j.compositesb.2017.02.041
conv_794 .
Terzić, Anja, Radulović, Dragan, Pezo, Lato, Andrić, Ljubiša, Milicić, Ljiljana, Stojanović, Jovica, Grigorova, Irena, "The effect of mechano-chemical activation and surface treatment of limestone filler on the properties of construction composites" in Composites Part B-Engineering, 117 (2017):61-73,
https://doi.org/10.1016/j.compositesb.2017.02.041 .,
conv_794 .
11
9
12

The effects of the phosphates mechanical activation

Andrić, Ljubiša; Terzić, Anja; Pašalić, Snežana; Petrov, Milan

(Paris : Atlantis Press, 2016)

TY  - CHAP
AU  - Andrić, Ljubiša
AU  - Terzić, Anja
AU  - Pašalić, Snežana
AU  - Petrov, Milan
PY  - 2016
UR  - https://ritnms.itnms.ac.rs/handle/123456789/1093
AB  - The investigation was conducted with an aim to increase the reactivity of the comminuted phosphate ore and to establish the optimal mechanical activation period of the grain mixture. In order to obtain complete insight into the process and phenomena of the phosphate grain mixture activation, a good understanding of the theoretical principles of the activation operation is necessary. In the experiments, the vibratory and planetary mills were used as activators. The obtained results pointed out that both amorphous and crystallized forms appeared within the Lisina ore deposit mixture due to the specific genetic conditions which rarely occur in the deposits. Such a heterogenic composition of the useful phosphoric part of the ore gave a variety of the results during the leaching. For the first time, the experiments of phosphate (apatite) mechanochemical activation from Lisina ore deposit were performed in order to improve its reactivity.
PB  - Paris : Atlantis Press
T2  - III Advanced Ceramics and Applications Conference
T1  - The effects of the phosphates mechanical activation
EP  - 352
SP  - 339
DO  - 10.2991/978-94-6239-157-4_23
ER  - 
@inbook{
author = "Andrić, Ljubiša and Terzić, Anja and Pašalić, Snežana and Petrov, Milan",
year = "2016",
abstract = "The investigation was conducted with an aim to increase the reactivity of the comminuted phosphate ore and to establish the optimal mechanical activation period of the grain mixture. In order to obtain complete insight into the process and phenomena of the phosphate grain mixture activation, a good understanding of the theoretical principles of the activation operation is necessary. In the experiments, the vibratory and planetary mills were used as activators. The obtained results pointed out that both amorphous and crystallized forms appeared within the Lisina ore deposit mixture due to the specific genetic conditions which rarely occur in the deposits. Such a heterogenic composition of the useful phosphoric part of the ore gave a variety of the results during the leaching. For the first time, the experiments of phosphate (apatite) mechanochemical activation from Lisina ore deposit were performed in order to improve its reactivity.",
publisher = "Paris : Atlantis Press",
journal = "III Advanced Ceramics and Applications Conference",
booktitle = "The effects of the phosphates mechanical activation",
pages = "352-339",
doi = "10.2991/978-94-6239-157-4_23"
}
Andrić, L., Terzić, A., Pašalić, S.,& Petrov, M.. (2016). The effects of the phosphates mechanical activation. in III Advanced Ceramics and Applications Conference
Paris : Atlantis Press., 339-352.
https://doi.org/10.2991/978-94-6239-157-4_23
Andrić L, Terzić A, Pašalić S, Petrov M. The effects of the phosphates mechanical activation. in III Advanced Ceramics and Applications Conference. 2016;:339-352.
doi:10.2991/978-94-6239-157-4_23 .
Andrić, Ljubiša, Terzić, Anja, Pašalić, Snežana, Petrov, Milan, "The effects of the phosphates mechanical activation" in III Advanced Ceramics and Applications Conference (2016):339-352,
https://doi.org/10.2991/978-94-6239-157-4_23 . .

Reaction kinetics of mechanically activated cordierite-based ceramics studied via DTA

Obradović, Nina; Đorđević, Nataša; Filipović, Suzana; Marković, Smilja; Kosanović, Darko; Mitrić, Miodrag; Pavlović, Vladimir

(Springer, Dordrecht, 2016)

TY  - JOUR
AU  - Obradović, Nina
AU  - Đorđević, Nataša
AU  - Filipović, Suzana
AU  - Marković, Smilja
AU  - Kosanović, Darko
AU  - Mitrić, Miodrag
AU  - Pavlović, Vladimir
PY  - 2016
UR  - https://ritnms.itnms.ac.rs/handle/123456789/410
AB  - Since cordierite, 2MgO center dot 2Al(2)O(3)center dot 5SiO(2) (MAS), is a very useful high-temperature ceramic material, it is important to decrease its sintering temperature. In order to accelerate the process of sintering, 5.00 mass% MoO3 was added to the starting mixtures. The mechanical activation of the starting mixtures was performed in a high-energy ball mill in time intervals from 0 to 160 min. After the activation, starting mixtures were sintered at 1300 A degrees C for 2 h. In order to determine the impact of mechanical activation on particle size distribution and powders morphology, the mechanically treated powders were characterized by a laser light-scattering particle size analyzer and scanning electron microscopy. The phase composition of the starting mixtures and sintered samples was analyzed by the X-ray diffraction method. In order to determine temperature intervals of chemical reactions and phase transitions, differential thermal analyses (DTA) and thermo-gravimetric analysis were used. Kissinger's equation was employed to calculate apparent activation energies of various processes that occur within the system during heating. Based on the obtained DTA results, it was established that mechanical activation along with MoO3 additive has influence on sintering temperature which was decreased for more than 100 A degrees C, comparing to the literature data.
PB  - Springer, Dordrecht
T2  - Journal of Thermal Analysis and Calorimetry
T1  - Reaction kinetics of mechanically activated cordierite-based ceramics studied via DTA
EP  - 673
IS  - 2
SP  - 667
VL  - 124
DO  - 10.1007/s10973-015-5132-9
UR  - conv_757
ER  - 
@article{
author = "Obradović, Nina and Đorđević, Nataša and Filipović, Suzana and Marković, Smilja and Kosanović, Darko and Mitrić, Miodrag and Pavlović, Vladimir",
year = "2016",
abstract = "Since cordierite, 2MgO center dot 2Al(2)O(3)center dot 5SiO(2) (MAS), is a very useful high-temperature ceramic material, it is important to decrease its sintering temperature. In order to accelerate the process of sintering, 5.00 mass% MoO3 was added to the starting mixtures. The mechanical activation of the starting mixtures was performed in a high-energy ball mill in time intervals from 0 to 160 min. After the activation, starting mixtures were sintered at 1300 A degrees C for 2 h. In order to determine the impact of mechanical activation on particle size distribution and powders morphology, the mechanically treated powders were characterized by a laser light-scattering particle size analyzer and scanning electron microscopy. The phase composition of the starting mixtures and sintered samples was analyzed by the X-ray diffraction method. In order to determine temperature intervals of chemical reactions and phase transitions, differential thermal analyses (DTA) and thermo-gravimetric analysis were used. Kissinger's equation was employed to calculate apparent activation energies of various processes that occur within the system during heating. Based on the obtained DTA results, it was established that mechanical activation along with MoO3 additive has influence on sintering temperature which was decreased for more than 100 A degrees C, comparing to the literature data.",
publisher = "Springer, Dordrecht",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "Reaction kinetics of mechanically activated cordierite-based ceramics studied via DTA",
pages = "673-667",
number = "2",
volume = "124",
doi = "10.1007/s10973-015-5132-9",
url = "conv_757"
}
Obradović, N., Đorđević, N., Filipović, S., Marković, S., Kosanović, D., Mitrić, M.,& Pavlović, V.. (2016). Reaction kinetics of mechanically activated cordierite-based ceramics studied via DTA. in Journal of Thermal Analysis and Calorimetry
Springer, Dordrecht., 124(2), 667-673.
https://doi.org/10.1007/s10973-015-5132-9
conv_757
Obradović N, Đorđević N, Filipović S, Marković S, Kosanović D, Mitrić M, Pavlović V. Reaction kinetics of mechanically activated cordierite-based ceramics studied via DTA. in Journal of Thermal Analysis and Calorimetry. 2016;124(2):667-673.
doi:10.1007/s10973-015-5132-9
conv_757 .
Obradović, Nina, Đorđević, Nataša, Filipović, Suzana, Marković, Smilja, Kosanović, Darko, Mitrić, Miodrag, Pavlović, Vladimir, "Reaction kinetics of mechanically activated cordierite-based ceramics studied via DTA" in Journal of Thermal Analysis and Calorimetry, 124, no. 2 (2016):667-673,
https://doi.org/10.1007/s10973-015-5132-9 .,
conv_757 .
7
8
9

Microstructural and Electrical Properties of Cordierite-based Ceramics Obtained After Two-step Sintering Technique

Obradović, Nina; Filipović, Suzana; Đorđević, Nataša; Kosanović, Darko; Pavlović, Vladimir; Olcan, Dragan; Đorđević, Antonije; Kachlik, Martin; Maca, Karel

(Međunarodni Institut za nauku o sinterovanju, Beograd, 2016)

TY  - JOUR
AU  - Obradović, Nina
AU  - Filipović, Suzana
AU  - Đorđević, Nataša
AU  - Kosanović, Darko
AU  - Pavlović, Vladimir
AU  - Olcan, Dragan
AU  - Đorđević, Antonije
AU  - Kachlik, Martin
AU  - Maca, Karel
PY  - 2016
UR  - https://ritnms.itnms.ac.rs/handle/123456789/395
AB  - Cordierite-based ceramic materials are attracting much interest for their various applications in industry, for manufacturing multilayer circuit boards, catalytic converters, filters, thermal insulation, kiln furniture, components of portable electronic devices, etc. In order to reduce production costs and modify cordierite-based materials, mechanical activation can be used. In this study, microstructural and electrical properties of mechanically activated MgO-Al2O3-SiO2 system have been analyzed. The mixtures of MgO-Al2O3-SiO2 powders were mechanically activated in a planetary ball mill for the time periods from 0 to 160 min. Morphological investigations have been performed on the obtained powders. The effects of activation and two-step sintering process on microstructure were investigated by scanning electron microscopy (SEM). Electrical measurements showed variations of the dielectric constant (epsilon(r)) and loss tangent (tan delta) as a function of time of mechanical treatment.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - Microstructural and Electrical Properties of Cordierite-based Ceramics Obtained After Two-step Sintering Technique
EP  - 165
IS  - 2
SP  - 157
VL  - 48
DO  - 10.2298/SOS1602157O
UR  - https://hdl.handle.net/21.15107/rcub_dais_2314
UR  - conv_766
ER  - 
@article{
author = "Obradović, Nina and Filipović, Suzana and Đorđević, Nataša and Kosanović, Darko and Pavlović, Vladimir and Olcan, Dragan and Đorđević, Antonije and Kachlik, Martin and Maca, Karel",
year = "2016",
abstract = "Cordierite-based ceramic materials are attracting much interest for their various applications in industry, for manufacturing multilayer circuit boards, catalytic converters, filters, thermal insulation, kiln furniture, components of portable electronic devices, etc. In order to reduce production costs and modify cordierite-based materials, mechanical activation can be used. In this study, microstructural and electrical properties of mechanically activated MgO-Al2O3-SiO2 system have been analyzed. The mixtures of MgO-Al2O3-SiO2 powders were mechanically activated in a planetary ball mill for the time periods from 0 to 160 min. Morphological investigations have been performed on the obtained powders. The effects of activation and two-step sintering process on microstructure were investigated by scanning electron microscopy (SEM). Electrical measurements showed variations of the dielectric constant (epsilon(r)) and loss tangent (tan delta) as a function of time of mechanical treatment.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "Microstructural and Electrical Properties of Cordierite-based Ceramics Obtained After Two-step Sintering Technique",
pages = "165-157",
number = "2",
volume = "48",
doi = "10.2298/SOS1602157O",
url = "https://hdl.handle.net/21.15107/rcub_dais_2314, conv_766"
}
Obradović, N., Filipović, S., Đorđević, N., Kosanović, D., Pavlović, V., Olcan, D., Đorđević, A., Kachlik, M.,& Maca, K.. (2016). Microstructural and Electrical Properties of Cordierite-based Ceramics Obtained After Two-step Sintering Technique. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 48(2), 157-165.
https://doi.org/10.2298/SOS1602157O
https://hdl.handle.net/21.15107/rcub_dais_2314
Obradović N, Filipović S, Đorđević N, Kosanović D, Pavlović V, Olcan D, Đorđević A, Kachlik M, Maca K. Microstructural and Electrical Properties of Cordierite-based Ceramics Obtained After Two-step Sintering Technique. in Science of Sintering. 2016;48(2):157-165.
doi:10.2298/SOS1602157O
https://hdl.handle.net/21.15107/rcub_dais_2314 .
Obradović, Nina, Filipović, Suzana, Đorđević, Nataša, Kosanović, Darko, Pavlović, Vladimir, Olcan, Dragan, Đorđević, Antonije, Kachlik, Martin, Maca, Karel, "Microstructural and Electrical Properties of Cordierite-based Ceramics Obtained After Two-step Sintering Technique" in Science of Sintering, 48, no. 2 (2016):157-165,
https://doi.org/10.2298/SOS1602157O .,
https://hdl.handle.net/21.15107/rcub_dais_2314 .
9
12
14

Uticaj mehaničke aktivacije na sistem MgO-Al2O3-SiO2 u prisustvu aditiva TeO2

Filipović, Suzana; Obradović, Nina; Đorđević, Nataša; Kosanović, Darko; Marković, Smilja; Mitrić, Miodrag N.; Pavlović, Vladimir B.

(Savez inženjera i tehničara Srbije, Beograd, 2016)

TY  - JOUR
AU  - Filipović, Suzana
AU  - Obradović, Nina
AU  - Đorđević, Nataša
AU  - Kosanović, Darko
AU  - Marković, Smilja
AU  - Mitrić, Miodrag N.
AU  - Pavlović, Vladimir B.
PY  - 2016
UR  - https://ritnms.itnms.ac.rs/handle/123456789/382
AB  - Ova istraživanja posvećena su uticaju mehaničke aktivacije na strukturu kordijeritne smeše 2MgO+2Al2O3+5SiO2. Praćena su i testirana dva paralelna sistema, jedan bez, i drugi u prisustvu 5 masenih % TeO2 kao aditiva. Mehanička aktivacija prahova vršena je u visoko energetskom mlinu sa kuglama u vremenskom intervalu od 0 do 40 minuta. Tokom aktivacije došlo je do reakcije polaznih komponenti u čvrstoj fazi, pri čemu su nastala intermedijarna jedinjenja. Metoda rendgenske difrakcije je korišćena radi identifikacije faznog sastava tokom reakcije, dok su SEM i PSA metode korišćene za praćenje promene morfologije mehanički tretiranih prahova. Cilj aktivacije polaznih prahova je sniženje temperature i mogućnost da se skrati vreme trajanja procesa sinterovanja u postupku dobijanja krajnjeg proizvoda.
AB  - Cordierite 2MgO+2Al2O3+5SiO2 is frequently used ceramic material, that is commonly used as a carrier of electrical components due to its low dielectric constant (~ 5), and low temperature thermal expansion coefficient (20·10-7 oC-1). In order to accelerate the process of sintering, 5.00 mass% TeO2 was added to the starting mixtures. System was tested in two parallel mixtures, one with no additives, and the other one with TeO2. The mechanical activation of the both mixtures was performed in a highenergy ball mill in time intervals from 0 to 40 min with ball to powder mass ratio 1:40. The particle size analysis (PSA) was employed in order to determine the changes in the particle size of the mechanically treated powders. The phase composition of the starting powders as well as microstructures was analyzed by the means of X-ray diffraction method and SEM.
PB  - Savez inženjera i tehničara Srbije, Beograd
T2  - Tehnika
T1  - Uticaj mehaničke aktivacije na sistem MgO-Al2O3-SiO2 u prisustvu aditiva TeO2
T1  - Influence of mechanical activation on MgO-Al2O3-SiO2 system in the presence of TeO2 additive
EP  - 802
IS  - 6
SP  - 797
VL  - 71
DO  - 10.5937/tehnika1606797F
UR  - conv_21
ER  - 
@article{
author = "Filipović, Suzana and Obradović, Nina and Đorđević, Nataša and Kosanović, Darko and Marković, Smilja and Mitrić, Miodrag N. and Pavlović, Vladimir B.",
year = "2016",
abstract = "Ova istraživanja posvećena su uticaju mehaničke aktivacije na strukturu kordijeritne smeše 2MgO+2Al2O3+5SiO2. Praćena su i testirana dva paralelna sistema, jedan bez, i drugi u prisustvu 5 masenih % TeO2 kao aditiva. Mehanička aktivacija prahova vršena je u visoko energetskom mlinu sa kuglama u vremenskom intervalu od 0 do 40 minuta. Tokom aktivacije došlo je do reakcije polaznih komponenti u čvrstoj fazi, pri čemu su nastala intermedijarna jedinjenja. Metoda rendgenske difrakcije je korišćena radi identifikacije faznog sastava tokom reakcije, dok su SEM i PSA metode korišćene za praćenje promene morfologije mehanički tretiranih prahova. Cilj aktivacije polaznih prahova je sniženje temperature i mogućnost da se skrati vreme trajanja procesa sinterovanja u postupku dobijanja krajnjeg proizvoda., Cordierite 2MgO+2Al2O3+5SiO2 is frequently used ceramic material, that is commonly used as a carrier of electrical components due to its low dielectric constant (~ 5), and low temperature thermal expansion coefficient (20·10-7 oC-1). In order to accelerate the process of sintering, 5.00 mass% TeO2 was added to the starting mixtures. System was tested in two parallel mixtures, one with no additives, and the other one with TeO2. The mechanical activation of the both mixtures was performed in a highenergy ball mill in time intervals from 0 to 40 min with ball to powder mass ratio 1:40. The particle size analysis (PSA) was employed in order to determine the changes in the particle size of the mechanically treated powders. The phase composition of the starting powders as well as microstructures was analyzed by the means of X-ray diffraction method and SEM.",
publisher = "Savez inženjera i tehničara Srbije, Beograd",
journal = "Tehnika",
title = "Uticaj mehaničke aktivacije na sistem MgO-Al2O3-SiO2 u prisustvu aditiva TeO2, Influence of mechanical activation on MgO-Al2O3-SiO2 system in the presence of TeO2 additive",
pages = "802-797",
number = "6",
volume = "71",
doi = "10.5937/tehnika1606797F",
url = "conv_21"
}
Filipović, S., Obradović, N., Đorđević, N., Kosanović, D., Marković, S., Mitrić, M. N.,& Pavlović, V. B.. (2016). Uticaj mehaničke aktivacije na sistem MgO-Al2O3-SiO2 u prisustvu aditiva TeO2. in Tehnika
Savez inženjera i tehničara Srbije, Beograd., 71(6), 797-802.
https://doi.org/10.5937/tehnika1606797F
conv_21
Filipović S, Obradović N, Đorđević N, Kosanović D, Marković S, Mitrić MN, Pavlović VB. Uticaj mehaničke aktivacije na sistem MgO-Al2O3-SiO2 u prisustvu aditiva TeO2. in Tehnika. 2016;71(6):797-802.
doi:10.5937/tehnika1606797F
conv_21 .
Filipović, Suzana, Obradović, Nina, Đorđević, Nataša, Kosanović, Darko, Marković, Smilja, Mitrić, Miodrag N., Pavlović, Vladimir B., "Uticaj mehaničke aktivacije na sistem MgO-Al2O3-SiO2 u prisustvu aditiva TeO2" in Tehnika, 71, no. 6 (2016):797-802,
https://doi.org/10.5937/tehnika1606797F .,
conv_21 .
1

Effects of mechanical activation and two-step sintering on the structure and electrical properties of cordierite-based ceramics

Obradović, Nina; Filipović, Suzana; Đorđević, Nataša; Kosanović, Darko; Marković, Smilja; Pavlović, Vladimir; Olcan, Dragan; Đorđević, Antonije; Kachlik, Martin; Maca, Karel

(Elsevier Sci Ltd, Oxford, 2016)

TY  - JOUR
AU  - Obradović, Nina
AU  - Filipović, Suzana
AU  - Đorđević, Nataša
AU  - Kosanović, Darko
AU  - Marković, Smilja
AU  - Pavlović, Vladimir
AU  - Olcan, Dragan
AU  - Đorđević, Antonije
AU  - Kachlik, Martin
AU  - Maca, Karel
PY  - 2016
UR  - https://ritnms.itnms.ac.rs/handle/123456789/393
AB  - The mechanical activation can help reduce production costs and modify cordierite-based materials. In this study, the structure and electrical properties of the mechanically activated MgO-Al2O3-SiO2 system have been analyzed. The mixtures of MgO-Al2O3-SiO2 powders were mechanically activated in a planetary ball mill for time periods ranging from 0 to 160 min. Structural investigations were performed on the obtained powders. The effects of activation and a two-step sintering process on the microstructure and crystal structure were investigated by scanning electron microscopy (SEM) and X-ray diffraction (XRD). The thermal stability was analyzed using DTA. Electrical measurements showed variations of the dielectric constant (epsilon(r)) and loss tangent (tan delta) as a function of the time of mechanical treatment.
PB  - Elsevier Sci Ltd, Oxford
T2  - Ceramics International
T1  - Effects of mechanical activation and two-step sintering on the structure and electrical properties of cordierite-based ceramics
EP  - 13918
IS  - 12
SP  - 13909
VL  - 42
DO  - 10.1016/j.ceramint.2016.05.201
UR  - conv_763
UR  - https://hdl.handle.net/21.15107/rcub_dais_2322
ER  - 
@article{
author = "Obradović, Nina and Filipović, Suzana and Đorđević, Nataša and Kosanović, Darko and Marković, Smilja and Pavlović, Vladimir and Olcan, Dragan and Đorđević, Antonije and Kachlik, Martin and Maca, Karel",
year = "2016",
abstract = "The mechanical activation can help reduce production costs and modify cordierite-based materials. In this study, the structure and electrical properties of the mechanically activated MgO-Al2O3-SiO2 system have been analyzed. The mixtures of MgO-Al2O3-SiO2 powders were mechanically activated in a planetary ball mill for time periods ranging from 0 to 160 min. Structural investigations were performed on the obtained powders. The effects of activation and a two-step sintering process on the microstructure and crystal structure were investigated by scanning electron microscopy (SEM) and X-ray diffraction (XRD). The thermal stability was analyzed using DTA. Electrical measurements showed variations of the dielectric constant (epsilon(r)) and loss tangent (tan delta) as a function of the time of mechanical treatment.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Ceramics International",
title = "Effects of mechanical activation and two-step sintering on the structure and electrical properties of cordierite-based ceramics",
pages = "13918-13909",
number = "12",
volume = "42",
doi = "10.1016/j.ceramint.2016.05.201",
url = "conv_763, https://hdl.handle.net/21.15107/rcub_dais_2322"
}
Obradović, N., Filipović, S., Đorđević, N., Kosanović, D., Marković, S., Pavlović, V., Olcan, D., Đorđević, A., Kachlik, M.,& Maca, K.. (2016). Effects of mechanical activation and two-step sintering on the structure and electrical properties of cordierite-based ceramics. in Ceramics International
Elsevier Sci Ltd, Oxford., 42(12), 13909-13918.
https://doi.org/10.1016/j.ceramint.2016.05.201
conv_763
Obradović N, Filipović S, Đorđević N, Kosanović D, Marković S, Pavlović V, Olcan D, Đorđević A, Kachlik M, Maca K. Effects of mechanical activation and two-step sintering on the structure and electrical properties of cordierite-based ceramics. in Ceramics International. 2016;42(12):13909-13918.
doi:10.1016/j.ceramint.2016.05.201
conv_763 .
Obradović, Nina, Filipović, Suzana, Đorđević, Nataša, Kosanović, Darko, Marković, Smilja, Pavlović, Vladimir, Olcan, Dragan, Đorđević, Antonije, Kachlik, Martin, Maca, Karel, "Effects of mechanical activation and two-step sintering on the structure and electrical properties of cordierite-based ceramics" in Ceramics International, 42, no. 12 (2016):13909-13918,
https://doi.org/10.1016/j.ceramint.2016.05.201 .,
conv_763 .
30
19
28

Activation of phosphates for aplication in composite ceramic materials

Andrić, Ljubiša; Terzić, Anja; Pašalić, Snežana; Petrov, Milan; Radulović, Dragan

(Bor : Mining and Metallurgy Institute Bor, 2015)

TY  - CONF
AU  - Andrić, Ljubiša
AU  - Terzić, Anja
AU  - Pašalić, Snežana
AU  - Petrov, Milan
AU  - Radulović, Dragan
PY  - 2015
UR  - https://ritnms.itnms.ac.rs/handle/123456789/1054
AB  - The aim of this investigation was to increase the reactivity of comminuted phosphate ore for application in composite ceramic materials. The vibratory and planetary mills were used as mechanical activators during experimental research. The obtained results highlighted the presence of both amorphous and crystallized forms appearing in the observed phosphate ore mixture due to the specific genetic conditions which rarely occur in deposits. The heterogenic composition of the ore useful phosphoric part gave optimal results during the leaching test. For the first time, the experiments of phosphate mechano-chemical activation from Lisina ore deposit were performed in order to improve its reactivity.
PB  - Bor : Mining and Metallurgy Institute Bor
PB  - Bor : University of Belgrade, Technical Faculty in Bor
C3  - 47th International October Conference on Mining and Metallurgy
T1  - Activation of phosphates for aplication in composite ceramic materials
EP  - 82
SP  - 77
ER  - 
@conference{
author = "Andrić, Ljubiša and Terzić, Anja and Pašalić, Snežana and Petrov, Milan and Radulović, Dragan",
year = "2015",
abstract = "The aim of this investigation was to increase the reactivity of comminuted phosphate ore for application in composite ceramic materials. The vibratory and planetary mills were used as mechanical activators during experimental research. The obtained results highlighted the presence of both amorphous and crystallized forms appearing in the observed phosphate ore mixture due to the specific genetic conditions which rarely occur in deposits. The heterogenic composition of the ore useful phosphoric part gave optimal results during the leaching test. For the first time, the experiments of phosphate mechano-chemical activation from Lisina ore deposit were performed in order to improve its reactivity.",
publisher = "Bor : Mining and Metallurgy Institute Bor, Bor : University of Belgrade, Technical Faculty in Bor",
journal = "47th International October Conference on Mining and Metallurgy",
title = "Activation of phosphates for aplication in composite ceramic materials",
pages = "82-77"
}
Andrić, L., Terzić, A., Pašalić, S., Petrov, M.,& Radulović, D.. (2015). Activation of phosphates for aplication in composite ceramic materials. in 47th International October Conference on Mining and Metallurgy
Bor : Mining and Metallurgy Institute Bor., 77-82.
Andrić L, Terzić A, Pašalić S, Petrov M, Radulović D. Activation of phosphates for aplication in composite ceramic materials. in 47th International October Conference on Mining and Metallurgy. 2015;:77-82..
Andrić, Ljubiša, Terzić, Anja, Pašalić, Snežana, Petrov, Milan, Radulović, Dragan, "Activation of phosphates for aplication in composite ceramic materials" in 47th International October Conference on Mining and Metallurgy (2015):77-82.

Energy conversion in phosphate ore grain mixture activated via ultra-centrifugal mill

Andrić, Ljubiša; Terzić, Anja; Petrov, Milan; Stojanović, Jovica; Kostović, Milena

(Elsevier, Amsterdam, 2015)

TY  - JOUR
AU  - Andrić, Ljubiša
AU  - Terzić, Anja
AU  - Petrov, Milan
AU  - Stojanović, Jovica
AU  - Kostović, Milena
PY  - 2015
UR  - https://ritnms.itnms.ac.rs/handle/123456789/336
AB  - The aim of this investigation was to establish the optimal processing parameters of the comminuted phosphate grain mixture mechanical treatment by monitoring and evaluating the activated product characteristics. An ultra-centrifugal mill with a peripheral comminuting path was used as activator in the experiment. A mathematical model based on the theoretical principles of the grain mixture mechanical processing was applied in order to characterize the phosphate activation procedure. As the energy conversion that takes place by the interaction mill-material during activation is recorded on the processed phosphate grains, the increase in potential energy of the activated grains was measured by means of an automatic grain counter. Following the operating hypothesis of the automatic grain counter, the energy conversion and the properties of phosphate grains induced by mechanical force were monitored and expressed in the form of the grain inertia change. The phosphate ore grain mixture used in the experiment was thoroughly analyzed, particularly in its activated state. Analytically obtained results were supported by X-ray diffraction analysis for identification of crystalline phases and change in crystallinity, and SEM microphotography of initial and activated phosphate grains. Diverse comparison analyses disclosed that the optimal set of activation process parameters could reduce the negative effect of phosphate sample immanent properties on the final score and furthermore enhance the material reactivity.
PB  - Elsevier, Amsterdam
T2  - International Journal of Mineral Processing
T1  - Energy conversion in phosphate ore grain mixture activated via ultra-centrifugal mill
EP  - 11
SP  - 1
VL  - 143
DO  - 10.1016/j.minpro.2015.08.005
UR  - conv_741
ER  - 
@article{
author = "Andrić, Ljubiša and Terzić, Anja and Petrov, Milan and Stojanović, Jovica and Kostović, Milena",
year = "2015",
abstract = "The aim of this investigation was to establish the optimal processing parameters of the comminuted phosphate grain mixture mechanical treatment by monitoring and evaluating the activated product characteristics. An ultra-centrifugal mill with a peripheral comminuting path was used as activator in the experiment. A mathematical model based on the theoretical principles of the grain mixture mechanical processing was applied in order to characterize the phosphate activation procedure. As the energy conversion that takes place by the interaction mill-material during activation is recorded on the processed phosphate grains, the increase in potential energy of the activated grains was measured by means of an automatic grain counter. Following the operating hypothesis of the automatic grain counter, the energy conversion and the properties of phosphate grains induced by mechanical force were monitored and expressed in the form of the grain inertia change. The phosphate ore grain mixture used in the experiment was thoroughly analyzed, particularly in its activated state. Analytically obtained results were supported by X-ray diffraction analysis for identification of crystalline phases and change in crystallinity, and SEM microphotography of initial and activated phosphate grains. Diverse comparison analyses disclosed that the optimal set of activation process parameters could reduce the negative effect of phosphate sample immanent properties on the final score and furthermore enhance the material reactivity.",
publisher = "Elsevier, Amsterdam",
journal = "International Journal of Mineral Processing",
title = "Energy conversion in phosphate ore grain mixture activated via ultra-centrifugal mill",
pages = "11-1",
volume = "143",
doi = "10.1016/j.minpro.2015.08.005",
url = "conv_741"
}
Andrić, L., Terzić, A., Petrov, M., Stojanović, J.,& Kostović, M.. (2015). Energy conversion in phosphate ore grain mixture activated via ultra-centrifugal mill. in International Journal of Mineral Processing
Elsevier, Amsterdam., 143, 1-11.
https://doi.org/10.1016/j.minpro.2015.08.005
conv_741
Andrić L, Terzić A, Petrov M, Stojanović J, Kostović M. Energy conversion in phosphate ore grain mixture activated via ultra-centrifugal mill. in International Journal of Mineral Processing. 2015;143:1-11.
doi:10.1016/j.minpro.2015.08.005
conv_741 .
Andrić, Ljubiša, Terzić, Anja, Petrov, Milan, Stojanović, Jovica, Kostović, Milena, "Energy conversion in phosphate ore grain mixture activated via ultra-centrifugal mill" in International Journal of Mineral Processing, 143 (2015):1-11,
https://doi.org/10.1016/j.minpro.2015.08.005 .,
conv_741 .
7
5
7

Investigation of thermally induced processes in corundum refractory concretes with addition of fly ash

Terzić, Anja; Obradović, Nina; Andrić, Ljubiša; Stojanović, Jovica; Pavlović, Vladimir

(Springer, Dordrecht, 2015)

TY  - JOUR
AU  - Terzić, Anja
AU  - Obradović, Nina
AU  - Andrić, Ljubiša
AU  - Stojanović, Jovica
AU  - Pavlović, Vladimir
PY  - 2015
UR  - https://ritnms.itnms.ac.rs/handle/123456789/370
AB  - The effects that the fly ash addition has on the behavior of thermally resistant corundum concrete were discussed. Experimental program implied production of two refractory composites: "referent" concrete from 20 % of high-aluminate cement and 80 % of corundum aggregate, "recycled" concrete from 10 % of high-aluminate cement, 20 % of lignite coal ash, and 70 % of corundum aggregate. The fly ash was mechanically activated by a vibratory disk mill. In the concrete matrix, the ash had a role of cement partial replacement and microfiller. The mechanical and thermal properties of the concretes were studied at temperatures ranging from ambient to 1,400 A degrees C as adopted maximum. Mechanisms of thermally induced processes were observed by differential thermal analysis at 10, 20, and 30 A degrees C min(-1) heating rates. Referent and recycled concretes showed differences in calculated activation energies. The variations in refractory concretes performances were discussed with support of scanning electron microscope imagining and X-ray diffraction results. The recycled ash concrete exhibited properties that met the requirements for the castables, which proves it suitable for use in severe conditions at high temperature and highlights the reusing principle and possibility of cleaner and economically sustainable production.
PB  - Springer, Dordrecht
T2  - Journal of Thermal Analysis and Calorimetry
T1  - Investigation of thermally induced processes in corundum refractory concretes with addition of fly ash
EP  - 1352
IS  - 2
SP  - 1339
VL  - 119
DO  - 10.1007/s10973-014-4230-4
UR  - conv_718
ER  - 
@article{
author = "Terzić, Anja and Obradović, Nina and Andrić, Ljubiša and Stojanović, Jovica and Pavlović, Vladimir",
year = "2015",
abstract = "The effects that the fly ash addition has on the behavior of thermally resistant corundum concrete were discussed. Experimental program implied production of two refractory composites: "referent" concrete from 20 % of high-aluminate cement and 80 % of corundum aggregate, "recycled" concrete from 10 % of high-aluminate cement, 20 % of lignite coal ash, and 70 % of corundum aggregate. The fly ash was mechanically activated by a vibratory disk mill. In the concrete matrix, the ash had a role of cement partial replacement and microfiller. The mechanical and thermal properties of the concretes were studied at temperatures ranging from ambient to 1,400 A degrees C as adopted maximum. Mechanisms of thermally induced processes were observed by differential thermal analysis at 10, 20, and 30 A degrees C min(-1) heating rates. Referent and recycled concretes showed differences in calculated activation energies. The variations in refractory concretes performances were discussed with support of scanning electron microscope imagining and X-ray diffraction results. The recycled ash concrete exhibited properties that met the requirements for the castables, which proves it suitable for use in severe conditions at high temperature and highlights the reusing principle and possibility of cleaner and economically sustainable production.",
publisher = "Springer, Dordrecht",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "Investigation of thermally induced processes in corundum refractory concretes with addition of fly ash",
pages = "1352-1339",
number = "2",
volume = "119",
doi = "10.1007/s10973-014-4230-4",
url = "conv_718"
}
Terzić, A., Obradović, N., Andrić, L., Stojanović, J.,& Pavlović, V.. (2015). Investigation of thermally induced processes in corundum refractory concretes with addition of fly ash. in Journal of Thermal Analysis and Calorimetry
Springer, Dordrecht., 119(2), 1339-1352.
https://doi.org/10.1007/s10973-014-4230-4
conv_718
Terzić A, Obradović N, Andrić L, Stojanović J, Pavlović V. Investigation of thermally induced processes in corundum refractory concretes with addition of fly ash. in Journal of Thermal Analysis and Calorimetry. 2015;119(2):1339-1352.
doi:10.1007/s10973-014-4230-4
conv_718 .
Terzić, Anja, Obradović, Nina, Andrić, Ljubiša, Stojanović, Jovica, Pavlović, Vladimir, "Investigation of thermally induced processes in corundum refractory concretes with addition of fly ash" in Journal of Thermal Analysis and Calorimetry, 119, no. 2 (2015):1339-1352,
https://doi.org/10.1007/s10973-014-4230-4 .,
conv_718 .
7
5
8

Sintering of Cordierite in the Presence of MoO3 and Crystallization Analysis

Đorđević, Nataša; Obradović, Nina; Kosanović, Darko; Mitrić, Miodrag; Pavlović, V. P.

(Međunarodni Institut za nauku o sinterovanju, Beograd, 2014)

TY  - JOUR
AU  - Đorđević, Nataša
AU  - Obradović, Nina
AU  - Kosanović, Darko
AU  - Mitrić, Miodrag
AU  - Pavlović, V. P.
PY  - 2014
UR  - https://ritnms.itnms.ac.rs/handle/123456789/313
AB  - Cordierite (MAS) is difficult to sinter because of the very narrow sintering temperature range (1300-1400 degrees C). Because a low temperature process is desirable, it is necessary to find functional ads which can allow easier sintering process at lower temperature. The influence of MoO3 on the preparation process of cordierite ceramics was investigated. 2MgO-2Al(2)O(3)-5SiO(2) was researched by sintering followed binary systems: MgO/MoO3, Al2O3/MoO3 and SiO2/MoO3 (all sintered at 850 degrees C and 1100 degrees C, sintering time 2h). Composition of these systems was 80 mass% of oxide and 20 mass% MoO3. The effects of sintering, the composition and morphology were followed by X-ray diffraction and SEM microscopy. It has been found that MoO3, beside liquid phase, forms intermediary unstable compounds with MgO and Al2O3, which is the significance information for further research. MAS ceramics were sintered with 20 mass% MoO3 at 1100 degrees C, 1200 degrees C and 1300 degrees C, during 2h.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - Sintering of Cordierite in the Presence of MoO3 and Crystallization Analysis
EP  - 313
IS  - 3
SP  - 307
VL  - 46
DO  - 10.2298/SOS1403307D
UR  - conv_720
ER  - 
@article{
author = "Đorđević, Nataša and Obradović, Nina and Kosanović, Darko and Mitrić, Miodrag and Pavlović, V. P.",
year = "2014",
abstract = "Cordierite (MAS) is difficult to sinter because of the very narrow sintering temperature range (1300-1400 degrees C). Because a low temperature process is desirable, it is necessary to find functional ads which can allow easier sintering process at lower temperature. The influence of MoO3 on the preparation process of cordierite ceramics was investigated. 2MgO-2Al(2)O(3)-5SiO(2) was researched by sintering followed binary systems: MgO/MoO3, Al2O3/MoO3 and SiO2/MoO3 (all sintered at 850 degrees C and 1100 degrees C, sintering time 2h). Composition of these systems was 80 mass% of oxide and 20 mass% MoO3. The effects of sintering, the composition and morphology were followed by X-ray diffraction and SEM microscopy. It has been found that MoO3, beside liquid phase, forms intermediary unstable compounds with MgO and Al2O3, which is the significance information for further research. MAS ceramics were sintered with 20 mass% MoO3 at 1100 degrees C, 1200 degrees C and 1300 degrees C, during 2h.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "Sintering of Cordierite in the Presence of MoO3 and Crystallization Analysis",
pages = "313-307",
number = "3",
volume = "46",
doi = "10.2298/SOS1403307D",
url = "conv_720"
}
Đorđević, N., Obradović, N., Kosanović, D., Mitrić, M.,& Pavlović, V. P.. (2014). Sintering of Cordierite in the Presence of MoO3 and Crystallization Analysis. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 46(3), 307-313.
https://doi.org/10.2298/SOS1403307D
conv_720
Đorđević N, Obradović N, Kosanović D, Mitrić M, Pavlović VP. Sintering of Cordierite in the Presence of MoO3 and Crystallization Analysis. in Science of Sintering. 2014;46(3):307-313.
doi:10.2298/SOS1403307D
conv_720 .
Đorđević, Nataša, Obradović, Nina, Kosanović, Darko, Mitrić, Miodrag, Pavlović, V. P., "Sintering of Cordierite in the Presence of MoO3 and Crystallization Analysis" in Science of Sintering, 46, no. 3 (2014):307-313,
https://doi.org/10.2298/SOS1403307D .,
conv_720 .
4
3
4

Mechanical Activation as Sintering Pre-treatment of Talc for Steatite Ceramics

Terzić, Anja; Andrić, Ljubiša; Stojanović, Jovica; Obradović, Nina; Kostović, M.

(Međunarodni Institut za nauku o sinterovanju, Beograd, 2014)

TY  - JOUR
AU  - Terzić, Anja
AU  - Andrić, Ljubiša
AU  - Stojanović, Jovica
AU  - Obradović, Nina
AU  - Kostović, M.
PY  - 2014
UR  - https://ritnms.itnms.ac.rs/handle/123456789/320
AB  - The effect of vibratory mill induced mechanical activation on the change of the particle size, crystallinity and the phase transformations of the minerals present in the activated material, was studied with the purpose of decreasing of the sintering temperature of talc (Mg3Si4O10(OH)(2)) as raw material which is the basic component of the steatite ceramics. The aims of the conducted investigation were, also, increasing of the reactivity of the comminuted raw material and establishing of the optimal activation period. The properties of the activated talc induced by mechanical force were expressed in form of the grain inertia change which was measured by means of automatic grain counter. Mechanically activated grains are the most convenient mineral form for physical concentration since the energy change of the mill-material system is recorded on them. The effect of dry grinding on the structure, particle size and shape of talc was studied by means of XRD, DTA and SEM/EDS methods. Activation of talc produced an increase of the starting surface area value progressively from 4.5 m(2)/g up to a maximum of 108.5 m(2)/g achieved at 30 min. A subsequent decrease of rate of surface area change and the rate of size reduction were observed following the prolonged grinding. Talc activated in vibratory mill for optimal 30 min showed properties which positively influence the decrease of sintering temperature and the increase of the sintering rate of steatite ceramics.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - Mechanical Activation as Sintering Pre-treatment of Talc for Steatite Ceramics
EP  - 258
IS  - 2
SP  - 247
VL  - 46
DO  - 10.2298/SOS1402247T
UR  - conv_706
ER  - 
@article{
author = "Terzić, Anja and Andrić, Ljubiša and Stojanović, Jovica and Obradović, Nina and Kostović, M.",
year = "2014",
abstract = "The effect of vibratory mill induced mechanical activation on the change of the particle size, crystallinity and the phase transformations of the minerals present in the activated material, was studied with the purpose of decreasing of the sintering temperature of talc (Mg3Si4O10(OH)(2)) as raw material which is the basic component of the steatite ceramics. The aims of the conducted investigation were, also, increasing of the reactivity of the comminuted raw material and establishing of the optimal activation period. The properties of the activated talc induced by mechanical force were expressed in form of the grain inertia change which was measured by means of automatic grain counter. Mechanically activated grains are the most convenient mineral form for physical concentration since the energy change of the mill-material system is recorded on them. The effect of dry grinding on the structure, particle size and shape of talc was studied by means of XRD, DTA and SEM/EDS methods. Activation of talc produced an increase of the starting surface area value progressively from 4.5 m(2)/g up to a maximum of 108.5 m(2)/g achieved at 30 min. A subsequent decrease of rate of surface area change and the rate of size reduction were observed following the prolonged grinding. Talc activated in vibratory mill for optimal 30 min showed properties which positively influence the decrease of sintering temperature and the increase of the sintering rate of steatite ceramics.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "Mechanical Activation as Sintering Pre-treatment of Talc for Steatite Ceramics",
pages = "258-247",
number = "2",
volume = "46",
doi = "10.2298/SOS1402247T",
url = "conv_706"
}
Terzić, A., Andrić, L., Stojanović, J., Obradović, N.,& Kostović, M.. (2014). Mechanical Activation as Sintering Pre-treatment of Talc for Steatite Ceramics. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 46(2), 247-258.
https://doi.org/10.2298/SOS1402247T
conv_706
Terzić A, Andrić L, Stojanović J, Obradović N, Kostović M. Mechanical Activation as Sintering Pre-treatment of Talc for Steatite Ceramics. in Science of Sintering. 2014;46(2):247-258.
doi:10.2298/SOS1402247T
conv_706 .
Terzić, Anja, Andrić, Ljubiša, Stojanović, Jovica, Obradović, Nina, Kostović, M., "Mechanical Activation as Sintering Pre-treatment of Talc for Steatite Ceramics" in Science of Sintering, 46, no. 2 (2014):247-258,
https://doi.org/10.2298/SOS1402247T .,
conv_706 .
8
6
11

Influence of prolonged sintering time on density and electrical properties of isothermally sintered cordierite-based ceramics

Peleš, A.; Đorđević, Nataša; Obradović, Nina; Tadić, N.; Pavlović, Vladimir

(Međunarodni Institut za nauku o sinterovanju, Beograd, 2013)

TY  - JOUR
AU  - Peleš, A.
AU  - Đorđević, Nataša
AU  - Obradović, Nina
AU  - Tadić, N.
AU  - Pavlović, Vladimir
PY  - 2013
UR  - https://ritnms.itnms.ac.rs/handle/123456789/258
AB  - Mehanička aktivacija je brza i jeftina procedura koja se obično koristi za pripremanje uzoraka pre procesa sinterovanja. Kordijerit, stehiometrijska mešavina tri različita oksida (2MgO⋅2Al2O3⋅5SiO2) je veoma atraktivan, i široko korišćen visokotemperaturni keramički materijal. Početna smeša sa 5.00 masenih % TiO2 je mehanički aktivirana u visokoenergetskom mlinu sa kuglicama u vremenskom intervalu od 10- 80 minuta. Pre procesa sinterovanja uzorci su ispresovani pod pritiskom od 2t/cm2, bazirano na našem pređašnjem istraživanju. Uzorci su sinterovani na temperaturi od 1350°C u periodu od 2 i 4 sata u atmosferi vazduha. Difrakcijom H zraka je ustanovljena faza neaktiviranih i uzoraka aktiviranih 80 minuta, sinterovanih 2 i 4 sata, respektivno. Skenirajućom elektronskom mikroskopijom je analizirana mikrostruktura oba sinterovana uzorka. Mikroskopom atomskih sila smo analizirali površinu oba uzorka. Ovaj rad ispituje uticaj produženog vremena sinterovanja na gustinu sinterovanih uzoraka, kao i električne osobine.
AB  - Mechanical activation is a commonly used and relatively fast and inexpensive procedure for sample preparation before the sintering process. Cordierite, a stoichiometric mixture of three different oxides (2MgO⋅2Al2O3⋅5SiO2) is a very attractive, widely used high-temperature ceramic material. The mechanical activation of the starting mixtures with 5.00 mass% TiO2 was performed in a high energy ball mill during 10-80 min. The applied compaction pressure before the sintering process was 2t/cm2, based on our recent investigation. The sintering process was performed at 1350°C for 2h and 4h in air atmosphere. X-ray diffraction was used to analyze the phase composition of non-activated and 80 min activated samples, sintered for 2 and 4h, respectively. Scanning electron microscopy was performed to analyze the microstructure of both compacted and sintered samples. Atomic force microscope was used to investigate the surface of the sintered samples. This paper investigates the influence of prolonged sintering time on the densities of the sintered samples, along with electrical properties.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - Influence of prolonged sintering time on density and electrical properties of isothermally sintered cordierite-based ceramics
EP  - 164
IS  - 2
SP  - 157
VL  - 45
DO  - 10.2298/SOS1302157P
UR  - https://hdl.handle.net/21.15107/rcub_dais_188
UR  - conv_662
ER  - 
@article{
author = "Peleš, A. and Đorđević, Nataša and Obradović, Nina and Tadić, N. and Pavlović, Vladimir",
year = "2013",
abstract = "Mehanička aktivacija je brza i jeftina procedura koja se obično koristi za pripremanje uzoraka pre procesa sinterovanja. Kordijerit, stehiometrijska mešavina tri različita oksida (2MgO⋅2Al2O3⋅5SiO2) je veoma atraktivan, i široko korišćen visokotemperaturni keramički materijal. Početna smeša sa 5.00 masenih % TiO2 je mehanički aktivirana u visokoenergetskom mlinu sa kuglicama u vremenskom intervalu od 10- 80 minuta. Pre procesa sinterovanja uzorci su ispresovani pod pritiskom od 2t/cm2, bazirano na našem pređašnjem istraživanju. Uzorci su sinterovani na temperaturi od 1350°C u periodu od 2 i 4 sata u atmosferi vazduha. Difrakcijom H zraka je ustanovljena faza neaktiviranih i uzoraka aktiviranih 80 minuta, sinterovanih 2 i 4 sata, respektivno. Skenirajućom elektronskom mikroskopijom je analizirana mikrostruktura oba sinterovana uzorka. Mikroskopom atomskih sila smo analizirali površinu oba uzorka. Ovaj rad ispituje uticaj produženog vremena sinterovanja na gustinu sinterovanih uzoraka, kao i električne osobine., Mechanical activation is a commonly used and relatively fast and inexpensive procedure for sample preparation before the sintering process. Cordierite, a stoichiometric mixture of three different oxides (2MgO⋅2Al2O3⋅5SiO2) is a very attractive, widely used high-temperature ceramic material. The mechanical activation of the starting mixtures with 5.00 mass% TiO2 was performed in a high energy ball mill during 10-80 min. The applied compaction pressure before the sintering process was 2t/cm2, based on our recent investigation. The sintering process was performed at 1350°C for 2h and 4h in air atmosphere. X-ray diffraction was used to analyze the phase composition of non-activated and 80 min activated samples, sintered for 2 and 4h, respectively. Scanning electron microscopy was performed to analyze the microstructure of both compacted and sintered samples. Atomic force microscope was used to investigate the surface of the sintered samples. This paper investigates the influence of prolonged sintering time on the densities of the sintered samples, along with electrical properties.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "Influence of prolonged sintering time on density and electrical properties of isothermally sintered cordierite-based ceramics",
pages = "164-157",
number = "2",
volume = "45",
doi = "10.2298/SOS1302157P",
url = "https://hdl.handle.net/21.15107/rcub_dais_188, conv_662"
}
Peleš, A., Đorđević, N., Obradović, N., Tadić, N.,& Pavlović, V.. (2013). Influence of prolonged sintering time on density and electrical properties of isothermally sintered cordierite-based ceramics. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 45(2), 157-164.
https://doi.org/10.2298/SOS1302157P
https://hdl.handle.net/21.15107/rcub_dais_188
Peleš A, Đorđević N, Obradović N, Tadić N, Pavlović V. Influence of prolonged sintering time on density and electrical properties of isothermally sintered cordierite-based ceramics. in Science of Sintering. 2013;45(2):157-164.
doi:10.2298/SOS1302157P
https://hdl.handle.net/21.15107/rcub_dais_188 .
Peleš, A., Đorđević, Nataša, Obradović, Nina, Tadić, N., Pavlović, Vladimir, "Influence of prolonged sintering time on density and electrical properties of isothermally sintered cordierite-based ceramics" in Science of Sintering, 45, no. 2 (2013):157-164,
https://doi.org/10.2298/SOS1302157P .,
https://hdl.handle.net/21.15107/rcub_dais_188 .
7
7
7

High-temperature concrete binders based on fly ash

Terzić, Anja; Radojević, Zagorka; Milicić, Ljiljana; Pavlović, Ljubica; Stojanović, Jovica

(2013)

TY  - JOUR
AU  - Terzić, Anja
AU  - Radojević, Zagorka
AU  - Milicić, Ljiljana
AU  - Pavlović, Ljubica
AU  - Stojanović, Jovica
PY  - 2013
UR  - https://ritnms.itnms.ac.rs/handle/123456789/280
AB  - High-temperature concrete binders in which fly ash, as environmentally harmful secondary raw material, is combined with masonry and refractory cement is a new option for reapplication of this coal combustion by-product. In this study, the design of the bonding agents was based on the fly ash from lignite coal combustion process and two types of cement: Portland cement and aluminate cement. Fly ash was applied without any further mechanical or thermal treatment. Mechanical properties of the binders were investigated and subsequently correlated with changes which occurred in the phase composition and microstructure of the agents. Scanning electron microscopy was used in investigation of microstructural changes caused by temperature. X-ray diffraction method was used in monitoring of the mineral phase changes also induced by increasing temperature. The investigations conducted on the bonding agents highlighted presence of good refractory properties and temperature-resistance, and also showed high values of compressive strength. The investigated bonding agents, thus, can be applied in refractory concretes, but also in various types of thermo-insulations.
T2  - Revista Romana de Materiale/ Romanian Journal of Materials
T1  - High-temperature concrete binders based on fly ash
EP  - 275
IS  - 3
SP  - 269
VL  - 43
UR  - https://hdl.handle.net/21.15107/rcub_rims_203
UR  - conv_1056
ER  - 
@article{
author = "Terzić, Anja and Radojević, Zagorka and Milicić, Ljiljana and Pavlović, Ljubica and Stojanović, Jovica",
year = "2013",
abstract = "High-temperature concrete binders in which fly ash, as environmentally harmful secondary raw material, is combined with masonry and refractory cement is a new option for reapplication of this coal combustion by-product. In this study, the design of the bonding agents was based on the fly ash from lignite coal combustion process and two types of cement: Portland cement and aluminate cement. Fly ash was applied without any further mechanical or thermal treatment. Mechanical properties of the binders were investigated and subsequently correlated with changes which occurred in the phase composition and microstructure of the agents. Scanning electron microscopy was used in investigation of microstructural changes caused by temperature. X-ray diffraction method was used in monitoring of the mineral phase changes also induced by increasing temperature. The investigations conducted on the bonding agents highlighted presence of good refractory properties and temperature-resistance, and also showed high values of compressive strength. The investigated bonding agents, thus, can be applied in refractory concretes, but also in various types of thermo-insulations.",
journal = "Revista Romana de Materiale/ Romanian Journal of Materials",
title = "High-temperature concrete binders based on fly ash",
pages = "275-269",
number = "3",
volume = "43",
url = "https://hdl.handle.net/21.15107/rcub_rims_203, conv_1056"
}
Terzić, A., Radojević, Z., Milicić, L., Pavlović, L.,& Stojanović, J.. (2013). High-temperature concrete binders based on fly ash. in Revista Romana de Materiale/ Romanian Journal of Materials, 43(3), 269-275.
https://hdl.handle.net/21.15107/rcub_rims_203
Terzić A, Radojević Z, Milicić L, Pavlović L, Stojanović J. High-temperature concrete binders based on fly ash. in Revista Romana de Materiale/ Romanian Journal of Materials. 2013;43(3):269-275.
https://hdl.handle.net/21.15107/rcub_rims_203 .
Terzić, Anja, Radojević, Zagorka, Milicić, Ljiljana, Pavlović, Ljubica, Stojanović, Jovica, "High-temperature concrete binders based on fly ash" in Revista Romana de Materiale/ Romanian Journal of Materials, 43, no. 3 (2013):269-275,
https://hdl.handle.net/21.15107/rcub_rims_203 .
3
3