Karanović, Ljiljana

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orcid::0000-0001-9534-1315
  • Karanović, Ljiljana (6)

Author's Bibliography

Structural features of two novel alluaudite-like arsenates Cd1.16Zn2.34(AsO4)(1.5)(HAsO4)(H2AsO4)(0.5) and Cd0.74Mg2.76(AsO4)(1.5)(HAsO4)(H2AsO4)(0.5)

Stojanović, Jovica; Đorđević, Tamara; Karanović, Ljiljana

(Elsevier Science Sa, Lausanne, 2012)

TY  - JOUR
AU  - Stojanović, Jovica
AU  - Đorđević, Tamara
AU  - Karanović, Ljiljana
PY  - 2012
UR  - https://ritnms.itnms.ac.rs/handle/123456789/205
AB  - Two new compounds, Cd1.16Zn2.34(AsO4)(1.5)(HAsO4)(H2AsO4)(0.5) (1) and Cd0.74Mg2.76(AsO4)(1.5)-(HAsO4)(H2AsO4)(0.5) (2), have been prepared hydrothermally. Their crystal structures consist of chains of edge-sharing M1O(4)(OH0.5)(2), M1aO(4)(OH0.5)(2), M2O5(OH0.5), and M(2)aO(5)(OH0.5) octahedra (M1, M1a = Zn, Cd; M2, M2a = Zn for 1, and M1, M1a = Mg, Cd; M2, M2a = Mg for 2) that are stacked parallel to (1 0 1) and are connected by the [(AsO4)(0.5)(AsO3(OH))(0.5)](2.5-) and [(AsO4)(0.5)(AsO2(OH)(2))(0.5)](2-) tetrahedra. These chains produce two types of channels parallel to the c-axis. Cd atoms are located in channels 2, while in channels 1 are situated hydrogen atoms of O-H groups. The infrared spectra clearly show the presence of broad O-H stretching and bending vibrations centred at 3236, 2392 1575 and 1396 cm(-1) in (1), and 3210, 2379 1602 and 1310 cm(-1) in (2). The O-H stretching frequency is in good agreement with O center dot center dot center dot O distances. Furthermore, structural characteristics of compounds with similar alluaudite-like structures were discussed.
PB  - Elsevier Science Sa, Lausanne
T2  - Journal of Alloys and Compounds
T1  - Structural features of two novel alluaudite-like arsenates Cd1.16Zn2.34(AsO4)(1.5)(HAsO4)(H2AsO4)(0.5) and Cd0.74Mg2.76(AsO4)(1.5)(HAsO4)(H2AsO4)(0.5)
EP  - 189
SP  - 180
VL  - 520
DO  - 10.1016/j.jallcom.2012.01.002
UR  - conv_614
ER  - 
@article{
author = "Stojanović, Jovica and Đorđević, Tamara and Karanović, Ljiljana",
year = "2012",
abstract = "Two new compounds, Cd1.16Zn2.34(AsO4)(1.5)(HAsO4)(H2AsO4)(0.5) (1) and Cd0.74Mg2.76(AsO4)(1.5)-(HAsO4)(H2AsO4)(0.5) (2), have been prepared hydrothermally. Their crystal structures consist of chains of edge-sharing M1O(4)(OH0.5)(2), M1aO(4)(OH0.5)(2), M2O5(OH0.5), and M(2)aO(5)(OH0.5) octahedra (M1, M1a = Zn, Cd; M2, M2a = Zn for 1, and M1, M1a = Mg, Cd; M2, M2a = Mg for 2) that are stacked parallel to (1 0 1) and are connected by the [(AsO4)(0.5)(AsO3(OH))(0.5)](2.5-) and [(AsO4)(0.5)(AsO2(OH)(2))(0.5)](2-) tetrahedra. These chains produce two types of channels parallel to the c-axis. Cd atoms are located in channels 2, while in channels 1 are situated hydrogen atoms of O-H groups. The infrared spectra clearly show the presence of broad O-H stretching and bending vibrations centred at 3236, 2392 1575 and 1396 cm(-1) in (1), and 3210, 2379 1602 and 1310 cm(-1) in (2). The O-H stretching frequency is in good agreement with O center dot center dot center dot O distances. Furthermore, structural characteristics of compounds with similar alluaudite-like structures were discussed.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Journal of Alloys and Compounds",
title = "Structural features of two novel alluaudite-like arsenates Cd1.16Zn2.34(AsO4)(1.5)(HAsO4)(H2AsO4)(0.5) and Cd0.74Mg2.76(AsO4)(1.5)(HAsO4)(H2AsO4)(0.5)",
pages = "189-180",
volume = "520",
doi = "10.1016/j.jallcom.2012.01.002",
url = "conv_614"
}
Stojanović, J., Đorđević, T.,& Karanović, L.. (2012). Structural features of two novel alluaudite-like arsenates Cd1.16Zn2.34(AsO4)(1.5)(HAsO4)(H2AsO4)(0.5) and Cd0.74Mg2.76(AsO4)(1.5)(HAsO4)(H2AsO4)(0.5). in Journal of Alloys and Compounds
Elsevier Science Sa, Lausanne., 520, 180-189.
https://doi.org/10.1016/j.jallcom.2012.01.002
conv_614
Stojanović J, Đorđević T, Karanović L. Structural features of two novel alluaudite-like arsenates Cd1.16Zn2.34(AsO4)(1.5)(HAsO4)(H2AsO4)(0.5) and Cd0.74Mg2.76(AsO4)(1.5)(HAsO4)(H2AsO4)(0.5). in Journal of Alloys and Compounds. 2012;520:180-189.
doi:10.1016/j.jallcom.2012.01.002
conv_614 .
Stojanović, Jovica, Đorđević, Tamara, Karanović, Ljiljana, "Structural features of two novel alluaudite-like arsenates Cd1.16Zn2.34(AsO4)(1.5)(HAsO4)(H2AsO4)(0.5) and Cd0.74Mg2.76(AsO4)(1.5)(HAsO4)(H2AsO4)(0.5)" in Journal of Alloys and Compounds, 520 (2012):180-189,
https://doi.org/10.1016/j.jallcom.2012.01.002 .,
conv_614 .
9
6
10

Zn1.86Cd0.14(OH)VO4

Đorđević, Tamara; Stojanović, Jovica; Karanović, Ljiljana

(International Union of Crystallography, 2010)

TY  - JOUR
AU  - Đorđević, Tamara
AU  - Stojanović, Jovica
AU  - Karanović, Ljiljana
PY  - 2010
UR  - https://ritnms.itnms.ac.rs/handle/123456789/184
AB  - The title compound, dizinc cadmium hydroxide tetraoxido-vanadate, Zn 1.86Cd0.14(OH)VO4, was prepared under low-temperature hydro-thermal conditions. It is isostructural with Zn 2(OH)VO4 and Cu2(OH)VO4. In the crystal structure, chains of edge-sharing [ZnO6] octahedra are inter-connected by VO4 tetra-hedra (site symmetries of both V atoms and their coordination polyhedra are.m.) to form a three-dimensional [Zn(OH)VO4]2- framework with channels occupied by Zn and Zn/Cd cations adopting trigonal-bipyramidal and distorted octa-hedral coordinations, respectively. Zn1.86Cd0.14(OH)VO 4 is topologically related to adamite-type phases, and descloizite- and tsumcorite-type structures.
PB  - International Union of Crystallography
T2  - Acta Crystallographica Section E: Structure Reports Online
T1  - Zn1.86Cd0.14(OH)VO4
IS  - 12
VL  - 66
DO  - 10.1107/S1600536810044806
UR  - conv_1083
ER  - 
@article{
author = "Đorđević, Tamara and Stojanović, Jovica and Karanović, Ljiljana",
year = "2010",
abstract = "The title compound, dizinc cadmium hydroxide tetraoxido-vanadate, Zn 1.86Cd0.14(OH)VO4, was prepared under low-temperature hydro-thermal conditions. It is isostructural with Zn 2(OH)VO4 and Cu2(OH)VO4. In the crystal structure, chains of edge-sharing [ZnO6] octahedra are inter-connected by VO4 tetra-hedra (site symmetries of both V atoms and their coordination polyhedra are.m.) to form a three-dimensional [Zn(OH)VO4]2- framework with channels occupied by Zn and Zn/Cd cations adopting trigonal-bipyramidal and distorted octa-hedral coordinations, respectively. Zn1.86Cd0.14(OH)VO 4 is topologically related to adamite-type phases, and descloizite- and tsumcorite-type structures.",
publisher = "International Union of Crystallography",
journal = "Acta Crystallographica Section E: Structure Reports Online",
title = "Zn1.86Cd0.14(OH)VO4",
number = "12",
volume = "66",
doi = "10.1107/S1600536810044806",
url = "conv_1083"
}
Đorđević, T., Stojanović, J.,& Karanović, L.. (2010). Zn1.86Cd0.14(OH)VO4. in Acta Crystallographica Section E: Structure Reports Online
International Union of Crystallography., 66(12).
https://doi.org/10.1107/S1600536810044806
conv_1083
Đorđević T, Stojanović J, Karanović L. Zn1.86Cd0.14(OH)VO4. in Acta Crystallographica Section E: Structure Reports Online. 2010;66(12).
doi:10.1107/S1600536810044806
conv_1083 .
Đorđević, Tamara, Stojanović, Jovica, Karanović, Ljiljana, "Zn1.86Cd0.14(OH)VO4" in Acta Crystallographica Section E: Structure Reports Online, 66, no. 12 (2010),
https://doi.org/10.1107/S1600536810044806 .,
conv_1083 .
7
8

[Zn-3(PO4)(2)(H2O)(0.8)(NH3)(1.2)]

Stojanović, Jovica; Đorđević, Tamara; Karanović, Ljiljana

(Wiley-Blackwell, Malden, 2010)

TY  - JOUR
AU  - Stojanović, Jovica
AU  - Đorđević, Tamara
AU  - Karanović, Ljiljana
PY  - 2010
UR  - https://ritnms.itnms.ac.rs/handle/123456789/180
AB  - The structure of the title compound, ammineaquadi-mu(5)-phosphato-trizinc(II), [Zn-3(PO4)(2)(H2O)(0.8)(NH3)(1.2)], consists of two parts: (i) PO4 and ZnO4 vertex-sharing tetrahedra arranged in layers parallel to (100) and (ii) ZnO2(N/O)(2) tetrahedra located between the layers. Elemental analysis establishes the ammine-to-water ratio as 3:2. ZnO2(N/O)(2) tetrahedra are located at special position 4e (site symmetry 2) in C2/c. The two O atoms of ZnO2(N/O)(2) are bonded to neighbouring P atoms, forming two Zn-O-P linkages and connecting ZnO2(N/O)(2) tetrahedra with two adjacent bc plane layers. A noteworthy feature of the structure is the presence of NH3 and H2O at the same crystallographic position and, consequently, qualitative changes in the pattern of hydrogen bonding and weaker N/O-H center dot center dot center dot O electrostatic interactions, as compared to two closely related structures.
PB  - Wiley-Blackwell, Malden
T2  - Acta Crystallographica Section C-Crystal Structure Communications
T1  - [Zn-3(PO4)(2)(H2O)(0.8)(NH3)(1.2)]
EP  - I57
SP  - I55
VL  - 66
DO  - 10.1107/S0108270110014885
UR  - conv_581
ER  - 
@article{
author = "Stojanović, Jovica and Đorđević, Tamara and Karanović, Ljiljana",
year = "2010",
abstract = "The structure of the title compound, ammineaquadi-mu(5)-phosphato-trizinc(II), [Zn-3(PO4)(2)(H2O)(0.8)(NH3)(1.2)], consists of two parts: (i) PO4 and ZnO4 vertex-sharing tetrahedra arranged in layers parallel to (100) and (ii) ZnO2(N/O)(2) tetrahedra located between the layers. Elemental analysis establishes the ammine-to-water ratio as 3:2. ZnO2(N/O)(2) tetrahedra are located at special position 4e (site symmetry 2) in C2/c. The two O atoms of ZnO2(N/O)(2) are bonded to neighbouring P atoms, forming two Zn-O-P linkages and connecting ZnO2(N/O)(2) tetrahedra with two adjacent bc plane layers. A noteworthy feature of the structure is the presence of NH3 and H2O at the same crystallographic position and, consequently, qualitative changes in the pattern of hydrogen bonding and weaker N/O-H center dot center dot center dot O electrostatic interactions, as compared to two closely related structures.",
publisher = "Wiley-Blackwell, Malden",
journal = "Acta Crystallographica Section C-Crystal Structure Communications",
title = "[Zn-3(PO4)(2)(H2O)(0.8)(NH3)(1.2)]",
pages = "I57-I55",
volume = "66",
doi = "10.1107/S0108270110014885",
url = "conv_581"
}
Stojanović, J., Đorđević, T.,& Karanović, L.. (2010). [Zn-3(PO4)(2)(H2O)(0.8)(NH3)(1.2)]. in Acta Crystallographica Section C-Crystal Structure Communications
Wiley-Blackwell, Malden., 66, I55-I57.
https://doi.org/10.1107/S0108270110014885
conv_581
Stojanović J, Đorđević T, Karanović L. [Zn-3(PO4)(2)(H2O)(0.8)(NH3)(1.2)]. in Acta Crystallographica Section C-Crystal Structure Communications. 2010;66:I55-I57.
doi:10.1107/S0108270110014885
conv_581 .
Stojanović, Jovica, Đorđević, Tamara, Karanović, Ljiljana, "[Zn-3(PO4)(2)(H2O)(0.8)(NH3)(1.2)]" in Acta Crystallographica Section C-Crystal Structure Communications, 66 (2010):I55-I57,
https://doi.org/10.1107/S0108270110014885 .,
conv_581 .
1
1
2

Sr, Ba and Cd arsenates with the apatite-type structure

Đorđević, Tamara; Sutović, Sabina; Stojanović, Jovica; Karanović, Ljiljana

(Wiley-Blackwell, Malden, 2008)

TY  - JOUR
AU  - Đorđević, Tamara
AU  - Sutović, Sabina
AU  - Stojanović, Jovica
AU  - Karanović, Ljiljana
PY  - 2008
UR  - https://ritnms.itnms.ac.rs/handle/123456789/136
AB  - X-ray diffraction analysis of single crystals of three new arsenates adopting apatite-type structures yielded formula Sr(5)(AsO(4))(3)F for strontium arsenate fluoride, (I), (Sr(1.66)Ba(0.34))-(Ba(2.61)Sr(0.39))(AsO(4))(3)Cl for strontium barium arsenate chloride, (II), and Cd(5)(AsO(4))(3)Cl(0.58)(OH)(0.42) for cadmium arsenate hydroxide chloride, (III). All three structures are built up of isolated slightly distorted AsO(4) tetrahedra that are bridged by Sr(2+) in (I), by Sr(2+)/Ba(2+) in (II) and by Cd(2+) in (III). Compounds (I) and ( II) represent typical fluorapatites and chlorapatites, respectively, with F(-) at the 2a (0, 0, 1/4) site and Cl(-) at the 2b (0, 0, 0) site of P6(3)/m. In contrast, in (III), due to the requirement that the smaller Cd(2+) cation is positioned closer to the channel Cl(-) anion (partially substituted by OH(-)), the anion occupies the unusual 2a (0, 0, 1/4) site. Therefore, Cl(-) is similar to F(-) in (I), coordinated by three A2 cations, unlike the octahedrally coordinated Cl(-) in (II) and other ordinary chlorapatites. Furthermore, in (III), using FTIR studies, we have inferred the existence of H(+) outside the channel in oxyhydroxyapatites and provided possible atomic coordinates for a H atom in HAsO(4)(2-), leading to a proposed formulation of the compound as Cd(5)(AsO(4))(3-x)(HAsO(4))(x)-Cl(0.58)(OH)(0.42-x-(y/2))O(x+(y/2))square(y/2).
PB  - Wiley-Blackwell, Malden
T2  - Acta Crystallographica Section C-Crystal Structure Communications
T1  - Sr, Ba and Cd arsenates with the apatite-type structure
EP  - I86
SP  - I82
VL  - 64
DO  - 10.1107/S0108270108023457
UR  - conv_549
ER  - 
@article{
author = "Đorđević, Tamara and Sutović, Sabina and Stojanović, Jovica and Karanović, Ljiljana",
year = "2008",
abstract = "X-ray diffraction analysis of single crystals of three new arsenates adopting apatite-type structures yielded formula Sr(5)(AsO(4))(3)F for strontium arsenate fluoride, (I), (Sr(1.66)Ba(0.34))-(Ba(2.61)Sr(0.39))(AsO(4))(3)Cl for strontium barium arsenate chloride, (II), and Cd(5)(AsO(4))(3)Cl(0.58)(OH)(0.42) for cadmium arsenate hydroxide chloride, (III). All three structures are built up of isolated slightly distorted AsO(4) tetrahedra that are bridged by Sr(2+) in (I), by Sr(2+)/Ba(2+) in (II) and by Cd(2+) in (III). Compounds (I) and ( II) represent typical fluorapatites and chlorapatites, respectively, with F(-) at the 2a (0, 0, 1/4) site and Cl(-) at the 2b (0, 0, 0) site of P6(3)/m. In contrast, in (III), due to the requirement that the smaller Cd(2+) cation is positioned closer to the channel Cl(-) anion (partially substituted by OH(-)), the anion occupies the unusual 2a (0, 0, 1/4) site. Therefore, Cl(-) is similar to F(-) in (I), coordinated by three A2 cations, unlike the octahedrally coordinated Cl(-) in (II) and other ordinary chlorapatites. Furthermore, in (III), using FTIR studies, we have inferred the existence of H(+) outside the channel in oxyhydroxyapatites and provided possible atomic coordinates for a H atom in HAsO(4)(2-), leading to a proposed formulation of the compound as Cd(5)(AsO(4))(3-x)(HAsO(4))(x)-Cl(0.58)(OH)(0.42-x-(y/2))O(x+(y/2))square(y/2).",
publisher = "Wiley-Blackwell, Malden",
journal = "Acta Crystallographica Section C-Crystal Structure Communications",
title = "Sr, Ba and Cd arsenates with the apatite-type structure",
pages = "I86-I82",
volume = "64",
doi = "10.1107/S0108270108023457",
url = "conv_549"
}
Đorđević, T., Sutović, S., Stojanović, J.,& Karanović, L.. (2008). Sr, Ba and Cd arsenates with the apatite-type structure. in Acta Crystallographica Section C-Crystal Structure Communications
Wiley-Blackwell, Malden., 64, I82-I86.
https://doi.org/10.1107/S0108270108023457
conv_549
Đorđević T, Sutović S, Stojanović J, Karanović L. Sr, Ba and Cd arsenates with the apatite-type structure. in Acta Crystallographica Section C-Crystal Structure Communications. 2008;64:I82-I86.
doi:10.1107/S0108270108023457
conv_549 .
Đorđević, Tamara, Sutović, Sabina, Stojanović, Jovica, Karanović, Ljiljana, "Sr, Ba and Cd arsenates with the apatite-type structure" in Acta Crystallographica Section C-Crystal Structure Communications, 64 (2008):I82-I86,
https://doi.org/10.1107/S0108270108023457 .,
conv_549 .
20
17
26

Cd(2)Cu(PO(4))(2)

Stojanović, Jovica; Đorđević, Tamara; Karanović, Ljiljana

(Wiley-Blackwell, Malden, 2008)

TY  - JOUR
AU  - Stojanović, Jovica
AU  - Đorđević, Tamara
AU  - Karanović, Ljiljana
PY  - 2008
UR  - https://ritnms.itnms.ac.rs/handle/123456789/126
AB  - During an investigation of the insufficiently known system M1O-M2O-X(2)O(5)-H(2)O (M1 = Cd(2+), Sr(2+) and Ba(2+); M2 = Cu(2+), Ni(2+), Co(2+), Zn(2+) and Mg(2+); X = P(5+), As(5+) and V(5+)), single crystals of the novel compound dicadmium copper(II) bis[phosphate(V)], Cd(2)Cu(PO(4))(2), were obtained. This compound belongs to a small group of compounds adopting a Cu(3)(PO(4))(2)-type structure and having the general formula M1(2)M(2)(XO(4))(2) (M1/M2 = Cd(2+), Cu(2+), Mg(2+) and Zn(2+); X = As(5+), P(5+) and V(5+)). The crystal structure is characterized by the interconnection of infinite [Cu(PO(4))(2)] n chains and [Cd(2)O(10)](n) double chains, both extending along the a axis. Exceptional characteristics of this structure are its novel chemical composition and the occurrence of double chains of CdO(6) polyhedra that were not found in related structures. In contrast to the isomorphous compounds, where the M1 cations are coordinated by five O atoms, the Cd atom is coordinated by six. The dissimilarity in the geometry of M1 coordination between Cd(2)Cu(PO(4))(2) and the isomorphous compounds is mostly due to the larger ionic radius of the Cd cation in comparison with the Cu, Mg and Zn cations. Sharing a common edge, two CdO(6) polyhedra form Cd(2)O(10) dimers. Each such dimer is bonded to another dimer sharing common vertices, forming [Cd(2)O(10)](n) double chains in the [100] direction. The Cu atoms, located on an inversion centre (site symmetry 1), form isolated CuO(4) squares interconnected by PO(4) tetrahedra, forming [Cu(PO(4))(2)](n) chains similar to those found in related structures. Conversely, the [Cd(2)O(10)](n) double chains, which were not found in related structures, are an exclusive feature of this structure.
PB  - Wiley-Blackwell, Malden
T2  - Acta Crystallographica Section C-Crystal Structure Communications
T1  - Cd(2)Cu(PO(4))(2)
EP  - I94
SP  - I91
VL  - 64
DO  - 10.1107/S0108270108032332
UR  - conv_493
ER  - 
@article{
author = "Stojanović, Jovica and Đorđević, Tamara and Karanović, Ljiljana",
year = "2008",
abstract = "During an investigation of the insufficiently known system M1O-M2O-X(2)O(5)-H(2)O (M1 = Cd(2+), Sr(2+) and Ba(2+); M2 = Cu(2+), Ni(2+), Co(2+), Zn(2+) and Mg(2+); X = P(5+), As(5+) and V(5+)), single crystals of the novel compound dicadmium copper(II) bis[phosphate(V)], Cd(2)Cu(PO(4))(2), were obtained. This compound belongs to a small group of compounds adopting a Cu(3)(PO(4))(2)-type structure and having the general formula M1(2)M(2)(XO(4))(2) (M1/M2 = Cd(2+), Cu(2+), Mg(2+) and Zn(2+); X = As(5+), P(5+) and V(5+)). The crystal structure is characterized by the interconnection of infinite [Cu(PO(4))(2)] n chains and [Cd(2)O(10)](n) double chains, both extending along the a axis. Exceptional characteristics of this structure are its novel chemical composition and the occurrence of double chains of CdO(6) polyhedra that were not found in related structures. In contrast to the isomorphous compounds, where the M1 cations are coordinated by five O atoms, the Cd atom is coordinated by six. The dissimilarity in the geometry of M1 coordination between Cd(2)Cu(PO(4))(2) and the isomorphous compounds is mostly due to the larger ionic radius of the Cd cation in comparison with the Cu, Mg and Zn cations. Sharing a common edge, two CdO(6) polyhedra form Cd(2)O(10) dimers. Each such dimer is bonded to another dimer sharing common vertices, forming [Cd(2)O(10)](n) double chains in the [100] direction. The Cu atoms, located on an inversion centre (site symmetry 1), form isolated CuO(4) squares interconnected by PO(4) tetrahedra, forming [Cu(PO(4))(2)](n) chains similar to those found in related structures. Conversely, the [Cd(2)O(10)](n) double chains, which were not found in related structures, are an exclusive feature of this structure.",
publisher = "Wiley-Blackwell, Malden",
journal = "Acta Crystallographica Section C-Crystal Structure Communications",
title = "Cd(2)Cu(PO(4))(2)",
pages = "I94-I91",
volume = "64",
doi = "10.1107/S0108270108032332",
url = "conv_493"
}
Stojanović, J., Đorđević, T.,& Karanović, L.. (2008). Cd(2)Cu(PO(4))(2). in Acta Crystallographica Section C-Crystal Structure Communications
Wiley-Blackwell, Malden., 64, I91-I94.
https://doi.org/10.1107/S0108270108032332
conv_493
Stojanović J, Đorđević T, Karanović L. Cd(2)Cu(PO(4))(2). in Acta Crystallographica Section C-Crystal Structure Communications. 2008;64:I91-I94.
doi:10.1107/S0108270108032332
conv_493 .
Stojanović, Jovica, Đorđević, Tamara, Karanović, Ljiljana, "Cd(2)Cu(PO(4))(2)" in Acta Crystallographica Section C-Crystal Structure Communications, 64 (2008):I91-I94,
https://doi.org/10.1107/S0108270108032332 .,
conv_493 .
6
3
7

Mineralogy of W-Pb-Bi ores from Rudnik Mt., Serbia

Stojanović, Jovica; Radosavljević, Slobodan; Karanović, Ljiljana; Cvetković, Ljubomir

(E Schweizerbartsche Verlags, Stuttgart, 2006)

TY  - JOUR
AU  - Stojanović, Jovica
AU  - Radosavljević, Slobodan
AU  - Karanović, Ljiljana
AU  - Cvetković, Ljubomir
PY  - 2006
UR  - https://ritnms.itnms.ac.rs/handle/123456789/102
AB  - Polymetallic W-Pb-Bi ores have been found in the Nova jama ore zone of Rudnik Mt., Serbia. They are situated on the contact of quartzlatite dykes and breccias; mostly occur in a stockwork-type form. In this ore zone three mineralization phases can be distinguished: pyrometasomatic (skarn), pyrometasomatic-hydrothermal and hydrothermal. The pyrometasomatic-hydrothermal phase is the most significant mineralization phase because it is represented by massive ore bodies. They contain a wide variety of minerals including significant amounts of scheelite, native bismuth and sulphosalts, mostly presented by Pb-Bi-sulphosalts. Mo-free scheelite, the only tungsten bearing mineral, was found in economically interesting amounts. Energy Dispersive Spectrometry (EDS) analyses yielded the empirical formulae: Ca0.98WO4 for scheelite, Pb0.99S for galena, (Pb1.91Ag0.05Cu0.08)(2.04)Bi1.93S5 for cosalite and (Pb0.98Ag0.03Cu0.05)(1.06)Bi1.99S4 for galenobismutite. Tetragonal unit-cell parameters for scheelite amount to a = 5.24291 (6), c = 11.3738 (2) angstrom, V = 312.644 (7) angstrom(3). Atomic coordinates, isotropic displacement parameters, interatomic distances, and angles of scheelite were refined from X-ray powder diffraction data using the Rietveld method. Orthorhombic unit-cell parameters were calculated from single crystal data for cosalite to a = 19.13 (1), b = 23.64 (5), c 4.070 (3) angstrom, V = 1839 (5) angstrom(3) and for galenobismutite to a = 11.743 (3), b = 14.525 (8), c = 4.087 (8) angstrom, V = 696.0 (7) angstrom(3).
PB  - E Schweizerbartsche Verlags, Stuttgart
T2  - Neues Jahrbuch Fur Mineralogie-Abhandlungen
T1  - Mineralogy of W-Pb-Bi ores from Rudnik Mt., Serbia
EP  - 306
IS  - 3
SP  - 299
VL  - 182
DO  - 10.1127/0077-7757/2006/0053
UR  - conv_516
ER  - 
@article{
author = "Stojanović, Jovica and Radosavljević, Slobodan and Karanović, Ljiljana and Cvetković, Ljubomir",
year = "2006",
abstract = "Polymetallic W-Pb-Bi ores have been found in the Nova jama ore zone of Rudnik Mt., Serbia. They are situated on the contact of quartzlatite dykes and breccias; mostly occur in a stockwork-type form. In this ore zone three mineralization phases can be distinguished: pyrometasomatic (skarn), pyrometasomatic-hydrothermal and hydrothermal. The pyrometasomatic-hydrothermal phase is the most significant mineralization phase because it is represented by massive ore bodies. They contain a wide variety of minerals including significant amounts of scheelite, native bismuth and sulphosalts, mostly presented by Pb-Bi-sulphosalts. Mo-free scheelite, the only tungsten bearing mineral, was found in economically interesting amounts. Energy Dispersive Spectrometry (EDS) analyses yielded the empirical formulae: Ca0.98WO4 for scheelite, Pb0.99S for galena, (Pb1.91Ag0.05Cu0.08)(2.04)Bi1.93S5 for cosalite and (Pb0.98Ag0.03Cu0.05)(1.06)Bi1.99S4 for galenobismutite. Tetragonal unit-cell parameters for scheelite amount to a = 5.24291 (6), c = 11.3738 (2) angstrom, V = 312.644 (7) angstrom(3). Atomic coordinates, isotropic displacement parameters, interatomic distances, and angles of scheelite were refined from X-ray powder diffraction data using the Rietveld method. Orthorhombic unit-cell parameters were calculated from single crystal data for cosalite to a = 19.13 (1), b = 23.64 (5), c 4.070 (3) angstrom, V = 1839 (5) angstrom(3) and for galenobismutite to a = 11.743 (3), b = 14.525 (8), c = 4.087 (8) angstrom, V = 696.0 (7) angstrom(3).",
publisher = "E Schweizerbartsche Verlags, Stuttgart",
journal = "Neues Jahrbuch Fur Mineralogie-Abhandlungen",
title = "Mineralogy of W-Pb-Bi ores from Rudnik Mt., Serbia",
pages = "306-299",
number = "3",
volume = "182",
doi = "10.1127/0077-7757/2006/0053",
url = "conv_516"
}
Stojanović, J., Radosavljević, S., Karanović, L.,& Cvetković, L.. (2006). Mineralogy of W-Pb-Bi ores from Rudnik Mt., Serbia. in Neues Jahrbuch Fur Mineralogie-Abhandlungen
E Schweizerbartsche Verlags, Stuttgart., 182(3), 299-306.
https://doi.org/10.1127/0077-7757/2006/0053
conv_516
Stojanović J, Radosavljević S, Karanović L, Cvetković L. Mineralogy of W-Pb-Bi ores from Rudnik Mt., Serbia. in Neues Jahrbuch Fur Mineralogie-Abhandlungen. 2006;182(3):299-306.
doi:10.1127/0077-7757/2006/0053
conv_516 .
Stojanović, Jovica, Radosavljević, Slobodan, Karanović, Ljiljana, Cvetković, Ljubomir, "Mineralogy of W-Pb-Bi ores from Rudnik Mt., Serbia" in Neues Jahrbuch Fur Mineralogie-Abhandlungen, 182, no. 3 (2006):299-306,
https://doi.org/10.1127/0077-7757/2006/0053 .,
conv_516 .
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