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To what extent do soft mechanical activation and process parameters increase the efficiency of different zeolite/phosphate rock fertilizer mixtures?

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2017
452.pdf (654.1Kb)
Authors
Mihajlović, Marija
Stanojević, Marija
Stojanović, Mirjana
Petrović, Jelena
Milojković, Jelena
Petrović, Marija
Lopičić, Zorica
Article (Published version)
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Abstract
In order to obtain effective mineral fertilizer, different mixtures of phosphate rock (PR) with natural clinoptilolite (Cp) and NH4+ saturated clinoptilolite (NH4-Cp) were subjected to soft mechanical activation. Mean concentrations of P released from mechanically activated (MA) substrates, MACp/PR and MANH(4)-Cp/PR, ranged between 281-3.19 mg L-1 and 202-774 mg L-1, respectively. These are 10 to 15 times higher P concentrations than those released from the corresponding non-activated mixtures. Solution Ca2+, K+, Na+ and Mg2+ concentrations varied according to the composition of the mixtures and the contact time between the two minerals within their optimal values required for plant growth. The obtained results suggest that the efficiency of the NH4-Cp/PR mixtures can be significantly increased by the proposed mechanical activation. Influence of process parameters on the observed concentrations of nutrients was shown using multivariate statistics. The highest fertilization potential de...monstrated MANH(4)-Cp/PR mixture with the largest NH4-Cp share and the longest proposed mixing time.

Keywords:
phosphate rock / multivariate analysis / mechanical activation / exchange-fertilizer mixtures / clinoptilolite
Source:
Chemical Industry and Chemical Engineering Quarterly / CICEQ, 2017, 23, 1, 1-9
Publisher:
  • Savez hemijskih inženjera, Beograd
Funding / projects:
  • Development of technologies and products based on mineral raw materials and waste biomass for protection of natural resources for safe food production (RS-31003)

DOI: 10.2298/CICEQ150622047M

ISSN: 1451-9372

WoS: 000402144500001

Scopus: 2-s2.0-85018764449
[ Google Scholar ]
1
URI
https://ritnms.itnms.ac.rs/handle/123456789/455
Collections
  • Radovi istraživača / Researchers’ publications
Institution/Community
Institut za tehnologiju nuklearnih i drugih mineralnih sirovina
TY  - JOUR
AU  - Mihajlović, Marija
AU  - Stanojević, Marija
AU  - Stojanović, Mirjana
AU  - Petrović, Jelena
AU  - Milojković, Jelena
AU  - Petrović, Marija
AU  - Lopičić, Zorica
PY  - 2017
UR  - https://ritnms.itnms.ac.rs/handle/123456789/455
AB  - In order to obtain effective mineral fertilizer, different mixtures of phosphate rock (PR) with natural clinoptilolite (Cp) and NH4+ saturated clinoptilolite (NH4-Cp) were subjected to soft mechanical activation. Mean concentrations of P released from mechanically activated (MA) substrates, MACp/PR and MANH(4)-Cp/PR, ranged between 281-3.19 mg L-1 and 202-774 mg L-1, respectively. These are 10 to 15 times higher P concentrations than those released from the corresponding non-activated mixtures. Solution Ca2+, K+, Na+ and Mg2+ concentrations varied according to the composition of the mixtures and the contact time between the two minerals within their optimal values required for plant growth. The obtained results suggest that the efficiency of the NH4-Cp/PR mixtures can be significantly increased by the proposed mechanical activation. Influence of process parameters on the observed concentrations of nutrients was shown using multivariate statistics. The highest fertilization potential demonstrated MANH(4)-Cp/PR mixture with the largest NH4-Cp share and the longest proposed mixing time.
PB  - Savez hemijskih inženjera, Beograd
T2  - Chemical Industry and Chemical Engineering Quarterly / CICEQ
T1  - To what extent do soft mechanical activation and process parameters increase the efficiency of different zeolite/phosphate rock fertilizer mixtures?
EP  - 9
IS  - 1
SP  - 1
VL  - 23
DO  - 10.2298/CICEQ150622047M
UR  - conv_795
ER  - 
@article{
author = "Mihajlović, Marija and Stanojević, Marija and Stojanović, Mirjana and Petrović, Jelena and Milojković, Jelena and Petrović, Marija and Lopičić, Zorica",
year = "2017",
abstract = "In order to obtain effective mineral fertilizer, different mixtures of phosphate rock (PR) with natural clinoptilolite (Cp) and NH4+ saturated clinoptilolite (NH4-Cp) were subjected to soft mechanical activation. Mean concentrations of P released from mechanically activated (MA) substrates, MACp/PR and MANH(4)-Cp/PR, ranged between 281-3.19 mg L-1 and 202-774 mg L-1, respectively. These are 10 to 15 times higher P concentrations than those released from the corresponding non-activated mixtures. Solution Ca2+, K+, Na+ and Mg2+ concentrations varied according to the composition of the mixtures and the contact time between the two minerals within their optimal values required for plant growth. The obtained results suggest that the efficiency of the NH4-Cp/PR mixtures can be significantly increased by the proposed mechanical activation. Influence of process parameters on the observed concentrations of nutrients was shown using multivariate statistics. The highest fertilization potential demonstrated MANH(4)-Cp/PR mixture with the largest NH4-Cp share and the longest proposed mixing time.",
publisher = "Savez hemijskih inženjera, Beograd",
journal = "Chemical Industry and Chemical Engineering Quarterly / CICEQ",
title = "To what extent do soft mechanical activation and process parameters increase the efficiency of different zeolite/phosphate rock fertilizer mixtures?",
pages = "9-1",
number = "1",
volume = "23",
doi = "10.2298/CICEQ150622047M",
url = "conv_795"
}
Mihajlović, M., Stanojević, M., Stojanović, M., Petrović, J., Milojković, J., Petrović, M.,& Lopičić, Z.. (2017). To what extent do soft mechanical activation and process parameters increase the efficiency of different zeolite/phosphate rock fertilizer mixtures?. in Chemical Industry and Chemical Engineering Quarterly / CICEQ
Savez hemijskih inženjera, Beograd., 23(1), 1-9.
https://doi.org/10.2298/CICEQ150622047M
conv_795
Mihajlović M, Stanojević M, Stojanović M, Petrović J, Milojković J, Petrović M, Lopičić Z. To what extent do soft mechanical activation and process parameters increase the efficiency of different zeolite/phosphate rock fertilizer mixtures?. in Chemical Industry and Chemical Engineering Quarterly / CICEQ. 2017;23(1):1-9.
doi:10.2298/CICEQ150622047M
conv_795 .
Mihajlović, Marija, Stanojević, Marija, Stojanović, Mirjana, Petrović, Jelena, Milojković, Jelena, Petrović, Marija, Lopičić, Zorica, "To what extent do soft mechanical activation and process parameters increase the efficiency of different zeolite/phosphate rock fertilizer mixtures?" in Chemical Industry and Chemical Engineering Quarterly / CICEQ, 23, no. 1 (2017):1-9,
https://doi.org/10.2298/CICEQ150622047M .,
conv_795 .

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