Physics and Chemistry with Ion Beams

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Physics and Chemistry with Ion Beams (en)
Физика и хемија са јонским сноповима (sr)
Fizika i hemija sa jonskim snopovima (sr_RS)
Authors

Publications

In situ synthesis of potassium tungstophosphate supported on BEA zeolite and perspective application for pesticide removal

Nedić-Vasiljević, Bojana; Obradović, Milena; Bajuk-Bogdanović, Danica; Milojević-Rakić, Maja; Jovanović, Zoran; Gavrilov, Nemanja; Holclajtner-Antunović, Ivanka

(Science Press, Beijing, 2019)

TY  - JOUR
AU  - Nedić-Vasiljević, Bojana
AU  - Obradović, Milena
AU  - Bajuk-Bogdanović, Danica
AU  - Milojević-Rakić, Maja
AU  - Jovanović, Zoran
AU  - Gavrilov, Nemanja
AU  - Holclajtner-Antunović, Ivanka
PY  - 2019
UR  - https://ritnms.itnms.ac.rs/handle/123456789/524
AB  - Potassium tungstophosphate is supported on BEA zeolite by in situ synthesis for glyphosate removal. Spectroscopic measurements identified hydrogen bonding as a primal interaction of potassium salt and BEA zeolite. Composites are evaluated for glyphosate herbicide removal and adsorption process is analyzed using two isotherm models. Obtained adsorption capacities for all prepared composites lay between 45.2 and 92.2 mg of glyphosate per gram of investigated composite. Suspension acidity revealed that glyphosate is adsorbed mainly in the zwitter-ion form at the composite surface while the amount of potassium salt in the composites is crucial for the adsorption application. Exceptional adsorption behavior is postulated to come from a high degree of homogeneity among surface active sites which is confirmed by different experimental methods. Temperature programmed desorption of glyphosate coupled with mass spectrometer detected one broad, high-temperature peak which represents overlapped desorption processes from active sights of similar strength. Introduction of potassium tungstophosphate affects active sites present in BEA zeolite for glyphosate desorption and significantly increases the amount of adsorbed pesticide in comparison to BEA zeolite. Supporting of potassium tungstophosphate on BEA zeolite via in situ synthesis procedure enables the formation of highly efficient adsorbents and revealed their perspective environmental application.
PB  - Science Press, Beijing
T2  - Journal of Environmental Sciences
T1  - In situ synthesis of potassium tungstophosphate supported on BEA zeolite and perspective application for pesticide removal
EP  - 147
SP  - 136
VL  - 81
DO  - 10.1016/j.jes.2019.01.018
UR  - conv_846
ER  - 
@article{
author = "Nedić-Vasiljević, Bojana and Obradović, Milena and Bajuk-Bogdanović, Danica and Milojević-Rakić, Maja and Jovanović, Zoran and Gavrilov, Nemanja and Holclajtner-Antunović, Ivanka",
year = "2019",
abstract = "Potassium tungstophosphate is supported on BEA zeolite by in situ synthesis for glyphosate removal. Spectroscopic measurements identified hydrogen bonding as a primal interaction of potassium salt and BEA zeolite. Composites are evaluated for glyphosate herbicide removal and adsorption process is analyzed using two isotherm models. Obtained adsorption capacities for all prepared composites lay between 45.2 and 92.2 mg of glyphosate per gram of investigated composite. Suspension acidity revealed that glyphosate is adsorbed mainly in the zwitter-ion form at the composite surface while the amount of potassium salt in the composites is crucial for the adsorption application. Exceptional adsorption behavior is postulated to come from a high degree of homogeneity among surface active sites which is confirmed by different experimental methods. Temperature programmed desorption of glyphosate coupled with mass spectrometer detected one broad, high-temperature peak which represents overlapped desorption processes from active sights of similar strength. Introduction of potassium tungstophosphate affects active sites present in BEA zeolite for glyphosate desorption and significantly increases the amount of adsorbed pesticide in comparison to BEA zeolite. Supporting of potassium tungstophosphate on BEA zeolite via in situ synthesis procedure enables the formation of highly efficient adsorbents and revealed their perspective environmental application.",
publisher = "Science Press, Beijing",
journal = "Journal of Environmental Sciences",
title = "In situ synthesis of potassium tungstophosphate supported on BEA zeolite and perspective application for pesticide removal",
pages = "147-136",
volume = "81",
doi = "10.1016/j.jes.2019.01.018",
url = "conv_846"
}
Nedić-Vasiljević, B., Obradović, M., Bajuk-Bogdanović, D., Milojević-Rakić, M., Jovanović, Z., Gavrilov, N.,& Holclajtner-Antunović, I.. (2019). In situ synthesis of potassium tungstophosphate supported on BEA zeolite and perspective application for pesticide removal. in Journal of Environmental Sciences
Science Press, Beijing., 81, 136-147.
https://doi.org/10.1016/j.jes.2019.01.018
conv_846
Nedić-Vasiljević B, Obradović M, Bajuk-Bogdanović D, Milojević-Rakić M, Jovanović Z, Gavrilov N, Holclajtner-Antunović I. In situ synthesis of potassium tungstophosphate supported on BEA zeolite and perspective application for pesticide removal. in Journal of Environmental Sciences. 2019;81:136-147.
doi:10.1016/j.jes.2019.01.018
conv_846 .
Nedić-Vasiljević, Bojana, Obradović, Milena, Bajuk-Bogdanović, Danica, Milojević-Rakić, Maja, Jovanović, Zoran, Gavrilov, Nemanja, Holclajtner-Antunović, Ivanka, "In situ synthesis of potassium tungstophosphate supported on BEA zeolite and perspective application for pesticide removal" in Journal of Environmental Sciences, 81 (2019):136-147,
https://doi.org/10.1016/j.jes.2019.01.018 .,
conv_846 .
17
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Surfactant modification and adsorption properties of clinoptilolite for the removal of pertechnetate from aqueous solutions

Milićević, Sonja; Matović, Ljiljana; Petrović, Đorđe; Aukić, Anđelka; Milošević, Vladan; Dokić, Divna; Kumrić, Ksenija

(Springer, Dordrecht, 2016)

TY  - JOUR
AU  - Milićević, Sonja
AU  - Matović, Ljiljana
AU  - Petrović, Đorđe
AU  - Aukić, Anđelka
AU  - Milošević, Vladan
AU  - Dokić, Divna
AU  - Kumrić, Ksenija
PY  - 2016
UR  - https://ritnms.itnms.ac.rs/handle/123456789/401
AB  - Natural clinoptilolite modified with a cationic surfactant stearyldimethylbenzylammonium chloride (SDBAC) was used as an adsorbent for the removal of pertechnetate from aqueous solutions. Adsorption studies were performed in a batch system. The effects of various experimental parameters (amount of surfactant loading, contact time, solution pH, competing anions) on the removal efficiency of TcO4 (-) were investigated. SDBAC-clinoptilolite with organo-bilayer was successfully used to remove TcO4 (-) from aqueous solutions in the pH range of 5.0-8.0. ReO4 (-) as an analogue of TcO4 (-) was used to model the isotherms. Adsorption capacity of the SDBAC-clinoptilolite and the mechanism of ReO4 (-) (TcO4 (-)) sorption were also determined.
PB  - Springer, Dordrecht
T2  - Journal of Radioanalytical and Nuclear Chemistry
T1  - Surfactant modification and adsorption properties of clinoptilolite for the removal of pertechnetate from aqueous solutions
EP  - 815
IS  - 2
SP  - 805
VL  - 310
DO  - 10.1007/s10967-016-4850-1
UR  - conv_773
ER  - 
@article{
author = "Milićević, Sonja and Matović, Ljiljana and Petrović, Đorđe and Aukić, Anđelka and Milošević, Vladan and Dokić, Divna and Kumrić, Ksenija",
year = "2016",
abstract = "Natural clinoptilolite modified with a cationic surfactant stearyldimethylbenzylammonium chloride (SDBAC) was used as an adsorbent for the removal of pertechnetate from aqueous solutions. Adsorption studies were performed in a batch system. The effects of various experimental parameters (amount of surfactant loading, contact time, solution pH, competing anions) on the removal efficiency of TcO4 (-) were investigated. SDBAC-clinoptilolite with organo-bilayer was successfully used to remove TcO4 (-) from aqueous solutions in the pH range of 5.0-8.0. ReO4 (-) as an analogue of TcO4 (-) was used to model the isotherms. Adsorption capacity of the SDBAC-clinoptilolite and the mechanism of ReO4 (-) (TcO4 (-)) sorption were also determined.",
publisher = "Springer, Dordrecht",
journal = "Journal of Radioanalytical and Nuclear Chemistry",
title = "Surfactant modification and adsorption properties of clinoptilolite for the removal of pertechnetate from aqueous solutions",
pages = "815-805",
number = "2",
volume = "310",
doi = "10.1007/s10967-016-4850-1",
url = "conv_773"
}
Milićević, S., Matović, L., Petrović, Đ., Aukić, A., Milošević, V., Dokić, D.,& Kumrić, K.. (2016). Surfactant modification and adsorption properties of clinoptilolite for the removal of pertechnetate from aqueous solutions. in Journal of Radioanalytical and Nuclear Chemistry
Springer, Dordrecht., 310(2), 805-815.
https://doi.org/10.1007/s10967-016-4850-1
conv_773
Milićević S, Matović L, Petrović Đ, Aukić A, Milošević V, Dokić D, Kumrić K. Surfactant modification and adsorption properties of clinoptilolite for the removal of pertechnetate from aqueous solutions. in Journal of Radioanalytical and Nuclear Chemistry. 2016;310(2):805-815.
doi:10.1007/s10967-016-4850-1
conv_773 .
Milićević, Sonja, Matović, Ljiljana, Petrović, Đorđe, Aukić, Anđelka, Milošević, Vladan, Dokić, Divna, Kumrić, Ksenija, "Surfactant modification and adsorption properties of clinoptilolite for the removal of pertechnetate from aqueous solutions" in Journal of Radioanalytical and Nuclear Chemistry, 310, no. 2 (2016):805-815,
https://doi.org/10.1007/s10967-016-4850-1 .,
conv_773 .
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