Extraction of ammonium nickel sulfate hexahydrate by hydrometallurgical process from the hyperaccumulating plant Odontarrhena muralis - case study from Serbia
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Marković, BranislavRanđelović, Dragana
Jovanović, Gvozden
Tomović, Gordana
Jakovljević, Ksenija
Mišljenović, Tomica
Sokić, Miroslav
Article (Published version)
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Phytomining is a new promising technique that is based on using hyperaccumulating plants which biomass is utilized as a bio-ore for metal extraction. The Ni-hyperaccumulating species Odontarrhena muralis is widely distributed on ultramafic soils in Serbia, and could be a promising candidate for Ni agromining. In the present study, efficiency of a hydrometallurgical process for Ni recovery using biomass of O. muralis wild population through the synthesis of Ni salts from plant ash in the form of ammonium nickel sulfate hexahydrate, Ni(NH4)(2)(SO4)(2) 6H(2)O-(ANSH) was assessed. The average Ni content in the plant from ultramafic sites in West Serbia was up to 3.300 g kg(-1). The mass yield of ANSH crystals from the crude ash was similar to 12 % with the average purity of 73 % were obtained. By optimizing the purification process before precipitation of ANSH crystals, it is possible to obtain salt crystals of higher purity, which increases the economic profitability of this process. The ...results of this preliminary study on wild population of O. muralis show the increased potential for implementation of phytomining practices as an alternative way of Ni extraction on ultramafic sites in Serbia.
rcub.field.subject:
phytomining / nickel extraction / leaching / bio-orercub.field.source:
Hemijska industrija, 2021, 75, 5, 285-296rcub.field.publisher:
- Savez hemijskih inženjera, Beograd
rcub.projects:
- Ministry of Science, Technological Development and Innovation of the Republic of Serbia, institutional funding - 200023 (Institute of Technology of Nuclear and Other Mineral Row Materials - ITNMS, Belgrade) (RS-MESTD-inst-2020-200023)
- Ministry of Science, Technological Development and Innovation of the Republic of Serbia, institutional funding - 200178 (University of Belgrade, Faculty of Biology) (RS-MESTD-inst-2020-200178)
DOI: 10.2298/HEMIND210701027M
ISSN: 0367-598X
WoS: 000718928900003
Scopus: 2-s2.0-85121101062
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https://ritnms.itnms.ac.rs/handle/123456789/563xmlui.mirage2.itemSummaryView.Collections
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Institut za tehnologiju nuklearnih i drugih mineralnih sirovinaTY - JOUR AU - Marković, Branislav AU - Ranđelović, Dragana AU - Jovanović, Gvozden AU - Tomović, Gordana AU - Jakovljević, Ksenija AU - Mišljenović, Tomica AU - Sokić, Miroslav PY - 2021 UR - https://ritnms.itnms.ac.rs/handle/123456789/563 AB - Phytomining is a new promising technique that is based on using hyperaccumulating plants which biomass is utilized as a bio-ore for metal extraction. The Ni-hyperaccumulating species Odontarrhena muralis is widely distributed on ultramafic soils in Serbia, and could be a promising candidate for Ni agromining. In the present study, efficiency of a hydrometallurgical process for Ni recovery using biomass of O. muralis wild population through the synthesis of Ni salts from plant ash in the form of ammonium nickel sulfate hexahydrate, Ni(NH4)(2)(SO4)(2) 6H(2)O-(ANSH) was assessed. The average Ni content in the plant from ultramafic sites in West Serbia was up to 3.300 g kg(-1). The mass yield of ANSH crystals from the crude ash was similar to 12 % with the average purity of 73 % were obtained. By optimizing the purification process before precipitation of ANSH crystals, it is possible to obtain salt crystals of higher purity, which increases the economic profitability of this process. The results of this preliminary study on wild population of O. muralis show the increased potential for implementation of phytomining practices as an alternative way of Ni extraction on ultramafic sites in Serbia. PB - Savez hemijskih inženjera, Beograd T2 - Hemijska industrija T1 - Extraction of ammonium nickel sulfate hexahydrate by hydrometallurgical process from the hyperaccumulating plant Odontarrhena muralis - case study from Serbia EP - 296 IS - 5 SP - 285 VL - 75 DO - 10.2298/HEMIND210701027M UR - conv_922 ER -
@article{ author = "Marković, Branislav and Ranđelović, Dragana and Jovanović, Gvozden and Tomović, Gordana and Jakovljević, Ksenija and Mišljenović, Tomica and Sokić, Miroslav", year = "2021", abstract = "Phytomining is a new promising technique that is based on using hyperaccumulating plants which biomass is utilized as a bio-ore for metal extraction. The Ni-hyperaccumulating species Odontarrhena muralis is widely distributed on ultramafic soils in Serbia, and could be a promising candidate for Ni agromining. In the present study, efficiency of a hydrometallurgical process for Ni recovery using biomass of O. muralis wild population through the synthesis of Ni salts from plant ash in the form of ammonium nickel sulfate hexahydrate, Ni(NH4)(2)(SO4)(2) 6H(2)O-(ANSH) was assessed. The average Ni content in the plant from ultramafic sites in West Serbia was up to 3.300 g kg(-1). The mass yield of ANSH crystals from the crude ash was similar to 12 % with the average purity of 73 % were obtained. By optimizing the purification process before precipitation of ANSH crystals, it is possible to obtain salt crystals of higher purity, which increases the economic profitability of this process. The results of this preliminary study on wild population of O. muralis show the increased potential for implementation of phytomining practices as an alternative way of Ni extraction on ultramafic sites in Serbia.", publisher = "Savez hemijskih inženjera, Beograd", journal = "Hemijska industrija", title = "Extraction of ammonium nickel sulfate hexahydrate by hydrometallurgical process from the hyperaccumulating plant Odontarrhena muralis - case study from Serbia", pages = "296-285", number = "5", volume = "75", doi = "10.2298/HEMIND210701027M", url = "conv_922" }
Marković, B., Ranđelović, D., Jovanović, G., Tomović, G., Jakovljević, K., Mišljenović, T.,& Sokić, M.. (2021). Extraction of ammonium nickel sulfate hexahydrate by hydrometallurgical process from the hyperaccumulating plant Odontarrhena muralis - case study from Serbia. in Hemijska industrija Savez hemijskih inženjera, Beograd., 75(5), 285-296. https://doi.org/10.2298/HEMIND210701027M conv_922
Marković B, Ranđelović D, Jovanović G, Tomović G, Jakovljević K, Mišljenović T, Sokić M. Extraction of ammonium nickel sulfate hexahydrate by hydrometallurgical process from the hyperaccumulating plant Odontarrhena muralis - case study from Serbia. in Hemijska industrija. 2021;75(5):285-296. doi:10.2298/HEMIND210701027M conv_922 .
Marković, Branislav, Ranđelović, Dragana, Jovanović, Gvozden, Tomović, Gordana, Jakovljević, Ksenija, Mišljenović, Tomica, Sokić, Miroslav, "Extraction of ammonium nickel sulfate hexahydrate by hydrometallurgical process from the hyperaccumulating plant Odontarrhena muralis - case study from Serbia" in Hemijska industrija, 75, no. 5 (2021):285-296, https://doi.org/10.2298/HEMIND210701027M ., conv_922 .