Removal of arsenic(III) oxyanions from wastewater using aminosilane-modified natural and synthetic zeolite
Abstract
Silanization of the natural and synthetic zeolites as well as their use as adsorbents for removing arsenic(III) oxyanions from wastewater are the topic of this paper. Two types of zeolite were used: natural zeolite-clinoptilolite from Zlatokop deposit, Vranjska Banja, Serbia,
previously converted to H + -form and synthetic zeolite, mordenite. The modification was
performed with solution (3-aminopropyl) triethoxysilane (APTES). The presence of APTES
on the surface of zeolite was confirmed using TG/DSC and FTIR analysis. The results showed
that natural aminosilane-modified zeolite has a higher adsorption capacity for arsenic(III)
oxyanions compared to mordenite prepared in the same way. The kinetic data follow the
Lagergren pseudo-second-order model. This model implies a chemical interaction between
As 3+ - ions and functional groups on the silanized zeolite surface.
Keywords:
zeolite / aminosilane / modification / arsenic / wastewaterSource:
9th Croatian-Slovenian-Serbian Symposium on Zeolites, 2021, 47-50Publisher:
- Croatian Zeolite Association (CROZA)
Collections
Institution/Community
Institut za tehnologiju nuklearnih i drugih mineralnih sirovinaTY - CONF AU - Dimitrijević, Jelena AU - Petrović, Jelena AU - Milošević, Dragana AU - Dikić, Jelena AU - Jevtić, Sanja PY - 2021 UR - https://ritnms.itnms.ac.rs/handle/123456789/831 AB - Silanization of the natural and synthetic zeolites as well as their use as adsorbents for removing arsenic(III) oxyanions from wastewater are the topic of this paper. Two types of zeolite were used: natural zeolite-clinoptilolite from Zlatokop deposit, Vranjska Banja, Serbia, previously converted to H + -form and synthetic zeolite, mordenite. The modification was performed with solution (3-aminopropyl) triethoxysilane (APTES). The presence of APTES on the surface of zeolite was confirmed using TG/DSC and FTIR analysis. The results showed that natural aminosilane-modified zeolite has a higher adsorption capacity for arsenic(III) oxyanions compared to mordenite prepared in the same way. The kinetic data follow the Lagergren pseudo-second-order model. This model implies a chemical interaction between As 3+ - ions and functional groups on the silanized zeolite surface. PB - Croatian Zeolite Association (CROZA) C3 - 9th Croatian-Slovenian-Serbian Symposium on Zeolites T1 - Removal of arsenic(III) oxyanions from wastewater using aminosilane-modified natural and synthetic zeolite EP - 50 SP - 47 ER -
@conference{ author = "Dimitrijević, Jelena and Petrović, Jelena and Milošević, Dragana and Dikić, Jelena and Jevtić, Sanja", year = "2021", abstract = "Silanization of the natural and synthetic zeolites as well as their use as adsorbents for removing arsenic(III) oxyanions from wastewater are the topic of this paper. Two types of zeolite were used: natural zeolite-clinoptilolite from Zlatokop deposit, Vranjska Banja, Serbia, previously converted to H + -form and synthetic zeolite, mordenite. The modification was performed with solution (3-aminopropyl) triethoxysilane (APTES). The presence of APTES on the surface of zeolite was confirmed using TG/DSC and FTIR analysis. The results showed that natural aminosilane-modified zeolite has a higher adsorption capacity for arsenic(III) oxyanions compared to mordenite prepared in the same way. The kinetic data follow the Lagergren pseudo-second-order model. This model implies a chemical interaction between As 3+ - ions and functional groups on the silanized zeolite surface.", publisher = "Croatian Zeolite Association (CROZA)", journal = "9th Croatian-Slovenian-Serbian Symposium on Zeolites", title = "Removal of arsenic(III) oxyanions from wastewater using aminosilane-modified natural and synthetic zeolite", pages = "50-47" }
Dimitrijević, J., Petrović, J., Milošević, D., Dikić, J.,& Jevtić, S.. (2021). Removal of arsenic(III) oxyanions from wastewater using aminosilane-modified natural and synthetic zeolite. in 9th Croatian-Slovenian-Serbian Symposium on Zeolites Croatian Zeolite Association (CROZA)., 47-50.
Dimitrijević J, Petrović J, Milošević D, Dikić J, Jevtić S. Removal of arsenic(III) oxyanions from wastewater using aminosilane-modified natural and synthetic zeolite. in 9th Croatian-Slovenian-Serbian Symposium on Zeolites. 2021;:47-50..
Dimitrijević, Jelena, Petrović, Jelena, Milošević, Dragana, Dikić, Jelena, Jevtić, Sanja, "Removal of arsenic(III) oxyanions from wastewater using aminosilane-modified natural and synthetic zeolite" in 9th Croatian-Slovenian-Serbian Symposium on Zeolites (2021):47-50.