Glass-ceramics obtained from copper mine tailings and glass cullets
Authors
Savić, VeljkoMatijašević, Srđan

Topalović, Vladimir
Smiljanić, Sonja

Nikolić, Jelena

Zildžović, Snežana

Grujić, Snežana
Contributors
Glišić, DragomirMarković, Branislav
Manojlović, Vaso
Conference object (Published version)

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Copper mine tailings is one of the most used secondary raw materials. The most common use is in cement industry and as filler in road construction. The area of secondary raw materials utilization offering the greatest potential is in the development of glass-ceramic compositions, where the waste is melted to form a glass, fabricated using conventional glass forming techniques, and subsequently nucleated and devitrified in a controlled manner through heat treatment. The resultant, partially crystallized material offers improved strength, chemical and abrasion resistance. Copper mine tailings was mixed with 30% glass cullets and melted in electric furnace BLF 17/3 at T=1450 °C during t=0.5 h. The obtained glass sample was black, without visible residual gas bubbles. X-ray powder diffraction (XRD) analysis confirmed the quenched melt to be amorphous. DTA and HSM analysis was performed on the previously prepared glass powder. The glass powder samples were pressed in pellets and sintered in... an electric furnace at the temperature of 1040 °C for 2h and a glass- ceramics was obtained. Applications for these glass-ceramic materials would include structural products, pipe or pipeliners to transport abrasive or corrosive fluids, alkali-resistant fibers to replace asbestos in concrete products, and use as a matrix material in which radioactive wastes could be chemically incorporated in a stable, nonleachable, solid form.
Keywords:
glass / glass-ceramics / mine tailingsSource:
4th Metallurgical & Materials Engineering Congress of South-East Europe MME SEE 2019, 2019, 33-33Publisher:
- Belgrade : Association of Metallurgical Engineers of Serbia
Funding / projects:
- The development of glasses with controlled ions release for application in agriculture and medicine (RS-34001)
- Phenomena and processes of the synthesis of new glassy and nano-structured glass-ceramics materials (RS-172004)
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Institution/Community
Institut za tehnologiju nuklearnih i drugih mineralnih sirovinaTY - CONF AU - Savić, Veljko AU - Matijašević, Srđan AU - Topalović, Vladimir AU - Smiljanić, Sonja AU - Nikolić, Jelena AU - Zildžović, Snežana AU - Grujić, Snežana PY - 2019 UR - https://ritnms.itnms.ac.rs/handle/123456789/790 AB - Copper mine tailings is one of the most used secondary raw materials. The most common use is in cement industry and as filler in road construction. The area of secondary raw materials utilization offering the greatest potential is in the development of glass-ceramic compositions, where the waste is melted to form a glass, fabricated using conventional glass forming techniques, and subsequently nucleated and devitrified in a controlled manner through heat treatment. The resultant, partially crystallized material offers improved strength, chemical and abrasion resistance. Copper mine tailings was mixed with 30% glass cullets and melted in electric furnace BLF 17/3 at T=1450 °C during t=0.5 h. The obtained glass sample was black, without visible residual gas bubbles. X-ray powder diffraction (XRD) analysis confirmed the quenched melt to be amorphous. DTA and HSM analysis was performed on the previously prepared glass powder. The glass powder samples were pressed in pellets and sintered in an electric furnace at the temperature of 1040 °C for 2h and a glass- ceramics was obtained. Applications for these glass-ceramic materials would include structural products, pipe or pipeliners to transport abrasive or corrosive fluids, alkali-resistant fibers to replace asbestos in concrete products, and use as a matrix material in which radioactive wastes could be chemically incorporated in a stable, nonleachable, solid form. PB - Belgrade : Association of Metallurgical Engineers of Serbia C3 - 4th Metallurgical & Materials Engineering Congress of South-East Europe MME SEE 2019 T1 - Glass-ceramics obtained from copper mine tailings and glass cullets EP - 33 SP - 33 ER -
@conference{ author = "Savić, Veljko and Matijašević, Srđan and Topalović, Vladimir and Smiljanić, Sonja and Nikolić, Jelena and Zildžović, Snežana and Grujić, Snežana", year = "2019", abstract = "Copper mine tailings is one of the most used secondary raw materials. The most common use is in cement industry and as filler in road construction. The area of secondary raw materials utilization offering the greatest potential is in the development of glass-ceramic compositions, where the waste is melted to form a glass, fabricated using conventional glass forming techniques, and subsequently nucleated and devitrified in a controlled manner through heat treatment. The resultant, partially crystallized material offers improved strength, chemical and abrasion resistance. Copper mine tailings was mixed with 30% glass cullets and melted in electric furnace BLF 17/3 at T=1450 °C during t=0.5 h. The obtained glass sample was black, without visible residual gas bubbles. X-ray powder diffraction (XRD) analysis confirmed the quenched melt to be amorphous. DTA and HSM analysis was performed on the previously prepared glass powder. The glass powder samples were pressed in pellets and sintered in an electric furnace at the temperature of 1040 °C for 2h and a glass- ceramics was obtained. Applications for these glass-ceramic materials would include structural products, pipe or pipeliners to transport abrasive or corrosive fluids, alkali-resistant fibers to replace asbestos in concrete products, and use as a matrix material in which radioactive wastes could be chemically incorporated in a stable, nonleachable, solid form.", publisher = "Belgrade : Association of Metallurgical Engineers of Serbia", journal = "4th Metallurgical & Materials Engineering Congress of South-East Europe MME SEE 2019", title = "Glass-ceramics obtained from copper mine tailings and glass cullets", pages = "33-33" }
Savić, V., Matijašević, S., Topalović, V., Smiljanić, S., Nikolić, J., Zildžović, S.,& Grujić, S.. (2019). Glass-ceramics obtained from copper mine tailings and glass cullets. in 4th Metallurgical & Materials Engineering Congress of South-East Europe MME SEE 2019 Belgrade : Association of Metallurgical Engineers of Serbia., 33-33.
Savić V, Matijašević S, Topalović V, Smiljanić S, Nikolić J, Zildžović S, Grujić S. Glass-ceramics obtained from copper mine tailings and glass cullets. in 4th Metallurgical & Materials Engineering Congress of South-East Europe MME SEE 2019. 2019;:33-33..
Savić, Veljko, Matijašević, Srđan, Topalović, Vladimir, Smiljanić, Sonja, Nikolić, Jelena, Zildžović, Snežana, Grujić, Snežana, "Glass-ceramics obtained from copper mine tailings and glass cullets" in 4th Metallurgical & Materials Engineering Congress of South-East Europe MME SEE 2019 (2019):33-33.