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dc.creatorRadosavljević-Mihajlović, Ana
dc.creatorStojanović, Jovica
dc.creatorRadosavljević, Slobodan
dc.creatorPačevski, Aleksandar M.
dc.creatorVuković, Nikola
dc.creatorTošović, Radule D.
dc.date.accessioned2023-04-21T11:32:00Z
dc.date.available2023-04-21T11:32:00Z
dc.date.issued2017
dc.identifier.issn0169-1368
dc.identifier.urihttps://ritnms.itnms.ac.rs/handle/123456789/426
dc.description.abstract(Ni-Sb)-bearing Cu-arsenides are rare minerals within the Mlakva and Kram mining sectors (Boranja ore field) one of the less-known Serbian Cu deposits. (Ni-Sb)-bearing Cu-arsenides were collected from the Mlakva skarn-replacement Cu(Ag,Bi)-FeS polymetallic deposit. The identified phases include/3-domeykite, Ni-bearing koutekite and (Ni-Sb)-bearing alpha-domeykite. (Ni-Sb)-bearing Cu-arsenides are associated with nickeline, arsenical breithauptite, chalcocite, native Ag, native Pb and litharge. Pyrrhotite, pyrite, chalcopyrite, cubanite, bismuthinite, molybdenite, sphalerite, galena, Pb(Cu)-Bi sulfosalts and native Bi, as well as minor magnetite, scheelite and powellite are associated with the sulfide paragenesis. The electron microprobe analyses of the (Ni-Sb)-bearing Cu-arsenides yielded the following average formulae: (Cu-2.73,Ni-0.17,Fe-0.03,Ag-0.01)(Sigma 2.94)(-AS(0.98)Sb(0.05)S(0.02))(Sigma) (1.06-)beta-domeykite (simplified formula ( CU2.7,Ni-0,Ni-2)(Sigma 2.9)AS(1.1)); (Cu-3.40,Ni-1.40,Fe-0.11)(Sigma 4.91)(-AS(1.94)Sb(0.13)S(0.02))(Sigma 2.08)-Ni-bearing koutekite (simplified formula (Cu3.4Ni1.5)Sigma As-4.9(2.1)); and Cu-1.97(Ni-0.98,Fe-0.03)Sigma(1.01)(As-0.81,Sb-0.22)Sigma(1.03)-(Ni-Sb)-bearing alpha-domeykite (simplified formula Cu2NiAs). The Rietveld refinement yielded the following unit-cell parameters for beta-domeyldte and Ni-bearing koutekite: a = 7.1331(4); c = 7.3042(5) A; V = 321.86(2) A(3), and a = 5.922(4); b = 11.447(9); c = 5.480(4) A; V = 371.48(5) A(3), respectively. Ore geology, paragenetic assemblages and genesis of the Mlakva deposit are discussed in detail and the Cu-As-Ni-Sb-Pb mineralization has been compared with similar well-known global deposits.en
dc.publisherElsevier Science Bv, Amsterdam
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/176016/RS//
dc.rightsrestrictedAccess
dc.sourceOre Geology Reviews
dc.subjectNickelineen
dc.subjectNi-bearing koutekiteen
dc.subjectBoranja ore fielden
dc.subjectbeta-domeykiteen
dc.subjectArsenical breithauptiteen
dc.subject(Ni-Sb)-bearing alpha-domeykiteen
dc.titleMineralogy and genetic features of the Cu-As-Ni-Sb-Pb mineralization from the Mlakva polymetallic deposit (Serbia) - New occurrence of (Ni-Sb)-bearing Cu-arsenidesen
dc.typearticle
dc.rights.licenseARR
dc.citation.epage1258
dc.citation.other80: 1245-1258
dc.citation.rankaM21
dc.citation.spage1245
dc.citation.volume80
dc.identifier.doi10.1016/j.oregeorev.2016.08.036
dc.identifier.rcubconv_776
dc.identifier.scopus2-s2.0-84988710961
dc.identifier.wos000387625800067
dc.type.versionpublishedVersion


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