Thermal analysis and phase changes of mechanochemically activated sodium carbonate
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Đorđević, Nataša
Mihajlović, Slavica

Vlahović, Milica

Lozanović-Sajić, Jasmina

Martinović, Sanja

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Sodium carbonate is a well-known material for being used as a good sorbent of carbon dioxide from the atmosphere, and as such has gained increasing importance in environmental protection. In order to enhance its sorption ability, mechanochemical activation of sodium carbonate was carried out in this study while the occurred changes after the activation and the relaxation time in a controlled environment were monitored. Activation was performed in a vibro-mill from 1 to 28 min. Based on the results of specific surface area, obtained by BET, the samples activated for 2 and 7 min were chosen and placed in a moist carbon dioxide atmosphere for 96 h, a period called the relaxation time. Differential thermal and thermogravimetric analyses were applied with the aim of determining the changes that occurred on the activated samples during the relaxation period. The decomposition temperature change of activated Na2CO3 samples, as well as mass loss and conversion level of Na2CO3 to NaHCO3 were mo...nitored depending on activation and relaxation time periods. The conversion reactions of sodium carbonate to sodium bicarbonate under the specified environment of carbon dioxide and moisture were also studied, and the thermodynamic data such are changes in enthalpy, entropy, and Gibbs energy at the temperature range of 0-160 degrees C are given.
Keywords:
Thermal and termodynamical analysis / Phase changes / Na2CO3 / Mechanochemical activationSource:
Thermochimica Acta, 2022, 708Publisher:
- Elsevier, Amsterdam
Funding / projects:
- Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200023 (Institute of Technology of Nuclear and Other Mineral Row Materials - ITNMS, Belgrade) (RS-200023)
- Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200026 (University of Belgrade, Institute of Chemistry, Technology and Metallurgy - IChTM) (RS-200026)
DOI: 10.1016/j.tca.2021.179139
ISSN: 0040-6031
WoS: 000743952800015
Scopus: 2-s2.0-85122314119
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Institut za tehnologiju nuklearnih i drugih mineralnih sirovinaTY - JOUR AU - Đorđević, Nataša AU - Mihajlović, Slavica AU - Vlahović, Milica AU - Lozanović-Sajić, Jasmina AU - Martinović, Sanja PY - 2022 UR - https://ritnms.itnms.ac.rs/handle/123456789/635 AB - Sodium carbonate is a well-known material for being used as a good sorbent of carbon dioxide from the atmosphere, and as such has gained increasing importance in environmental protection. In order to enhance its sorption ability, mechanochemical activation of sodium carbonate was carried out in this study while the occurred changes after the activation and the relaxation time in a controlled environment were monitored. Activation was performed in a vibro-mill from 1 to 28 min. Based on the results of specific surface area, obtained by BET, the samples activated for 2 and 7 min were chosen and placed in a moist carbon dioxide atmosphere for 96 h, a period called the relaxation time. Differential thermal and thermogravimetric analyses were applied with the aim of determining the changes that occurred on the activated samples during the relaxation period. The decomposition temperature change of activated Na2CO3 samples, as well as mass loss and conversion level of Na2CO3 to NaHCO3 were monitored depending on activation and relaxation time periods. The conversion reactions of sodium carbonate to sodium bicarbonate under the specified environment of carbon dioxide and moisture were also studied, and the thermodynamic data such are changes in enthalpy, entropy, and Gibbs energy at the temperature range of 0-160 degrees C are given. PB - Elsevier, Amsterdam T2 - Thermochimica Acta T1 - Thermal analysis and phase changes of mechanochemically activated sodium carbonate VL - 708 DO - 10.1016/j.tca.2021.179139 UR - conv_931 ER -
@article{ author = "Đorđević, Nataša and Mihajlović, Slavica and Vlahović, Milica and Lozanović-Sajić, Jasmina and Martinović, Sanja", year = "2022", abstract = "Sodium carbonate is a well-known material for being used as a good sorbent of carbon dioxide from the atmosphere, and as such has gained increasing importance in environmental protection. In order to enhance its sorption ability, mechanochemical activation of sodium carbonate was carried out in this study while the occurred changes after the activation and the relaxation time in a controlled environment were monitored. Activation was performed in a vibro-mill from 1 to 28 min. Based on the results of specific surface area, obtained by BET, the samples activated for 2 and 7 min were chosen and placed in a moist carbon dioxide atmosphere for 96 h, a period called the relaxation time. Differential thermal and thermogravimetric analyses were applied with the aim of determining the changes that occurred on the activated samples during the relaxation period. The decomposition temperature change of activated Na2CO3 samples, as well as mass loss and conversion level of Na2CO3 to NaHCO3 were monitored depending on activation and relaxation time periods. The conversion reactions of sodium carbonate to sodium bicarbonate under the specified environment of carbon dioxide and moisture were also studied, and the thermodynamic data such are changes in enthalpy, entropy, and Gibbs energy at the temperature range of 0-160 degrees C are given.", publisher = "Elsevier, Amsterdam", journal = "Thermochimica Acta", title = "Thermal analysis and phase changes of mechanochemically activated sodium carbonate", volume = "708", doi = "10.1016/j.tca.2021.179139", url = "conv_931" }
Đorđević, N., Mihajlović, S., Vlahović, M., Lozanović-Sajić, J.,& Martinović, S.. (2022). Thermal analysis and phase changes of mechanochemically activated sodium carbonate. in Thermochimica Acta Elsevier, Amsterdam., 708. https://doi.org/10.1016/j.tca.2021.179139 conv_931
Đorđević N, Mihajlović S, Vlahović M, Lozanović-Sajić J, Martinović S. Thermal analysis and phase changes of mechanochemically activated sodium carbonate. in Thermochimica Acta. 2022;708. doi:10.1016/j.tca.2021.179139 conv_931 .
Đorđević, Nataša, Mihajlović, Slavica, Vlahović, Milica, Lozanović-Sajić, Jasmina, Martinović, Sanja, "Thermal analysis and phase changes of mechanochemically activated sodium carbonate" in Thermochimica Acta, 708 (2022), https://doi.org/10.1016/j.tca.2021.179139 ., conv_931 .