[Zn-3(PO4)(2)(H2O)(0.8)(NH3)(1.2)]
Abstract
The structure of the title compound, ammineaquadi-mu(5)-phosphato-trizinc(II), [Zn-3(PO4)(2)(H2O)(0.8)(NH3)(1.2)], consists of two parts: (i) PO4 and ZnO4 vertex-sharing tetrahedra arranged in layers parallel to (100) and (ii) ZnO2(N/O)(2) tetrahedra located between the layers. Elemental analysis establishes the ammine-to-water ratio as 3:2. ZnO2(N/O)(2) tetrahedra are located at special position 4e (site symmetry 2) in C2/c. The two O atoms of ZnO2(N/O)(2) are bonded to neighbouring P atoms, forming two Zn-O-P linkages and connecting ZnO2(N/O)(2) tetrahedra with two adjacent bc plane layers. A noteworthy feature of the structure is the presence of NH3 and H2O at the same crystallographic position and, consequently, qualitative changes in the pattern of hydrogen bonding and weaker N/O-H center dot center dot center dot O electrostatic interactions, as compared to two closely related structures.
Source:
Acta Crystallographica Section C-Crystal Structure Communications, 2010, 66, I55-I57Publisher:
- Wiley-Blackwell, Malden
Funding / projects:
- Austrian Science Foundation (FWF) [T300-N19]
- Strukturna i funkcionalna hemija nekih prelaznih i postprelaznih elemenata (RS-142030)
- Razvoj novih tehnoloških postupaka oplemenjivanja osnovnih koncentrata šelita i sulfida u cilju dobijanja jedinjenja volframa, bizmuta i srebra (RS-19002)
DOI: 10.1107/S0108270110014885
ISSN: 0108-2701
PubMed: 20442499
WoS: 000277260300003
Scopus: 2-s2.0-77951962031
Collections
Institution/Community
Institut za tehnologiju nuklearnih i drugih mineralnih sirovinaTY - JOUR AU - Stojanović, Jovica AU - Đorđević, Tamara AU - Karanović, Ljiljana PY - 2010 UR - https://ritnms.itnms.ac.rs/handle/123456789/180 AB - The structure of the title compound, ammineaquadi-mu(5)-phosphato-trizinc(II), [Zn-3(PO4)(2)(H2O)(0.8)(NH3)(1.2)], consists of two parts: (i) PO4 and ZnO4 vertex-sharing tetrahedra arranged in layers parallel to (100) and (ii) ZnO2(N/O)(2) tetrahedra located between the layers. Elemental analysis establishes the ammine-to-water ratio as 3:2. ZnO2(N/O)(2) tetrahedra are located at special position 4e (site symmetry 2) in C2/c. The two O atoms of ZnO2(N/O)(2) are bonded to neighbouring P atoms, forming two Zn-O-P linkages and connecting ZnO2(N/O)(2) tetrahedra with two adjacent bc plane layers. A noteworthy feature of the structure is the presence of NH3 and H2O at the same crystallographic position and, consequently, qualitative changes in the pattern of hydrogen bonding and weaker N/O-H center dot center dot center dot O electrostatic interactions, as compared to two closely related structures. PB - Wiley-Blackwell, Malden T2 - Acta Crystallographica Section C-Crystal Structure Communications T1 - [Zn-3(PO4)(2)(H2O)(0.8)(NH3)(1.2)] EP - I57 SP - I55 VL - 66 DO - 10.1107/S0108270110014885 UR - conv_581 ER -
@article{ author = "Stojanović, Jovica and Đorđević, Tamara and Karanović, Ljiljana", year = "2010", abstract = "The structure of the title compound, ammineaquadi-mu(5)-phosphato-trizinc(II), [Zn-3(PO4)(2)(H2O)(0.8)(NH3)(1.2)], consists of two parts: (i) PO4 and ZnO4 vertex-sharing tetrahedra arranged in layers parallel to (100) and (ii) ZnO2(N/O)(2) tetrahedra located between the layers. Elemental analysis establishes the ammine-to-water ratio as 3:2. ZnO2(N/O)(2) tetrahedra are located at special position 4e (site symmetry 2) in C2/c. The two O atoms of ZnO2(N/O)(2) are bonded to neighbouring P atoms, forming two Zn-O-P linkages and connecting ZnO2(N/O)(2) tetrahedra with two adjacent bc plane layers. A noteworthy feature of the structure is the presence of NH3 and H2O at the same crystallographic position and, consequently, qualitative changes in the pattern of hydrogen bonding and weaker N/O-H center dot center dot center dot O electrostatic interactions, as compared to two closely related structures.", publisher = "Wiley-Blackwell, Malden", journal = "Acta Crystallographica Section C-Crystal Structure Communications", title = "[Zn-3(PO4)(2)(H2O)(0.8)(NH3)(1.2)]", pages = "I57-I55", volume = "66", doi = "10.1107/S0108270110014885", url = "conv_581" }
Stojanović, J., Đorđević, T.,& Karanović, L.. (2010). [Zn-3(PO4)(2)(H2O)(0.8)(NH3)(1.2)]. in Acta Crystallographica Section C-Crystal Structure Communications Wiley-Blackwell, Malden., 66, I55-I57. https://doi.org/10.1107/S0108270110014885 conv_581
Stojanović J, Đorđević T, Karanović L. [Zn-3(PO4)(2)(H2O)(0.8)(NH3)(1.2)]. in Acta Crystallographica Section C-Crystal Structure Communications. 2010;66:I55-I57. doi:10.1107/S0108270110014885 conv_581 .
Stojanović, Jovica, Đorđević, Tamara, Karanović, Ljiljana, "[Zn-3(PO4)(2)(H2O)(0.8)(NH3)(1.2)]" in Acta Crystallographica Section C-Crystal Structure Communications, 66 (2010):I55-I57, https://doi.org/10.1107/S0108270110014885 ., conv_581 .