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Removal of Cs Ions from Aqueous Solutions by Using Matrices of Natural Clinoptilolite and its Safe Disposal

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2016
389.pdf (539.2Kb)
Authors
Omerasević, Mia
Ruzić, Jovana
Vuković, Nikola
Jovanović, Uros
Mirković, Miljana
Maksimović, Vesna
Dondur, Vera
Article (Published version)
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Abstract
The possibility to use natural zeolite - clinoptilolite as a host material for radioactive Cs immobilization has been investigated. Cs-exchanged form of clinoptilolite which was prepared by treatment of clinoptilolite powder with 0.25 M CsCl solution was compacted. Both, powder and powder compact of exchanged clinoptilolite were thermally treated at 1200 C-0. The XRPD analysis showed that Cs was successfully immobilized after heat treatment by formation of stable cesium dodecaoxo-alumopentasilicate in both, powder sample and compact. The newly formed compound showed satisfactory Cs ions retention during leaching test. The sintered compact showed somewhat better resistance to Cs leaching than the thermally treated powder. The compressive strength of sintered compact was close to 200 MPa which is more than enough for easy handling and safe storage.
Keywords:
Sintering / Leaching tests / Ion exchange / Cs disposal / Clinoptilolite
Source:
Science of Sintering, 2016, 48, 1, 101-107
Publisher:
  • Međunarodni Institut za nauku o sinterovanju, Beograd
Funding / projects:
  • Synthesis, processing and characterization of nanostructured materials for application in the field of energy, mechanical engineering, environmental protection and biomedicine (RS-45012)

DOI: 10.2298/SOS1601101O

ISSN: 0350-820X

WoS: 000378175000010

Scopus: 2-s2.0-84965028560
[ Google Scholar ]
5
3
URI
https://ritnms.itnms.ac.rs/handle/123456789/392
Collections
  • Radovi istraživača / Researchers’ publications
Institution/Community
Institut za tehnologiju nuklearnih i drugih mineralnih sirovina
TY  - JOUR
AU  - Omerasević, Mia
AU  - Ruzić, Jovana
AU  - Vuković, Nikola
AU  - Jovanović, Uros
AU  - Mirković, Miljana
AU  - Maksimović, Vesna
AU  - Dondur, Vera
PY  - 2016
UR  - https://ritnms.itnms.ac.rs/handle/123456789/392
AB  - The possibility to use natural zeolite - clinoptilolite as a host material for radioactive Cs immobilization has been investigated. Cs-exchanged form of clinoptilolite which was prepared by treatment of clinoptilolite powder with 0.25 M CsCl solution was compacted. Both, powder and powder compact of exchanged clinoptilolite were thermally treated at 1200 C-0. The XRPD analysis showed that Cs was successfully immobilized after heat treatment by formation of stable cesium dodecaoxo-alumopentasilicate in both, powder sample and compact. The newly formed compound showed satisfactory Cs ions retention during leaching test. The sintered compact showed somewhat better resistance to Cs leaching than the thermally treated powder. The compressive strength of sintered compact was close to 200 MPa which is more than enough for easy handling and safe storage.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - Removal of Cs Ions from Aqueous Solutions by Using Matrices of Natural Clinoptilolite and its Safe Disposal
EP  - 107
IS  - 1
SP  - 101
VL  - 48
DO  - 10.2298/SOS1601101O
UR  - conv_761
ER  - 
@article{
author = "Omerasević, Mia and Ruzić, Jovana and Vuković, Nikola and Jovanović, Uros and Mirković, Miljana and Maksimović, Vesna and Dondur, Vera",
year = "2016",
abstract = "The possibility to use natural zeolite - clinoptilolite as a host material for radioactive Cs immobilization has been investigated. Cs-exchanged form of clinoptilolite which was prepared by treatment of clinoptilolite powder with 0.25 M CsCl solution was compacted. Both, powder and powder compact of exchanged clinoptilolite were thermally treated at 1200 C-0. The XRPD analysis showed that Cs was successfully immobilized after heat treatment by formation of stable cesium dodecaoxo-alumopentasilicate in both, powder sample and compact. The newly formed compound showed satisfactory Cs ions retention during leaching test. The sintered compact showed somewhat better resistance to Cs leaching than the thermally treated powder. The compressive strength of sintered compact was close to 200 MPa which is more than enough for easy handling and safe storage.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "Removal of Cs Ions from Aqueous Solutions by Using Matrices of Natural Clinoptilolite and its Safe Disposal",
pages = "107-101",
number = "1",
volume = "48",
doi = "10.2298/SOS1601101O",
url = "conv_761"
}
Omerasević, M., Ruzić, J., Vuković, N., Jovanović, U., Mirković, M., Maksimović, V.,& Dondur, V.. (2016). Removal of Cs Ions from Aqueous Solutions by Using Matrices of Natural Clinoptilolite and its Safe Disposal. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 48(1), 101-107.
https://doi.org/10.2298/SOS1601101O
conv_761
Omerasević M, Ruzić J, Vuković N, Jovanović U, Mirković M, Maksimović V, Dondur V. Removal of Cs Ions from Aqueous Solutions by Using Matrices of Natural Clinoptilolite and its Safe Disposal. in Science of Sintering. 2016;48(1):101-107.
doi:10.2298/SOS1601101O
conv_761 .
Omerasević, Mia, Ruzić, Jovana, Vuković, Nikola, Jovanović, Uros, Mirković, Miljana, Maksimović, Vesna, Dondur, Vera, "Removal of Cs Ions from Aqueous Solutions by Using Matrices of Natural Clinoptilolite and its Safe Disposal" in Science of Sintering, 48, no. 1 (2016):101-107,
https://doi.org/10.2298/SOS1601101O .,
conv_761 .

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