The goal of this research is to investigate the effect of SrO and La2O3 addition on the crystallization characteristics and sintering behavior of polyphosphate glasses. Differential scanning calorimetry (DSC), hot stage microscopy (HSM), X-ray diffraction (XRD), and scanning electron microscopy (SEM) methods were used to investigate the crystallization and sintering behaviors of glasses. The addition of SrO and La2O3 (1 or 5%), at the expense of phosphate mole fraction in polyphosphate bioactive glass, raises the characteristic temperature of glasses, and resistance to crystallization. Furthermore, the temperature of maximal shrinkage increases with the addition of SrO and La2O3. Surface crystallization is the dominant mechanism of crystallization in all samples. All glasses show complex crystallization leading to the formation of several crystalline phases. Sintered phosphate glass-ceramic containing bioactive beta-CaP2O6, alpha-Ca-3(PO4)(2,) and beta-Ca-3(PO4)(2) phases were successf...ully prepared.
TY - JOUR
AU - Topalović, Vladimir
AU - Nikolić, Jelena
AU - Matijašević, Srđan
AU - Stojanović, Jovica
AU - Karamanov, Alexander
AU - Grujić, Snežana
AU - Jevtić, Sanja
PY - 2023
UR - https://ritnms.itnms.ac.rs/handle/123456789/650
AB - The goal of this research is to investigate the effect of SrO and La2O3 addition on the crystallization characteristics and sintering behavior of polyphosphate glasses. Differential scanning calorimetry (DSC), hot stage microscopy (HSM), X-ray diffraction (XRD), and scanning electron microscopy (SEM) methods were used to investigate the crystallization and sintering behaviors of glasses. The addition of SrO and La2O3 (1 or 5%), at the expense of phosphate mole fraction in polyphosphate bioactive glass, raises the characteristic temperature of glasses, and resistance to crystallization. Furthermore, the temperature of maximal shrinkage increases with the addition of SrO and La2O3. Surface crystallization is the dominant mechanism of crystallization in all samples. All glasses show complex crystallization leading to the formation of several crystalline phases. Sintered phosphate glass-ceramic containing bioactive beta-CaP2O6, alpha-Ca-3(PO4)(2,) and beta-Ca-3(PO4)(2) phases were successfully prepared.
PB - Dordrecht : Springer
T2 - Journal of Thermal Analysis and Calorimetry
T1 - The effect of SrO and La2O3 addition on the crystallization characteristics and sintering behavior of distinct polyphosphate glasses
EP - 732
EP -
IS - 3
SP - 721
VL - 148
DO - 10.1007/s10973-022-11777-8
UR - conv_958
ER -
@article{
author = "Topalović, Vladimir and Nikolić, Jelena and Matijašević, Srđan and Stojanović, Jovica and Karamanov, Alexander and Grujić, Snežana and Jevtić, Sanja",
year = "2023",
abstract = "The goal of this research is to investigate the effect of SrO and La2O3 addition on the crystallization characteristics and sintering behavior of polyphosphate glasses. Differential scanning calorimetry (DSC), hot stage microscopy (HSM), X-ray diffraction (XRD), and scanning electron microscopy (SEM) methods were used to investigate the crystallization and sintering behaviors of glasses. The addition of SrO and La2O3 (1 or 5%), at the expense of phosphate mole fraction in polyphosphate bioactive glass, raises the characteristic temperature of glasses, and resistance to crystallization. Furthermore, the temperature of maximal shrinkage increases with the addition of SrO and La2O3. Surface crystallization is the dominant mechanism of crystallization in all samples. All glasses show complex crystallization leading to the formation of several crystalline phases. Sintered phosphate glass-ceramic containing bioactive beta-CaP2O6, alpha-Ca-3(PO4)(2,) and beta-Ca-3(PO4)(2) phases were successfully prepared.",
publisher = "Dordrecht : Springer",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "The effect of SrO and La2O3 addition on the crystallization characteristics and sintering behavior of distinct polyphosphate glasses",
pages = "732--721",
number = "3",
volume = "148",
doi = "10.1007/s10973-022-11777-8",
url = "conv_958"
}
Topalović, V., Nikolić, J., Matijašević, S., Stojanović, J., Karamanov, A., Grujić, S.,& Jevtić, S.. (2023). The effect of SrO and La2O3 addition on the crystallization characteristics and sintering behavior of distinct polyphosphate glasses. in Journal of Thermal Analysis and Calorimetry
Dordrecht : Springer., 148(3), 721-732.
https://doi.org/10.1007/s10973-022-11777-8
conv_958
Topalović V, Nikolić J, Matijašević S, Stojanović J, Karamanov A, Grujić S, Jevtić S. The effect of SrO and La2O3 addition on the crystallization characteristics and sintering behavior of distinct polyphosphate glasses. in Journal of Thermal Analysis and Calorimetry. 2023;148(3):721-732.
doi:10.1007/s10973-022-11777-8
conv_958 .
Topalović, Vladimir, Nikolić, Jelena, Matijašević, Srđan, Stojanović, Jovica, Karamanov, Alexander, Grujić, Snežana, Jevtić, Sanja, "The effect of SrO and La2O3 addition on the crystallization characteristics and sintering behavior of distinct polyphosphate glasses" in Journal of Thermal Analysis and Calorimetry, 148, no. 3 (2023):721-732,
https://doi.org/10.1007/s10973-022-11777-8 .,
conv_958 .
