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A review of the Pb-Zn-Cu-Ag-Bi-W polymetallic ore from the Rudnik orefield, Central Serbia

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2018
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Authors
Stojanović, Jovica
Radosavljević, Slobodan
Tošović, Radule D.
Pačevski, Aleksandar M.
Radosavljević-Mihajlović, Ana
Kašić, Vladan
Vuković, Nikola
Article (Published version)
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Abstract
The Rudnik orefield is one of the well-known skarn-replacement and high-temperature hydrothermal Pb-Zn-Cu-Ag-Bi-W polymetallic sulfide deposits, and is a part of the Šumadija Metallogenic District, Serbia. It comprises ore bodies grouped into several major ore zones. The pseudostratified and platelike ore bodies have relatively high content of valuable metals. The average content varies in wide ranges: Pb (0.94-5.66 wt%), Zn (0.49-4.49 wt%), Cu (0.08-2.18 wt%), Ag (50-297 ppm), Bi (~100-150 ppm), and Cd (~100-150 ppm). Generally, a complex mineral association has been determined. Iron sulfides, arsenopyrite, chalcopyrite, sphalerite, galena and sulfosalts are abundant minerals in the ore. Carrier minerals of Bi and Ag are Bi-sulfosalts, such as galenobismutite, cosalite, Ag-bearing aschamalmite, vikingite, schirmerite and gustavite. Copper, Ag and Pb-Sb sulfosalts have been found only locally. Complex Ni-minerals (sulfides, arsenides ...and sulfoarsenidеs) with Fe, Co and Ag were formed under to the influence of present serpentine rocks and their yield of Ni, Co and Cr in the hydrothermal ore-bearing solutions. Significant scheelite mineralizations have been found in the Nova Jama, Gušavi Potok and Azna ore zones. The presence of Bi-sulfosalts and argentopentlandite suggests formation temperatures higher than 350, and lower than 445°C, respectively. Therefore, the mineralization was formed in the temperature range 350 to 400°C. The continuity of pyrite, pyrrhotite and siderite colloform bands in relic aggregates shows frequent changes of fS2 and fO2 in hydrothermal solutions. Isotopic composition of sulfur also confirms that the source of the ore-bearing fluids was magmatic. In addition, the enrichment of Bi and Ag indicates a magmatic origin. The appearance of Biminerals represents a significant genetic indicator for detection of increased Ag concentrations within the ore mineralizations. Typical gangue minerals are quartz, silicates, carbonates, oxides and different oxy-hydroxides. Special attention is given to the paragenetic relationships and the genetic significance of mineral associations as indicators of ore-forming conditions.

Keywords:
ore mineralogy / Pb-Zn-Cu-Ag-Bi-W polymetallic ore / sulfosalts / Rudnik orefield / Serbia
Source:
Geološki Anali Balkanskoga Poluostrva, 2018, 79, 1, 47-69
Publisher:
  • Univerzitet u Beogradu - Rudarsko-geološki fakultet, Beograd
Funding / projects:
  • Magmatism and geodynamics of the Balkan Peninsula from Mesozoic to present day: significance for the formation of metallic and non-metallic mineral deposits (RS-176016)

DOI: 10.2298/GABP1879047S

ISSN: 0350-0608

[ Google Scholar ]
URI
https://ritnms.itnms.ac.rs/handle/123456789/470
Collections
  • Radovi istraživača / Researchers’ publications
Institution/Community
Institut za tehnologiju nuklearnih i drugih mineralnih sirovina
TY  - JOUR
AU  - Stojanović, Jovica
AU  - Radosavljević, Slobodan
AU  - Tošović, Radule D.
AU  - Pačevski, Aleksandar M.
AU  - Radosavljević-Mihajlović, Ana
AU  - Kašić, Vladan
AU  - Vuković, Nikola
PY  - 2018
UR  - https://ritnms.itnms.ac.rs/handle/123456789/470
AB  - The Rudnik orefield is one of the well-known skarn-replacement and
   high-temperature hydrothermal Pb-Zn-Cu-Ag-Bi-W polymetallic sulfide
   deposits, and is a part of the Šumadija Metallogenic District, Serbia. It
   comprises ore bodies grouped into several major ore zones. The
   pseudostratified and platelike ore bodies have relatively high content of
   valuable metals. The average content varies in wide ranges: Pb (0.94-5.66
   wt%), Zn (0.49-4.49 wt%), Cu (0.08-2.18 wt%), Ag (50-297 ppm), Bi (~100-150
   ppm), and Cd (~100-150 ppm). Generally, a complex mineral association has
   been determined. Iron sulfides, arsenopyrite, chalcopyrite, sphalerite,
   galena and sulfosalts are abundant minerals in the ore. Carrier minerals of
   Bi and Ag are Bi-sulfosalts, such as galenobismutite, cosalite, Ag-bearing
   aschamalmite, vikingite, schirmerite and gustavite. Copper, Ag and Pb-Sb
   sulfosalts have been found only locally. Complex Ni-minerals (sulfides,
   arsenides and sulfoarsenidеs) with Fe, Co and Ag were formed under to the
   influence of present serpentine rocks and their yield of Ni, Co and Cr in
   the hydrothermal ore-bearing solutions. Significant scheelite
   mineralizations have been found in the Nova Jama, Gušavi Potok and Azna ore
   zones. The presence of Bi-sulfosalts and argentopentlandite suggests
   formation temperatures higher than 350, and lower than 445°C, respectively.
   Therefore, the mineralization was formed in the temperature range 350 to
   400°C. The continuity of pyrite, pyrrhotite and siderite colloform bands in
   relic aggregates shows frequent changes of fS2 and fO2 in hydrothermal
   solutions. Isotopic composition of sulfur also confirms that the source of
   the ore-bearing fluids was magmatic. In addition, the enrichment of Bi and
   Ag indicates a magmatic origin. The appearance of Biminerals represents a
   significant genetic indicator for detection of increased Ag concentrations
   within the ore mineralizations. Typical gangue minerals are quartz,
   silicates, carbonates, oxides and different oxy-hydroxides. Special
   attention is given to the paragenetic relationships and the genetic
   significance of mineral associations as indicators of ore-forming conditions.
PB  - Univerzitet u Beogradu - Rudarsko-geološki fakultet, Beograd
T2  - Geološki Anali Balkanskoga Poluostrva
T1  - A review of the Pb-Zn-Cu-Ag-Bi-W polymetallic ore from the Rudnik orefield, Central Serbia
EP  - 69
IS  - 1
SP  - 47
VL  - 79
DO  - 10.2298/GABP1879047S
UR  - conv_1203
ER  - 
@article{
author = "Stojanović, Jovica and Radosavljević, Slobodan and Tošović, Radule D. and Pačevski, Aleksandar M. and Radosavljević-Mihajlović, Ana and Kašić, Vladan and Vuković, Nikola",
year = "2018",
abstract = "The Rudnik orefield is one of the well-known skarn-replacement and
   high-temperature hydrothermal Pb-Zn-Cu-Ag-Bi-W polymetallic sulfide
   deposits, and is a part of the Šumadija Metallogenic District, Serbia. It
   comprises ore bodies grouped into several major ore zones. The
   pseudostratified and platelike ore bodies have relatively high content of
   valuable metals. The average content varies in wide ranges: Pb (0.94-5.66
   wt%), Zn (0.49-4.49 wt%), Cu (0.08-2.18 wt%), Ag (50-297 ppm), Bi (~100-150
   ppm), and Cd (~100-150 ppm). Generally, a complex mineral association has
   been determined. Iron sulfides, arsenopyrite, chalcopyrite, sphalerite,
   galena and sulfosalts are abundant minerals in the ore. Carrier minerals of
   Bi and Ag are Bi-sulfosalts, such as galenobismutite, cosalite, Ag-bearing
   aschamalmite, vikingite, schirmerite and gustavite. Copper, Ag and Pb-Sb
   sulfosalts have been found only locally. Complex Ni-minerals (sulfides,
   arsenides and sulfoarsenidеs) with Fe, Co and Ag were formed under to the
   influence of present serpentine rocks and their yield of Ni, Co and Cr in
   the hydrothermal ore-bearing solutions. Significant scheelite
   mineralizations have been found in the Nova Jama, Gušavi Potok and Azna ore
   zones. The presence of Bi-sulfosalts and argentopentlandite suggests
   formation temperatures higher than 350, and lower than 445°C, respectively.
   Therefore, the mineralization was formed in the temperature range 350 to
   400°C. The continuity of pyrite, pyrrhotite and siderite colloform bands in
   relic aggregates shows frequent changes of fS2 and fO2 in hydrothermal
   solutions. Isotopic composition of sulfur also confirms that the source of
   the ore-bearing fluids was magmatic. In addition, the enrichment of Bi and
   Ag indicates a magmatic origin. The appearance of Biminerals represents a
   significant genetic indicator for detection of increased Ag concentrations
   within the ore mineralizations. Typical gangue minerals are quartz,
   silicates, carbonates, oxides and different oxy-hydroxides. Special
   attention is given to the paragenetic relationships and the genetic
   significance of mineral associations as indicators of ore-forming conditions.",
publisher = "Univerzitet u Beogradu - Rudarsko-geološki fakultet, Beograd",
journal = "Geološki Anali Balkanskoga Poluostrva",
title = "A review of the Pb-Zn-Cu-Ag-Bi-W polymetallic ore from the Rudnik orefield, Central Serbia",
pages = "69-47",
number = "1",
volume = "79",
doi = "10.2298/GABP1879047S",
url = "conv_1203"
}
Stojanović, J., Radosavljević, S., Tošović, R. D., Pačevski, A. M., Radosavljević-Mihajlović, A., Kašić, V.,& Vuković, N.. (2018). A review of the Pb-Zn-Cu-Ag-Bi-W polymetallic ore from the Rudnik orefield, Central Serbia. in Geološki Anali Balkanskoga Poluostrva
Univerzitet u Beogradu - Rudarsko-geološki fakultet, Beograd., 79(1), 47-69.
https://doi.org/10.2298/GABP1879047S
conv_1203
Stojanović J, Radosavljević S, Tošović RD, Pačevski AM, Radosavljević-Mihajlović A, Kašić V, Vuković N. A review of the Pb-Zn-Cu-Ag-Bi-W polymetallic ore from the Rudnik orefield, Central Serbia. in Geološki Anali Balkanskoga Poluostrva. 2018;79(1):47-69.
doi:10.2298/GABP1879047S
conv_1203 .
Stojanović, Jovica, Radosavljević, Slobodan, Tošović, Radule D., Pačevski, Aleksandar M., Radosavljević-Mihajlović, Ana, Kašić, Vladan, Vuković, Nikola, "A review of the Pb-Zn-Cu-Ag-Bi-W polymetallic ore from the Rudnik orefield, Central Serbia" in Geološki Anali Balkanskoga Poluostrva, 79, no. 1 (2018):47-69,
https://doi.org/10.2298/GABP1879047S .,
conv_1203 .

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