Adsorption of estrone, 17 beta-estradiol, and 17 alpha-ethinylestradiol from water onto modified multi-walled carbon nanotubes, carbon cryogel, and carbonized hydrothermal carbon
2022
Аутори
Prokić, DanijelaVukcević, Marija
Mitrović, Angelina
Maletić, Marina
Kalijadis, Ana
Janković-Častvan, Ivona
Durkić, Tatjana
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Carbon materials of different structural and textural properties (multi-walled carbon nanotubes, carbon cryogel, and carbonized hydrothermal carbon) were used as adsorbents for the removal of estrone, 17 beta-estradiol, and 17 alpha-ethinylestradiol from aqueous solutions. Chemical modification and/or activation were applied to alter surface characteristics and to increase the adsorption and desorption efficiency of carbon materials. Surfaces of treated and untreated carbon materials were characterized through the examination of the textural properties, the nature of surface functional groups, and surface acidity. It was found that the adsorption capacity of tested carbon materials is not directly proportional to the specific surface area and the content of surface oxygen groups. However, a high ratio of surface mesoporosity affected the adsorption process most prominently, by increasing adsorption capacity and the rate of the adsorption process. Adsorption of estrone, 17 beta-estradio...l, and 17 alpha-ethinylestradiol followed pseudo-second-order kinetic model, while the equilibrium adsorption data were best fitted with the Langmuir isotherm model. Calculated mean adsorption energy values, along with the thermodynamic parameters, indicated that removal of selected hormones was dominated by the physisorption mechanism. High values of adsorption efficiency (88-100 %) and Langmuir adsorption capacities (29.45-194.7 mg/g) imply that examined materials, especially mesoporous carbon cryogel and multi-walled carbon nanotubes, can be used as powerful adsorbents for relatively fast removal of estrogen hormones from water.
Кључне речи:
Surface modification / Multi-walled carbon nanotubes / Hydrothermal carbon / Estrogenic hormones / Carbon cryogel / AdsorptionИзвор:
Environmental science and pollution research, 2022, 29, 3, 4431-4445Издавач:
- Springer Heidelberg, Heidelberg
Финансирање / пројекти:
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200135 (Универзитет у Београду, Технолошко-металуршки факултет) (RS-MESTD-inst-2020-200135)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200287 (Иновациони центар Технолошко-металуршког факултета у Београду доо) (RS-MESTD-inst-2020-200287)
DOI: 10.1007/s11356-021-15970-4
ISSN: 0944-1344
PubMed: 34405332
WoS: 000686507300002
Scopus: 2-s2.0-85112767178
Институција/група
Institut za tehnologiju nuklearnih i drugih mineralnih sirovinaTY - JOUR AU - Prokić, Danijela AU - Vukcević, Marija AU - Mitrović, Angelina AU - Maletić, Marina AU - Kalijadis, Ana AU - Janković-Častvan, Ivona AU - Durkić, Tatjana PY - 2022 UR - https://ritnms.itnms.ac.rs/handle/123456789/642 AB - Carbon materials of different structural and textural properties (multi-walled carbon nanotubes, carbon cryogel, and carbonized hydrothermal carbon) were used as adsorbents for the removal of estrone, 17 beta-estradiol, and 17 alpha-ethinylestradiol from aqueous solutions. Chemical modification and/or activation were applied to alter surface characteristics and to increase the adsorption and desorption efficiency of carbon materials. Surfaces of treated and untreated carbon materials were characterized through the examination of the textural properties, the nature of surface functional groups, and surface acidity. It was found that the adsorption capacity of tested carbon materials is not directly proportional to the specific surface area and the content of surface oxygen groups. However, a high ratio of surface mesoporosity affected the adsorption process most prominently, by increasing adsorption capacity and the rate of the adsorption process. Adsorption of estrone, 17 beta-estradiol, and 17 alpha-ethinylestradiol followed pseudo-second-order kinetic model, while the equilibrium adsorption data were best fitted with the Langmuir isotherm model. Calculated mean adsorption energy values, along with the thermodynamic parameters, indicated that removal of selected hormones was dominated by the physisorption mechanism. High values of adsorption efficiency (88-100 %) and Langmuir adsorption capacities (29.45-194.7 mg/g) imply that examined materials, especially mesoporous carbon cryogel and multi-walled carbon nanotubes, can be used as powerful adsorbents for relatively fast removal of estrogen hormones from water. PB - Springer Heidelberg, Heidelberg T2 - Environmental science and pollution research T1 - Adsorption of estrone, 17 beta-estradiol, and 17 alpha-ethinylestradiol from water onto modified multi-walled carbon nanotubes, carbon cryogel, and carbonized hydrothermal carbon EP - 4445 IS - 3 SP - 4431 VL - 29 DO - 10.1007/s11356-021-15970-4 UR - conv_913 ER -
@article{ author = "Prokić, Danijela and Vukcević, Marija and Mitrović, Angelina and Maletić, Marina and Kalijadis, Ana and Janković-Častvan, Ivona and Durkić, Tatjana", year = "2022", abstract = "Carbon materials of different structural and textural properties (multi-walled carbon nanotubes, carbon cryogel, and carbonized hydrothermal carbon) were used as adsorbents for the removal of estrone, 17 beta-estradiol, and 17 alpha-ethinylestradiol from aqueous solutions. Chemical modification and/or activation were applied to alter surface characteristics and to increase the adsorption and desorption efficiency of carbon materials. Surfaces of treated and untreated carbon materials were characterized through the examination of the textural properties, the nature of surface functional groups, and surface acidity. It was found that the adsorption capacity of tested carbon materials is not directly proportional to the specific surface area and the content of surface oxygen groups. However, a high ratio of surface mesoporosity affected the adsorption process most prominently, by increasing adsorption capacity and the rate of the adsorption process. Adsorption of estrone, 17 beta-estradiol, and 17 alpha-ethinylestradiol followed pseudo-second-order kinetic model, while the equilibrium adsorption data were best fitted with the Langmuir isotherm model. Calculated mean adsorption energy values, along with the thermodynamic parameters, indicated that removal of selected hormones was dominated by the physisorption mechanism. High values of adsorption efficiency (88-100 %) and Langmuir adsorption capacities (29.45-194.7 mg/g) imply that examined materials, especially mesoporous carbon cryogel and multi-walled carbon nanotubes, can be used as powerful adsorbents for relatively fast removal of estrogen hormones from water.", publisher = "Springer Heidelberg, Heidelberg", journal = "Environmental science and pollution research", title = "Adsorption of estrone, 17 beta-estradiol, and 17 alpha-ethinylestradiol from water onto modified multi-walled carbon nanotubes, carbon cryogel, and carbonized hydrothermal carbon", pages = "4445-4431", number = "3", volume = "29", doi = "10.1007/s11356-021-15970-4", url = "conv_913" }
Prokić, D., Vukcević, M., Mitrović, A., Maletić, M., Kalijadis, A., Janković-Častvan, I.,& Durkić, T.. (2022). Adsorption of estrone, 17 beta-estradiol, and 17 alpha-ethinylestradiol from water onto modified multi-walled carbon nanotubes, carbon cryogel, and carbonized hydrothermal carbon. in Environmental science and pollution research Springer Heidelberg, Heidelberg., 29(3), 4431-4445. https://doi.org/10.1007/s11356-021-15970-4 conv_913
Prokić D, Vukcević M, Mitrović A, Maletić M, Kalijadis A, Janković-Častvan I, Durkić T. Adsorption of estrone, 17 beta-estradiol, and 17 alpha-ethinylestradiol from water onto modified multi-walled carbon nanotubes, carbon cryogel, and carbonized hydrothermal carbon. in Environmental science and pollution research. 2022;29(3):4431-4445. doi:10.1007/s11356-021-15970-4 conv_913 .
Prokić, Danijela, Vukcević, Marija, Mitrović, Angelina, Maletić, Marina, Kalijadis, Ana, Janković-Častvan, Ivona, Durkić, Tatjana, "Adsorption of estrone, 17 beta-estradiol, and 17 alpha-ethinylestradiol from water onto modified multi-walled carbon nanotubes, carbon cryogel, and carbonized hydrothermal carbon" in Environmental science and pollution research, 29, no. 3 (2022):4431-4445, https://doi.org/10.1007/s11356-021-15970-4 ., conv_913 .
Related items
Showing items related by title, author, creator and subject.
-
Hydrochar and Its Composites for Highly Efficient Pollutant Removal
Petrović, Jelena; Ercegović, Marija; Simić, Marija; Koprivica, Marija; Dimitrijević, Jelena (The 10th Global Conference on Polymer and Composite Materials (PCM 2023), 2023) -
Hydrothermal Carbonization of Waste Biomass: A Review of Hydrochar Preparation and Environmental Application
Petrović, Jelena; Ercegović, Marija; Simić, Marija; Koprivica, Marija; Dimitrijević, Jelena; Jovanović, Aleksandar; Janković Pantić, Jovana (MDPI, 2024) -
Grape pomace hydrochar as an efficient adsorbent for cadmium removal
Petrović, Jelena; Mihajlović, Marija; Petrović, Marija; Stojanović, Mirjana; Kojić, Marija; Lopičić, Zorica (Bor : University of Belgrade, Technical Faculty in Bor, Bor : Mining and Metallurgy Institute Bor, 2018)