TY  - JOUR
AU  - Ranđelović, Dragana
AU  - Mutić, Jelena
AU  - Marjanović, Prvoslav
AU  - Đorđević, Tamara
AU  - Kasanin-Grubin, Milica
PY  - 2020
UR  - https://ritnms.itnms.ac.rs/handle/123456789/533
AB  - Materials held within mine tailings pose a serious risk to the environment in cases of tailings dam failure. Collapse of the tailing dam at the Stolice antimony mine in West Serbia caused a spilling of tailing slurry into the nearby river watersheds. Medium-term effects of As, Pb, Sb, Zn, and Cd from the tailings material that remained in the flooded zone 3 years after the initial exposure were evaluated. Mobility of these elements was determined by analyzing their distribution between exchangeable, reducible, oxidizable, and residual phases. Results indicate that Fe-Mn oxides represent important sinks for As, Cd, Pb, and Sb. Multivariate statistical analysis revealed that concentrations of the analyzed elements were related to sand-sized fractions, as they tended to adsorb or co-precipitate as coatings on larger particles (particularly feldspar and quartz) upon the change of redox conditions. Assessment of the most relevant physico-chemical factors, metal(loid) concentration, and mobility can be used as tool to characterize the degree of contamination of impacted sites. Percentage of sand-sized particles, content of investigated metal(loid)s, and their amount in the reducible fractions are factors determining the best remediation techniques for the area impacted by tailing spill.
PB  - Springer Heidelberg, Heidelberg
T2  - Environmental science and pollution research
T1  - Geochemical distribution of selected elements in flotation tailings and soils/sediments from the dam spill at the abandoned antimony mine Stolice, Serbia
EP  - 6268
IS  - 6
SP  - 6253
VL  - 27
DO  - 10.1007/s11356-019-07348-4
UR  - conv_870
ER  - 

@article{
author = "Ranđelović, Dragana and Mutić, Jelena and Marjanović, Prvoslav and Đorđević, Tamara and Kasanin-Grubin, Milica",
year = "2020",
abstract = "Materials held within mine tailings pose a serious risk to the environment in cases of tailings dam failure. Collapse of the tailing dam at the Stolice antimony mine in West Serbia caused a spilling of tailing slurry into the nearby river watersheds. Medium-term effects of As, Pb, Sb, Zn, and Cd from the tailings material that remained in the flooded zone 3 years after the initial exposure were evaluated. Mobility of these elements was determined by analyzing their distribution between exchangeable, reducible, oxidizable, and residual phases. Results indicate that Fe-Mn oxides represent important sinks for As, Cd, Pb, and Sb. Multivariate statistical analysis revealed that concentrations of the analyzed elements were related to sand-sized fractions, as they tended to adsorb or co-precipitate as coatings on larger particles (particularly feldspar and quartz) upon the change of redox conditions. Assessment of the most relevant physico-chemical factors, metal(loid) concentration, and mobility can be used as tool to characterize the degree of contamination of impacted sites. Percentage of sand-sized particles, content of investigated metal(loid)s, and their amount in the reducible fractions are factors determining the best remediation techniques for the area impacted by tailing spill.",
publisher = "Springer Heidelberg, Heidelberg",
journal = "Environmental science and pollution research",
title = "Geochemical distribution of selected elements in flotation tailings and soils/sediments from the dam spill at the abandoned antimony mine Stolice, Serbia",
pages = "6268-6253",
number = "6",
volume = "27",
doi = "10.1007/s11356-019-07348-4",
url = "conv_870"
}

Ranđelović, D., Mutić, J., Marjanović, P., Đorđević, T.,& Kasanin-Grubin, M.. (2020). Geochemical distribution of selected elements in flotation tailings and soils/sediments from the dam spill at the abandoned antimony mine Stolice, Serbia. in Environmental science and pollution research
Springer Heidelberg, Heidelberg., 27(6), 6253-6268.
https://doi.org/10.1007/s11356-019-07348-4
conv_870

Ranđelović D, Mutić J, Marjanović P, Đorđević T, Kasanin-Grubin M. Geochemical distribution of selected elements in flotation tailings and soils/sediments from the dam spill at the abandoned antimony mine Stolice, Serbia. in Environmental science and pollution research. 2020;27(6):6253-6268.
doi:10.1007/s11356-019-07348-4
conv_870 .

Ranđelović, Dragana, Mutić, Jelena, Marjanović, Prvoslav, Đorđević, Tamara, Kasanin-Grubin, Milica, "Geochemical distribution of selected elements in flotation tailings and soils/sediments from the dam spill at the abandoned antimony mine Stolice, Serbia" in Environmental science and pollution research, 27, no. 6 (2020):6253-6268,
https://doi.org/10.1007/s11356-019-07348-4 .,
conv_870 .

TY  - JOUR
AU  - Stojanović, Jovica
AU  - Đorđević, Tamara
AU  - Karanović, Ljiljana
PY  - 2012
UR  - https://ritnms.itnms.ac.rs/handle/123456789/205
AB  - Two new compounds, Cd1.16Zn2.34(AsO4)(1.5)(HAsO4)(H2AsO4)(0.5) (1) and Cd0.74Mg2.76(AsO4)(1.5)-(HAsO4)(H2AsO4)(0.5) (2), have been prepared hydrothermally. Their crystal structures consist of chains of edge-sharing M1O(4)(OH0.5)(2), M1aO(4)(OH0.5)(2), M2O5(OH0.5), and M(2)aO(5)(OH0.5) octahedra (M1, M1a = Zn, Cd; M2, M2a = Zn for 1, and M1, M1a = Mg, Cd; M2, M2a = Mg for 2) that are stacked parallel to (1 0 1) and are connected by the [(AsO4)(0.5)(AsO3(OH))(0.5)](2.5-) and [(AsO4)(0.5)(AsO2(OH)(2))(0.5)](2-) tetrahedra. These chains produce two types of channels parallel to the c-axis. Cd atoms are located in channels 2, while in channels 1 are situated hydrogen atoms of O-H groups. The infrared spectra clearly show the presence of broad O-H stretching and bending vibrations centred at 3236, 2392 1575 and 1396 cm(-1) in (1), and 3210, 2379 1602 and 1310 cm(-1) in (2). The O-H stretching frequency is in good agreement with O center dot center dot center dot O distances. Furthermore, structural characteristics of compounds with similar alluaudite-like structures were discussed.
PB  - Elsevier Science Sa, Lausanne
T2  - Journal of Alloys and Compounds
T1  - Structural features of two novel alluaudite-like arsenates Cd1.16Zn2.34(AsO4)(1.5)(HAsO4)(H2AsO4)(0.5) and Cd0.74Mg2.76(AsO4)(1.5)(HAsO4)(H2AsO4)(0.5)
EP  - 189
SP  - 180
VL  - 520
DO  - 10.1016/j.jallcom.2012.01.002
UR  - conv_614
ER  - 

@article{
author = "Stojanović, Jovica and Đorđević, Tamara and Karanović, Ljiljana",
year = "2012",
abstract = "Two new compounds, Cd1.16Zn2.34(AsO4)(1.5)(HAsO4)(H2AsO4)(0.5) (1) and Cd0.74Mg2.76(AsO4)(1.5)-(HAsO4)(H2AsO4)(0.5) (2), have been prepared hydrothermally. Their crystal structures consist of chains of edge-sharing M1O(4)(OH0.5)(2), M1aO(4)(OH0.5)(2), M2O5(OH0.5), and M(2)aO(5)(OH0.5) octahedra (M1, M1a = Zn, Cd; M2, M2a = Zn for 1, and M1, M1a = Mg, Cd; M2, M2a = Mg for 2) that are stacked parallel to (1 0 1) and are connected by the [(AsO4)(0.5)(AsO3(OH))(0.5)](2.5-) and [(AsO4)(0.5)(AsO2(OH)(2))(0.5)](2-) tetrahedra. These chains produce two types of channels parallel to the c-axis. Cd atoms are located in channels 2, while in channels 1 are situated hydrogen atoms of O-H groups. The infrared spectra clearly show the presence of broad O-H stretching and bending vibrations centred at 3236, 2392 1575 and 1396 cm(-1) in (1), and 3210, 2379 1602 and 1310 cm(-1) in (2). The O-H stretching frequency is in good agreement with O center dot center dot center dot O distances. Furthermore, structural characteristics of compounds with similar alluaudite-like structures were discussed.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Journal of Alloys and Compounds",
title = "Structural features of two novel alluaudite-like arsenates Cd1.16Zn2.34(AsO4)(1.5)(HAsO4)(H2AsO4)(0.5) and Cd0.74Mg2.76(AsO4)(1.5)(HAsO4)(H2AsO4)(0.5)",
pages = "189-180",
volume = "520",
doi = "10.1016/j.jallcom.2012.01.002",
url = "conv_614"
}

Stojanović, J., Đorđević, T.,& Karanović, L.. (2012). Structural features of two novel alluaudite-like arsenates Cd1.16Zn2.34(AsO4)(1.5)(HAsO4)(H2AsO4)(0.5) and Cd0.74Mg2.76(AsO4)(1.5)(HAsO4)(H2AsO4)(0.5). in Journal of Alloys and Compounds
Elsevier Science Sa, Lausanne., 520, 180-189.
https://doi.org/10.1016/j.jallcom.2012.01.002
conv_614

Stojanović J, Đorđević T, Karanović L. Structural features of two novel alluaudite-like arsenates Cd1.16Zn2.34(AsO4)(1.5)(HAsO4)(H2AsO4)(0.5) and Cd0.74Mg2.76(AsO4)(1.5)(HAsO4)(H2AsO4)(0.5). in Journal of Alloys and Compounds. 2012;520:180-189.
doi:10.1016/j.jallcom.2012.01.002
conv_614 .

Stojanović, Jovica, Đorđević, Tamara, Karanović, Ljiljana, "Structural features of two novel alluaudite-like arsenates Cd1.16Zn2.34(AsO4)(1.5)(HAsO4)(H2AsO4)(0.5) and Cd0.74Mg2.76(AsO4)(1.5)(HAsO4)(H2AsO4)(0.5)" in Journal of Alloys and Compounds, 520 (2012):180-189,
https://doi.org/10.1016/j.jallcom.2012.01.002 .,
conv_614 .

TY  - JOUR
AU  - Đorđević, Tamara
AU  - Stojanović, Jovica
AU  - Karanović, Ljiljana
PY  - 2010
UR  - https://ritnms.itnms.ac.rs/handle/123456789/184
AB  - The title compound, dizinc cadmium hydroxide tetraoxido-vanadate, Zn 1.86Cd0.14(OH)VO4, was prepared under low-temperature hydro-thermal conditions. It is isostructural with Zn 2(OH)VO4 and Cu2(OH)VO4. In the crystal structure, chains of edge-sharing [ZnO6] octahedra are inter-connected by VO4 tetra-hedra (site symmetries of both V atoms and their coordination polyhedra are.m.) to form a three-dimensional [Zn(OH)VO4]2- framework with channels occupied by Zn and Zn/Cd cations adopting trigonal-bipyramidal and distorted octa-hedral coordinations, respectively. Zn1.86Cd0.14(OH)VO 4 is topologically related to adamite-type phases, and descloizite- and tsumcorite-type structures.
PB  - International Union of Crystallography
T2  - Acta Crystallographica Section E: Structure Reports Online
T1  - Zn1.86Cd0.14(OH)VO4
IS  - 12
VL  - 66
DO  - 10.1107/S1600536810044806
UR  - conv_1083
ER  - 

@article{
author = "Đorđević, Tamara and Stojanović, Jovica and Karanović, Ljiljana",
year = "2010",
abstract = "The title compound, dizinc cadmium hydroxide tetraoxido-vanadate, Zn 1.86Cd0.14(OH)VO4, was prepared under low-temperature hydro-thermal conditions. It is isostructural with Zn 2(OH)VO4 and Cu2(OH)VO4. In the crystal structure, chains of edge-sharing [ZnO6] octahedra are inter-connected by VO4 tetra-hedra (site symmetries of both V atoms and their coordination polyhedra are.m.) to form a three-dimensional [Zn(OH)VO4]2- framework with channels occupied by Zn and Zn/Cd cations adopting trigonal-bipyramidal and distorted octa-hedral coordinations, respectively. Zn1.86Cd0.14(OH)VO 4 is topologically related to adamite-type phases, and descloizite- and tsumcorite-type structures.",
publisher = "International Union of Crystallography",
journal = "Acta Crystallographica Section E: Structure Reports Online",
title = "Zn1.86Cd0.14(OH)VO4",
number = "12",
volume = "66",
doi = "10.1107/S1600536810044806",
url = "conv_1083"
}

Đorđević, T., Stojanović, J.,& Karanović, L.. (2010). Zn1.86Cd0.14(OH)VO4. in Acta Crystallographica Section E: Structure Reports Online
International Union of Crystallography., 66(12).
https://doi.org/10.1107/S1600536810044806
conv_1083

Đorđević T, Stojanović J, Karanović L. Zn1.86Cd0.14(OH)VO4. in Acta Crystallographica Section E: Structure Reports Online. 2010;66(12).
doi:10.1107/S1600536810044806
conv_1083 .

Đorđević, Tamara, Stojanović, Jovica, Karanović, Ljiljana, "Zn1.86Cd0.14(OH)VO4" in Acta Crystallographica Section E: Structure Reports Online, 66, no. 12 (2010),
https://doi.org/10.1107/S1600536810044806 .,
conv_1083 .

TY  - JOUR
AU  - Stojanović, Jovica
AU  - Đorđević, Tamara
AU  - Karanović, Ljiljana
PY  - 2010
UR  - https://ritnms.itnms.ac.rs/handle/123456789/180
AB  - The structure of the title compound, ammineaquadi-mu(5)-phosphato-trizinc(II), [Zn-3(PO4)(2)(H2O)(0.8)(NH3)(1.2)], consists of two parts: (i) PO4 and ZnO4 vertex-sharing tetrahedra arranged in layers parallel to (100) and (ii) ZnO2(N/O)(2) tetrahedra located between the layers. Elemental analysis establishes the ammine-to-water ratio as 3:2. ZnO2(N/O)(2) tetrahedra are located at special position 4e (site symmetry 2) in C2/c. The two O atoms of ZnO2(N/O)(2) are bonded to neighbouring P atoms, forming two Zn-O-P linkages and connecting ZnO2(N/O)(2) tetrahedra with two adjacent bc plane layers. A noteworthy feature of the structure is the presence of NH3 and H2O at the same crystallographic position and, consequently, qualitative changes in the pattern of hydrogen bonding and weaker N/O-H center dot center dot center dot O electrostatic interactions, as compared to two closely related structures.
PB  - Wiley-Blackwell, Malden
T2  - Acta Crystallographica Section C-Crystal Structure Communications
T1  - [Zn-3(PO4)(2)(H2O)(0.8)(NH3)(1.2)]
EP  - I57
SP  - I55
VL  - 66
DO  - 10.1107/S0108270110014885
UR  - conv_581
ER  - 

@article{
author = "Stojanović, Jovica and Đorđević, Tamara and Karanović, Ljiljana",
year = "2010",
abstract = "The structure of the title compound, ammineaquadi-mu(5)-phosphato-trizinc(II), [Zn-3(PO4)(2)(H2O)(0.8)(NH3)(1.2)], consists of two parts: (i) PO4 and ZnO4 vertex-sharing tetrahedra arranged in layers parallel to (100) and (ii) ZnO2(N/O)(2) tetrahedra located between the layers. Elemental analysis establishes the ammine-to-water ratio as 3:2. ZnO2(N/O)(2) tetrahedra are located at special position 4e (site symmetry 2) in C2/c. The two O atoms of ZnO2(N/O)(2) are bonded to neighbouring P atoms, forming two Zn-O-P linkages and connecting ZnO2(N/O)(2) tetrahedra with two adjacent bc plane layers. A noteworthy feature of the structure is the presence of NH3 and H2O at the same crystallographic position and, consequently, qualitative changes in the pattern of hydrogen bonding and weaker N/O-H center dot center dot center dot O electrostatic interactions, as compared to two closely related structures.",
publisher = "Wiley-Blackwell, Malden",
journal = "Acta Crystallographica Section C-Crystal Structure Communications",
title = "[Zn-3(PO4)(2)(H2O)(0.8)(NH3)(1.2)]",
pages = "I57-I55",
volume = "66",
doi = "10.1107/S0108270110014885",
url = "conv_581"
}

Stojanović, J., Đorđević, T.,& Karanović, L.. (2010). [Zn-3(PO4)(2)(H2O)(0.8)(NH3)(1.2)]. in Acta Crystallographica Section C-Crystal Structure Communications
Wiley-Blackwell, Malden., 66, I55-I57.
https://doi.org/10.1107/S0108270110014885
conv_581

Stojanović J, Đorđević T, Karanović L. [Zn-3(PO4)(2)(H2O)(0.8)(NH3)(1.2)]. in Acta Crystallographica Section C-Crystal Structure Communications. 2010;66:I55-I57.
doi:10.1107/S0108270110014885
conv_581 .

Stojanović, Jovica, Đorđević, Tamara, Karanović, Ljiljana, "[Zn-3(PO4)(2)(H2O)(0.8)(NH3)(1.2)]" in Acta Crystallographica Section C-Crystal Structure Communications, 66 (2010):I55-I57,
https://doi.org/10.1107/S0108270110014885 .,
conv_581 .

TY  - JOUR
AU  - Đorđević, Tamara
AU  - Sutović, Sabina
AU  - Stojanović, Jovica
AU  - Karanović, Ljiljana
PY  - 2008
UR  - https://ritnms.itnms.ac.rs/handle/123456789/136
AB  - X-ray diffraction analysis of single crystals of three new arsenates adopting apatite-type structures yielded formula Sr(5)(AsO(4))(3)F for strontium arsenate fluoride, (I), (Sr(1.66)Ba(0.34))-(Ba(2.61)Sr(0.39))(AsO(4))(3)Cl for strontium barium arsenate chloride, (II), and Cd(5)(AsO(4))(3)Cl(0.58)(OH)(0.42) for cadmium arsenate hydroxide chloride, (III). All three structures are built up of isolated slightly distorted AsO(4) tetrahedra that are bridged by Sr(2+) in (I), by Sr(2+)/Ba(2+) in (II) and by Cd(2+) in (III). Compounds (I) and ( II) represent typical fluorapatites and chlorapatites, respectively, with F(-) at the 2a (0, 0, 1/4) site and Cl(-) at the 2b (0, 0, 0) site of P6(3)/m. In contrast, in (III), due to the requirement that the smaller Cd(2+) cation is positioned closer to the channel Cl(-) anion (partially substituted by OH(-)), the anion occupies the unusual 2a (0, 0, 1/4) site. Therefore, Cl(-) is similar to F(-) in (I), coordinated by three A2 cations, unlike the octahedrally coordinated Cl(-) in (II) and other ordinary chlorapatites. Furthermore, in (III), using FTIR studies, we have inferred the existence of H(+) outside the channel in oxyhydroxyapatites and provided possible atomic coordinates for a H atom in HAsO(4)(2-), leading to a proposed formulation of the compound as Cd(5)(AsO(4))(3-x)(HAsO(4))(x)-Cl(0.58)(OH)(0.42-x-(y/2))O(x+(y/2))square(y/2).
PB  - Wiley-Blackwell, Malden
T2  - Acta Crystallographica Section C-Crystal Structure Communications
T1  - Sr, Ba and Cd arsenates with the apatite-type structure
EP  - I86
SP  - I82
VL  - 64
DO  - 10.1107/S0108270108023457
UR  - conv_549
ER  - 

@article{
author = "Đorđević, Tamara and Sutović, Sabina and Stojanović, Jovica and Karanović, Ljiljana",
year = "2008",
abstract = "X-ray diffraction analysis of single crystals of three new arsenates adopting apatite-type structures yielded formula Sr(5)(AsO(4))(3)F for strontium arsenate fluoride, (I), (Sr(1.66)Ba(0.34))-(Ba(2.61)Sr(0.39))(AsO(4))(3)Cl for strontium barium arsenate chloride, (II), and Cd(5)(AsO(4))(3)Cl(0.58)(OH)(0.42) for cadmium arsenate hydroxide chloride, (III). All three structures are built up of isolated slightly distorted AsO(4) tetrahedra that are bridged by Sr(2+) in (I), by Sr(2+)/Ba(2+) in (II) and by Cd(2+) in (III). Compounds (I) and ( II) represent typical fluorapatites and chlorapatites, respectively, with F(-) at the 2a (0, 0, 1/4) site and Cl(-) at the 2b (0, 0, 0) site of P6(3)/m. In contrast, in (III), due to the requirement that the smaller Cd(2+) cation is positioned closer to the channel Cl(-) anion (partially substituted by OH(-)), the anion occupies the unusual 2a (0, 0, 1/4) site. Therefore, Cl(-) is similar to F(-) in (I), coordinated by three A2 cations, unlike the octahedrally coordinated Cl(-) in (II) and other ordinary chlorapatites. Furthermore, in (III), using FTIR studies, we have inferred the existence of H(+) outside the channel in oxyhydroxyapatites and provided possible atomic coordinates for a H atom in HAsO(4)(2-), leading to a proposed formulation of the compound as Cd(5)(AsO(4))(3-x)(HAsO(4))(x)-Cl(0.58)(OH)(0.42-x-(y/2))O(x+(y/2))square(y/2).",
publisher = "Wiley-Blackwell, Malden",
journal = "Acta Crystallographica Section C-Crystal Structure Communications",
title = "Sr, Ba and Cd arsenates with the apatite-type structure",
pages = "I86-I82",
volume = "64",
doi = "10.1107/S0108270108023457",
url = "conv_549"
}

Đorđević, T., Sutović, S., Stojanović, J.,& Karanović, L.. (2008). Sr, Ba and Cd arsenates with the apatite-type structure. in Acta Crystallographica Section C-Crystal Structure Communications
Wiley-Blackwell, Malden., 64, I82-I86.
https://doi.org/10.1107/S0108270108023457
conv_549

Đorđević T, Sutović S, Stojanović J, Karanović L. Sr, Ba and Cd arsenates with the apatite-type structure. in Acta Crystallographica Section C-Crystal Structure Communications. 2008;64:I82-I86.
doi:10.1107/S0108270108023457
conv_549 .

Đorđević, Tamara, Sutović, Sabina, Stojanović, Jovica, Karanović, Ljiljana, "Sr, Ba and Cd arsenates with the apatite-type structure" in Acta Crystallographica Section C-Crystal Structure Communications, 64 (2008):I82-I86,
https://doi.org/10.1107/S0108270108023457 .,
conv_549 .

TY  - JOUR
AU  - Stojanović, Jovica
AU  - Đorđević, Tamara
AU  - Karanović, Ljiljana
PY  - 2008
UR  - https://ritnms.itnms.ac.rs/handle/123456789/126
AB  - During an investigation of the insufficiently known system M1O-M2O-X(2)O(5)-H(2)O (M1 = Cd(2+), Sr(2+) and Ba(2+); M2 = Cu(2+), Ni(2+), Co(2+), Zn(2+) and Mg(2+); X = P(5+), As(5+) and V(5+)), single crystals of the novel compound dicadmium copper(II) bis[phosphate(V)], Cd(2)Cu(PO(4))(2), were obtained. This compound belongs to a small group of compounds adopting a Cu(3)(PO(4))(2)-type structure and having the general formula M1(2)M(2)(XO(4))(2) (M1/M2 = Cd(2+), Cu(2+), Mg(2+) and Zn(2+); X = As(5+), P(5+) and V(5+)). The crystal structure is characterized by the interconnection of infinite [Cu(PO(4))(2)] n chains and [Cd(2)O(10)](n) double chains, both extending along the a axis. Exceptional characteristics of this structure are its novel chemical composition and the occurrence of double chains of CdO(6) polyhedra that were not found in related structures. In contrast to the isomorphous compounds, where the M1 cations are coordinated by five O atoms, the Cd atom is coordinated by six. The dissimilarity in the geometry of M1 coordination between Cd(2)Cu(PO(4))(2) and the isomorphous compounds is mostly due to the larger ionic radius of the Cd cation in comparison with the Cu, Mg and Zn cations. Sharing a common edge, two CdO(6) polyhedra form Cd(2)O(10) dimers. Each such dimer is bonded to another dimer sharing common vertices, forming [Cd(2)O(10)](n) double chains in the [100] direction. The Cu atoms, located on an inversion centre (site symmetry 1), form isolated CuO(4) squares interconnected by PO(4) tetrahedra, forming [Cu(PO(4))(2)](n) chains similar to those found in related structures. Conversely, the [Cd(2)O(10)](n) double chains, which were not found in related structures, are an exclusive feature of this structure.
PB  - Wiley-Blackwell, Malden
T2  - Acta Crystallographica Section C-Crystal Structure Communications
T1  - Cd(2)Cu(PO(4))(2)
EP  - I94
SP  - I91
VL  - 64
DO  - 10.1107/S0108270108032332
UR  - conv_493
ER  - 

@article{
author = "Stojanović, Jovica and Đorđević, Tamara and Karanović, Ljiljana",
year = "2008",
abstract = "During an investigation of the insufficiently known system M1O-M2O-X(2)O(5)-H(2)O (M1 = Cd(2+), Sr(2+) and Ba(2+); M2 = Cu(2+), Ni(2+), Co(2+), Zn(2+) and Mg(2+); X = P(5+), As(5+) and V(5+)), single crystals of the novel compound dicadmium copper(II) bis[phosphate(V)], Cd(2)Cu(PO(4))(2), were obtained. This compound belongs to a small group of compounds adopting a Cu(3)(PO(4))(2)-type structure and having the general formula M1(2)M(2)(XO(4))(2) (M1/M2 = Cd(2+), Cu(2+), Mg(2+) and Zn(2+); X = As(5+), P(5+) and V(5+)). The crystal structure is characterized by the interconnection of infinite [Cu(PO(4))(2)] n chains and [Cd(2)O(10)](n) double chains, both extending along the a axis. Exceptional characteristics of this structure are its novel chemical composition and the occurrence of double chains of CdO(6) polyhedra that were not found in related structures. In contrast to the isomorphous compounds, where the M1 cations are coordinated by five O atoms, the Cd atom is coordinated by six. The dissimilarity in the geometry of M1 coordination between Cd(2)Cu(PO(4))(2) and the isomorphous compounds is mostly due to the larger ionic radius of the Cd cation in comparison with the Cu, Mg and Zn cations. Sharing a common edge, two CdO(6) polyhedra form Cd(2)O(10) dimers. Each such dimer is bonded to another dimer sharing common vertices, forming [Cd(2)O(10)](n) double chains in the [100] direction. The Cu atoms, located on an inversion centre (site symmetry 1), form isolated CuO(4) squares interconnected by PO(4) tetrahedra, forming [Cu(PO(4))(2)](n) chains similar to those found in related structures. Conversely, the [Cd(2)O(10)](n) double chains, which were not found in related structures, are an exclusive feature of this structure.",
publisher = "Wiley-Blackwell, Malden",
journal = "Acta Crystallographica Section C-Crystal Structure Communications",
title = "Cd(2)Cu(PO(4))(2)",
pages = "I94-I91",
volume = "64",
doi = "10.1107/S0108270108032332",
url = "conv_493"
}

Stojanović, J., Đorđević, T.,& Karanović, L.. (2008). Cd(2)Cu(PO(4))(2). in Acta Crystallographica Section C-Crystal Structure Communications
Wiley-Blackwell, Malden., 64, I91-I94.
https://doi.org/10.1107/S0108270108032332
conv_493

Stojanović J, Đorđević T, Karanović L. Cd(2)Cu(PO(4))(2). in Acta Crystallographica Section C-Crystal Structure Communications. 2008;64:I91-I94.
doi:10.1107/S0108270108032332
conv_493 .

Stojanović, Jovica, Đorđević, Tamara, Karanović, Ljiljana, "Cd(2)Cu(PO(4))(2)" in Acta Crystallographica Section C-Crystal Structure Communications, 64 (2008):I91-I94,
https://doi.org/10.1107/S0108270108032332 .,
conv_493 .