Topalović, Vladimir

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orcid::0000-0002-4177-4649
  • Topalović, Vladimir (9)
Projects

Author's Bibliography

The effect of SrO and La2O3 addition on the crystallization characteristics and sintering behavior of distinct polyphosphate glasses

Topalović, Vladimir; Nikolić, Jelena; Matijašević, Srđan; Stojanović, Jovica; Karamanov, Alexander; Grujić, Snežana; Jevtić, Sanja

(Dordrecht : Springer, 2023)

TY  - JOUR
AU  - Topalović, Vladimir
AU  - Nikolić, Jelena
AU  - Matijašević, Srđan
AU  - Stojanović, Jovica
AU  - Karamanov, Alexander
AU  - Grujić, Snežana
AU  - Jevtić, Sanja
PY  - 2023
UR  - https://ritnms.itnms.ac.rs/handle/123456789/650
AB  - The goal of this research is to investigate the effect of SrO and La2O3 addition on the crystallization characteristics and sintering behavior of polyphosphate glasses. Differential scanning calorimetry (DSC), hot stage microscopy (HSM), X-ray diffraction (XRD), and scanning electron microscopy (SEM) methods were used to investigate the crystallization and sintering behaviors of glasses. The addition of SrO and La2O3 (1 or 5%), at the expense of phosphate mole fraction in polyphosphate bioactive glass, raises the characteristic temperature of glasses, and resistance to crystallization. Furthermore, the temperature of maximal shrinkage increases with the addition of SrO and La2O3. Surface crystallization is the dominant mechanism of crystallization in all samples. All glasses show complex crystallization leading to the formation of several crystalline phases. Sintered phosphate glass-ceramic containing bioactive beta-CaP2O6, alpha-Ca-3(PO4)(2,) and beta-Ca-3(PO4)(2) phases were successfully prepared.
PB  - Dordrecht : Springer
T2  - Journal of Thermal Analysis and Calorimetry
T1  - The effect of SrO and La2O3 addition on the crystallization characteristics and sintering behavior of distinct polyphosphate glasses
EP  - 732
EP  - 
IS  - 3
SP  - 721
VL  - 148
DO  - 10.1007/s10973-022-11777-8
UR  - conv_958
ER  - 
@article{
author = "Topalović, Vladimir and Nikolić, Jelena and Matijašević, Srđan and Stojanović, Jovica and Karamanov, Alexander and Grujić, Snežana and Jevtić, Sanja",
year = "2023",
abstract = "The goal of this research is to investigate the effect of SrO and La2O3 addition on the crystallization characteristics and sintering behavior of polyphosphate glasses. Differential scanning calorimetry (DSC), hot stage microscopy (HSM), X-ray diffraction (XRD), and scanning electron microscopy (SEM) methods were used to investigate the crystallization and sintering behaviors of glasses. The addition of SrO and La2O3 (1 or 5%), at the expense of phosphate mole fraction in polyphosphate bioactive glass, raises the characteristic temperature of glasses, and resistance to crystallization. Furthermore, the temperature of maximal shrinkage increases with the addition of SrO and La2O3. Surface crystallization is the dominant mechanism of crystallization in all samples. All glasses show complex crystallization leading to the formation of several crystalline phases. Sintered phosphate glass-ceramic containing bioactive beta-CaP2O6, alpha-Ca-3(PO4)(2,) and beta-Ca-3(PO4)(2) phases were successfully prepared.",
publisher = "Dordrecht : Springer",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "The effect of SrO and La2O3 addition on the crystallization characteristics and sintering behavior of distinct polyphosphate glasses",
pages = "732--721",
number = "3",
volume = "148",
doi = "10.1007/s10973-022-11777-8",
url = "conv_958"
}
Topalović, V., Nikolić, J., Matijašević, S., Stojanović, J., Karamanov, A., Grujić, S.,& Jevtić, S.. (2023). The effect of SrO and La2O3 addition on the crystallization characteristics and sintering behavior of distinct polyphosphate glasses. in Journal of Thermal Analysis and Calorimetry
Dordrecht : Springer., 148(3), 721-732.
https://doi.org/10.1007/s10973-022-11777-8
conv_958
Topalović V, Nikolić J, Matijašević S, Stojanović J, Karamanov A, Grujić S, Jevtić S. The effect of SrO and La2O3 addition on the crystallization characteristics and sintering behavior of distinct polyphosphate glasses. in Journal of Thermal Analysis and Calorimetry. 2023;148(3):721-732.
doi:10.1007/s10973-022-11777-8
conv_958 .
Topalović, Vladimir, Nikolić, Jelena, Matijašević, Srđan, Stojanović, Jovica, Karamanov, Alexander, Grujić, Snežana, Jevtić, Sanja, "The effect of SrO and La2O3 addition on the crystallization characteristics and sintering behavior of distinct polyphosphate glasses" in Journal of Thermal Analysis and Calorimetry, 148, no. 3 (2023):721-732,
https://doi.org/10.1007/s10973-022-11777-8 .,
conv_958 .
2
2

The Analysis of the Nucleation Process of the Lithium Germanium Phosphate Glass

Matijašević, Srđan; Grujić, Snežana R.; Nikolić, Jelena; Topalović, Vladimir; Savić, Veljko; Zildžović, Snežana; Labus, Nebojša

(Međunarodni Institut za nauku o sinterovanju, Beograd, 2022)

TY  - JOUR
AU  - Matijašević, Srđan
AU  - Grujić, Snežana R.
AU  - Nikolić, Jelena
AU  - Topalović, Vladimir
AU  - Savić, Veljko
AU  - Zildžović, Snežana
AU  - Labus, Nebojša
PY  - 2022
UR  - https://ritnms.itnms.ac.rs/handle/123456789/619
AB  - The nucleation process of lithium germanium-phosphate glass was studied to determine the temperature range of nucleation and the temperature of the maximum nucleation rate. The differential thermal analysis (DTA), and scanning electron microscope (SEM) were used to reveal the nonisothermal and isothermal process of nucleation, respectively. The crystallization process occurred at a high homogeneous nucleation rate and the spherulitic crystal growth morphology. Nanostructured samples were obtained.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - The Analysis of the Nucleation Process of the Lithium Germanium Phosphate Glass
EP  - 334
IS  - 3
SP  - 321
VL  - 54
DO  - 10.2298/SOS2203321M
UR  - conv_960
UR  - https://hdl.handle.net/21.15107/rcub_dais_13580
ER  - 
@article{
author = "Matijašević, Srđan and Grujić, Snežana R. and Nikolić, Jelena and Topalović, Vladimir and Savić, Veljko and Zildžović, Snežana and Labus, Nebojša",
year = "2022",
abstract = "The nucleation process of lithium germanium-phosphate glass was studied to determine the temperature range of nucleation and the temperature of the maximum nucleation rate. The differential thermal analysis (DTA), and scanning electron microscope (SEM) were used to reveal the nonisothermal and isothermal process of nucleation, respectively. The crystallization process occurred at a high homogeneous nucleation rate and the spherulitic crystal growth morphology. Nanostructured samples were obtained.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "The Analysis of the Nucleation Process of the Lithium Germanium Phosphate Glass",
pages = "334-321",
number = "3",
volume = "54",
doi = "10.2298/SOS2203321M",
url = "conv_960, https://hdl.handle.net/21.15107/rcub_dais_13580"
}
Matijašević, S., Grujić, S. R., Nikolić, J., Topalović, V., Savić, V., Zildžović, S.,& Labus, N.. (2022). The Analysis of the Nucleation Process of the Lithium Germanium Phosphate Glass. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 54(3), 321-334.
https://doi.org/10.2298/SOS2203321M
conv_960
Matijašević S, Grujić SR, Nikolić J, Topalović V, Savić V, Zildžović S, Labus N. The Analysis of the Nucleation Process of the Lithium Germanium Phosphate Glass. in Science of Sintering. 2022;54(3):321-334.
doi:10.2298/SOS2203321M
conv_960 .
Matijašević, Srđan, Grujić, Snežana R., Nikolić, Jelena, Topalović, Vladimir, Savić, Veljko, Zildžović, Snežana, Labus, Nebojša, "The Analysis of the Nucleation Process of the Lithium Germanium Phosphate Glass" in Science of Sintering, 54, no. 3 (2022):321-334,
https://doi.org/10.2298/SOS2203321M .,
conv_960 .
1

Chemical durability of sintered glass-composite prepared from glass cullet and waste foundry sand

Savić, Veljko; Topalović, Vladimir; Matijašević, Srđan; Nikolić, Jelena; Grujić, Snežana; Zildžović, Snežana; Radulović, Aleksandra

(Savez inženjera metalurgije Srbije, Beograd, 2021)

TY  - JOUR
AU  - Savić, Veljko
AU  - Topalović, Vladimir
AU  - Matijašević, Srđan
AU  - Nikolić, Jelena
AU  - Grujić, Snežana
AU  - Zildžović, Snežana
AU  - Radulović, Aleksandra
PY  - 2021
UR  - https://ritnms.itnms.ac.rs/handle/123456789/597
AB  - In this study, the glass-composite was prepared using glass cullet and waste foundry sand as raw materials. The powder technology route was employed. The mixtures containing 10-50 wt% of the sand were sintered at T = 750 degrees C for t =1h. XRD and DTA analyses were performed. The chemical durability of the resulting glass-composite was determined by leaching test in HCl, H2SO4, NaOH and distilled water at T = 95 degrees C for t =1h. It was shown that the sintering process carried out without the crystallization of the glass matrix. The lowest chemical durability was determined in alkali solution of glasscomposite.
PB  - Savez inženjera metalurgije Srbije, Beograd
T2  - Metallurgical & Materials Engineering
T1  - Chemical durability of sintered glass-composite prepared from glass cullet and waste foundry sand
EP  - 113
IS  - 1
SP  - 105
VL  - 27
DO  - 10.30544/477
UR  - conv_906
ER  - 
@article{
author = "Savić, Veljko and Topalović, Vladimir and Matijašević, Srđan and Nikolić, Jelena and Grujić, Snežana and Zildžović, Snežana and Radulović, Aleksandra",
year = "2021",
abstract = "In this study, the glass-composite was prepared using glass cullet and waste foundry sand as raw materials. The powder technology route was employed. The mixtures containing 10-50 wt% of the sand were sintered at T = 750 degrees C for t =1h. XRD and DTA analyses were performed. The chemical durability of the resulting glass-composite was determined by leaching test in HCl, H2SO4, NaOH and distilled water at T = 95 degrees C for t =1h. It was shown that the sintering process carried out without the crystallization of the glass matrix. The lowest chemical durability was determined in alkali solution of glasscomposite.",
publisher = "Savez inženjera metalurgije Srbije, Beograd",
journal = "Metallurgical & Materials Engineering",
title = "Chemical durability of sintered glass-composite prepared from glass cullet and waste foundry sand",
pages = "113-105",
number = "1",
volume = "27",
doi = "10.30544/477",
url = "conv_906"
}
Savić, V., Topalović, V., Matijašević, S., Nikolić, J., Grujić, S., Zildžović, S.,& Radulović, A.. (2021). Chemical durability of sintered glass-composite prepared from glass cullet and waste foundry sand. in Metallurgical & Materials Engineering
Savez inženjera metalurgije Srbije, Beograd., 27(1), 105-113.
https://doi.org/10.30544/477
conv_906
Savić V, Topalović V, Matijašević S, Nikolić J, Grujić S, Zildžović S, Radulović A. Chemical durability of sintered glass-composite prepared from glass cullet and waste foundry sand. in Metallurgical & Materials Engineering. 2021;27(1):105-113.
doi:10.30544/477
conv_906 .
Savić, Veljko, Topalović, Vladimir, Matijašević, Srđan, Nikolić, Jelena, Grujić, Snežana, Zildžović, Snežana, Radulović, Aleksandra, "Chemical durability of sintered glass-composite prepared from glass cullet and waste foundry sand" in Metallurgical & Materials Engineering, 27, no. 1 (2021):105-113,
https://doi.org/10.30544/477 .,
conv_906 .
2
2

The Thermophysical Properties of Primary Phase in Lithium Germanium Phosphate Glass

Matijašević, Srđan; Topalović, Vladimir; Grujić, Snežana R.; Savić, Veljko; Nikolić, Jelena; Labus, Nebojša; Zildžović, Snežana

(Međunarodni Institut za nauku o sinterovanju, Beograd, 2021)

TY  - JOUR
AU  - Matijašević, Srđan
AU  - Topalović, Vladimir
AU  - Grujić, Snežana R.
AU  - Savić, Veljko
AU  - Nikolić, Jelena
AU  - Labus, Nebojša
AU  - Zildžović, Snežana
PY  - 2021
UR  - https://ritnms.itnms.ac.rs/handle/123456789/576
AB  - The selected lithium germanium-phosphate glass was prepared by a conventional melt-quenching technique. The XRD method was employed to confirm the glass was obtained and to reveal crystalline phases during heat treatment. The dilatometry (DIL), differential thermal analysis (DTA), and differential scanning calorimetry (DSC) were used to determine the characteristic temperatures and enthalpies of crystallization and melting of the crystalline phase. The DTA and DIL were used to obtain the viscosity curves by applying the VogelFulcher-Tammann (VFT) equation.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - The Thermophysical Properties of Primary Phase in Lithium Germanium Phosphate Glass
EP  - 310
IS  - 3
SP  - 301
VL  - 53
DO  - 10.2298/SOS2103301M
UR  - conv_926
ER  - 
@article{
author = "Matijašević, Srđan and Topalović, Vladimir and Grujić, Snežana R. and Savić, Veljko and Nikolić, Jelena and Labus, Nebojša and Zildžović, Snežana",
year = "2021",
abstract = "The selected lithium germanium-phosphate glass was prepared by a conventional melt-quenching technique. The XRD method was employed to confirm the glass was obtained and to reveal crystalline phases during heat treatment. The dilatometry (DIL), differential thermal analysis (DTA), and differential scanning calorimetry (DSC) were used to determine the characteristic temperatures and enthalpies of crystallization and melting of the crystalline phase. The DTA and DIL were used to obtain the viscosity curves by applying the VogelFulcher-Tammann (VFT) equation.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "The Thermophysical Properties of Primary Phase in Lithium Germanium Phosphate Glass",
pages = "310-301",
number = "3",
volume = "53",
doi = "10.2298/SOS2103301M",
url = "conv_926"
}
Matijašević, S., Topalović, V., Grujić, S. R., Savić, V., Nikolić, J., Labus, N.,& Zildžović, S.. (2021). The Thermophysical Properties of Primary Phase in Lithium Germanium Phosphate Glass. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 53(3), 301-310.
https://doi.org/10.2298/SOS2103301M
conv_926
Matijašević S, Topalović V, Grujić SR, Savić V, Nikolić J, Labus N, Zildžović S. The Thermophysical Properties of Primary Phase in Lithium Germanium Phosphate Glass. in Science of Sintering. 2021;53(3):301-310.
doi:10.2298/SOS2103301M
conv_926 .
Matijašević, Srđan, Topalović, Vladimir, Grujić, Snežana R., Savić, Veljko, Nikolić, Jelena, Labus, Nebojša, Zildžović, Snežana, "The Thermophysical Properties of Primary Phase in Lithium Germanium Phosphate Glass" in Science of Sintering, 53, no. 3 (2021):301-310,
https://doi.org/10.2298/SOS2103301M .,
conv_926 .
1
4

Efekat primene polifosfatnog stakla u supstratima za gajenje cveća i povrća

Vujošević, Ana; Matijašević, Srđan; Smiljanić, Sonja; Nikolić, Jelena; Zečević, Bogoljub; Topalović, Vladimir; Savić, Veljko

(Inženjersko društvo za koroziju, Beograd, 2019)

TY  - JOUR
AU  - Vujošević, Ana
AU  - Matijašević, Srđan
AU  - Smiljanić, Sonja
AU  - Nikolić, Jelena
AU  - Zečević, Bogoljub
AU  - Topalović, Vladimir
AU  - Savić, Veljko
PY  - 2019
UR  - https://ritnms.itnms.ac.rs/handle/123456789/495
AB  - Polifosfatno staklo, u kome je molski odnos (M2O + MO)/P2O5 >1, koje sadrži i mikroelemente Zn2+, Mn2+, Fe3+ i Cu2+, korišćeno je u supstratu za proizvodnju rasada cveća i povrća. Eksperimenti su izvedeni u stakleniku na Poljoprivrednom fakultetu u Beogradu i u laboratorijama ITNMS. Ispitivano je ponašanje polifosfatnog stakla prilikom rastvaranja u dejonizovanoj vodi i 2% rastvoru limunske kiseline na temperaturama od 20, 30, 37 i 50 °C. Ispitan je uticaj vremena rastvaranja na normalizovani gubitak mase (fm) i normalizovane koncentracije jona (fi). Određene su i konstante brzina rastvaranja(kw-dejonizovana voda, kc -2% rastvor limunske kiseline). Vrednosti kc su veće od vrednosti za kw, što potvrđuje uticaj rastvarača i temperature na proces rastvaranja. Rezultati su pokazali pozitivan efekat polifosfatnog stakla na rast i kvalitet ispitivanih biljaka. Primenjena doza polifosfatnog stakla od 1 gl-1 pokazala je najbolji efekat na rast ispitivanih biljaka-rasada.
AB  - Due to the dissolution properties the phosphate glasses can be promising materials for the development of new ecologically safe fertilizers. The complex polyphosphate glass with a molar ratio (M2O + MO)/P2O5 >1 and addition of microelements Zn2+, Mn2+, Fe3+ and Cu2+ were used in substrate for production of flower and vegetables seedlings. Dissolution tests were conducted in deionized water and 2% citric acid. The effects of the reaction time on the normalized glass mass loss (fm) and the normalized concentrations of the ions (fi) at 20, 30, 37 and 50°C were determined. Dissolution rate constants (kw - deionized water, kc -2% citric acid) were also determined (kw-0.0028-0.0094 gm-2, kc-0.029-0.011 gm-2). Values of kc were higher than those of kw, which confirms a significant effect of solvent type and temperature on the dissolution kinetics of glass. The experiments with plants (one vegetable and one flower) showed that the addition of phosphate glass caused an increase in yield and quality of plants. The applied dose of polyphosphate glass of 1gl-1 showed the best effect on the growth of the examined plant seedlings.
PB  - Inženjersko društvo za koroziju, Beograd
T2  - Zaštita materijala
T1  - Efekat primene polifosfatnog stakla u supstratima za gajenje cveća i povrća
T1  - Polyphosphate glass as fertilizer for plant seedlings
EP  - 104
IS  - 1
SP  - 96
VL  - 60
DO  - 10.5937/zasmat1901096V
UR  - conv_159
ER  - 
@article{
author = "Vujošević, Ana and Matijašević, Srđan and Smiljanić, Sonja and Nikolić, Jelena and Zečević, Bogoljub and Topalović, Vladimir and Savić, Veljko",
year = "2019",
abstract = "Polifosfatno staklo, u kome je molski odnos (M2O + MO)/P2O5 >1, koje sadrži i mikroelemente Zn2+, Mn2+, Fe3+ i Cu2+, korišćeno je u supstratu za proizvodnju rasada cveća i povrća. Eksperimenti su izvedeni u stakleniku na Poljoprivrednom fakultetu u Beogradu i u laboratorijama ITNMS. Ispitivano je ponašanje polifosfatnog stakla prilikom rastvaranja u dejonizovanoj vodi i 2% rastvoru limunske kiseline na temperaturama od 20, 30, 37 i 50 °C. Ispitan je uticaj vremena rastvaranja na normalizovani gubitak mase (fm) i normalizovane koncentracije jona (fi). Određene su i konstante brzina rastvaranja(kw-dejonizovana voda, kc -2% rastvor limunske kiseline). Vrednosti kc su veće od vrednosti za kw, što potvrđuje uticaj rastvarača i temperature na proces rastvaranja. Rezultati su pokazali pozitivan efekat polifosfatnog stakla na rast i kvalitet ispitivanih biljaka. Primenjena doza polifosfatnog stakla od 1 gl-1 pokazala je najbolji efekat na rast ispitivanih biljaka-rasada., Due to the dissolution properties the phosphate glasses can be promising materials for the development of new ecologically safe fertilizers. The complex polyphosphate glass with a molar ratio (M2O + MO)/P2O5 >1 and addition of microelements Zn2+, Mn2+, Fe3+ and Cu2+ were used in substrate for production of flower and vegetables seedlings. Dissolution tests were conducted in deionized water and 2% citric acid. The effects of the reaction time on the normalized glass mass loss (fm) and the normalized concentrations of the ions (fi) at 20, 30, 37 and 50°C were determined. Dissolution rate constants (kw - deionized water, kc -2% citric acid) were also determined (kw-0.0028-0.0094 gm-2, kc-0.029-0.011 gm-2). Values of kc were higher than those of kw, which confirms a significant effect of solvent type and temperature on the dissolution kinetics of glass. The experiments with plants (one vegetable and one flower) showed that the addition of phosphate glass caused an increase in yield and quality of plants. The applied dose of polyphosphate glass of 1gl-1 showed the best effect on the growth of the examined plant seedlings.",
publisher = "Inženjersko društvo za koroziju, Beograd",
journal = "Zaštita materijala",
title = "Efekat primene polifosfatnog stakla u supstratima za gajenje cveća i povrća, Polyphosphate glass as fertilizer for plant seedlings",
pages = "104-96",
number = "1",
volume = "60",
doi = "10.5937/zasmat1901096V",
url = "conv_159"
}
Vujošević, A., Matijašević, S., Smiljanić, S., Nikolić, J., Zečević, B., Topalović, V.,& Savić, V.. (2019). Efekat primene polifosfatnog stakla u supstratima za gajenje cveća i povrća. in Zaštita materijala
Inženjersko društvo za koroziju, Beograd., 60(1), 96-104.
https://doi.org/10.5937/zasmat1901096V
conv_159
Vujošević A, Matijašević S, Smiljanić S, Nikolić J, Zečević B, Topalović V, Savić V. Efekat primene polifosfatnog stakla u supstratima za gajenje cveća i povrća. in Zaštita materijala. 2019;60(1):96-104.
doi:10.5937/zasmat1901096V
conv_159 .
Vujošević, Ana, Matijašević, Srđan, Smiljanić, Sonja, Nikolić, Jelena, Zečević, Bogoljub, Topalović, Vladimir, Savić, Veljko, "Efekat primene polifosfatnog stakla u supstratima za gajenje cveća i povrća" in Zaštita materijala, 60, no. 1 (2019):96-104,
https://doi.org/10.5937/zasmat1901096V .,
conv_159 .
1
1

Non-Isothermal Crystallization of Lithium Germanophosphate Glass Studied by Different Kinetic Methods

Matijašević, Srđan; Grujić, Snežana R.; Topalović, Vladimir; Nikolić, Jelena; Smiljanić, Sonja; Labus, Nebojša; Savić, Veljko

(Međunarodni Institut za nauku o sinterovanju, Beograd, 2018)

TY  - JOUR
AU  - Matijašević, Srđan
AU  - Grujić, Snežana R.
AU  - Topalović, Vladimir
AU  - Nikolić, Jelena
AU  - Smiljanić, Sonja
AU  - Labus, Nebojša
AU  - Savić, Veljko
PY  - 2018
UR  - https://ritnms.itnms.ac.rs/handle/123456789/472
AB  - Crystallization kinetics of 22.5Li(2)O center dot 10Al(2)O(3)center dot 30GeO(2)center dot 37.5P(2)O(5) (mol%) glass was studied under non-isothermal condition using the differential thermal analysis (DTA). The study was performed by using the first crystallization peak temperature (T-p1) which belongs to the precipitation of LiGe2(PO4)(3) phase in the glass. The activation energy of glass crystallization (E-a) was determined using different isokinetic methods. The dependence of E-a on the degree of glass-crystal transformation (alpha) was studied using model-free isoconversional linear integral KAS (Kissinger-Akahira-Sunose) and FWO (Flynn-Wall-Ozawa) methods. It was shown that the E-a varies with a and hence with temperature and consequently the glass/crystal transformation can be described as a complex process involving different mechanisms of nucleation and growth.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - Non-Isothermal Crystallization of Lithium Germanophosphate Glass Studied by Different Kinetic Methods
EP  - 203
IS  - 2
SP  - 193
VL  - 50
DO  - 10.2298/SOS1802193M
UR  - conv_837
ER  - 
@article{
author = "Matijašević, Srđan and Grujić, Snežana R. and Topalović, Vladimir and Nikolić, Jelena and Smiljanić, Sonja and Labus, Nebojša and Savić, Veljko",
year = "2018",
abstract = "Crystallization kinetics of 22.5Li(2)O center dot 10Al(2)O(3)center dot 30GeO(2)center dot 37.5P(2)O(5) (mol%) glass was studied under non-isothermal condition using the differential thermal analysis (DTA). The study was performed by using the first crystallization peak temperature (T-p1) which belongs to the precipitation of LiGe2(PO4)(3) phase in the glass. The activation energy of glass crystallization (E-a) was determined using different isokinetic methods. The dependence of E-a on the degree of glass-crystal transformation (alpha) was studied using model-free isoconversional linear integral KAS (Kissinger-Akahira-Sunose) and FWO (Flynn-Wall-Ozawa) methods. It was shown that the E-a varies with a and hence with temperature and consequently the glass/crystal transformation can be described as a complex process involving different mechanisms of nucleation and growth.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "Non-Isothermal Crystallization of Lithium Germanophosphate Glass Studied by Different Kinetic Methods",
pages = "203-193",
number = "2",
volume = "50",
doi = "10.2298/SOS1802193M",
url = "conv_837"
}
Matijašević, S., Grujić, S. R., Topalović, V., Nikolić, J., Smiljanić, S., Labus, N.,& Savić, V.. (2018). Non-Isothermal Crystallization of Lithium Germanophosphate Glass Studied by Different Kinetic Methods. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 50(2), 193-203.
https://doi.org/10.2298/SOS1802193M
conv_837
Matijašević S, Grujić SR, Topalović V, Nikolić J, Smiljanić S, Labus N, Savić V. Non-Isothermal Crystallization of Lithium Germanophosphate Glass Studied by Different Kinetic Methods. in Science of Sintering. 2018;50(2):193-203.
doi:10.2298/SOS1802193M
conv_837 .
Matijašević, Srđan, Grujić, Snežana R., Topalović, Vladimir, Nikolić, Jelena, Smiljanić, Sonja, Labus, Nebojša, Savić, Veljko, "Non-Isothermal Crystallization of Lithium Germanophosphate Glass Studied by Different Kinetic Methods" in Science of Sintering, 50, no. 2 (2018):193-203,
https://doi.org/10.2298/SOS1802193M .,
conv_837 .
1
2
4

Bioactive glass-ceramics prepared by powder sintering and crystallization of polyphosphate glass containing strontium

Topalović, Vladimir; Grujić, Snežana R.; Živanović, Vladimir D.; Matijašević, Srđan; Nikolić, Jelena; Stojanović, Jovica; Smiljanić, Sonja

(Elsevier Sci Ltd, Oxford, 2017)

TY  - JOUR
AU  - Topalović, Vladimir
AU  - Grujić, Snežana R.
AU  - Živanović, Vladimir D.
AU  - Matijašević, Srđan
AU  - Nikolić, Jelena
AU  - Stojanović, Jovica
AU  - Smiljanić, Sonja
PY  - 2017
UR  - https://ritnms.itnms.ac.rs/handle/123456789/437
AB  - Melt-quenching method was employed for obtaining a glass-ceramic with the following composition 42P(2)O(5). 40CaO.5SrO.10Na(2)O.3TiO(2) (mol%) glass. The crystallization and sintering behavior of glass have been studied by using DTA, HSM, XRD, FTIR and SEM methods. It was determined that the surface and volume crystallization mechanisms act simultaneously in bulk glass samples. The comparison of DTA and HSM data revealed that the sintering and crystallization processes are independent. The sintered calcium phosphate glass ceramic which contained bioactive beta-Ca-3(PO4)(2) and beta-Ca2P2O7 phases was successfully prepared. It was determined that during crystallization the primary phase in the precipitate was beta-Ca(PO3)(2). Other phases appearing in the resulting glass-ceramic were: alpha-Ca2P2O7, gamma-Ca2PO7, Ca4P6O19 and CaHPO4(H2O)(2). Crystalline phases containing Sr and Ti were not detected. SEM analysis of the glass-ceramic microstructure revealed surface crystallization of glass particles and plate-like morphology of crystal growth. The result of the in vitro bioactivity showed that no apatite layer was formed on the surface of the as-prepared glass-ceramic samples after immersion in the simulated body fluid (SBF).
PB  - Elsevier Sci Ltd, Oxford
T2  - Ceramics International
T1  - Bioactive glass-ceramics prepared by powder sintering and crystallization of polyphosphate glass containing strontium
EP  - 12069
IS  - 15
SP  - 12061
VL  - 43
DO  - 10.1016/j.ceramint.2017.06.061
UR  - conv_803
ER  - 
@article{
author = "Topalović, Vladimir and Grujić, Snežana R. and Živanović, Vladimir D. and Matijašević, Srđan and Nikolić, Jelena and Stojanović, Jovica and Smiljanić, Sonja",
year = "2017",
abstract = "Melt-quenching method was employed for obtaining a glass-ceramic with the following composition 42P(2)O(5). 40CaO.5SrO.10Na(2)O.3TiO(2) (mol%) glass. The crystallization and sintering behavior of glass have been studied by using DTA, HSM, XRD, FTIR and SEM methods. It was determined that the surface and volume crystallization mechanisms act simultaneously in bulk glass samples. The comparison of DTA and HSM data revealed that the sintering and crystallization processes are independent. The sintered calcium phosphate glass ceramic which contained bioactive beta-Ca-3(PO4)(2) and beta-Ca2P2O7 phases was successfully prepared. It was determined that during crystallization the primary phase in the precipitate was beta-Ca(PO3)(2). Other phases appearing in the resulting glass-ceramic were: alpha-Ca2P2O7, gamma-Ca2PO7, Ca4P6O19 and CaHPO4(H2O)(2). Crystalline phases containing Sr and Ti were not detected. SEM analysis of the glass-ceramic microstructure revealed surface crystallization of glass particles and plate-like morphology of crystal growth. The result of the in vitro bioactivity showed that no apatite layer was formed on the surface of the as-prepared glass-ceramic samples after immersion in the simulated body fluid (SBF).",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Ceramics International",
title = "Bioactive glass-ceramics prepared by powder sintering and crystallization of polyphosphate glass containing strontium",
pages = "12069-12061",
number = "15",
volume = "43",
doi = "10.1016/j.ceramint.2017.06.061",
url = "conv_803"
}
Topalović, V., Grujić, S. R., Živanović, V. D., Matijašević, S., Nikolić, J., Stojanović, J.,& Smiljanić, S.. (2017). Bioactive glass-ceramics prepared by powder sintering and crystallization of polyphosphate glass containing strontium. in Ceramics International
Elsevier Sci Ltd, Oxford., 43(15), 12061-12069.
https://doi.org/10.1016/j.ceramint.2017.06.061
conv_803
Topalović V, Grujić SR, Živanović VD, Matijašević S, Nikolić J, Stojanović J, Smiljanić S. Bioactive glass-ceramics prepared by powder sintering and crystallization of polyphosphate glass containing strontium. in Ceramics International. 2017;43(15):12061-12069.
doi:10.1016/j.ceramint.2017.06.061
conv_803 .
Topalović, Vladimir, Grujić, Snežana R., Živanović, Vladimir D., Matijašević, Srđan, Nikolić, Jelena, Stojanović, Jovica, Smiljanić, Sonja, "Bioactive glass-ceramics prepared by powder sintering and crystallization of polyphosphate glass containing strontium" in Ceramics International, 43, no. 15 (2017):12061-12069,
https://doi.org/10.1016/j.ceramint.2017.06.061 .,
conv_803 .
13
9
14

Crystallization and sintering behaviors of the polyphosphate glass doped with Zn and Mn

Nikolić, Jelena; Živanović, Vladimir D.; Matijašević, Srđan; Stojanović, Jovica; Grujić, Snežana R.; Smiljanić, Sonja; Topalović, Vladimir

(Springer, Dordrecht, 2016)

TY  - JOUR
AU  - Nikolić, Jelena
AU  - Živanović, Vladimir D.
AU  - Matijašević, Srđan
AU  - Stojanović, Jovica
AU  - Grujić, Snežana R.
AU  - Smiljanić, Sonja
AU  - Topalović, Vladimir
PY  - 2016
UR  - https://ritnms.itnms.ac.rs/handle/123456789/415
AB  - The crystallization and sintering behaviors of polyphosphate glass doped with trace elements Zn and Mn were examined. The heating experiments on bulk and powder glass samples were performed. The parent glass revealed low crystallization ability and the glass crystallization carried out under simultaneous acting of the surface and volume mechanisms. The bulk glass sample isothermally heated at T (c) = 500 A degrees C commences to crystallize after 12 h, and KPO3 and Ca2KP3O10 crystalline phases appeared. The dendritic morphology of the crystals growing on sample surface was determined. The DTA and HSM results showed that the sintering and crystallization processes are independent. Phosphate glass-ceramics containing KPO3, K2Mg(PO3)(4), Ca(PO3)(2) and KCa(PO3)(3) crystalline phases has been prepared by sintering of the glass powder compacts at T (c) = 500 A degrees C for t = 12 h. A plate-like morphology of crystals which grow on glass grains surface was observed. The activation energies of crystal growth, E (a,k) = (246.6 +/- A 19.74) kJ mol(-1) (Kissinger) and E (a,oz) = (258.80 +/- A 19.70) kJ mol(-1) (Ozawa), were calculated.
PB  - Springer, Dordrecht
T2  - Journal of Thermal Analysis and Calorimetry
T1  - Crystallization and sintering behaviors of the polyphosphate glass doped with Zn and Mn
EP  - 592
IS  - 2
SP  - 585
VL  - 124
DO  - 10.1007/s10973-015-5184-x
UR  - conv_756
ER  - 
@article{
author = "Nikolić, Jelena and Živanović, Vladimir D. and Matijašević, Srđan and Stojanović, Jovica and Grujić, Snežana R. and Smiljanić, Sonja and Topalović, Vladimir",
year = "2016",
abstract = "The crystallization and sintering behaviors of polyphosphate glass doped with trace elements Zn and Mn were examined. The heating experiments on bulk and powder glass samples were performed. The parent glass revealed low crystallization ability and the glass crystallization carried out under simultaneous acting of the surface and volume mechanisms. The bulk glass sample isothermally heated at T (c) = 500 A degrees C commences to crystallize after 12 h, and KPO3 and Ca2KP3O10 crystalline phases appeared. The dendritic morphology of the crystals growing on sample surface was determined. The DTA and HSM results showed that the sintering and crystallization processes are independent. Phosphate glass-ceramics containing KPO3, K2Mg(PO3)(4), Ca(PO3)(2) and KCa(PO3)(3) crystalline phases has been prepared by sintering of the glass powder compacts at T (c) = 500 A degrees C for t = 12 h. A plate-like morphology of crystals which grow on glass grains surface was observed. The activation energies of crystal growth, E (a,k) = (246.6 +/- A 19.74) kJ mol(-1) (Kissinger) and E (a,oz) = (258.80 +/- A 19.70) kJ mol(-1) (Ozawa), were calculated.",
publisher = "Springer, Dordrecht",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "Crystallization and sintering behaviors of the polyphosphate glass doped with Zn and Mn",
pages = "592-585",
number = "2",
volume = "124",
doi = "10.1007/s10973-015-5184-x",
url = "conv_756"
}
Nikolić, J., Živanović, V. D., Matijašević, S., Stojanović, J., Grujić, S. R., Smiljanić, S.,& Topalović, V.. (2016). Crystallization and sintering behaviors of the polyphosphate glass doped with Zn and Mn. in Journal of Thermal Analysis and Calorimetry
Springer, Dordrecht., 124(2), 585-592.
https://doi.org/10.1007/s10973-015-5184-x
conv_756
Nikolić J, Živanović VD, Matijašević S, Stojanović J, Grujić SR, Smiljanić S, Topalović V. Crystallization and sintering behaviors of the polyphosphate glass doped with Zn and Mn. in Journal of Thermal Analysis and Calorimetry. 2016;124(2):585-592.
doi:10.1007/s10973-015-5184-x
conv_756 .
Nikolić, Jelena, Živanović, Vladimir D., Matijašević, Srđan, Stojanović, Jovica, Grujić, Snežana R., Smiljanić, Sonja, Topalović, Vladimir, "Crystallization and sintering behaviors of the polyphosphate glass doped with Zn and Mn" in Journal of Thermal Analysis and Calorimetry, 124, no. 2 (2016):585-592,
https://doi.org/10.1007/s10973-015-5184-x .,
conv_756 .
5
5
5

Effect of la2o3 on the structure and the properties of strontium borate glasses

Smiljanić, Sonja; Grujić, Snežana R.; Tosić, Mihajlo B.; Živanović, Vladimir D.; Matijašević, Srđan; Nikolić, Jelena; Topalović, Vladimir

(Savez hemijskih inženjera, Beograd, 2016)

TY  - JOUR
AU  - Smiljanić, Sonja
AU  - Grujić, Snežana R.
AU  - Tosić, Mihajlo B.
AU  - Živanović, Vladimir D.
AU  - Matijašević, Srđan
AU  - Nikolić, Jelena
AU  - Topalović, Vladimir
PY  - 2016
UR  - https://ritnms.itnms.ac.rs/handle/123456789/396
AB  - The selected lanthanum-strontium borate glasses were prepared by a conventional melt-quenching technique. The compositions of the investigated glasses were chosen to be: 5.7, 9.5, 14.3, 19.1 mol% for La2O3, 22.9, 19.1, 14.3, 9.5 mol% for SrO and 71.4 mol% for B2O3. The density, molar volume, oxygen molar volume, oxygen packing density, oxygen/boron ratios and structural transformations in the glass network were investigated according to the substitution of SrO by La2O3. The density and the molar volume increased in parallel with La2O3 content increase. Simultaneously, oxygen molar volume values increased while the oxygen packing density values decreased. A hot stage microscope (HSM) and a differential thermal analysis (DTA) were used to determine the characteristic temperatures. By increasing the content of lanthanum, the glass transition temperatures, changed with the same trend as the molar volume. Glass stability parameters were calculated from the temperatures obtained by DTA and HSM. The HSM results were used to obtain the viscosity curves by applying the Vogel-Fulcher-Tamman (VFT) equation.
PB  - Savez hemijskih inženjera, Beograd
T2  - Chemical Industry and Chemical Engineering Quarterly / CICEQ
T1  - Effect of la2o3 on the structure and the properties of strontium borate glasses
EP  - 115
IS  - 1
SP  - 111
VL  - 22
DO  - 10.2298/CICEQ150213031S
UR  - conv_758
ER  - 
@article{
author = "Smiljanić, Sonja and Grujić, Snežana R. and Tosić, Mihajlo B. and Živanović, Vladimir D. and Matijašević, Srđan and Nikolić, Jelena and Topalović, Vladimir",
year = "2016",
abstract = "The selected lanthanum-strontium borate glasses were prepared by a conventional melt-quenching technique. The compositions of the investigated glasses were chosen to be: 5.7, 9.5, 14.3, 19.1 mol% for La2O3, 22.9, 19.1, 14.3, 9.5 mol% for SrO and 71.4 mol% for B2O3. The density, molar volume, oxygen molar volume, oxygen packing density, oxygen/boron ratios and structural transformations in the glass network were investigated according to the substitution of SrO by La2O3. The density and the molar volume increased in parallel with La2O3 content increase. Simultaneously, oxygen molar volume values increased while the oxygen packing density values decreased. A hot stage microscope (HSM) and a differential thermal analysis (DTA) were used to determine the characteristic temperatures. By increasing the content of lanthanum, the glass transition temperatures, changed with the same trend as the molar volume. Glass stability parameters were calculated from the temperatures obtained by DTA and HSM. The HSM results were used to obtain the viscosity curves by applying the Vogel-Fulcher-Tamman (VFT) equation.",
publisher = "Savez hemijskih inženjera, Beograd",
journal = "Chemical Industry and Chemical Engineering Quarterly / CICEQ",
title = "Effect of la2o3 on the structure and the properties of strontium borate glasses",
pages = "115-111",
number = "1",
volume = "22",
doi = "10.2298/CICEQ150213031S",
url = "conv_758"
}
Smiljanić, S., Grujić, S. R., Tosić, M. B., Živanović, V. D., Matijašević, S., Nikolić, J.,& Topalović, V.. (2016). Effect of la2o3 on the structure and the properties of strontium borate glasses. in Chemical Industry and Chemical Engineering Quarterly / CICEQ
Savez hemijskih inženjera, Beograd., 22(1), 111-115.
https://doi.org/10.2298/CICEQ150213031S
conv_758
Smiljanić S, Grujić SR, Tosić MB, Živanović VD, Matijašević S, Nikolić J, Topalović V. Effect of la2o3 on the structure and the properties of strontium borate glasses. in Chemical Industry and Chemical Engineering Quarterly / CICEQ. 2016;22(1):111-115.
doi:10.2298/CICEQ150213031S
conv_758 .
Smiljanić, Sonja, Grujić, Snežana R., Tosić, Mihajlo B., Živanović, Vladimir D., Matijašević, Srđan, Nikolić, Jelena, Topalović, Vladimir, "Effect of la2o3 on the structure and the properties of strontium borate glasses" in Chemical Industry and Chemical Engineering Quarterly / CICEQ, 22, no. 1 (2016):111-115,
https://doi.org/10.2298/CICEQ150213031S .,
conv_758 .
14
9
16