Luminescent Pr3+ doped fluorapatite nanoparticles with different excitation-emission profiles
Authors
Milojkov, DušanStanić, Vojislav
Janjić, Goran

Mutavdžić, Dragosav
Milanović, Marija

Contributors
Srdić, VladimirConference object (Published version)

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The fluorapatite (FAP) nanoparticles doped with rear earth elements have been extensively studied as a potential luminescence inorganic material for in-vitro and in vivo cells and tissue bioimaging [1-3]. Luminescent nanoparticles of undoped and Pr3+ doped fluorapatite (Pr-FAP) have been successfully synthesized by co-precipitation method followed by calcination. Obtained materials are characterized by XRD, FTIR FAR, PLE-PL and SEM-EDAX methods, and theoretical prediction of structural changes was also done.
Emission of FAP nanoparticles occurs in violet-blue region of visible part of
spectrum under excitation in UV region. Introducing the Pr3+ into the lattice causes the red or blue shift depending of Pr3+ concentration and synthesis conditions. MCR-ALS analyses of fluorescence spectra and ab initio calculation indicated that Pr3+ ions are located in Pr-FAP lattice at Ca2 (6h) sites. Assumed mechanism of substitution of Ca2+ with Pr3+ ion is accompanied with charge compensation by ...incorporation of CO32- ions into the structure or by vacancies formation on metal ions position. Synthesized nanoparticles can be potentially used as a luminescent nanomaterials in biomedicine for targeting, bioimaging, drug delivery and therapy.
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12th Conference for Young Scientists in Ceramics, CYSC-2017, 2017, 73-73Publisher:
- Novi Sad : University of Novi Sad, Faculty of Technology
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Institut za tehnologiju nuklearnih i drugih mineralnih sirovinaTY - CONF AU - Milojkov, Dušan AU - Stanić, Vojislav AU - Janjić, Goran AU - Mutavdžić, Dragosav AU - Milanović, Marija PY - 2017 UR - https://ritnms.itnms.ac.rs/handle/123456789/960 AB - The fluorapatite (FAP) nanoparticles doped with rear earth elements have been extensively studied as a potential luminescence inorganic material for in-vitro and in vivo cells and tissue bioimaging [1-3]. Luminescent nanoparticles of undoped and Pr3+ doped fluorapatite (Pr-FAP) have been successfully synthesized by co-precipitation method followed by calcination. Obtained materials are characterized by XRD, FTIR FAR, PLE-PL and SEM-EDAX methods, and theoretical prediction of structural changes was also done. Emission of FAP nanoparticles occurs in violet-blue region of visible part of spectrum under excitation in UV region. Introducing the Pr3+ into the lattice causes the red or blue shift depending of Pr3+ concentration and synthesis conditions. MCR-ALS analyses of fluorescence spectra and ab initio calculation indicated that Pr3+ ions are located in Pr-FAP lattice at Ca2 (6h) sites. Assumed mechanism of substitution of Ca2+ with Pr3+ ion is accompanied with charge compensation by incorporation of CO32- ions into the structure or by vacancies formation on metal ions position. Synthesized nanoparticles can be potentially used as a luminescent nanomaterials in biomedicine for targeting, bioimaging, drug delivery and therapy. PB - Novi Sad : University of Novi Sad, Faculty of Technology C3 - 12th Conference for Young Scientists in Ceramics, CYSC-2017 T1 - Luminescent Pr3+ doped fluorapatite nanoparticles with different excitation-emission profiles EP - 73 SP - 73 ER -
@conference{ author = "Milojkov, Dušan and Stanić, Vojislav and Janjić, Goran and Mutavdžić, Dragosav and Milanović, Marija", year = "2017", abstract = "The fluorapatite (FAP) nanoparticles doped with rear earth elements have been extensively studied as a potential luminescence inorganic material for in-vitro and in vivo cells and tissue bioimaging [1-3]. Luminescent nanoparticles of undoped and Pr3+ doped fluorapatite (Pr-FAP) have been successfully synthesized by co-precipitation method followed by calcination. Obtained materials are characterized by XRD, FTIR FAR, PLE-PL and SEM-EDAX methods, and theoretical prediction of structural changes was also done. Emission of FAP nanoparticles occurs in violet-blue region of visible part of spectrum under excitation in UV region. Introducing the Pr3+ into the lattice causes the red or blue shift depending of Pr3+ concentration and synthesis conditions. MCR-ALS analyses of fluorescence spectra and ab initio calculation indicated that Pr3+ ions are located in Pr-FAP lattice at Ca2 (6h) sites. Assumed mechanism of substitution of Ca2+ with Pr3+ ion is accompanied with charge compensation by incorporation of CO32- ions into the structure or by vacancies formation on metal ions position. Synthesized nanoparticles can be potentially used as a luminescent nanomaterials in biomedicine for targeting, bioimaging, drug delivery and therapy.", publisher = "Novi Sad : University of Novi Sad, Faculty of Technology", journal = "12th Conference for Young Scientists in Ceramics, CYSC-2017", title = "Luminescent Pr3+ doped fluorapatite nanoparticles with different excitation-emission profiles", pages = "73-73" }
Milojkov, D., Stanić, V., Janjić, G., Mutavdžić, D.,& Milanović, M.. (2017). Luminescent Pr3+ doped fluorapatite nanoparticles with different excitation-emission profiles. in 12th Conference for Young Scientists in Ceramics, CYSC-2017 Novi Sad : University of Novi Sad, Faculty of Technology., 73-73.
Milojkov D, Stanić V, Janjić G, Mutavdžić D, Milanović M. Luminescent Pr3+ doped fluorapatite nanoparticles with different excitation-emission profiles. in 12th Conference for Young Scientists in Ceramics, CYSC-2017. 2017;:73-73..
Milojkov, Dušan, Stanić, Vojislav, Janjić, Goran, Mutavdžić, Dragosav, Milanović, Marija, "Luminescent Pr3+ doped fluorapatite nanoparticles with different excitation-emission profiles" in 12th Conference for Young Scientists in Ceramics, CYSC-2017 (2017):73-73.