Serbian Ministry of Education, Science and Technological Development

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Kinetics of thermally activated processes in cordierite-based ceramics

Obradović, Nina; Blagojević, Vladimir; Filipović, Suzana; Đorđević, Nataša; Kosanović, Darko; Marković, Smilja; Kachlik, Martin; Maca, Karel; Pavlović, Vladimir

(Springer, Dordrecht, 2019)

TY  - JOUR
AU  - Obradović, Nina
AU  - Blagojević, Vladimir
AU  - Filipović, Suzana
AU  - Đorđević, Nataša
AU  - Kosanović, Darko
AU  - Marković, Smilja
AU  - Kachlik, Martin
AU  - Maca, Karel
AU  - Pavlović, Vladimir
PY  - 2019
UR  - https://ritnms.itnms.ac.rs/handle/123456789/501
AB  - Thermally activated processes in cordierite-based ceramics were investigated to determine the effect of the mechanical activation and the addition of TeO2 on kinetic and thermodynamic parameters of these processes. Using a combination of dilatometry and DTA measurements in the 100-1400 degrees C temperature range, it was established that both the mechanical activation and the addition of TeO2 have a significant effect on processes in cordierite-based ceramics. A combination of 5 mass% addition of TeO2 and mechanical activation for 40 min reduced the sintering temperature of cordierite ceramics to around 1100 degrees C. In addition, the analysis of DTA measurements of mechanically activated samples indicates that the mechanical activation leads to intensification of the cordierite formation through an increase in concentration of surface defects and an increase in grain contact surface in the initial powder.
PB  - Springer, Dordrecht
T2  - Journal of Thermal Analysis and Calorimetry
T1  - Kinetics of thermally activated processes in cordierite-based ceramics
EP  - 2998
IS  - 5
SP  - 2989
VL  - 138
DO  - 10.1007/s10973-018-7924-1
UR  - https://hdl.handle.net/21.15107/rcub_dais_7048
UR  - conv_867
ER  - 
@article{
author = "Obradović, Nina and Blagojević, Vladimir and Filipović, Suzana and Đorđević, Nataša and Kosanović, Darko and Marković, Smilja and Kachlik, Martin and Maca, Karel and Pavlović, Vladimir",
year = "2019",
abstract = "Thermally activated processes in cordierite-based ceramics were investigated to determine the effect of the mechanical activation and the addition of TeO2 on kinetic and thermodynamic parameters of these processes. Using a combination of dilatometry and DTA measurements in the 100-1400 degrees C temperature range, it was established that both the mechanical activation and the addition of TeO2 have a significant effect on processes in cordierite-based ceramics. A combination of 5 mass% addition of TeO2 and mechanical activation for 40 min reduced the sintering temperature of cordierite ceramics to around 1100 degrees C. In addition, the analysis of DTA measurements of mechanically activated samples indicates that the mechanical activation leads to intensification of the cordierite formation through an increase in concentration of surface defects and an increase in grain contact surface in the initial powder.",
publisher = "Springer, Dordrecht",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "Kinetics of thermally activated processes in cordierite-based ceramics",
pages = "2998-2989",
number = "5",
volume = "138",
doi = "10.1007/s10973-018-7924-1",
url = "https://hdl.handle.net/21.15107/rcub_dais_7048, conv_867"
}
Obradović, N., Blagojević, V., Filipović, S., Đorđević, N., Kosanović, D., Marković, S., Kachlik, M., Maca, K.,& Pavlović, V.. (2019). Kinetics of thermally activated processes in cordierite-based ceramics. in Journal of Thermal Analysis and Calorimetry
Springer, Dordrecht., 138(5), 2989-2998.
https://doi.org/10.1007/s10973-018-7924-1
https://hdl.handle.net/21.15107/rcub_dais_7048
Obradović N, Blagojević V, Filipović S, Đorđević N, Kosanović D, Marković S, Kachlik M, Maca K, Pavlović V. Kinetics of thermally activated processes in cordierite-based ceramics. in Journal of Thermal Analysis and Calorimetry. 2019;138(5):2989-2998.
doi:10.1007/s10973-018-7924-1
https://hdl.handle.net/21.15107/rcub_dais_7048 .
Obradović, Nina, Blagojević, Vladimir, Filipović, Suzana, Đorđević, Nataša, Kosanović, Darko, Marković, Smilja, Kachlik, Martin, Maca, Karel, Pavlović, Vladimir, "Kinetics of thermally activated processes in cordierite-based ceramics" in Journal of Thermal Analysis and Calorimetry, 138, no. 5 (2019):2989-2998,
https://doi.org/10.1007/s10973-018-7924-1 .,
https://hdl.handle.net/21.15107/rcub_dais_7048 .
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Energy conversion in phosphate ore grain mixture activated via ultra-centrifugal mill

Andrić, Ljubiša; Terzić, Anja; Petrov, Milan; Stojanović, Jovica; Kostović, Milena

(Elsevier, Amsterdam, 2015)

TY  - JOUR
AU  - Andrić, Ljubiša
AU  - Terzić, Anja
AU  - Petrov, Milan
AU  - Stojanović, Jovica
AU  - Kostović, Milena
PY  - 2015
UR  - https://ritnms.itnms.ac.rs/handle/123456789/336
AB  - The aim of this investigation was to establish the optimal processing parameters of the comminuted phosphate grain mixture mechanical treatment by monitoring and evaluating the activated product characteristics. An ultra-centrifugal mill with a peripheral comminuting path was used as activator in the experiment. A mathematical model based on the theoretical principles of the grain mixture mechanical processing was applied in order to characterize the phosphate activation procedure. As the energy conversion that takes place by the interaction mill-material during activation is recorded on the processed phosphate grains, the increase in potential energy of the activated grains was measured by means of an automatic grain counter. Following the operating hypothesis of the automatic grain counter, the energy conversion and the properties of phosphate grains induced by mechanical force were monitored and expressed in the form of the grain inertia change. The phosphate ore grain mixture used in the experiment was thoroughly analyzed, particularly in its activated state. Analytically obtained results were supported by X-ray diffraction analysis for identification of crystalline phases and change in crystallinity, and SEM microphotography of initial and activated phosphate grains. Diverse comparison analyses disclosed that the optimal set of activation process parameters could reduce the negative effect of phosphate sample immanent properties on the final score and furthermore enhance the material reactivity.
PB  - Elsevier, Amsterdam
T2  - International Journal of Mineral Processing
T1  - Energy conversion in phosphate ore grain mixture activated via ultra-centrifugal mill
EP  - 11
SP  - 1
VL  - 143
DO  - 10.1016/j.minpro.2015.08.005
UR  - conv_741
ER  - 
@article{
author = "Andrić, Ljubiša and Terzić, Anja and Petrov, Milan and Stojanović, Jovica and Kostović, Milena",
year = "2015",
abstract = "The aim of this investigation was to establish the optimal processing parameters of the comminuted phosphate grain mixture mechanical treatment by monitoring and evaluating the activated product characteristics. An ultra-centrifugal mill with a peripheral comminuting path was used as activator in the experiment. A mathematical model based on the theoretical principles of the grain mixture mechanical processing was applied in order to characterize the phosphate activation procedure. As the energy conversion that takes place by the interaction mill-material during activation is recorded on the processed phosphate grains, the increase in potential energy of the activated grains was measured by means of an automatic grain counter. Following the operating hypothesis of the automatic grain counter, the energy conversion and the properties of phosphate grains induced by mechanical force were monitored and expressed in the form of the grain inertia change. The phosphate ore grain mixture used in the experiment was thoroughly analyzed, particularly in its activated state. Analytically obtained results were supported by X-ray diffraction analysis for identification of crystalline phases and change in crystallinity, and SEM microphotography of initial and activated phosphate grains. Diverse comparison analyses disclosed that the optimal set of activation process parameters could reduce the negative effect of phosphate sample immanent properties on the final score and furthermore enhance the material reactivity.",
publisher = "Elsevier, Amsterdam",
journal = "International Journal of Mineral Processing",
title = "Energy conversion in phosphate ore grain mixture activated via ultra-centrifugal mill",
pages = "11-1",
volume = "143",
doi = "10.1016/j.minpro.2015.08.005",
url = "conv_741"
}
Andrić, L., Terzić, A., Petrov, M., Stojanović, J.,& Kostović, M.. (2015). Energy conversion in phosphate ore grain mixture activated via ultra-centrifugal mill. in International Journal of Mineral Processing
Elsevier, Amsterdam., 143, 1-11.
https://doi.org/10.1016/j.minpro.2015.08.005
conv_741
Andrić L, Terzić A, Petrov M, Stojanović J, Kostović M. Energy conversion in phosphate ore grain mixture activated via ultra-centrifugal mill. in International Journal of Mineral Processing. 2015;143:1-11.
doi:10.1016/j.minpro.2015.08.005
conv_741 .
Andrić, Ljubiša, Terzić, Anja, Petrov, Milan, Stojanović, Jovica, Kostović, Milena, "Energy conversion in phosphate ore grain mixture activated via ultra-centrifugal mill" in International Journal of Mineral Processing, 143 (2015):1-11,
https://doi.org/10.1016/j.minpro.2015.08.005 .,
conv_741 .
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