Adsorption of estrone, 17 beta-estradiol, and 17 alpha-ethinylestradiol from water onto modified multi-walled carbon nanotubes, carbon cryogel, and carbonized hydrothermal carbon

2022
Authors
Prokić, DanijelaVukcević, Marija

Mitrović, Angelina
Maletić, Marina

Kalijadis, Ana

Janković-Častvan, Ivona
Durkić, Tatjana
Article (Published version)

Metadata
Show full item recordAbstract
Carbon materials of different structural and textural properties (multi-walled carbon nanotubes, carbon cryogel, and carbonized hydrothermal carbon) were used as adsorbents for the removal of estrone, 17 beta-estradiol, and 17 alpha-ethinylestradiol from aqueous solutions. Chemical modification and/or activation were applied to alter surface characteristics and to increase the adsorption and desorption efficiency of carbon materials. Surfaces of treated and untreated carbon materials were characterized through the examination of the textural properties, the nature of surface functional groups, and surface acidity. It was found that the adsorption capacity of tested carbon materials is not directly proportional to the specific surface area and the content of surface oxygen groups. However, a high ratio of surface mesoporosity affected the adsorption process most prominently, by increasing adsorption capacity and the rate of the adsorption process. Adsorption of estrone, 17 beta-estradio...l, and 17 alpha-ethinylestradiol followed pseudo-second-order kinetic model, while the equilibrium adsorption data were best fitted with the Langmuir isotherm model. Calculated mean adsorption energy values, along with the thermodynamic parameters, indicated that removal of selected hormones was dominated by the physisorption mechanism. High values of adsorption efficiency (88-100 %) and Langmuir adsorption capacities (29.45-194.7 mg/g) imply that examined materials, especially mesoporous carbon cryogel and multi-walled carbon nanotubes, can be used as powerful adsorbents for relatively fast removal of estrogen hormones from water.
Keywords:
Surface modification / Multi-walled carbon nanotubes / Hydrothermal carbon / Estrogenic hormones / Carbon cryogel / AdsorptionSource:
Environmental science and pollution research, 2022, 29, 3, 4431-4445Publisher:
- Springer Heidelberg, Heidelberg
Funding / projects:
- Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200135 (University of Belgrade, Faculty of Technology and Metallurgy) (RS-200135)
- Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200287 (Innovation Center of the Faculty of Technology and Metallurgy) (RS-200287)
DOI: 10.1007/s11356-021-15970-4
ISSN: 0944-1344
PubMed: 34405332
WoS: 000686507300002
Scopus: 2-s2.0-85112767178
Collections
Institution/Community
Institut za tehnologiju nuklearnih i drugih mineralnih sirovinaTY - JOUR AU - Prokić, Danijela AU - Vukcević, Marija AU - Mitrović, Angelina AU - Maletić, Marina AU - Kalijadis, Ana AU - Janković-Častvan, Ivona AU - Durkić, Tatjana PY - 2022 UR - https://ritnms.itnms.ac.rs/handle/123456789/642 AB - Carbon materials of different structural and textural properties (multi-walled carbon nanotubes, carbon cryogel, and carbonized hydrothermal carbon) were used as adsorbents for the removal of estrone, 17 beta-estradiol, and 17 alpha-ethinylestradiol from aqueous solutions. Chemical modification and/or activation were applied to alter surface characteristics and to increase the adsorption and desorption efficiency of carbon materials. Surfaces of treated and untreated carbon materials were characterized through the examination of the textural properties, the nature of surface functional groups, and surface acidity. It was found that the adsorption capacity of tested carbon materials is not directly proportional to the specific surface area and the content of surface oxygen groups. However, a high ratio of surface mesoporosity affected the adsorption process most prominently, by increasing adsorption capacity and the rate of the adsorption process. Adsorption of estrone, 17 beta-estradiol, and 17 alpha-ethinylestradiol followed pseudo-second-order kinetic model, while the equilibrium adsorption data were best fitted with the Langmuir isotherm model. Calculated mean adsorption energy values, along with the thermodynamic parameters, indicated that removal of selected hormones was dominated by the physisorption mechanism. High values of adsorption efficiency (88-100 %) and Langmuir adsorption capacities (29.45-194.7 mg/g) imply that examined materials, especially mesoporous carbon cryogel and multi-walled carbon nanotubes, can be used as powerful adsorbents for relatively fast removal of estrogen hormones from water. PB - Springer Heidelberg, Heidelberg T2 - Environmental science and pollution research T1 - Adsorption of estrone, 17 beta-estradiol, and 17 alpha-ethinylestradiol from water onto modified multi-walled carbon nanotubes, carbon cryogel, and carbonized hydrothermal carbon EP - 4445 IS - 3 SP - 4431 VL - 29 DO - 10.1007/s11356-021-15970-4 UR - conv_913 ER -
@article{ author = "Prokić, Danijela and Vukcević, Marija and Mitrović, Angelina and Maletić, Marina and Kalijadis, Ana and Janković-Častvan, Ivona and Durkić, Tatjana", year = "2022", abstract = "Carbon materials of different structural and textural properties (multi-walled carbon nanotubes, carbon cryogel, and carbonized hydrothermal carbon) were used as adsorbents for the removal of estrone, 17 beta-estradiol, and 17 alpha-ethinylestradiol from aqueous solutions. Chemical modification and/or activation were applied to alter surface characteristics and to increase the adsorption and desorption efficiency of carbon materials. Surfaces of treated and untreated carbon materials were characterized through the examination of the textural properties, the nature of surface functional groups, and surface acidity. It was found that the adsorption capacity of tested carbon materials is not directly proportional to the specific surface area and the content of surface oxygen groups. However, a high ratio of surface mesoporosity affected the adsorption process most prominently, by increasing adsorption capacity and the rate of the adsorption process. Adsorption of estrone, 17 beta-estradiol, and 17 alpha-ethinylestradiol followed pseudo-second-order kinetic model, while the equilibrium adsorption data were best fitted with the Langmuir isotherm model. Calculated mean adsorption energy values, along with the thermodynamic parameters, indicated that removal of selected hormones was dominated by the physisorption mechanism. High values of adsorption efficiency (88-100 %) and Langmuir adsorption capacities (29.45-194.7 mg/g) imply that examined materials, especially mesoporous carbon cryogel and multi-walled carbon nanotubes, can be used as powerful adsorbents for relatively fast removal of estrogen hormones from water.", publisher = "Springer Heidelberg, Heidelberg", journal = "Environmental science and pollution research", title = "Adsorption of estrone, 17 beta-estradiol, and 17 alpha-ethinylestradiol from water onto modified multi-walled carbon nanotubes, carbon cryogel, and carbonized hydrothermal carbon", pages = "4445-4431", number = "3", volume = "29", doi = "10.1007/s11356-021-15970-4", url = "conv_913" }
Prokić, D., Vukcević, M., Mitrović, A., Maletić, M., Kalijadis, A., Janković-Častvan, I.,& Durkić, T.. (2022). Adsorption of estrone, 17 beta-estradiol, and 17 alpha-ethinylestradiol from water onto modified multi-walled carbon nanotubes, carbon cryogel, and carbonized hydrothermal carbon. in Environmental science and pollution research Springer Heidelberg, Heidelberg., 29(3), 4431-4445. https://doi.org/10.1007/s11356-021-15970-4 conv_913
Prokić D, Vukcević M, Mitrović A, Maletić M, Kalijadis A, Janković-Častvan I, Durkić T. Adsorption of estrone, 17 beta-estradiol, and 17 alpha-ethinylestradiol from water onto modified multi-walled carbon nanotubes, carbon cryogel, and carbonized hydrothermal carbon. in Environmental science and pollution research. 2022;29(3):4431-4445. doi:10.1007/s11356-021-15970-4 conv_913 .
Prokić, Danijela, Vukcević, Marija, Mitrović, Angelina, Maletić, Marina, Kalijadis, Ana, Janković-Častvan, Ivona, Durkić, Tatjana, "Adsorption of estrone, 17 beta-estradiol, and 17 alpha-ethinylestradiol from water onto modified multi-walled carbon nanotubes, carbon cryogel, and carbonized hydrothermal carbon" in Environmental science and pollution research, 29, no. 3 (2022):4431-4445, https://doi.org/10.1007/s11356-021-15970-4 ., conv_913 .
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