Kinetics of barite reduction from refractory barite-sulphide ore
Abstract
Refractory sulphide-barite ore was reduced with carbon in order to release lead, zinc, and copper sulphide from barite-pyrite base. Mineralogical investigations showed that due to the complex structural-textural relationships of lead, copper and zinc minerals with gangue minerals, it is not possible to enrich the ore using the conventional methods of mineral processing. The influence of temperature and time was studied to optimize the conditions, and to determine the kinetics of the barite reduction. The maximum removal of barite from ore was 96.7% at 900oC after 180 min. Chemically controlled kinetic model showed the best compliance with the experimental data. An activation energy of 142 kJ/mol was found.
Keywords:
refractory sulphide-barite ore / kinetic of barite reductionSource:
Metallurgical & Materials Engineering, 2016, 22, 4, 261-268Publisher:
- Savez inženjera metalurgije Srbije, Beograd
Funding / projects:
- Developing technological processes for nonstandard copper concentrates processing with the aim to decrease pollutants emission (RS-34023)
- The development of casting technologies under the influence of electromagnetic field and technologies of hot plastic forming of 7000 series aluminium alloys for special purposes (RS-34002)
Collections
Institution/Community
Institut za tehnologiju nuklearnih i drugih mineralnih sirovinaTY - JOUR AU - Sokić, Miroslav AU - Matković, Vladislav AU - Stojanović, Jovica AU - Marković, Branislav AU - Manojlović, Vaso PY - 2016 UR - https://ritnms.itnms.ac.rs/handle/123456789/409 AB - Refractory sulphide-barite ore was reduced with carbon in order to release lead, zinc, and copper sulphide from barite-pyrite base. Mineralogical investigations showed that due to the complex structural-textural relationships of lead, copper and zinc minerals with gangue minerals, it is not possible to enrich the ore using the conventional methods of mineral processing. The influence of temperature and time was studied to optimize the conditions, and to determine the kinetics of the barite reduction. The maximum removal of barite from ore was 96.7% at 900oC after 180 min. Chemically controlled kinetic model showed the best compliance with the experimental data. An activation energy of 142 kJ/mol was found. PB - Savez inženjera metalurgije Srbije, Beograd T2 - Metallurgical & Materials Engineering T1 - Kinetics of barite reduction from refractory barite-sulphide ore EP - 268 IS - 4 SP - 261 VL - 22 DO - 10.30544/237 UR - conv_805 ER -
@article{ author = "Sokić, Miroslav and Matković, Vladislav and Stojanović, Jovica and Marković, Branislav and Manojlović, Vaso", year = "2016", abstract = "Refractory sulphide-barite ore was reduced with carbon in order to release lead, zinc, and copper sulphide from barite-pyrite base. Mineralogical investigations showed that due to the complex structural-textural relationships of lead, copper and zinc minerals with gangue minerals, it is not possible to enrich the ore using the conventional methods of mineral processing. The influence of temperature and time was studied to optimize the conditions, and to determine the kinetics of the barite reduction. The maximum removal of barite from ore was 96.7% at 900oC after 180 min. Chemically controlled kinetic model showed the best compliance with the experimental data. An activation energy of 142 kJ/mol was found.", publisher = "Savez inženjera metalurgije Srbije, Beograd", journal = "Metallurgical & Materials Engineering", title = "Kinetics of barite reduction from refractory barite-sulphide ore", pages = "268-261", number = "4", volume = "22", doi = "10.30544/237", url = "conv_805" }
Sokić, M., Matković, V., Stojanović, J., Marković, B.,& Manojlović, V.. (2016). Kinetics of barite reduction from refractory barite-sulphide ore. in Metallurgical & Materials Engineering Savez inženjera metalurgije Srbije, Beograd., 22(4), 261-268. https://doi.org/10.30544/237 conv_805
Sokić M, Matković V, Stojanović J, Marković B, Manojlović V. Kinetics of barite reduction from refractory barite-sulphide ore. in Metallurgical & Materials Engineering. 2016;22(4):261-268. doi:10.30544/237 conv_805 .
Sokić, Miroslav, Matković, Vladislav, Stojanović, Jovica, Marković, Branislav, Manojlović, Vaso, "Kinetics of barite reduction from refractory barite-sulphide ore" in Metallurgical & Materials Engineering, 22, no. 4 (2016):261-268, https://doi.org/10.30544/237 ., conv_805 .