Removal of Pb2+ ions by raw corn silk (Zea mays L.) as a novel biosorbent
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Petrović, Marija
Šoštarić, Tatjana

Stojanović, Mirjana

Milojković, Jelena

Mihajlović, Marija

Stanojević, Marija

Stanković, Slavka
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There is no data about the corn silk usage as adsorbent for lead removal. In the present study, the corn silk (CS), without any modification, was investigated for adsorption of Pb2+ ions from aqueous solutions. The CS before and after Pb2+ adsorption was characterized by SEM-EDX and ATR-FTIR. The effect of pH, contact time, CS dosage and initial metal concentration on process of adsorption was investigated using batch adsorption procedure. The experimental data were fitted to Langmuir and Freundlich isotherm models, and the best data fit was achieved with the Freundlich isotherm model. Also the Langmuir and Freundlich isotherm models constants R-L and n suggesting favorable adsorption of Pb2+ on the CS. Not only the ion -exchange mechanism was confirmed as an adsorption mechanism but the complexation process has also been verified according to results from ATR-FTIR spectra. Thermodynamic parameters were investigated too. Based on desorption study result, the adsorbent can be efficientl...y recovered. The present investigation qualified the corn silk (Zea mays L.) as a possible good adsorbent of lead from aqueous solutions.
Keywords:
Real effluent / Pb2+ ions / Mechanism / Desorption / Corn silk / AdsorptionSource:
Journal of the Taiwan Institute of Chemical Engineers, 2016, 58, 407-416Publisher:
- Elsevier, Amsterdam
Funding / projects:
DOI: 10.1016/j.jtice.2015.06.025
ISSN: 1876-1070
WoS: 000369196100047
Scopus: 2-s2.0-84953837529
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Institut za tehnologiju nuklearnih i drugih mineralnih sirovinaTY - JOUR AU - Petrović, Marija AU - Šoštarić, Tatjana AU - Stojanović, Mirjana AU - Milojković, Jelena AU - Mihajlović, Marija AU - Stanojević, Marija AU - Stanković, Slavka PY - 2016 UR - https://ritnms.itnms.ac.rs/handle/123456789/411 AB - There is no data about the corn silk usage as adsorbent for lead removal. In the present study, the corn silk (CS), without any modification, was investigated for adsorption of Pb2+ ions from aqueous solutions. The CS before and after Pb2+ adsorption was characterized by SEM-EDX and ATR-FTIR. The effect of pH, contact time, CS dosage and initial metal concentration on process of adsorption was investigated using batch adsorption procedure. The experimental data were fitted to Langmuir and Freundlich isotherm models, and the best data fit was achieved with the Freundlich isotherm model. Also the Langmuir and Freundlich isotherm models constants R-L and n suggesting favorable adsorption of Pb2+ on the CS. Not only the ion -exchange mechanism was confirmed as an adsorption mechanism but the complexation process has also been verified according to results from ATR-FTIR spectra. Thermodynamic parameters were investigated too. Based on desorption study result, the adsorbent can be efficiently recovered. The present investigation qualified the corn silk (Zea mays L.) as a possible good adsorbent of lead from aqueous solutions. PB - Elsevier, Amsterdam T2 - Journal of the Taiwan Institute of Chemical Engineers T1 - Removal of Pb2+ ions by raw corn silk (Zea mays L.) as a novel biosorbent EP - 416 SP - 407 VL - 58 DO - 10.1016/j.jtice.2015.06.025 UR - conv_749 ER -
@article{ author = "Petrović, Marija and Šoštarić, Tatjana and Stojanović, Mirjana and Milojković, Jelena and Mihajlović, Marija and Stanojević, Marija and Stanković, Slavka", year = "2016", abstract = "There is no data about the corn silk usage as adsorbent for lead removal. In the present study, the corn silk (CS), without any modification, was investigated for adsorption of Pb2+ ions from aqueous solutions. The CS before and after Pb2+ adsorption was characterized by SEM-EDX and ATR-FTIR. The effect of pH, contact time, CS dosage and initial metal concentration on process of adsorption was investigated using batch adsorption procedure. The experimental data were fitted to Langmuir and Freundlich isotherm models, and the best data fit was achieved with the Freundlich isotherm model. Also the Langmuir and Freundlich isotherm models constants R-L and n suggesting favorable adsorption of Pb2+ on the CS. Not only the ion -exchange mechanism was confirmed as an adsorption mechanism but the complexation process has also been verified according to results from ATR-FTIR spectra. Thermodynamic parameters were investigated too. Based on desorption study result, the adsorbent can be efficiently recovered. The present investigation qualified the corn silk (Zea mays L.) as a possible good adsorbent of lead from aqueous solutions.", publisher = "Elsevier, Amsterdam", journal = "Journal of the Taiwan Institute of Chemical Engineers", title = "Removal of Pb2+ ions by raw corn silk (Zea mays L.) as a novel biosorbent", pages = "416-407", volume = "58", doi = "10.1016/j.jtice.2015.06.025", url = "conv_749" }
Petrović, M., Šoštarić, T., Stojanović, M., Milojković, J., Mihajlović, M., Stanojević, M.,& Stanković, S.. (2016). Removal of Pb2+ ions by raw corn silk (Zea mays L.) as a novel biosorbent. in Journal of the Taiwan Institute of Chemical Engineers Elsevier, Amsterdam., 58, 407-416. https://doi.org/10.1016/j.jtice.2015.06.025 conv_749
Petrović M, Šoštarić T, Stojanović M, Milojković J, Mihajlović M, Stanojević M, Stanković S. Removal of Pb2+ ions by raw corn silk (Zea mays L.) as a novel biosorbent. in Journal of the Taiwan Institute of Chemical Engineers. 2016;58:407-416. doi:10.1016/j.jtice.2015.06.025 conv_749 .
Petrović, Marija, Šoštarić, Tatjana, Stojanović, Mirjana, Milojković, Jelena, Mihajlović, Marija, Stanojević, Marija, Stanković, Slavka, "Removal of Pb2+ ions by raw corn silk (Zea mays L.) as a novel biosorbent" in Journal of the Taiwan Institute of Chemical Engineers, 58 (2016):407-416, https://doi.org/10.1016/j.jtice.2015.06.025 ., conv_749 .