Zearalenone and ochratoxin a: adsorption by kaolin modified with surfactant

2019
Authors
Spasojević, Milica
Daković, Aleksandra

Rottinghaus, George E.
Radosavljević-Mihajlović, Ana

Marković, Marija

Krajišnik, Danina

Article (Published version)
Metadata
Show full item recordAbstract
Octadecyldimethylbenzyl ammonium chloride (OA) was used as a surfactant for the preparation of organokaolin. The natural kaolin (from a plant for production of quartz sand in Rgotina, Serbia) was modified with a surfactant in amount equal to 90% of the kaolin cation exchange capacity (CEC). FTIR spectroscopy was used for characterization of the new product. FTIR spectra confirmed the presence of OA ions at the kaolin surface. Adsorption of mycotoxins - zearalenone (ZEN) and ochratoxin A (OCHRA) was studied by organokaolin at different amounts of adsorbent and pHs. Results showed that the presence of organic cations in the kaolin structure increased adsorption of both ZEN and OCHRA. Adsorption of the mycotoxins by organokaolin increased with increasing amounts of adsorbent and, at the lowest amount of solids in suspension, adsorption of ZEN and OCHRA was slightly higher at pH 7 and 9.
Keywords:
surfactants / mycotoxins / kaolin / adsorptionSource:
Metallurgical & Materials Engineering, 2019, 25, 1, 39-45Publisher:
- Savez inženjera metalurgije Srbije, Beograd
Funding / projects:
- Development of technological processes for obtaining of ecological materials based on nonmetallic minerals (RS-34013)
- Oxide-based environmentally-friendly porous materials for genotoxic substances removal (RS-172018)
DOI: 10.30544/413
ISSN: 2217-8961
WoS: 000465401600005
Scopus: 2-s2.0-85068057089
Collections
Institution/Community
Institut za tehnologiju nuklearnih i drugih mineralnih sirovinaTY - JOUR AU - Spasojević, Milica AU - Daković, Aleksandra AU - Rottinghaus, George E. AU - Radosavljević-Mihajlović, Ana AU - Marković, Marija AU - Krajišnik, Danina PY - 2019 UR - https://ritnms.itnms.ac.rs/handle/123456789/527 AB - Octadecyldimethylbenzyl ammonium chloride (OA) was used as a surfactant for the preparation of organokaolin. The natural kaolin (from a plant for production of quartz sand in Rgotina, Serbia) was modified with a surfactant in amount equal to 90% of the kaolin cation exchange capacity (CEC). FTIR spectroscopy was used for characterization of the new product. FTIR spectra confirmed the presence of OA ions at the kaolin surface. Adsorption of mycotoxins - zearalenone (ZEN) and ochratoxin A (OCHRA) was studied by organokaolin at different amounts of adsorbent and pHs. Results showed that the presence of organic cations in the kaolin structure increased adsorption of both ZEN and OCHRA. Adsorption of the mycotoxins by organokaolin increased with increasing amounts of adsorbent and, at the lowest amount of solids in suspension, adsorption of ZEN and OCHRA was slightly higher at pH 7 and 9. PB - Savez inženjera metalurgije Srbije, Beograd T2 - Metallurgical & Materials Engineering T1 - Zearalenone and ochratoxin a: adsorption by kaolin modified with surfactant EP - 45 IS - 1 SP - 39 VL - 25 DO - 10.30544/413 UR - conv_848 ER -
@article{ author = "Spasojević, Milica and Daković, Aleksandra and Rottinghaus, George E. and Radosavljević-Mihajlović, Ana and Marković, Marija and Krajišnik, Danina", year = "2019", abstract = "Octadecyldimethylbenzyl ammonium chloride (OA) was used as a surfactant for the preparation of organokaolin. The natural kaolin (from a plant for production of quartz sand in Rgotina, Serbia) was modified with a surfactant in amount equal to 90% of the kaolin cation exchange capacity (CEC). FTIR spectroscopy was used for characterization of the new product. FTIR spectra confirmed the presence of OA ions at the kaolin surface. Adsorption of mycotoxins - zearalenone (ZEN) and ochratoxin A (OCHRA) was studied by organokaolin at different amounts of adsorbent and pHs. Results showed that the presence of organic cations in the kaolin structure increased adsorption of both ZEN and OCHRA. Adsorption of the mycotoxins by organokaolin increased with increasing amounts of adsorbent and, at the lowest amount of solids in suspension, adsorption of ZEN and OCHRA was slightly higher at pH 7 and 9.", publisher = "Savez inženjera metalurgije Srbije, Beograd", journal = "Metallurgical & Materials Engineering", title = "Zearalenone and ochratoxin a: adsorption by kaolin modified with surfactant", pages = "45-39", number = "1", volume = "25", doi = "10.30544/413", url = "conv_848" }
Spasojević, M., Daković, A., Rottinghaus, G. E., Radosavljević-Mihajlović, A., Marković, M.,& Krajišnik, D.. (2019). Zearalenone and ochratoxin a: adsorption by kaolin modified with surfactant. in Metallurgical & Materials Engineering Savez inženjera metalurgije Srbije, Beograd., 25(1), 39-45. https://doi.org/10.30544/413 conv_848
Spasojević M, Daković A, Rottinghaus GE, Radosavljević-Mihajlović A, Marković M, Krajišnik D. Zearalenone and ochratoxin a: adsorption by kaolin modified with surfactant. in Metallurgical & Materials Engineering. 2019;25(1):39-45. doi:10.30544/413 conv_848 .
Spasojević, Milica, Daković, Aleksandra, Rottinghaus, George E., Radosavljević-Mihajlović, Ana, Marković, Marija, Krajišnik, Danina, "Zearalenone and ochratoxin a: adsorption by kaolin modified with surfactant" in Metallurgical & Materials Engineering, 25, no. 1 (2019):39-45, https://doi.org/10.30544/413 ., conv_848 .