Zn1.86Cd0.14(OH)VO4
Abstract
The title compound, dizinc cadmium hydroxide tetraoxido-vanadate, Zn 1.86Cd0.14(OH)VO4, was prepared under low-temperature hydro-thermal conditions. It is isostructural with Zn 2(OH)VO4 and Cu2(OH)VO4. In the crystal structure, chains of edge-sharing [ZnO6] octahedra are inter-connected by VO4 tetra-hedra (site symmetries of both V atoms and their coordination polyhedra are.m.) to form a three-dimensional [Zn(OH)VO4]2- framework with channels occupied by Zn and Zn/Cd cations adopting trigonal-bipyramidal and distorted octa-hedral coordinations, respectively. Zn1.86Cd0.14(OH)VO 4 is topologically related to adamite-type phases, and descloizite- and tsumcorite-type structures.
Source:
Acta Crystallographica Section E: Structure Reports Online, 2010, 66, 12Publisher:
- International Union of Crystallography
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Institution/Community
Institut za tehnologiju nuklearnih i drugih mineralnih sirovinaTY - JOUR AU - Đorđević, Tamara AU - Stojanović, Jovica AU - Karanović, Ljiljana PY - 2010 UR - https://ritnms.itnms.ac.rs/handle/123456789/184 AB - The title compound, dizinc cadmium hydroxide tetraoxido-vanadate, Zn 1.86Cd0.14(OH)VO4, was prepared under low-temperature hydro-thermal conditions. It is isostructural with Zn 2(OH)VO4 and Cu2(OH)VO4. In the crystal structure, chains of edge-sharing [ZnO6] octahedra are inter-connected by VO4 tetra-hedra (site symmetries of both V atoms and their coordination polyhedra are.m.) to form a three-dimensional [Zn(OH)VO4]2- framework with channels occupied by Zn and Zn/Cd cations adopting trigonal-bipyramidal and distorted octa-hedral coordinations, respectively. Zn1.86Cd0.14(OH)VO 4 is topologically related to adamite-type phases, and descloizite- and tsumcorite-type structures. PB - International Union of Crystallography T2 - Acta Crystallographica Section E: Structure Reports Online T1 - Zn1.86Cd0.14(OH)VO4 IS - 12 VL - 66 DO - 10.1107/S1600536810044806 UR - conv_1083 ER -
@article{ author = "Đorđević, Tamara and Stojanović, Jovica and Karanović, Ljiljana", year = "2010", abstract = "The title compound, dizinc cadmium hydroxide tetraoxido-vanadate, Zn 1.86Cd0.14(OH)VO4, was prepared under low-temperature hydro-thermal conditions. It is isostructural with Zn 2(OH)VO4 and Cu2(OH)VO4. In the crystal structure, chains of edge-sharing [ZnO6] octahedra are inter-connected by VO4 tetra-hedra (site symmetries of both V atoms and their coordination polyhedra are.m.) to form a three-dimensional [Zn(OH)VO4]2- framework with channels occupied by Zn and Zn/Cd cations adopting trigonal-bipyramidal and distorted octa-hedral coordinations, respectively. Zn1.86Cd0.14(OH)VO 4 is topologically related to adamite-type phases, and descloizite- and tsumcorite-type structures.", publisher = "International Union of Crystallography", journal = "Acta Crystallographica Section E: Structure Reports Online", title = "Zn1.86Cd0.14(OH)VO4", number = "12", volume = "66", doi = "10.1107/S1600536810044806", url = "conv_1083" }
Đorđević, T., Stojanović, J.,& Karanović, L.. (2010). Zn1.86Cd0.14(OH)VO4. in Acta Crystallographica Section E: Structure Reports Online International Union of Crystallography., 66(12). https://doi.org/10.1107/S1600536810044806 conv_1083
Đorđević T, Stojanović J, Karanović L. Zn1.86Cd0.14(OH)VO4. in Acta Crystallographica Section E: Structure Reports Online. 2010;66(12). doi:10.1107/S1600536810044806 conv_1083 .
Đorđević, Tamara, Stojanović, Jovica, Karanović, Ljiljana, "Zn1.86Cd0.14(OH)VO4" in Acta Crystallographica Section E: Structure Reports Online, 66, no. 12 (2010), https://doi.org/10.1107/S1600536810044806 ., conv_1083 .