Deposition of goethite and ferrihydrite onto expanded vermiculite surface: chemical properties and potential application
Authors
Bugarčić, Mladen
Jovanović, Aleksandar

Marinković, Aleksandar
Bošnjaković, Jovana
Sokić, Miroslav

Radosavljević-Mihajlović, Ana

Milivojević, Milan
Contributors
Malinović, BorislavConference object (Published version)

Metadata
Show full item recordAbstract
Current demand on adsorbent materials is in constant growth, hence scientific society is in ceaseless
research subjecting cheap and optimal adsorbent. Abundant raw materials which may be utilized as
adsorbent of cation species are mica minerals, and vermiculite as one of them is widely examined.
Since wastewater may contain anion or/ and non-ionic pollutants it is needed to functionalize
adsorbent so it may attract those species as well. Goethite and ferrihydrite are potential candidates
for such modification since they: have large specific surface area (SSA), possess hydroxide group
and they are not toxic to the environment. Goethite/ expanded vermiculite (Goe/EV) and ferrihydrite/
expanded vermiculite (Fer/EV) are successfully prepared and those composites have showed better
adsorption related chemical properties than expanded vermiculite (EV) itself. Utilizing BET
methodology, it is determined that Fer/EV possess five-time larger SSA than EV, while Goe/EV is
two times larg...er. Measuring cation exchange capacity (CEC) it is determined that modified samples
have only ~10% smaller values of CEC. Summary, both composites have shown higher affinity
toward cationic dye, malachite green and also showed their adsorbent potential toward anionic dye,
tartrazine. Thanks to facile preparation of such materials and its cost, it may be concluded that they
are prospective choice as adsorbents, in first order of heavy metals and dyes.
Keywords:
expanded vermiculite / adsorbent functionalization / goethite / ferrihydrite / wastewater treatmentSource:
XIV CONFERENCE OF CHEMISTS, TECHNOLOGISTS AND ENVIRONMENTALISTS OF REPUBLIC OF SRPSKA, 2022, 200-205Publisher:
- Banja Luka : University in Banja Luka, Faculty of Technology
Funding / projects:
- Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200023 (Institute of Technology of Nuclear and Other Mineral Row Materials - ITNMS, Belgrade) (RS-200023)
- Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200135 (University of Belgrade, Faculty of Technology and Metallurgy) (RS-200135)
Collections
Institution/Community
Institut za tehnologiju nuklearnih i drugih mineralnih sirovinaTY - CONF AU - Bugarčić, Mladen AU - Jovanović, Aleksandar AU - Marinković, Aleksandar AU - Bošnjaković, Jovana AU - Sokić, Miroslav AU - Radosavljević-Mihajlović, Ana AU - Milivojević, Milan PY - 2022 UR - https://ritnms.itnms.ac.rs/handle/123456789/1000 AB - Current demand on adsorbent materials is in constant growth, hence scientific society is in ceaseless research subjecting cheap and optimal adsorbent. Abundant raw materials which may be utilized as adsorbent of cation species are mica minerals, and vermiculite as one of them is widely examined. Since wastewater may contain anion or/ and non-ionic pollutants it is needed to functionalize adsorbent so it may attract those species as well. Goethite and ferrihydrite are potential candidates for such modification since they: have large specific surface area (SSA), possess hydroxide group and they are not toxic to the environment. Goethite/ expanded vermiculite (Goe/EV) and ferrihydrite/ expanded vermiculite (Fer/EV) are successfully prepared and those composites have showed better adsorption related chemical properties than expanded vermiculite (EV) itself. Utilizing BET methodology, it is determined that Fer/EV possess five-time larger SSA than EV, while Goe/EV is two times larger. Measuring cation exchange capacity (CEC) it is determined that modified samples have only ~10% smaller values of CEC. Summary, both composites have shown higher affinity toward cationic dye, malachite green and also showed their adsorbent potential toward anionic dye, tartrazine. Thanks to facile preparation of such materials and its cost, it may be concluded that they are prospective choice as adsorbents, in first order of heavy metals and dyes. PB - Banja Luka : University in Banja Luka, Faculty of Technology C3 - XIV CONFERENCE OF CHEMISTS, TECHNOLOGISTS AND ENVIRONMENTALISTS OF REPUBLIC OF SRPSKA T1 - Deposition of goethite and ferrihydrite onto expanded vermiculite surface: chemical properties and potential application EP - 205 SP - 200 ER -
@conference{ author = "Bugarčić, Mladen and Jovanović, Aleksandar and Marinković, Aleksandar and Bošnjaković, Jovana and Sokić, Miroslav and Radosavljević-Mihajlović, Ana and Milivojević, Milan", year = "2022", abstract = "Current demand on adsorbent materials is in constant growth, hence scientific society is in ceaseless research subjecting cheap and optimal adsorbent. Abundant raw materials which may be utilized as adsorbent of cation species are mica minerals, and vermiculite as one of them is widely examined. Since wastewater may contain anion or/ and non-ionic pollutants it is needed to functionalize adsorbent so it may attract those species as well. Goethite and ferrihydrite are potential candidates for such modification since they: have large specific surface area (SSA), possess hydroxide group and they are not toxic to the environment. Goethite/ expanded vermiculite (Goe/EV) and ferrihydrite/ expanded vermiculite (Fer/EV) are successfully prepared and those composites have showed better adsorption related chemical properties than expanded vermiculite (EV) itself. Utilizing BET methodology, it is determined that Fer/EV possess five-time larger SSA than EV, while Goe/EV is two times larger. Measuring cation exchange capacity (CEC) it is determined that modified samples have only ~10% smaller values of CEC. Summary, both composites have shown higher affinity toward cationic dye, malachite green and also showed their adsorbent potential toward anionic dye, tartrazine. Thanks to facile preparation of such materials and its cost, it may be concluded that they are prospective choice as adsorbents, in first order of heavy metals and dyes.", publisher = "Banja Luka : University in Banja Luka, Faculty of Technology", journal = "XIV CONFERENCE OF CHEMISTS, TECHNOLOGISTS AND ENVIRONMENTALISTS OF REPUBLIC OF SRPSKA", title = "Deposition of goethite and ferrihydrite onto expanded vermiculite surface: chemical properties and potential application", pages = "205-200" }
Bugarčić, M., Jovanović, A., Marinković, A., Bošnjaković, J., Sokić, M., Radosavljević-Mihajlović, A.,& Milivojević, M.. (2022). Deposition of goethite and ferrihydrite onto expanded vermiculite surface: chemical properties and potential application. in XIV CONFERENCE OF CHEMISTS, TECHNOLOGISTS AND ENVIRONMENTALISTS OF REPUBLIC OF SRPSKA Banja Luka : University in Banja Luka, Faculty of Technology., 200-205.
Bugarčić M, Jovanović A, Marinković A, Bošnjaković J, Sokić M, Radosavljević-Mihajlović A, Milivojević M. Deposition of goethite and ferrihydrite onto expanded vermiculite surface: chemical properties and potential application. in XIV CONFERENCE OF CHEMISTS, TECHNOLOGISTS AND ENVIRONMENTALISTS OF REPUBLIC OF SRPSKA. 2022;:200-205..
Bugarčić, Mladen, Jovanović, Aleksandar, Marinković, Aleksandar, Bošnjaković, Jovana, Sokić, Miroslav, Radosavljević-Mihajlović, Ana, Milivojević, Milan, "Deposition of goethite and ferrihydrite onto expanded vermiculite surface: chemical properties and potential application" in XIV CONFERENCE OF CHEMISTS, TECHNOLOGISTS AND ENVIRONMENTALISTS OF REPUBLIC OF SRPSKA (2022):200-205.