The effect of mechano-chemical activation and surface treatment of limestone filler on the properties of construction composites
Нема приказа
Аутори
Terzić, AnjaRadulović, Dragan
Pezo, Lato
Andrić, Ljubiša
Milicić, Ljiljana
Stojanović, Jovica
Grigorova, Irena
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
The effect of the combined actions of milling and hydrophobization procedures applied in construction composites synthesis was investigated. The mortars were prepared with cement (CEM I 42.5) and calcite aggregate complying the standard 1:3 mix ratio. The limestone filler (10 wt%) was added to the mixture upon its mechano-chemical activation in an ultra-centrifugal mill. The activation variables (milling time, rotor velocity, sieve mesh size) were altered to achieve the optimal quality of the powder. The treatment was optimized via chemometric tools. The r(2) values (0.955-0.998) of second order polynomial models accurately predicted the output and the Standard score analysis chose the optimal activation parameters: 4.25 min; 48.58 m/s and 80 gm sieve. The selected filler and all three aggregate fractions were coated with stearic acid via dry procedure. The mortar mixes, prepared with uncoated (M1) and coated (M2) aggregate and filler, were cured for a period of 28 days during which co...mpressive strength and water absorption were monitored. The dimensional changes in mortars were estimated via TMA dilatometer measurements. Thermo-analytical methods (DTA/TGA) were applied in the thermal behavior analysis. Mineralogical and morphological changes in the structure of hardened composite were detected by XRD and SEM, respectively. Limestone aggregate led to lower final compressive strengths in mortar, but it produced an infinitesimally small shrinkage at 1000 degrees C. The hydrophobization via stearic acid initiated the decrease in water absorption and formation of needle-like micro-network that filled structural voids reducing open porosity. The assessment of the effects of limestone utilization as a filler and as an aggregate on the mortar performances confirmed that this novel water-repellent composite is applicable in structural design.
Кључне речи:
Thermal analysis / Strength / Statistical methods/modeling / Powder processing / Mortar / Hydrophobization / Electron microscopyИзвор:
Composites Part B-Engineering, 2017, 117, 61-73Издавач:
- Elsevier Sci Ltd, Oxford
Финансирање / пројекти:
- Усмерена синтеза, структура и својства мултифункционалних материјала (RS-MESTD-Basic Research (BR or ON)-172057)
- Развој и примена мултифункционалних материјала на бази домаћих сировина модернизацијом традиционалних технологија (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45008)
- Осмотска дехидратација хране - енергетски и еколошки аспекти одрживе производње (RS-MESTD-Technological Development (TD or TR)-31055)
- Освајање технолошких поступака добијања еколошких материјала на бази неметаличних минералних сировина (RS-MESTD-Technological Development (TD or TR)-34013)
- Имплементација савременијих техничко-технолошких и еколошких решења у постојећим производним системима Рудника Бакра Бор и Рудника Бакра Мајданпек (RS-MESTD-Technological Development (TD or TR)-33007)
DOI: 10.1016/j.compositesb.2017.02.041
ISSN: 1359-8368
WoS: 000401676600008
Scopus: 2-s2.0-85014476309
Институција/група
Institut za tehnologiju nuklearnih i drugih mineralnih sirovinaTY - JOUR AU - Terzić, Anja AU - Radulović, Dragan AU - Pezo, Lato AU - Andrić, Ljubiša AU - Milicić, Ljiljana AU - Stojanović, Jovica AU - Grigorova, Irena PY - 2017 UR - https://ritnms.itnms.ac.rs/handle/123456789/454 AB - The effect of the combined actions of milling and hydrophobization procedures applied in construction composites synthesis was investigated. The mortars were prepared with cement (CEM I 42.5) and calcite aggregate complying the standard 1:3 mix ratio. The limestone filler (10 wt%) was added to the mixture upon its mechano-chemical activation in an ultra-centrifugal mill. The activation variables (milling time, rotor velocity, sieve mesh size) were altered to achieve the optimal quality of the powder. The treatment was optimized via chemometric tools. The r(2) values (0.955-0.998) of second order polynomial models accurately predicted the output and the Standard score analysis chose the optimal activation parameters: 4.25 min; 48.58 m/s and 80 gm sieve. The selected filler and all three aggregate fractions were coated with stearic acid via dry procedure. The mortar mixes, prepared with uncoated (M1) and coated (M2) aggregate and filler, were cured for a period of 28 days during which compressive strength and water absorption were monitored. The dimensional changes in mortars were estimated via TMA dilatometer measurements. Thermo-analytical methods (DTA/TGA) were applied in the thermal behavior analysis. Mineralogical and morphological changes in the structure of hardened composite were detected by XRD and SEM, respectively. Limestone aggregate led to lower final compressive strengths in mortar, but it produced an infinitesimally small shrinkage at 1000 degrees C. The hydrophobization via stearic acid initiated the decrease in water absorption and formation of needle-like micro-network that filled structural voids reducing open porosity. The assessment of the effects of limestone utilization as a filler and as an aggregate on the mortar performances confirmed that this novel water-repellent composite is applicable in structural design. PB - Elsevier Sci Ltd, Oxford T2 - Composites Part B-Engineering T1 - The effect of mechano-chemical activation and surface treatment of limestone filler on the properties of construction composites EP - 73 SP - 61 VL - 117 DO - 10.1016/j.compositesb.2017.02.041 UR - conv_794 ER -
@article{ author = "Terzić, Anja and Radulović, Dragan and Pezo, Lato and Andrić, Ljubiša and Milicić, Ljiljana and Stojanović, Jovica and Grigorova, Irena", year = "2017", abstract = "The effect of the combined actions of milling and hydrophobization procedures applied in construction composites synthesis was investigated. The mortars were prepared with cement (CEM I 42.5) and calcite aggregate complying the standard 1:3 mix ratio. The limestone filler (10 wt%) was added to the mixture upon its mechano-chemical activation in an ultra-centrifugal mill. The activation variables (milling time, rotor velocity, sieve mesh size) were altered to achieve the optimal quality of the powder. The treatment was optimized via chemometric tools. The r(2) values (0.955-0.998) of second order polynomial models accurately predicted the output and the Standard score analysis chose the optimal activation parameters: 4.25 min; 48.58 m/s and 80 gm sieve. The selected filler and all three aggregate fractions were coated with stearic acid via dry procedure. The mortar mixes, prepared with uncoated (M1) and coated (M2) aggregate and filler, were cured for a period of 28 days during which compressive strength and water absorption were monitored. The dimensional changes in mortars were estimated via TMA dilatometer measurements. Thermo-analytical methods (DTA/TGA) were applied in the thermal behavior analysis. Mineralogical and morphological changes in the structure of hardened composite were detected by XRD and SEM, respectively. Limestone aggregate led to lower final compressive strengths in mortar, but it produced an infinitesimally small shrinkage at 1000 degrees C. The hydrophobization via stearic acid initiated the decrease in water absorption and formation of needle-like micro-network that filled structural voids reducing open porosity. The assessment of the effects of limestone utilization as a filler and as an aggregate on the mortar performances confirmed that this novel water-repellent composite is applicable in structural design.", publisher = "Elsevier Sci Ltd, Oxford", journal = "Composites Part B-Engineering", title = "The effect of mechano-chemical activation and surface treatment of limestone filler on the properties of construction composites", pages = "73-61", volume = "117", doi = "10.1016/j.compositesb.2017.02.041", url = "conv_794" }
Terzić, A., Radulović, D., Pezo, L., Andrić, L., Milicić, L., Stojanović, J.,& Grigorova, I.. (2017). The effect of mechano-chemical activation and surface treatment of limestone filler on the properties of construction composites. in Composites Part B-Engineering Elsevier Sci Ltd, Oxford., 117, 61-73. https://doi.org/10.1016/j.compositesb.2017.02.041 conv_794
Terzić A, Radulović D, Pezo L, Andrić L, Milicić L, Stojanović J, Grigorova I. The effect of mechano-chemical activation and surface treatment of limestone filler on the properties of construction composites. in Composites Part B-Engineering. 2017;117:61-73. doi:10.1016/j.compositesb.2017.02.041 conv_794 .
Terzić, Anja, Radulović, Dragan, Pezo, Lato, Andrić, Ljubiša, Milicić, Ljiljana, Stojanović, Jovica, Grigorova, Irena, "The effect of mechano-chemical activation and surface treatment of limestone filler on the properties of construction composites" in Composites Part B-Engineering, 117 (2017):61-73, https://doi.org/10.1016/j.compositesb.2017.02.041 ., conv_794 .