Kinetics of thermally activated processes in cordierite-based ceramics

2019
Authors
Obradović, Nina
Blagojević, Vladimir

Filipović, Suzana

Đorđević, Nataša

Kosanović, Darko

Marković, Smilja

Kachlik, Martin
Maca, Karel

Pavlović, Vladimir

Article (Published version)

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Show full item recordAbstract
Thermally activated processes in cordierite-based ceramics were investigated to determine the effect of the mechanical activation and the addition of TeO2 on kinetic and thermodynamic parameters of these processes. Using a combination of dilatometry and DTA measurements in the 100-1400 degrees C temperature range, it was established that both the mechanical activation and the addition of TeO2 have a significant effect on processes in cordierite-based ceramics. A combination of 5 mass% addition of TeO2 and mechanical activation for 40 min reduced the sintering temperature of cordierite ceramics to around 1100 degrees C. In addition, the analysis of DTA measurements of mechanically activated samples indicates that the mechanical activation leads to intensification of the cordierite formation through an increase in concentration of surface defects and an increase in grain contact surface in the initial powder.
Keywords:
TeO2 / Sintering kinetics / Mechanical activation / DTA / CordieriteSource:
Journal of Thermal Analysis and Calorimetry, 2019, 138, 5, 2989-2998Publisher:
- Springer, Dordrecht
Funding / projects:
- Serbian Ministry of Education, Science and Technological Development
- Grant agency of Czech Republic [17-05620S]
- Ministry of Education, Youth and Sports of the Czech Republic [LQ1601]
- Directed synthesis, structure and properties of multifunctional materials (RS-172057)
DOI: 10.1007/s10973-018-7924-1
ISSN: 1388-6150
WoS: 000499706100003
Scopus: 2-s2.0-85057947179
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Institut za tehnologiju nuklearnih i drugih mineralnih sirovinaTY - JOUR AU - Obradović, Nina AU - Blagojević, Vladimir AU - Filipović, Suzana AU - Đorđević, Nataša AU - Kosanović, Darko AU - Marković, Smilja AU - Kachlik, Martin AU - Maca, Karel AU - Pavlović, Vladimir PY - 2019 UR - https://ritnms.itnms.ac.rs/handle/123456789/501 AB - Thermally activated processes in cordierite-based ceramics were investigated to determine the effect of the mechanical activation and the addition of TeO2 on kinetic and thermodynamic parameters of these processes. Using a combination of dilatometry and DTA measurements in the 100-1400 degrees C temperature range, it was established that both the mechanical activation and the addition of TeO2 have a significant effect on processes in cordierite-based ceramics. A combination of 5 mass% addition of TeO2 and mechanical activation for 40 min reduced the sintering temperature of cordierite ceramics to around 1100 degrees C. In addition, the analysis of DTA measurements of mechanically activated samples indicates that the mechanical activation leads to intensification of the cordierite formation through an increase in concentration of surface defects and an increase in grain contact surface in the initial powder. PB - Springer, Dordrecht T2 - Journal of Thermal Analysis and Calorimetry T1 - Kinetics of thermally activated processes in cordierite-based ceramics EP - 2998 IS - 5 SP - 2989 VL - 138 DO - 10.1007/s10973-018-7924-1 UR - https://hdl.handle.net/21.15107/rcub_dais_7048 UR - conv_867 ER -
@article{ author = "Obradović, Nina and Blagojević, Vladimir and Filipović, Suzana and Đorđević, Nataša and Kosanović, Darko and Marković, Smilja and Kachlik, Martin and Maca, Karel and Pavlović, Vladimir", year = "2019", abstract = "Thermally activated processes in cordierite-based ceramics were investigated to determine the effect of the mechanical activation and the addition of TeO2 on kinetic and thermodynamic parameters of these processes. Using a combination of dilatometry and DTA measurements in the 100-1400 degrees C temperature range, it was established that both the mechanical activation and the addition of TeO2 have a significant effect on processes in cordierite-based ceramics. A combination of 5 mass% addition of TeO2 and mechanical activation for 40 min reduced the sintering temperature of cordierite ceramics to around 1100 degrees C. In addition, the analysis of DTA measurements of mechanically activated samples indicates that the mechanical activation leads to intensification of the cordierite formation through an increase in concentration of surface defects and an increase in grain contact surface in the initial powder.", publisher = "Springer, Dordrecht", journal = "Journal of Thermal Analysis and Calorimetry", title = "Kinetics of thermally activated processes in cordierite-based ceramics", pages = "2998-2989", number = "5", volume = "138", doi = "10.1007/s10973-018-7924-1", url = "https://hdl.handle.net/21.15107/rcub_dais_7048, conv_867" }
Obradović, N., Blagojević, V., Filipović, S., Đorđević, N., Kosanović, D., Marković, S., Kachlik, M., Maca, K.,& Pavlović, V.. (2019). Kinetics of thermally activated processes in cordierite-based ceramics. in Journal of Thermal Analysis and Calorimetry Springer, Dordrecht., 138(5), 2989-2998. https://doi.org/10.1007/s10973-018-7924-1 https://hdl.handle.net/21.15107/rcub_dais_7048
Obradović N, Blagojević V, Filipović S, Đorđević N, Kosanović D, Marković S, Kachlik M, Maca K, Pavlović V. Kinetics of thermally activated processes in cordierite-based ceramics. in Journal of Thermal Analysis and Calorimetry. 2019;138(5):2989-2998. doi:10.1007/s10973-018-7924-1 https://hdl.handle.net/21.15107/rcub_dais_7048 .
Obradović, Nina, Blagojević, Vladimir, Filipović, Suzana, Đorđević, Nataša, Kosanović, Darko, Marković, Smilja, Kachlik, Martin, Maca, Karel, Pavlović, Vladimir, "Kinetics of thermally activated processes in cordierite-based ceramics" in Journal of Thermal Analysis and Calorimetry, 138, no. 5 (2019):2989-2998, https://doi.org/10.1007/s10973-018-7924-1 ., https://hdl.handle.net/21.15107/rcub_dais_7048 .