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Reaction kinetics of mechanically activated cordierite-based ceramics studied via DTA

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2016
407.pdf (1.467Mb)
Authors
Obradović, Nina
Đorđević, Nataša
Filipović, Suzana
Marković, Smilja
Kosanović, Darko
Mitrić, Miodrag
Pavlović, Vladimir
Article (Published version)
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Abstract
Since cordierite, 2MgO center dot 2Al(2)O(3)center dot 5SiO(2) (MAS), is a very useful high-temperature ceramic material, it is important to decrease its sintering temperature. In order to accelerate the process of sintering, 5.00 mass% MoO3 was added to the starting mixtures. The mechanical activation of the starting mixtures was performed in a high-energy ball mill in time intervals from 0 to 160 min. After the activation, starting mixtures were sintered at 1300 A degrees C for 2 h. In order to determine the impact of mechanical activation on particle size distribution and powders morphology, the mechanically treated powders were characterized by a laser light-scattering particle size analyzer and scanning electron microscopy. The phase composition of the starting mixtures and sintered samples was analyzed by the X-ray diffraction method. In order to determine temperature intervals of chemical reactions and phase transitions, differential thermal analyses (DTA) and thermo-gravimetric... analysis were used. Kissinger's equation was employed to calculate apparent activation energies of various processes that occur within the system during heating. Based on the obtained DTA results, it was established that mechanical activation along with MoO3 additive has influence on sintering temperature which was decreased for more than 100 A degrees C, comparing to the literature data.

Keywords:
Sintering / Mechanical activation / Kinetics / DTA-TG / Cordierite
Source:
Journal of Thermal Analysis and Calorimetry, 2016, 124, 2, 667-673
Publisher:
  • Springer, Dordrecht
Funding / projects:
  • Directed synthesis, structure and properties of multifunctional materials (RS-172057)
  • Serbian Academy of Sciences and Arts [F-7/II]

DOI: 10.1007/s10973-015-5132-9

ISSN: 1388-6150

WoS: 000373576600011

Scopus: 2-s2.0-84976342017
[ Google Scholar ]
9
8
URI
https://ritnms.itnms.ac.rs/handle/123456789/410
Collections
  • Radovi istraživača / Researchers’ publications
Institution/Community
Institut za tehnologiju nuklearnih i drugih mineralnih sirovina
TY  - JOUR
AU  - Obradović, Nina
AU  - Đorđević, Nataša
AU  - Filipović, Suzana
AU  - Marković, Smilja
AU  - Kosanović, Darko
AU  - Mitrić, Miodrag
AU  - Pavlović, Vladimir
PY  - 2016
UR  - https://ritnms.itnms.ac.rs/handle/123456789/410
AB  - Since cordierite, 2MgO center dot 2Al(2)O(3)center dot 5SiO(2) (MAS), is a very useful high-temperature ceramic material, it is important to decrease its sintering temperature. In order to accelerate the process of sintering, 5.00 mass% MoO3 was added to the starting mixtures. The mechanical activation of the starting mixtures was performed in a high-energy ball mill in time intervals from 0 to 160 min. After the activation, starting mixtures were sintered at 1300 A degrees C for 2 h. In order to determine the impact of mechanical activation on particle size distribution and powders morphology, the mechanically treated powders were characterized by a laser light-scattering particle size analyzer and scanning electron microscopy. The phase composition of the starting mixtures and sintered samples was analyzed by the X-ray diffraction method. In order to determine temperature intervals of chemical reactions and phase transitions, differential thermal analyses (DTA) and thermo-gravimetric analysis were used. Kissinger's equation was employed to calculate apparent activation energies of various processes that occur within the system during heating. Based on the obtained DTA results, it was established that mechanical activation along with MoO3 additive has influence on sintering temperature which was decreased for more than 100 A degrees C, comparing to the literature data.
PB  - Springer, Dordrecht
T2  - Journal of Thermal Analysis and Calorimetry
T1  - Reaction kinetics of mechanically activated cordierite-based ceramics studied via DTA
EP  - 673
IS  - 2
SP  - 667
VL  - 124
DO  - 10.1007/s10973-015-5132-9
UR  - conv_757
ER  - 
@article{
author = "Obradović, Nina and Đorđević, Nataša and Filipović, Suzana and Marković, Smilja and Kosanović, Darko and Mitrić, Miodrag and Pavlović, Vladimir",
year = "2016",
abstract = "Since cordierite, 2MgO center dot 2Al(2)O(3)center dot 5SiO(2) (MAS), is a very useful high-temperature ceramic material, it is important to decrease its sintering temperature. In order to accelerate the process of sintering, 5.00 mass% MoO3 was added to the starting mixtures. The mechanical activation of the starting mixtures was performed in a high-energy ball mill in time intervals from 0 to 160 min. After the activation, starting mixtures were sintered at 1300 A degrees C for 2 h. In order to determine the impact of mechanical activation on particle size distribution and powders morphology, the mechanically treated powders were characterized by a laser light-scattering particle size analyzer and scanning electron microscopy. The phase composition of the starting mixtures and sintered samples was analyzed by the X-ray diffraction method. In order to determine temperature intervals of chemical reactions and phase transitions, differential thermal analyses (DTA) and thermo-gravimetric analysis were used. Kissinger's equation was employed to calculate apparent activation energies of various processes that occur within the system during heating. Based on the obtained DTA results, it was established that mechanical activation along with MoO3 additive has influence on sintering temperature which was decreased for more than 100 A degrees C, comparing to the literature data.",
publisher = "Springer, Dordrecht",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "Reaction kinetics of mechanically activated cordierite-based ceramics studied via DTA",
pages = "673-667",
number = "2",
volume = "124",
doi = "10.1007/s10973-015-5132-9",
url = "conv_757"
}
Obradović, N., Đorđević, N., Filipović, S., Marković, S., Kosanović, D., Mitrić, M.,& Pavlović, V.. (2016). Reaction kinetics of mechanically activated cordierite-based ceramics studied via DTA. in Journal of Thermal Analysis and Calorimetry
Springer, Dordrecht., 124(2), 667-673.
https://doi.org/10.1007/s10973-015-5132-9
conv_757
Obradović N, Đorđević N, Filipović S, Marković S, Kosanović D, Mitrić M, Pavlović V. Reaction kinetics of mechanically activated cordierite-based ceramics studied via DTA. in Journal of Thermal Analysis and Calorimetry. 2016;124(2):667-673.
doi:10.1007/s10973-015-5132-9
conv_757 .
Obradović, Nina, Đorđević, Nataša, Filipović, Suzana, Marković, Smilja, Kosanović, Darko, Mitrić, Miodrag, Pavlović, Vladimir, "Reaction kinetics of mechanically activated cordierite-based ceramics studied via DTA" in Journal of Thermal Analysis and Calorimetry, 124, no. 2 (2016):667-673,
https://doi.org/10.1007/s10973-015-5132-9 .,
conv_757 .

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