Jovanović, Gvozden

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orcid::0000-0002-9754-2230
  • Jovanović, Gvozden (37)
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Author's Bibliography

Nanofabrication and characterisation of magnetic Fe3O4 nanostructures for potential environmental and biomedical applications

Milojkov, Dušan; Mraković, Ana; Jovanović, Gvozden; Vuković, Nikola; Bugarčić, Mladen; Antanasković, Anja; Živković-Radovanović, Vukosava

(Belgrade : Institute of Technical Sciences of SASA, 2023)

TY  - CONF
AU  - Milojkov, Dušan
AU  - Mraković, Ana
AU  - Jovanović, Gvozden
AU  - Vuković, Nikola
AU  - Bugarčić, Mladen
AU  - Antanasković, Anja
AU  - Živković-Radovanović, Vukosava
PY  - 2023
UR  - https://ritnms.itnms.ac.rs/handle/123456789/1185
AB  - Magnetic iron oxide nanomaterials, which enable a multitude of uses, are given special focus in the fields of biomedicine and environmental protection. The detection, sorption, and/or degradation of inorganic (lead, chromium, arsenic, and cadmium), organic (dyes, pharmaceuticals, pesticides, phenols, and benzene), and biological (viruses and bacteria) pollutants can all be effectively accomplished with the use of magnetic nanoparticles. Magnetic iron oxide nanomaterials are in particular focus for use as hyperthermia media in cancer treatment and as magnetic resonance imaging (MRI) contrast agents. The possibility of magnetic separation of such materials, due to their essential properties under the influence of an external magnetic field, reduces production costs and also prevents the production and accumulation of toxic waste. Among the many metal oxide nanomaterials, magnetite (Fe3O4) and maghemite (γ-Fe2O3) are currently the only two magnetic materials approved by the US Food and Drug Administration (FDA) for human use as iron deficiency therapeutics and as contrast agents for MRI. Here, we synthesized nanoparticles of magnetite (Fe3O4) by the method of reduction-precipitation and characterized. Additionally, potential binding of brilliant green dye on Fe3O4 and construction of innovative magnetic composite was investigated. The physicochemical features were explored using X-ray diffraction (XRD), 
Fourier-transform infrared spectroscopy (FTIR), and field emission scanning electron microscopy (FESEM). XRD analysis confirms formation of the crystal phase of magnetite. The presence of magnetite nanoparticles is shown by typical groups for the peaks of iron compounds at a lower wavelength (≤ 700 cm-1) that are characteristic of the Fe-O bond. Morphological analyzes with FESEM showed that magnetite is a composite of nanospheres and nanorods that provide a large surface area. Dye binding study was performed using UV visible and FTIR spectrometer.
PB  - Belgrade : Institute of Technical Sciences of SASA
C3  - Twenty-First Young Researchers’ Conference - Materials Science and Engineering
T1  - Nanofabrication and characterisation of magnetic Fe3O4 nanostructures  for potential environmental and biomedical applications
EP  - 14
SP  - 14
ER  - 
@conference{
author = "Milojkov, Dušan and Mraković, Ana and Jovanović, Gvozden and Vuković, Nikola and Bugarčić, Mladen and Antanasković, Anja and Živković-Radovanović, Vukosava",
year = "2023",
abstract = "Magnetic iron oxide nanomaterials, which enable a multitude of uses, are given special focus in the fields of biomedicine and environmental protection. The detection, sorption, and/or degradation of inorganic (lead, chromium, arsenic, and cadmium), organic (dyes, pharmaceuticals, pesticides, phenols, and benzene), and biological (viruses and bacteria) pollutants can all be effectively accomplished with the use of magnetic nanoparticles. Magnetic iron oxide nanomaterials are in particular focus for use as hyperthermia media in cancer treatment and as magnetic resonance imaging (MRI) contrast agents. The possibility of magnetic separation of such materials, due to their essential properties under the influence of an external magnetic field, reduces production costs and also prevents the production and accumulation of toxic waste. Among the many metal oxide nanomaterials, magnetite (Fe3O4) and maghemite (γ-Fe2O3) are currently the only two magnetic materials approved by the US Food and Drug Administration (FDA) for human use as iron deficiency therapeutics and as contrast agents for MRI. Here, we synthesized nanoparticles of magnetite (Fe3O4) by the method of reduction-precipitation and characterized. Additionally, potential binding of brilliant green dye on Fe3O4 and construction of innovative magnetic composite was investigated. The physicochemical features were explored using X-ray diffraction (XRD), 
Fourier-transform infrared spectroscopy (FTIR), and field emission scanning electron microscopy (FESEM). XRD analysis confirms formation of the crystal phase of magnetite. The presence of magnetite nanoparticles is shown by typical groups for the peaks of iron compounds at a lower wavelength (≤ 700 cm-1) that are characteristic of the Fe-O bond. Morphological analyzes with FESEM showed that magnetite is a composite of nanospheres and nanorods that provide a large surface area. Dye binding study was performed using UV visible and FTIR spectrometer.",
publisher = "Belgrade : Institute of Technical Sciences of SASA",
journal = "Twenty-First Young Researchers’ Conference - Materials Science and Engineering",
title = "Nanofabrication and characterisation of magnetic Fe3O4 nanostructures  for potential environmental and biomedical applications",
pages = "14-14"
}
Milojkov, D., Mraković, A., Jovanović, G., Vuković, N., Bugarčić, M., Antanasković, A.,& Živković-Radovanović, V.. (2023). Nanofabrication and characterisation of magnetic Fe3O4 nanostructures  for potential environmental and biomedical applications. in Twenty-First Young Researchers’ Conference - Materials Science and Engineering
Belgrade : Institute of Technical Sciences of SASA., 14-14.
Milojkov D, Mraković A, Jovanović G, Vuković N, Bugarčić M, Antanasković A, Živković-Radovanović V. Nanofabrication and characterisation of magnetic Fe3O4 nanostructures  for potential environmental and biomedical applications. in Twenty-First Young Researchers’ Conference - Materials Science and Engineering. 2023;:14-14..
Milojkov, Dušan, Mraković, Ana, Jovanović, Gvozden, Vuković, Nikola, Bugarčić, Mladen, Antanasković, Anja, Živković-Radovanović, Vukosava, "Nanofabrication and characterisation of magnetic Fe3O4 nanostructures  for potential environmental and biomedical applications" in Twenty-First Young Researchers’ Conference - Materials Science and Engineering (2023):14-14.

Stability of solid residue after integral treatment of acid mine drainage

Petronijević, Nela; Radovanović, Dragana; Stanković, Srđan; Sokić, Miroslav; Kamberović, Željko; Onjia, Antonije; Jovanović, Gvozden

(Belgrade : Association of Metallurgical Engineers of Serbia, 2023)

TY  - JOUR
AU  - Petronijević, Nela
AU  - Radovanović, Dragana
AU  - Stanković, Srđan
AU  - Sokić, Miroslav
AU  - Kamberović, Željko
AU  - Onjia, Antonije
AU  - Jovanović, Gvozden
PY  - 2023
UR  - https://ritnms.itnms.ac.rs/handle/123456789/1208
AB  - Acid mine drainage is a challenging environmental problem caused by mining activities. Long-term  copper  ore  exploitation  and  vast  amounts  of  mining  waste  lead  to  severe  soil  contamination as well as river and groundwater pollution. In this paper, research is focused on utilizing waste mine waters and off-balance parts of the mine deposit (such as flotation tailings) and converting their negative characteristics to an environmentally friendly one. In the  authors’  previous  work,  acid  mine  water  from  Robule,  which  is  part  of  the  Bor  copper  mining and smelting complex in Serbia, was successfully treated using flotation tailings, and the resulting solution was suitable for safe discharge. This paper investigates the characteristics of the solid residue that remained after the treatment of the modified flotation tailings in order to  evaluate  the  possibility  of  its  safe  disposal  back  into  the  environment.  The  solid  residue  was subjected to TCLP and EN 12457-4 tests as standard procedures that assess the leaching characteristics  of  a  material.  The  solid  residue  was  also  exposed  to  long-term  leaching  with  melted  snow  to  simulate  environmental  conditions  for  one  year.  This  drainage  water  was  analyzed and compared with the results of the standard leaching procedures. The investigated treatments lead to improved economic and environmental effects, while the process itself is adjusted to preserve the environment.
PB  - Belgrade : Association of Metallurgical Engineers of Serbia
T2  - Metallurgical and Materials Data
T1  - Stability of solid residue after integral treatment of acid mine drainage
EP  - 63
IS  - 2
SP  - 57
VL  - 1
DO  - 10.30544/MMD6
ER  - 
@article{
author = "Petronijević, Nela and Radovanović, Dragana and Stanković, Srđan and Sokić, Miroslav and Kamberović, Željko and Onjia, Antonije and Jovanović, Gvozden",
year = "2023",
abstract = "Acid mine drainage is a challenging environmental problem caused by mining activities. Long-term  copper  ore  exploitation  and  vast  amounts  of  mining  waste  lead  to  severe  soil  contamination as well as river and groundwater pollution. In this paper, research is focused on utilizing waste mine waters and off-balance parts of the mine deposit (such as flotation tailings) and converting their negative characteristics to an environmentally friendly one. In the  authors’  previous  work,  acid  mine  water  from  Robule,  which  is  part  of  the  Bor  copper  mining and smelting complex in Serbia, was successfully treated using flotation tailings, and the resulting solution was suitable for safe discharge. This paper investigates the characteristics of the solid residue that remained after the treatment of the modified flotation tailings in order to  evaluate  the  possibility  of  its  safe  disposal  back  into  the  environment.  The  solid  residue  was subjected to TCLP and EN 12457-4 tests as standard procedures that assess the leaching characteristics  of  a  material.  The  solid  residue  was  also  exposed  to  long-term  leaching  with  melted  snow  to  simulate  environmental  conditions  for  one  year.  This  drainage  water  was  analyzed and compared with the results of the standard leaching procedures. The investigated treatments lead to improved economic and environmental effects, while the process itself is adjusted to preserve the environment.",
publisher = "Belgrade : Association of Metallurgical Engineers of Serbia",
journal = "Metallurgical and Materials Data",
title = "Stability of solid residue after integral treatment of acid mine drainage",
pages = "63-57",
number = "2",
volume = "1",
doi = "10.30544/MMD6"
}
Petronijević, N., Radovanović, D., Stanković, S., Sokić, M., Kamberović, Ž., Onjia, A.,& Jovanović, G.. (2023). Stability of solid residue after integral treatment of acid mine drainage. in Metallurgical and Materials Data
Belgrade : Association of Metallurgical Engineers of Serbia., 1(2), 57-63.
https://doi.org/10.30544/MMD6
Petronijević N, Radovanović D, Stanković S, Sokić M, Kamberović Ž, Onjia A, Jovanović G. Stability of solid residue after integral treatment of acid mine drainage. in Metallurgical and Materials Data. 2023;1(2):57-63.
doi:10.30544/MMD6 .
Petronijević, Nela, Radovanović, Dragana, Stanković, Srđan, Sokić, Miroslav, Kamberović, Željko, Onjia, Antonije, Jovanović, Gvozden, "Stability of solid residue after integral treatment of acid mine drainage" in Metallurgical and Materials Data, 1, no. 2 (2023):57-63,
https://doi.org/10.30544/MMD6 . .

Innovative industrial symbiosis approach for acidic mine drainage neutralization

Vujović, Nela; Alivojvodić, Vesna; Sokić, Miroslav; Jovanović, Gvozden; Marković, Branislav; Kamberović, Željko

(Belgrade : Association of Metallurgical Engineers of Serbia, 2023)

TY  - CONF
AU  - Vujović, Nela
AU  - Alivojvodić, Vesna
AU  - Sokić, Miroslav
AU  - Jovanović, Gvozden
AU  - Marković, Branislav
AU  - Kamberović, Željko
PY  - 2023
UR  - https://ritnms.itnms.ac.rs/handle/123456789/940
AB  - Following the principles of sustainable development and circular economy, an innovative industrial symbiosis approach
has been developed that uses already disposed voluminous waste. The research was focused on the utilization potential
of vast amounts of flotation tailings, fly ash and acidic mine waters. Numerous previous case studies have pointed out the
harmful, long-lasting environmental damage from waste disposal. In this case, the emphasis is on finding a practical
approach for using industrial waste, specifically thermal power plant fly ash, in order to neutralize acidic mine waters
resulting from tailings disposal. The proposed treatment gives waste a practical value, eliminates its harmful effect on the
environment and redefines (lowers) regular waste management costs. In addition, it is possible to obtain valuable metals
by exploiting and reprocessing acidic mine drainage.
PB  - Belgrade : Association of Metallurgical Engineers of Serbia
C3  - 5th Metallurgical & Materials Engineering Congress of South-East Europe MME SEE 2023
T1  - Innovative industrial symbiosis approach for acidic mine drainage neutralization
EP  - 382
SP  - 377
ER  - 
@conference{
author = "Vujović, Nela and Alivojvodić, Vesna and Sokić, Miroslav and Jovanović, Gvozden and Marković, Branislav and Kamberović, Željko",
year = "2023",
abstract = "Following the principles of sustainable development and circular economy, an innovative industrial symbiosis approach
has been developed that uses already disposed voluminous waste. The research was focused on the utilization potential
of vast amounts of flotation tailings, fly ash and acidic mine waters. Numerous previous case studies have pointed out the
harmful, long-lasting environmental damage from waste disposal. In this case, the emphasis is on finding a practical
approach for using industrial waste, specifically thermal power plant fly ash, in order to neutralize acidic mine waters
resulting from tailings disposal. The proposed treatment gives waste a practical value, eliminates its harmful effect on the
environment and redefines (lowers) regular waste management costs. In addition, it is possible to obtain valuable metals
by exploiting and reprocessing acidic mine drainage.",
publisher = "Belgrade : Association of Metallurgical Engineers of Serbia",
journal = "5th Metallurgical & Materials Engineering Congress of South-East Europe MME SEE 2023",
title = "Innovative industrial symbiosis approach for acidic mine drainage neutralization",
pages = "382-377"
}
Vujović, N., Alivojvodić, V., Sokić, M., Jovanović, G., Marković, B.,& Kamberović, Ž.. (2023). Innovative industrial symbiosis approach for acidic mine drainage neutralization. in 5th Metallurgical & Materials Engineering Congress of South-East Europe MME SEE 2023
Belgrade : Association of Metallurgical Engineers of Serbia., 377-382.
Vujović N, Alivojvodić V, Sokić M, Jovanović G, Marković B, Kamberović Ž. Innovative industrial symbiosis approach for acidic mine drainage neutralization. in 5th Metallurgical & Materials Engineering Congress of South-East Europe MME SEE 2023. 2023;:377-382..
Vujović, Nela, Alivojvodić, Vesna, Sokić, Miroslav, Jovanović, Gvozden, Marković, Branislav, Kamberović, Željko, "Innovative industrial symbiosis approach for acidic mine drainage neutralization" in 5th Metallurgical & Materials Engineering Congress of South-East Europe MME SEE 2023 (2023):377-382.

Determining the role of acicular ferrite carbides in cleavage fracture crack Initiation for two medium carbon microalloyed steels

Jovanović, Gvozden; Glišić, Dragomir; Dikić, Stefan; Međo, Bojan; Marković, Branislav; Vuković, Nikola; Radović, Nenad

(MDPI, 2023)

TY  - JOUR
AU  - Jovanović, Gvozden
AU  - Glišić, Dragomir
AU  - Dikić, Stefan
AU  - Međo, Bojan
AU  - Marković, Branislav
AU  - Vuković, Nikola
AU  - Radović, Nenad
PY  - 2023
UR  - https://ritnms.itnms.ac.rs/handle/123456789/1174
AB  - Two medium-carbon microalloyed steels with a predominant acicular ferrite microstructure were investigated in this study in order to determine the initial micro-crack formation mechanism and the role of acicular ferrite structure in cleavage fracture. In order to ensure cleavage fracture, samples were investigated at −196 ◦C for uniaxial tension and four point bending fracture. Previous investigations have shown that cleavage fracture for steels with a predominant acicular ferrite microstructure has not been initiated by the fracture of coarse TiN particles as in ferrite-pearlite,
bainite, or martensitic microalloyed steels. The average maximal thickness of cementite plates measured in this work is 0.798 µm and 0.966 µm, for V and TiV steel, respectively. The corresponding stress values required for their fracture according to Griffith’s equation are 1970 MPa and 1791 MPa,
respectively. Estimated values of the effective surface energy for the V steel with an average cementite volume fraction of 3.8% range from 40 Jm−2 to 86 Jm−2, and for the TiV steel with an average cementite volume fraction of 18.3% range from 55 Jm−2 to 82 Jm−2. The fracture of coarse cementite plates was found to not to be responsible for the cleavage fracture initiation in case of both steels.
PB  - MDPI
T2  - Materials
T1  - Determining the role of acicular ferrite carbides in cleavage fracture crack Initiation for two medium carbon microalloyed steels
IS  - 22
VL  - 16
DO  - 10.3390/ma16227192
ER  - 
@article{
author = "Jovanović, Gvozden and Glišić, Dragomir and Dikić, Stefan and Međo, Bojan and Marković, Branislav and Vuković, Nikola and Radović, Nenad",
year = "2023",
abstract = "Two medium-carbon microalloyed steels with a predominant acicular ferrite microstructure were investigated in this study in order to determine the initial micro-crack formation mechanism and the role of acicular ferrite structure in cleavage fracture. In order to ensure cleavage fracture, samples were investigated at −196 ◦C for uniaxial tension and four point bending fracture. Previous investigations have shown that cleavage fracture for steels with a predominant acicular ferrite microstructure has not been initiated by the fracture of coarse TiN particles as in ferrite-pearlite,
bainite, or martensitic microalloyed steels. The average maximal thickness of cementite plates measured in this work is 0.798 µm and 0.966 µm, for V and TiV steel, respectively. The corresponding stress values required for their fracture according to Griffith’s equation are 1970 MPa and 1791 MPa,
respectively. Estimated values of the effective surface energy for the V steel with an average cementite volume fraction of 3.8% range from 40 Jm−2 to 86 Jm−2, and for the TiV steel with an average cementite volume fraction of 18.3% range from 55 Jm−2 to 82 Jm−2. The fracture of coarse cementite plates was found to not to be responsible for the cleavage fracture initiation in case of both steels.",
publisher = "MDPI",
journal = "Materials",
title = "Determining the role of acicular ferrite carbides in cleavage fracture crack Initiation for two medium carbon microalloyed steels",
number = "22",
volume = "16",
doi = "10.3390/ma16227192"
}
Jovanović, G., Glišić, D., Dikić, S., Međo, B., Marković, B., Vuković, N.,& Radović, N.. (2023). Determining the role of acicular ferrite carbides in cleavage fracture crack Initiation for two medium carbon microalloyed steels. in Materials
MDPI., 16(22).
https://doi.org/10.3390/ma16227192
Jovanović G, Glišić D, Dikić S, Međo B, Marković B, Vuković N, Radović N. Determining the role of acicular ferrite carbides in cleavage fracture crack Initiation for two medium carbon microalloyed steels. in Materials. 2023;16(22).
doi:10.3390/ma16227192 .
Jovanović, Gvozden, Glišić, Dragomir, Dikić, Stefan, Međo, Bojan, Marković, Branislav, Vuković, Nikola, Radović, Nenad, "Determining the role of acicular ferrite carbides in cleavage fracture crack Initiation for two medium carbon microalloyed steels" in Materials, 16, no. 22 (2023),
https://doi.org/10.3390/ma16227192 . .

REE extraction from hyperaccumulating plants: challenges and prospects

Ranđelović, Dragana; Jovanović, Gvozden; Marković, Branislav; Sokić, Miroslav

(Belgrade : Association of Metallurgical Engineers of Serbia, 2023)

TY  - CONF
AU  - Ranđelović, Dragana
AU  - Jovanović, Gvozden
AU  - Marković, Branislav
AU  - Sokić, Miroslav
PY  - 2023
UR  - https://ritnms.itnms.ac.rs/handle/123456789/947
AB  - Phytomining although predominantly in its early stages on the broader scientific scope of investigation has garnered
interest in metals such as Ni, Au, Zn or REE. Rare earth elements (REE) are commonly defined as the 15 lanthanides
with the addition of Sc and Y. Since studies of other hyperaccumulating plant species have been conducted before, similar techniques were tried with REE. With the concentration threshold at 0.1 wt% of the dry biomass there have been identified about 22 plant species that hyperaccumulate REE from five families (Phytolaccaceae. Gleicheniaceae, Blechnaceae, Juglandaceae, Thelypteridaceae). One of the most studied REE hyperaccumulators is Dicranopteris linearis (formerly
known as D.dichotoma), a fern native to China that grows on mine tailings. Generally, the techniques for REE
phytomining can be separated into Pyrometallurgy, Hydrometallurgy, Biometallurgy and Novel approaches. Currently most of the research is still focusing on the optimal utilization of various hiperaccumulators and the enchantment of REE extraction from the soil as well as from the enriched biomass. Since recovery of REEs via phytomining is just in its
infancy further multidisciplinary investigations are needed, especially when it comes to valorization and REE recovery.
This paper presents a quick review for the concept of REE phytomining, current state of research, challenges and
prospects.
PB  - Belgrade : Association of Metallurgical Engineers of Serbia
C3  - 5th Metallurgical & Materials Engineering Congress of South-East Europe MME SEE 2023
T1  - REE extraction from hyperaccumulating plants: challenges and prospects
EP  - 43
SP  - 37
ER  - 
@conference{
author = "Ranđelović, Dragana and Jovanović, Gvozden and Marković, Branislav and Sokić, Miroslav",
year = "2023",
abstract = "Phytomining although predominantly in its early stages on the broader scientific scope of investigation has garnered
interest in metals such as Ni, Au, Zn or REE. Rare earth elements (REE) are commonly defined as the 15 lanthanides
with the addition of Sc and Y. Since studies of other hyperaccumulating plant species have been conducted before, similar techniques were tried with REE. With the concentration threshold at 0.1 wt% of the dry biomass there have been identified about 22 plant species that hyperaccumulate REE from five families (Phytolaccaceae. Gleicheniaceae, Blechnaceae, Juglandaceae, Thelypteridaceae). One of the most studied REE hyperaccumulators is Dicranopteris linearis (formerly
known as D.dichotoma), a fern native to China that grows on mine tailings. Generally, the techniques for REE
phytomining can be separated into Pyrometallurgy, Hydrometallurgy, Biometallurgy and Novel approaches. Currently most of the research is still focusing on the optimal utilization of various hiperaccumulators and the enchantment of REE extraction from the soil as well as from the enriched biomass. Since recovery of REEs via phytomining is just in its
infancy further multidisciplinary investigations are needed, especially when it comes to valorization and REE recovery.
This paper presents a quick review for the concept of REE phytomining, current state of research, challenges and
prospects.",
publisher = "Belgrade : Association of Metallurgical Engineers of Serbia",
journal = "5th Metallurgical & Materials Engineering Congress of South-East Europe MME SEE 2023",
title = "REE extraction from hyperaccumulating plants: challenges and prospects",
pages = "43-37"
}
Ranđelović, D., Jovanović, G., Marković, B.,& Sokić, M.. (2023). REE extraction from hyperaccumulating plants: challenges and prospects. in 5th Metallurgical & Materials Engineering Congress of South-East Europe MME SEE 2023
Belgrade : Association of Metallurgical Engineers of Serbia., 37-43.
Ranđelović D, Jovanović G, Marković B, Sokić M. REE extraction from hyperaccumulating plants: challenges and prospects. in 5th Metallurgical & Materials Engineering Congress of South-East Europe MME SEE 2023. 2023;:37-43..
Ranđelović, Dragana, Jovanović, Gvozden, Marković, Branislav, Sokić, Miroslav, "REE extraction from hyperaccumulating plants: challenges and prospects" in 5th Metallurgical & Materials Engineering Congress of South-East Europe MME SEE 2023 (2023):37-43.

Exergy analysis of steel manufacturing in the oxygen converter

Manojlović, Vaso; Jovanović, Aleksandar; Bugarčić, Mladen; Jovanović, Gvozden; Marković, Branislav; Sokić, Miroslav

(Kosovska Mitrovica : Fakultet Tehničkih nauka, 2023)

TY  - CONF
AU  - Manojlović, Vaso
AU  - Jovanović, Aleksandar
AU  - Bugarčić, Mladen
AU  - Jovanović, Gvozden
AU  - Marković, Branislav
AU  - Sokić, Miroslav
PY  - 2023
UR  - https://ritnms.itnms.ac.rs/handle/123456789/955
AB  - In oxygen converters, molten iron from the blast furnace is refined with steel waste under oxidizing conditions [1]. The injected oxygen passes into the iron melt, after which it reacts with the impurities. Analysis of exergy losses clearly indicates the place of energy losses in the observed process, so a detailed analysis can influence the improvement of a complex process [2]. Exergy losses occur due to technological imperfections such as heat dissipation or friction and system irreversibility according to the second law of thermodynamics [3]. The concept of exergy can be used for a better understanding of the feasibility of a process, as well as for the techno-economic analysis of the process at different variations of input/operating parameters. In this work througtful calculation of exergy oxygen convertor was done. According to the obtained data, out of a total of 972.2 MJ of thermal energy, which is released by exothermic reactions in the refining process, 817.5 MJ is pure exergy and can be used, the rest is anergy that arises due to irreversibility.
PB  - Kosovska Mitrovica : Fakultet Tehničkih nauka
C3  - Jedanaesti simpozijum o termodinamici i faznim dijagramima
T1  - Exergy analysis of steel manufacturing in the oxygen converter
EP  - 54
SP  - 53
ER  - 
@conference{
author = "Manojlović, Vaso and Jovanović, Aleksandar and Bugarčić, Mladen and Jovanović, Gvozden and Marković, Branislav and Sokić, Miroslav",
year = "2023",
abstract = "In oxygen converters, molten iron from the blast furnace is refined with steel waste under oxidizing conditions [1]. The injected oxygen passes into the iron melt, after which it reacts with the impurities. Analysis of exergy losses clearly indicates the place of energy losses in the observed process, so a detailed analysis can influence the improvement of a complex process [2]. Exergy losses occur due to technological imperfections such as heat dissipation or friction and system irreversibility according to the second law of thermodynamics [3]. The concept of exergy can be used for a better understanding of the feasibility of a process, as well as for the techno-economic analysis of the process at different variations of input/operating parameters. In this work througtful calculation of exergy oxygen convertor was done. According to the obtained data, out of a total of 972.2 MJ of thermal energy, which is released by exothermic reactions in the refining process, 817.5 MJ is pure exergy and can be used, the rest is anergy that arises due to irreversibility.",
publisher = "Kosovska Mitrovica : Fakultet Tehničkih nauka",
journal = "Jedanaesti simpozijum o termodinamici i faznim dijagramima",
title = "Exergy analysis of steel manufacturing in the oxygen converter",
pages = "54-53"
}
Manojlović, V., Jovanović, A., Bugarčić, M., Jovanović, G., Marković, B.,& Sokić, M.. (2023). Exergy analysis of steel manufacturing in the oxygen converter. in Jedanaesti simpozijum o termodinamici i faznim dijagramima
Kosovska Mitrovica : Fakultet Tehničkih nauka., 53-54.
Manojlović V, Jovanović A, Bugarčić M, Jovanović G, Marković B, Sokić M. Exergy analysis of steel manufacturing in the oxygen converter. in Jedanaesti simpozijum o termodinamici i faznim dijagramima. 2023;:53-54..
Manojlović, Vaso, Jovanović, Aleksandar, Bugarčić, Mladen, Jovanović, Gvozden, Marković, Branislav, Sokić, Miroslav, "Exergy analysis of steel manufacturing in the oxygen converter" in Jedanaesti simpozijum o termodinamici i faznim dijagramima (2023):53-54.

Model Development for Casting Simulation of Railway Aluminothermic Welding

Jovanović, Gvozden; Manojlović, Vaso; Sokić, Miroslav; Delić, Alen; Gavrilovski, Milorad

(Beograd : Savez inženjera i tehničara Srbije, 2023)

TY  - JOUR
AU  - Jovanović, Gvozden
AU  - Manojlović, Vaso
AU  - Sokić, Miroslav
AU  - Delić, Alen
AU  - Gavrilovski, Milorad
PY  - 2023
UR  - https://ritnms.itnms.ac.rs/handle/123456789/942
AB  - Aluminothermic welding has been used to connect railway rails for over a century. This technique has the advantages of flexibility, weld compactness, and simplicity. External energy is not required for the procedure. Exothermic heat is produced by chemical reactions of aluminothermic elements. To create a quality welded connection, the mold and pouring system must provide uniform pouring of hot steel
without turbulence, even heat dissipation or cooling, and an acceptable micro and macro structure of steel free of internal and external faults. The design of the mould was constantly changing, necessitating costly industrial experimentation. As a result, the mould's design was constantly evolving, necessitating the use of costly experimental procedures in industrial settings. The latest iteration of the model the
casting cavity was improved by adding hoes in the sand and putting rails on both sides in order to more aquratly simuate heat transfer. Software programs are emulating conventional casting procedures for thermite steel casting in welded railway connections to save money and effort on costly and timeconsuming industrial testing. For the 49E1 rail, NovaFlow & Solid CV were utilized to simulate casting thermite steel in the mould cavity or weld junction.
PB  - Beograd : Savez inženjera i tehničara Srbije
T2  - Tehnika
T1  - Model Development for Casting Simulation of Railway Aluminothermic Welding
EP  - 430
IS  - 4
SP  - 425
VL  - 78
DO  - 10.5937/tehnika2304425J
ER  - 
@article{
author = "Jovanović, Gvozden and Manojlović, Vaso and Sokić, Miroslav and Delić, Alen and Gavrilovski, Milorad",
year = "2023",
abstract = "Aluminothermic welding has been used to connect railway rails for over a century. This technique has the advantages of flexibility, weld compactness, and simplicity. External energy is not required for the procedure. Exothermic heat is produced by chemical reactions of aluminothermic elements. To create a quality welded connection, the mold and pouring system must provide uniform pouring of hot steel
without turbulence, even heat dissipation or cooling, and an acceptable micro and macro structure of steel free of internal and external faults. The design of the mould was constantly changing, necessitating costly industrial experimentation. As a result, the mould's design was constantly evolving, necessitating the use of costly experimental procedures in industrial settings. The latest iteration of the model the
casting cavity was improved by adding hoes in the sand and putting rails on both sides in order to more aquratly simuate heat transfer. Software programs are emulating conventional casting procedures for thermite steel casting in welded railway connections to save money and effort on costly and timeconsuming industrial testing. For the 49E1 rail, NovaFlow & Solid CV were utilized to simulate casting thermite steel in the mould cavity or weld junction.",
publisher = "Beograd : Savez inženjera i tehničara Srbije",
journal = "Tehnika",
title = "Model Development for Casting Simulation of Railway Aluminothermic Welding",
pages = "430-425",
number = "4",
volume = "78",
doi = "10.5937/tehnika2304425J"
}
Jovanović, G., Manojlović, V., Sokić, M., Delić, A.,& Gavrilovski, M.. (2023). Model Development for Casting Simulation of Railway Aluminothermic Welding. in Tehnika
Beograd : Savez inženjera i tehničara Srbije., 78(4), 425-430.
https://doi.org/10.5937/tehnika2304425J
Jovanović G, Manojlović V, Sokić M, Delić A, Gavrilovski M. Model Development for Casting Simulation of Railway Aluminothermic Welding. in Tehnika. 2023;78(4):425-430.
doi:10.5937/tehnika2304425J .
Jovanović, Gvozden, Manojlović, Vaso, Sokić, Miroslav, Delić, Alen, Gavrilovski, Milorad, "Model Development for Casting Simulation of Railway Aluminothermic Welding" in Tehnika, 78, no. 4 (2023):425-430,
https://doi.org/10.5937/tehnika2304425J . .

Evaluation of parameters for the production of Al–WO3 composites

Anđić, Dimitrije; Manojlović, Vaso; Kamberović, Željko; Marković, Branislav; Gajić, Nataša; Popović, Miljana; Jovanović, Gvozden

(Belgrade : Association of Metallurgical Engineers of Serbia, 2023)

TY  - CONF
AU  - Anđić, Dimitrije
AU  - Manojlović, Vaso
AU  - Kamberović, Željko
AU  - Marković, Branislav
AU  - Gajić, Nataša
AU  - Popović, Miljana
AU  - Jovanović, Gvozden
PY  - 2023
UR  - https://ritnms.itnms.ac.rs/handle/123456789/949
AB  - The paper presents the results of the analysis of the influence of the synthesis parameters on obtaining the composite
system (WAl12 + Al2O3)/Al with improved mechanical properties. The starting powders of Al and WO3 were
homogenized until reaching the required composition with 1%, 2%, 5% and 7% WO3. After homogenization,
the obtained samples were pressed under a pressure of 10 MPa. The sintering of the obtained samples was performed
in an argon atmosphere at temperatures of 550 oC, 585 oC, 615 oC and 650 oC for 20, 40 and 60 minutes. As a result
of the test, it was concluded that the sintering temperature, as well as the sintering time, do not have a significant effect
on the increase in hardness of these composites. The main parameter that affects the increase in strength of these
composites is the WO3 content. With an increase in the WO3 content, there is an increase in the hardness of
the composite.
PB  - Belgrade : Association of Metallurgical Engineers of Serbia
C3  - 5th Metallurgical & Materials Engineering Congress of South-East Europe MME SEE 2023
T1  - Evaluation of parameters for the production of Al–WO3 composites
EP  - 51
SP  - 51
ER  - 
@conference{
author = "Anđić, Dimitrije and Manojlović, Vaso and Kamberović, Željko and Marković, Branislav and Gajić, Nataša and Popović, Miljana and Jovanović, Gvozden",
year = "2023",
abstract = "The paper presents the results of the analysis of the influence of the synthesis parameters on obtaining the composite
system (WAl12 + Al2O3)/Al with improved mechanical properties. The starting powders of Al and WO3 were
homogenized until reaching the required composition with 1%, 2%, 5% and 7% WO3. After homogenization,
the obtained samples were pressed under a pressure of 10 MPa. The sintering of the obtained samples was performed
in an argon atmosphere at temperatures of 550 oC, 585 oC, 615 oC and 650 oC for 20, 40 and 60 minutes. As a result
of the test, it was concluded that the sintering temperature, as well as the sintering time, do not have a significant effect
on the increase in hardness of these composites. The main parameter that affects the increase in strength of these
composites is the WO3 content. With an increase in the WO3 content, there is an increase in the hardness of
the composite.",
publisher = "Belgrade : Association of Metallurgical Engineers of Serbia",
journal = "5th Metallurgical & Materials Engineering Congress of South-East Europe MME SEE 2023",
title = "Evaluation of parameters for the production of Al–WO3 composites",
pages = "51-51"
}
Anđić, D., Manojlović, V., Kamberović, Ž., Marković, B., Gajić, N., Popović, M.,& Jovanović, G.. (2023). Evaluation of parameters for the production of Al–WO3 composites. in 5th Metallurgical & Materials Engineering Congress of South-East Europe MME SEE 2023
Belgrade : Association of Metallurgical Engineers of Serbia., 51-51.
Anđić D, Manojlović V, Kamberović Ž, Marković B, Gajić N, Popović M, Jovanović G. Evaluation of parameters for the production of Al–WO3 composites. in 5th Metallurgical & Materials Engineering Congress of South-East Europe MME SEE 2023. 2023;:51-51..
Anđić, Dimitrije, Manojlović, Vaso, Kamberović, Željko, Marković, Branislav, Gajić, Nataša, Popović, Miljana, Jovanović, Gvozden, "Evaluation of parameters for the production of Al–WO3 composites" in 5th Metallurgical & Materials Engineering Congress of South-East Europe MME SEE 2023 (2023):51-51.

Nanoplastika u vodenoj sredini - poreklo, separacija i karakterizacija - pregled

Milojkov, Dušan; Mitrović, Angelina; Smiljanić, Danijela; Jovanović, Gvozden; Sokić, Miroslav

(Beograd : Savez inženjera i tehničara Srbije, 2023)

TY  - JOUR
AU  - Milojkov, Dušan
AU  - Mitrović, Angelina
AU  - Smiljanić, Danijela
AU  - Jovanović, Gvozden
AU  - Sokić, Miroslav
PY  - 2023
UR  - https://ritnms.itnms.ac.rs/handle/123456789/651
AB  - Naučnici su otkrili plastiku ranih 1900-ih, ali nisu shvatili kakve štetne efekte njena fragmentacija može imati na životnu sredinu 100 godina kasnije. Konkretno, čestice nanoplastike (NP) veličine od 1 do 100 nm mogu izazvati velike probleme u živom svetu zbog svoje velike specifične površine za adsorpciju drugih zagađujućih materija iz vode i njihove dalje bioakumulacije kroz lanac ishrane. Ne postoji poseban metod za identifikaciju, karakterizaciju i kvantifikaciju nanoplastike u vodenoj sredini. Iako mnoge metode razvijene za proučavanje mikroplastike nisu direktno primenljive na nanoplastiku, konvencionalne metode karakterizacije nanoplastike su obično zamorne jer proučavaju pojedinačne nanočestice u izolaciji. Pošto nanoplastika koja je rezultat razgradnje mikroplastike ima drugačija svojstva od sintetisanih plastičnih nanočestica, potrebno je razviti nove tehnike koje će nam pomoći da bolje razumemo ozbiljnost problema nanoplastike. Nanoplastika se može izolovati iz vodenog okruženja kombinacijom filtera i ultracentrifugiranja. U novijim publikacijama se navodi da će kombinovanje mikroskopije i spektroskopije, uz podršku hemometrijskih tehnika, omogućiti bolje razumevanje ponašanja čestica nanoplastike u životnoj sredini i organizmima. Velike nade se polažu u mikroskopiju u kombinaciji sa neuronskim mrežama za kvantifikaciju i karakterizaciju nanoplastike u složenim sistemima. Ovaj rad opisuje puteve degradacije plastike i formiranje nanoplastike u vodenim sredinama, kao i moguće metode za odvajanje i karakterizaciju nanoplastike u odnosu na nedavne publikacije.
AB  - Scientists discovered plastic in the early 1900s, but didn't realize the detrimental effects its fragmentation could have on the environment 100 years later. In particular, nanoplastics (NPs) particles ranging in size from 1 to 100 nm can cause major problems in the living world due to their high specific surface area for the adsorption other polluting substances from water, and their further bioaccumulation through the food chain. There is no distinctive method to identify, characterize, and quantify nanoplastics in aquatic environments. Although many of the methods developed to study microplastics are not directly applicable to nanoplastics, conventional methods of characterizing nanoplastics are usually tedious because they study individual nanoparticles in isolation. Since nanoplastics resulting from the decomposition of microplastics have different properties than engineering plastic nanoparticles, new techniques need to be developed to help us better understand the seriousness of the nanoplastic problem. Nanoplastic can be isolated from the water environment by a combination of filters and ultracentrifugation. A recent publications states that combining microscopy and spectroscopy, supported by chemometric techniques, will alow a better understand he behavior of nanoplastic particles in the environment and organisms. High hopes are placed on microscopies combined with neural networks for the quantification and characterization of nanoplastics in complex systems. This article describes the degradation pathways of plastics and the formation of nanoplastics in aquatic environments, and possible methods for separation and characterization of nanoplastics in relation to recent publications.
PB  - Beograd : Savez inženjera i tehničara Srbije
T2  - Tehnika
T1  - Nanoplastika u vodenoj sredini - poreklo, separacija i karakterizacija - pregled
T1  - Nanoplastics in aquatic environments: Origin, separation and characterization: Review
EP  - 108
IS  - 1
SP  - 103
VL  - 78
DO  - 10.5937/tehnika2301103M
UR  - conv_39
ER  - 
@article{
author = "Milojkov, Dušan and Mitrović, Angelina and Smiljanić, Danijela and Jovanović, Gvozden and Sokić, Miroslav",
year = "2023",
abstract = "Naučnici su otkrili plastiku ranih 1900-ih, ali nisu shvatili kakve štetne efekte njena fragmentacija može imati na životnu sredinu 100 godina kasnije. Konkretno, čestice nanoplastike (NP) veličine od 1 do 100 nm mogu izazvati velike probleme u živom svetu zbog svoje velike specifične površine za adsorpciju drugih zagađujućih materija iz vode i njihove dalje bioakumulacije kroz lanac ishrane. Ne postoji poseban metod za identifikaciju, karakterizaciju i kvantifikaciju nanoplastike u vodenoj sredini. Iako mnoge metode razvijene za proučavanje mikroplastike nisu direktno primenljive na nanoplastiku, konvencionalne metode karakterizacije nanoplastike su obično zamorne jer proučavaju pojedinačne nanočestice u izolaciji. Pošto nanoplastika koja je rezultat razgradnje mikroplastike ima drugačija svojstva od sintetisanih plastičnih nanočestica, potrebno je razviti nove tehnike koje će nam pomoći da bolje razumemo ozbiljnost problema nanoplastike. Nanoplastika se može izolovati iz vodenog okruženja kombinacijom filtera i ultracentrifugiranja. U novijim publikacijama se navodi da će kombinovanje mikroskopije i spektroskopije, uz podršku hemometrijskih tehnika, omogućiti bolje razumevanje ponašanja čestica nanoplastike u životnoj sredini i organizmima. Velike nade se polažu u mikroskopiju u kombinaciji sa neuronskim mrežama za kvantifikaciju i karakterizaciju nanoplastike u složenim sistemima. Ovaj rad opisuje puteve degradacije plastike i formiranje nanoplastike u vodenim sredinama, kao i moguće metode za odvajanje i karakterizaciju nanoplastike u odnosu na nedavne publikacije., Scientists discovered plastic in the early 1900s, but didn't realize the detrimental effects its fragmentation could have on the environment 100 years later. In particular, nanoplastics (NPs) particles ranging in size from 1 to 100 nm can cause major problems in the living world due to their high specific surface area for the adsorption other polluting substances from water, and their further bioaccumulation through the food chain. There is no distinctive method to identify, characterize, and quantify nanoplastics in aquatic environments. Although many of the methods developed to study microplastics are not directly applicable to nanoplastics, conventional methods of characterizing nanoplastics are usually tedious because they study individual nanoparticles in isolation. Since nanoplastics resulting from the decomposition of microplastics have different properties than engineering plastic nanoparticles, new techniques need to be developed to help us better understand the seriousness of the nanoplastic problem. Nanoplastic can be isolated from the water environment by a combination of filters and ultracentrifugation. A recent publications states that combining microscopy and spectroscopy, supported by chemometric techniques, will alow a better understand he behavior of nanoplastic particles in the environment and organisms. High hopes are placed on microscopies combined with neural networks for the quantification and characterization of nanoplastics in complex systems. This article describes the degradation pathways of plastics and the formation of nanoplastics in aquatic environments, and possible methods for separation and characterization of nanoplastics in relation to recent publications.",
publisher = "Beograd : Savez inženjera i tehničara Srbije",
journal = "Tehnika",
title = "Nanoplastika u vodenoj sredini - poreklo, separacija i karakterizacija - pregled, Nanoplastics in aquatic environments: Origin, separation and characterization: Review",
pages = "108-103",
number = "1",
volume = "78",
doi = "10.5937/tehnika2301103M",
url = "conv_39"
}
Milojkov, D., Mitrović, A., Smiljanić, D., Jovanović, G.,& Sokić, M.. (2023). Nanoplastika u vodenoj sredini - poreklo, separacija i karakterizacija - pregled. in Tehnika
Beograd : Savez inženjera i tehničara Srbije., 78(1), 103-108.
https://doi.org/10.5937/tehnika2301103M
conv_39
Milojkov D, Mitrović A, Smiljanić D, Jovanović G, Sokić M. Nanoplastika u vodenoj sredini - poreklo, separacija i karakterizacija - pregled. in Tehnika. 2023;78(1):103-108.
doi:10.5937/tehnika2301103M
conv_39 .
Milojkov, Dušan, Mitrović, Angelina, Smiljanić, Danijela, Jovanović, Gvozden, Sokić, Miroslav, "Nanoplastika u vodenoj sredini - poreklo, separacija i karakterizacija - pregled" in Tehnika, 78, no. 1 (2023):103-108,
https://doi.org/10.5937/tehnika2301103M .,
conv_39 .

Influence of mold preheating on railway aluminothermic welding casting simulation

Jovanović, Gvozden; Manojlović, Vaso; Sokić, Miroslav; Delić, Alen; Gavrilovski, Milorad

(Belgrade : Association of Metallurgical Engineers of Serbia, 2023)

TY  - CONF
AU  - Jovanović, Gvozden
AU  - Manojlović, Vaso
AU  - Sokić, Miroslav
AU  - Delić, Alen
AU  - Gavrilovski, Milorad
PY  - 2023
UR  - https://ritnms.itnms.ac.rs/handle/123456789/943
AB  - Railway rails have been linked using the aluminothermic welding process for over a century. This method has several
advantages, including flexibility, compactness of the weld, and ease of execution. It is not necessary to employ outside
energy to complete the procedure. It is provided by the exothermic effect of the chemical reactions of the aluminothermic combination's elements. The design of the mold with the pouring system, which should ensure even pouring of thermal steel without turbulence, then even heat dissipation or cooling in order to obtain an appropriate micro and macro structure of steel, free of internal and external defects, is an important factor in producing the required quality welded joint. As a result, the mold's design was constantly evolving, necessitating the use of costly experimental procedures in industrial settings. In this iteration of the model the casting cavity was improved by adding hoes in the sand and putting rails on both sides in order to more aquratly simuate heat transfer. Software programs are being used to simulate conventional
casting procedures that can be used in the casting of thermite steel during the fabrication of welded railway connections
in order to prevent costly and time-consuming industrial experimentation. The NovaFlow & Solid CV software package
was used to simulate casting thermite steel in the mold cavity, i.e. in the weld joint, for the 49E1 rail.
PB  - Belgrade : Association of Metallurgical Engineers of Serbia
C3  - 5th Metallurgical & Materials Engineering Congress of South-East Europe MME SEE 2023
T1  - Influence of mold preheating on railway aluminothermic welding casting simulation
EP  - 314
SP  - 307
ER  - 
@conference{
author = "Jovanović, Gvozden and Manojlović, Vaso and Sokić, Miroslav and Delić, Alen and Gavrilovski, Milorad",
year = "2023",
abstract = "Railway rails have been linked using the aluminothermic welding process for over a century. This method has several
advantages, including flexibility, compactness of the weld, and ease of execution. It is not necessary to employ outside
energy to complete the procedure. It is provided by the exothermic effect of the chemical reactions of the aluminothermic combination's elements. The design of the mold with the pouring system, which should ensure even pouring of thermal steel without turbulence, then even heat dissipation or cooling in order to obtain an appropriate micro and macro structure of steel, free of internal and external defects, is an important factor in producing the required quality welded joint. As a result, the mold's design was constantly evolving, necessitating the use of costly experimental procedures in industrial settings. In this iteration of the model the casting cavity was improved by adding hoes in the sand and putting rails on both sides in order to more aquratly simuate heat transfer. Software programs are being used to simulate conventional
casting procedures that can be used in the casting of thermite steel during the fabrication of welded railway connections
in order to prevent costly and time-consuming industrial experimentation. The NovaFlow & Solid CV software package
was used to simulate casting thermite steel in the mold cavity, i.e. in the weld joint, for the 49E1 rail.",
publisher = "Belgrade : Association of Metallurgical Engineers of Serbia",
journal = "5th Metallurgical & Materials Engineering Congress of South-East Europe MME SEE 2023",
title = "Influence of mold preheating on railway aluminothermic welding casting simulation",
pages = "314-307"
}
Jovanović, G., Manojlović, V., Sokić, M., Delić, A.,& Gavrilovski, M.. (2023). Influence of mold preheating on railway aluminothermic welding casting simulation. in 5th Metallurgical & Materials Engineering Congress of South-East Europe MME SEE 2023
Belgrade : Association of Metallurgical Engineers of Serbia., 307-314.
Jovanović G, Manojlović V, Sokić M, Delić A, Gavrilovski M. Influence of mold preheating on railway aluminothermic welding casting simulation. in 5th Metallurgical & Materials Engineering Congress of South-East Europe MME SEE 2023. 2023;:307-314..
Jovanović, Gvozden, Manojlović, Vaso, Sokić, Miroslav, Delić, Alen, Gavrilovski, Milorad, "Influence of mold preheating on railway aluminothermic welding casting simulation" in 5th Metallurgical & Materials Engineering Congress of South-East Europe MME SEE 2023 (2023):307-314.

Influence of mould preheating on solidification stress of railway aluminothermic welding by casting simulation aluminothermic welding by casting simulation

Jovanović, Gvozden; Manojlović, Vaso; Sokić, Miroslav; Delić, Alen; Gavrilovski, Milorad

(Kosovska Mitrovica : Fakultet Tehničkih nauka, 2023)

TY  - CONF
AU  - Jovanović, Gvozden
AU  - Manojlović, Vaso
AU  - Sokić, Miroslav
AU  - Delić, Alen
AU  - Gavrilovski, Milorad
PY  - 2023
UR  - https://ritnms.itnms.ac.rs/handle/123456789/941
AB  - Aluminothermic welding has been used to connect railway rails for over a century. This method has several advantages, including its versatility, the tightness of the weld it creates, and its ease of execution. To complete the procedure, no further power source is necessary. The design of the mold with the pouring system, which should ensure even pouring of thermal steel without turbulence, then even heat dissipation or cooling to obtain an appropriat  micro and acro structure of steel free of internal and external defects, is one of several factors that contribute to a quality welded joint. As a result, costly experimental techniques in industrial settings were necessary to keep up with the ever-changing mould design. The model design was upgraded in comparison to the previous version [1], and will be imroved even further.The two sets of solid steel rails put on either side of the casting mould will be adjusted as heating media within the mould material category in the future, bringing the model closer to reality. As a result, cooling and heating temperatures will be more evenly distributed. Stress and strain modeling were performed to the preheated model to provide a more complete understanding of how shrinkage is related to stress. In future iterations of the model, we will either move the heat source to its right place approximately 40 cm above ground or adjust the temperature, diameter, and gas at the current site to more exactly reproduce real-life circumstances. Furthermore, during simulation setup, the
replace material function may be used to model a new component that represents the divider that will be changed between air and silica sand material at the end of
prehearing. Software programs are being used to simulate conventional casting procedures that may be used in the casting of thermite steel during the fabrication
of welded railway connections in order to prevent costly and time-consuming
industrial experimentation. The NovaFlow & Solid CV software suite [2] was used
to simulate casting thermite steel in the mold cavity or weld joint for the 49E1 rail.
PB  - Kosovska Mitrovica : Fakultet Tehničkih nauka
C3  - Jedanaesti simpozijum o termodinamici i faznim dijagramima
T1  - Influence of mould preheating on solidification stress of railway aluminothermic welding by casting simulation aluminothermic welding by casting simulation
EP  - 52
SP  - 51
ER  - 
@conference{
author = "Jovanović, Gvozden and Manojlović, Vaso and Sokić, Miroslav and Delić, Alen and Gavrilovski, Milorad",
year = "2023",
abstract = "Aluminothermic welding has been used to connect railway rails for over a century. This method has several advantages, including its versatility, the tightness of the weld it creates, and its ease of execution. To complete the procedure, no further power source is necessary. The design of the mold with the pouring system, which should ensure even pouring of thermal steel without turbulence, then even heat dissipation or cooling to obtain an appropriat  micro and acro structure of steel free of internal and external defects, is one of several factors that contribute to a quality welded joint. As a result, costly experimental techniques in industrial settings were necessary to keep up with the ever-changing mould design. The model design was upgraded in comparison to the previous version [1], and will be imroved even further.The two sets of solid steel rails put on either side of the casting mould will be adjusted as heating media within the mould material category in the future, bringing the model closer to reality. As a result, cooling and heating temperatures will be more evenly distributed. Stress and strain modeling were performed to the preheated model to provide a more complete understanding of how shrinkage is related to stress. In future iterations of the model, we will either move the heat source to its right place approximately 40 cm above ground or adjust the temperature, diameter, and gas at the current site to more exactly reproduce real-life circumstances. Furthermore, during simulation setup, the
replace material function may be used to model a new component that represents the divider that will be changed between air and silica sand material at the end of
prehearing. Software programs are being used to simulate conventional casting procedures that may be used in the casting of thermite steel during the fabrication
of welded railway connections in order to prevent costly and time-consuming
industrial experimentation. The NovaFlow & Solid CV software suite [2] was used
to simulate casting thermite steel in the mold cavity or weld joint for the 49E1 rail.",
publisher = "Kosovska Mitrovica : Fakultet Tehničkih nauka",
journal = "Jedanaesti simpozijum o termodinamici i faznim dijagramima",
title = "Influence of mould preheating on solidification stress of railway aluminothermic welding by casting simulation aluminothermic welding by casting simulation",
pages = "52-51"
}
Jovanović, G., Manojlović, V., Sokić, M., Delić, A.,& Gavrilovski, M.. (2023). Influence of mould preheating on solidification stress of railway aluminothermic welding by casting simulation aluminothermic welding by casting simulation. in Jedanaesti simpozijum o termodinamici i faznim dijagramima
Kosovska Mitrovica : Fakultet Tehničkih nauka., 51-52.
Jovanović G, Manojlović V, Sokić M, Delić A, Gavrilovski M. Influence of mould preheating on solidification stress of railway aluminothermic welding by casting simulation aluminothermic welding by casting simulation. in Jedanaesti simpozijum o termodinamici i faznim dijagramima. 2023;:51-52..
Jovanović, Gvozden, Manojlović, Vaso, Sokić, Miroslav, Delić, Alen, Gavrilovski, Milorad, "Influence of mould preheating on solidification stress of railway aluminothermic welding by casting simulation aluminothermic welding by casting simulation" in Jedanaesti simpozijum o termodinamici i faznim dijagramima (2023):51-52.

Identifikacija metoda za separaciju i karakterizaciju nanoplastike iz vodenih sredina / Identification of methods for separation and characterisation of nanoplastic from aquatic environments

Milojkov, Dušan; Mitrović, Angelina; Smiljanić, Danijela; Jovanović, Gvozden; Sokić, Miroslav

(Beograd : Savez inženjera i tehničara Srbije, 2022)

TY  - CONF
AU  - Milojkov, Dušan
AU  - Mitrović, Angelina
AU  - Smiljanić, Danijela
AU  - Jovanović, Gvozden
AU  - Sokić, Miroslav
PY  - 2022
UR  - https://ritnms.itnms.ac.rs/handle/123456789/989
AB  - Zagađenje vodenih resursa mikro- i nano-plastikom je prepoznato kao globalni problem. Trenutno ne postoje dostupne specifične metode za identifikaciju, karakterizaciju i kvantifikaciju nanoplastike u vodenim sredinama. Mnoge od metodologija razvijenih za analizu mikroplastike ne mogu se direktno primeniti na nanoplastiku, dok konvencionalne
metode karakterizacije nanoplastike obično izoluju i proučavaju pojedinačne nanočestice, što može biti naporan i dugotrajan proces. Korišćenjem mikroskopskih tehnika u kombinaciji sa spektroskopijom, moguće je ubrzati proces analize, ispitati morfologiju i veličinu čestica i istovremeno identifikovati hemiju. Pošto nanoplastika nastala degradacijom mikroplastike
ima drugačija svojstva od sintetisanih nanočestica plastike, neophodno je kreirati nove analitičke i mikroskopske tehnike koje će pomoći da se bolje razume ozbiljnost problema nanoplastike. Ovaj rad ima za cilj da identifikuje metode koje bi mogle da se primene za odvajanje i karakterizaciju nanoplastike iz vodenih sredina.
AB  - Pollution of water resources with micro- and nanoplastics is recognized as a global problem. Currently, there are no specific methods available for the identification, characterization and quantification of nanoplastics in aquatic environments. Many of the methodologies developed for the analysis of microplastics cannot be directly applied to nanoplastics, while conventional nanoplastic characterization methods usually isolate and study individual nanoparticles, which can be a laborious and time-consuming process. By using microscopic techniques combined with spectroscopy, it is possible to speed up the analysis process, examine the morphology and size of the particle and identify the chemistry at the same time. Since nanoplastics created by the degradation of microplastics have
different properties than synthesized plastic nanoparticles, it is necessary to create new analytical and microscopic techniques that will help to better understand the seriousness of the nanoplastics problem. This work aims to identify methods that could be applied for the separation and characterization of nanoplastics from aquatic environments.
PB  - Beograd : Savez inženjera i tehničara Srbije
C3  - 43. Međunarodna konferencija Vodovod i kanalizacija '22, Zrenjanin
T1  - Identifikacija metoda za separaciju i karakterizaciju nanoplastike iz vodenih sredina / Identification of methods for separation and characterisation of nanoplastic from aquatic environments
EP  - 115
SP  - 110
ER  - 
@conference{
author = "Milojkov, Dušan and Mitrović, Angelina and Smiljanić, Danijela and Jovanović, Gvozden and Sokić, Miroslav",
year = "2022",
abstract = "Zagađenje vodenih resursa mikro- i nano-plastikom je prepoznato kao globalni problem. Trenutno ne postoje dostupne specifične metode za identifikaciju, karakterizaciju i kvantifikaciju nanoplastike u vodenim sredinama. Mnoge od metodologija razvijenih za analizu mikroplastike ne mogu se direktno primeniti na nanoplastiku, dok konvencionalne
metode karakterizacije nanoplastike obično izoluju i proučavaju pojedinačne nanočestice, što može biti naporan i dugotrajan proces. Korišćenjem mikroskopskih tehnika u kombinaciji sa spektroskopijom, moguće je ubrzati proces analize, ispitati morfologiju i veličinu čestica i istovremeno identifikovati hemiju. Pošto nanoplastika nastala degradacijom mikroplastike
ima drugačija svojstva od sintetisanih nanočestica plastike, neophodno je kreirati nove analitičke i mikroskopske tehnike koje će pomoći da se bolje razume ozbiljnost problema nanoplastike. Ovaj rad ima za cilj da identifikuje metode koje bi mogle da se primene za odvajanje i karakterizaciju nanoplastike iz vodenih sredina., Pollution of water resources with micro- and nanoplastics is recognized as a global problem. Currently, there are no specific methods available for the identification, characterization and quantification of nanoplastics in aquatic environments. Many of the methodologies developed for the analysis of microplastics cannot be directly applied to nanoplastics, while conventional nanoplastic characterization methods usually isolate and study individual nanoparticles, which can be a laborious and time-consuming process. By using microscopic techniques combined with spectroscopy, it is possible to speed up the analysis process, examine the morphology and size of the particle and identify the chemistry at the same time. Since nanoplastics created by the degradation of microplastics have
different properties than synthesized plastic nanoparticles, it is necessary to create new analytical and microscopic techniques that will help to better understand the seriousness of the nanoplastics problem. This work aims to identify methods that could be applied for the separation and characterization of nanoplastics from aquatic environments.",
publisher = "Beograd : Savez inženjera i tehničara Srbije",
journal = "43. Međunarodna konferencija Vodovod i kanalizacija '22, Zrenjanin",
title = "Identifikacija metoda za separaciju i karakterizaciju nanoplastike iz vodenih sredina / Identification of methods for separation and characterisation of nanoplastic from aquatic environments",
pages = "115-110"
}
Milojkov, D., Mitrović, A., Smiljanić, D., Jovanović, G.,& Sokić, M.. (2022). Identifikacija metoda za separaciju i karakterizaciju nanoplastike iz vodenih sredina / Identification of methods for separation and characterisation of nanoplastic from aquatic environments. in 43. Međunarodna konferencija Vodovod i kanalizacija '22, Zrenjanin
Beograd : Savez inženjera i tehničara Srbije., 110-115.
Milojkov D, Mitrović A, Smiljanić D, Jovanović G, Sokić M. Identifikacija metoda za separaciju i karakterizaciju nanoplastike iz vodenih sredina / Identification of methods for separation and characterisation of nanoplastic from aquatic environments. in 43. Međunarodna konferencija Vodovod i kanalizacija '22, Zrenjanin. 2022;:110-115..
Milojkov, Dušan, Mitrović, Angelina, Smiljanić, Danijela, Jovanović, Gvozden, Sokić, Miroslav, "Identifikacija metoda za separaciju i karakterizaciju nanoplastike iz vodenih sredina / Identification of methods for separation and characterisation of nanoplastic from aquatic environments" in 43. Međunarodna konferencija Vodovod i kanalizacija '22, Zrenjanin (2022):110-115.

Fitorudarenje nikla: razvoj, metode i mogućnost primene u Srbiji

Marković, Branislav; Ranđelović, Dragana; Jovanović, Gvozden; Sokić, Miroslav

(Beograd : Institut za tehnologiju nuklearnih i drugih mineralnih sirovina, 2022)

TY  - CONF
AU  - Marković, Branislav
AU  - Ranđelović, Dragana
AU  - Jovanović, Gvozden
AU  - Sokić, Miroslav
PY  - 2022
UR  - https://ritnms.itnms.ac.rs/handle/123456789/958
AB  - Razvoj industrije uticaće na potražnju i cenu nikla u narednim godinama, što otvara
mogućnost za razvoj i primenu dodatnih načina njegove eksploatacije iz sekundarnih
resursa. Fitorudarenje nikla je in situ tehnologija koja koristi biljke sa mogućnošću
hiperakumulacije ovog elementa za njegovo uklanjanje iz subekonomskih ruda. Ova studija
predstavlja analizu trenutno ustanovljenih metoda i postignutih rezultata u
hidrometalurškim postupcima pri fitorudarenju nikla, kao i mogućnost da se na terotoriji
Srbije razviju adekvatne metode i primeni ova tehnologija u praksi. Naša istraživanja su
dokazala da je moguće sintetisati soli nikla iz hiperakumulatorske vrste Odontarrhena
muralis, koja se od prirode javlja na ultramafitskim zemljištima u Srbiji. U preliminarnim
istraživanjima na domaćoj populaciji vrste koristeći ustanovljene metode, usled objektivnih
operativnih ograničenja i manje količine početne biomase dobijene su soli nikla čistoće 60%
i 73%. Obimnija istraživanja, koja podrazumevaju veće količine početne biomase i
namensku kultivaciju biljaka na odgovarajućim ultramafitskim zemljištima, neophodna su
kako bi se mogle ispitati dodatne mogućnosti za proizvodnju nikla i široke lepeze niklovih
produkata, kao i tehnološke aspekte ove proizvodnje sa posebnim naglaskom na održivost i
zaštitu životne sredine. Imajući u vidu takve benefite, kao i činjenicu da je cena nikla u
trendu porasta, fitorudarenje u budućnosti može imati značajniji udeo u proizvodnji metala
nikla i njegovih soli.
PB  - Beograd : Institut za tehnologiju nuklearnih i drugih mineralnih sirovina
C3  - „ RUDARSTVO 2022“  13. simpozijum sa međunarodnim učešćem
T1  - Fitorudarenje nikla: razvoj, metode i mogućnost primene u Srbiji
EP  - 22
SP  - 5
ER  - 
@conference{
author = "Marković, Branislav and Ranđelović, Dragana and Jovanović, Gvozden and Sokić, Miroslav",
year = "2022",
abstract = "Razvoj industrije uticaće na potražnju i cenu nikla u narednim godinama, što otvara
mogućnost za razvoj i primenu dodatnih načina njegove eksploatacije iz sekundarnih
resursa. Fitorudarenje nikla je in situ tehnologija koja koristi biljke sa mogućnošću
hiperakumulacije ovog elementa za njegovo uklanjanje iz subekonomskih ruda. Ova studija
predstavlja analizu trenutno ustanovljenih metoda i postignutih rezultata u
hidrometalurškim postupcima pri fitorudarenju nikla, kao i mogućnost da se na terotoriji
Srbije razviju adekvatne metode i primeni ova tehnologija u praksi. Naša istraživanja su
dokazala da je moguće sintetisati soli nikla iz hiperakumulatorske vrste Odontarrhena
muralis, koja se od prirode javlja na ultramafitskim zemljištima u Srbiji. U preliminarnim
istraživanjima na domaćoj populaciji vrste koristeći ustanovljene metode, usled objektivnih
operativnih ograničenja i manje količine početne biomase dobijene su soli nikla čistoće 60%
i 73%. Obimnija istraživanja, koja podrazumevaju veće količine početne biomase i
namensku kultivaciju biljaka na odgovarajućim ultramafitskim zemljištima, neophodna su
kako bi se mogle ispitati dodatne mogućnosti za proizvodnju nikla i široke lepeze niklovih
produkata, kao i tehnološke aspekte ove proizvodnje sa posebnim naglaskom na održivost i
zaštitu životne sredine. Imajući u vidu takve benefite, kao i činjenicu da je cena nikla u
trendu porasta, fitorudarenje u budućnosti može imati značajniji udeo u proizvodnji metala
nikla i njegovih soli.",
publisher = "Beograd : Institut za tehnologiju nuklearnih i drugih mineralnih sirovina",
journal = "„ RUDARSTVO 2022“  13. simpozijum sa međunarodnim učešćem",
title = "Fitorudarenje nikla: razvoj, metode i mogućnost primene u Srbiji",
pages = "22-5"
}
Marković, B., Ranđelović, D., Jovanović, G.,& Sokić, M.. (2022). Fitorudarenje nikla: razvoj, metode i mogućnost primene u Srbiji. in „ RUDARSTVO 2022“  13. simpozijum sa međunarodnim učešćem
Beograd : Institut za tehnologiju nuklearnih i drugih mineralnih sirovina., 5-22.
Marković B, Ranđelović D, Jovanović G, Sokić M. Fitorudarenje nikla: razvoj, metode i mogućnost primene u Srbiji. in „ RUDARSTVO 2022“  13. simpozijum sa međunarodnim učešćem. 2022;:5-22..
Marković, Branislav, Ranđelović, Dragana, Jovanović, Gvozden, Sokić, Miroslav, "Fitorudarenje nikla: razvoj, metode i mogućnost primene u Srbiji" in „ RUDARSTVO 2022“  13. simpozijum sa međunarodnim učešćem (2022):5-22.

The effect ultrasound sonification on nitric acid leaching of pyrolyzed printed circuit board powder

Jovanović, Gvozden; Bugarčić, Mladen; Petronijević, Nela; Stopić, Srećko; Marković, Branislav; Stanković, Srđan; Friedrich, Bernd; Sokić, Miroslav

(Belgrade : Serbian society of corrosion and materials protection (UISKOZAM), 2022)

TY  - CONF
AU  - Jovanović, Gvozden
AU  - Bugarčić, Mladen
AU  - Petronijević, Nela
AU  - Stopić, Srećko
AU  - Marković, Branislav
AU  - Stanković, Srđan
AU  - Friedrich, Bernd
AU  - Sokić, Miroslav
PY  - 2022
UR  - https://ritnms.itnms.ac.rs/handle/123456789/980
AB  - Numerous electronic devices are put out of use every day, and most of them have printed circuit boards (PCBs) that are lased and imbued with various precious and valuable metals in abundant amounts. This makes PCB an unexploited resource of the future from whom many metals such as Cu, Zn, Sn, Al, Li, Co, Nd, Pd, Pt, and Ba can be extracted. Since leaching plastic polymers can lead to the vaporization of toxic fumes, to avoid this the PCB are pyrolyzed. The PCB is crushed and the pyrolyzed product is a powder that can easily be separated into metallic and nonmetalic fractions. The aim of this work is to investigate the influence of ultrasound sonification on the nitric acid leaching of pyrolyzed printed circuit board (PPCB) powder. The impact of ultrasound sonification had a positive effect on the leaching degree for all investigated metals except for Cobalt. The biggest difference in leaching degree was for Lithium while the smallest was for platinum. Because of the complexity of the PPCB powder system overall, the measurement of oxidation-reduction potential (ORP) didn’t yield any insight into the leaching mechanism since the measured values mainly followed the expected trend due to nitric acid degradation.
PB  - Belgrade : Serbian society of corrosion and materials protection (UISKOZAM)
C3  - XXIII YuCorr International Conference
T1  - The effect ultrasound sonification on nitric acid leaching of pyrolyzed printed circuit board powder
EP  - 94
SP  - 86
ER  - 
@conference{
author = "Jovanović, Gvozden and Bugarčić, Mladen and Petronijević, Nela and Stopić, Srećko and Marković, Branislav and Stanković, Srđan and Friedrich, Bernd and Sokić, Miroslav",
year = "2022",
abstract = "Numerous electronic devices are put out of use every day, and most of them have printed circuit boards (PCBs) that are lased and imbued with various precious and valuable metals in abundant amounts. This makes PCB an unexploited resource of the future from whom many metals such as Cu, Zn, Sn, Al, Li, Co, Nd, Pd, Pt, and Ba can be extracted. Since leaching plastic polymers can lead to the vaporization of toxic fumes, to avoid this the PCB are pyrolyzed. The PCB is crushed and the pyrolyzed product is a powder that can easily be separated into metallic and nonmetalic fractions. The aim of this work is to investigate the influence of ultrasound sonification on the nitric acid leaching of pyrolyzed printed circuit board (PPCB) powder. The impact of ultrasound sonification had a positive effect on the leaching degree for all investigated metals except for Cobalt. The biggest difference in leaching degree was for Lithium while the smallest was for platinum. Because of the complexity of the PPCB powder system overall, the measurement of oxidation-reduction potential (ORP) didn’t yield any insight into the leaching mechanism since the measured values mainly followed the expected trend due to nitric acid degradation.",
publisher = "Belgrade : Serbian society of corrosion and materials protection (UISKOZAM)",
journal = "XXIII YuCorr International Conference",
title = "The effect ultrasound sonification on nitric acid leaching of pyrolyzed printed circuit board powder",
pages = "94-86"
}
Jovanović, G., Bugarčić, M., Petronijević, N., Stopić, S., Marković, B., Stanković, S., Friedrich, B.,& Sokić, M.. (2022). The effect ultrasound sonification on nitric acid leaching of pyrolyzed printed circuit board powder. in XXIII YuCorr International Conference
Belgrade : Serbian society of corrosion and materials protection (UISKOZAM)., 86-94.
Jovanović G, Bugarčić M, Petronijević N, Stopić S, Marković B, Stanković S, Friedrich B, Sokić M. The effect ultrasound sonification on nitric acid leaching of pyrolyzed printed circuit board powder. in XXIII YuCorr International Conference. 2022;:86-94..
Jovanović, Gvozden, Bugarčić, Mladen, Petronijević, Nela, Stopić, Srećko, Marković, Branislav, Stanković, Srđan, Friedrich, Bernd, Sokić, Miroslav, "The effect ultrasound sonification on nitric acid leaching of pyrolyzed printed circuit board powder" in XXIII YuCorr International Conference (2022):86-94.

Approach on recycling of printed circuit boards (PCB) via hydrometallurgical procedures: Principle and methodology

Bugarčić, Mladen; Jovanović, Gvozden; Petronijević, Nela; Marković, Branislav; Stopić, Srećko; Friedrich, Bernd; Sokić, Miroslav

(Split : University of Split, Faculty of Chemistry and Technology, 2022)

TY  - CONF
AU  - Bugarčić, Mladen
AU  - Jovanović, Gvozden
AU  - Petronijević, Nela
AU  - Marković, Branislav
AU  - Stopić, Srećko
AU  - Friedrich, Bernd
AU  - Sokić, Miroslav
PY  - 2022
UR  - https://ritnms.itnms.ac.rs/handle/123456789/986
AB  - Recent mankind demand for electronic devices is in constant upgrowth, those devices
always contain printed circuit boards (PCB) which are mainly constructed of plastics, semiconductors
and decent content of various metals. Hence, in the end-of-life of those
products, it is highly recommended to recover those materials or functionalize those waste
into other products or feed materials, in order to lessen their harmful impact on the
environment. One of the promising processing procedures is hydrometallurgical treatment,
since it is cost-effective and simple. In order to recover metals as aqueous soluble salts,
crushed and milled PCB is air-pyrolyzed and obtained powder is processed as start material
in leaching experiments. The use of concentrated aqua regia led to the passivation of solid
material and consequently impede the leaching process. Dry-digestion leaching using
concentrated sulfuric acid partially leached some metals. The highest leaching rate (≥70 %)
has been achieved using diluted sulfuric acid (for Al, Ni, Fe, Co, and rare-earth) and copper
yield was highest utilizing 2 M H2SO4 + 3 M H2O2; S/L = 0.1 g/ml. While sulfuric acid has
accomplished some results for enumerated leachates, it achieved limited success for
leaching Ba, Pb, Ag, Au, Pt and Pd. Overall findings imply that hydrometallurgical
procedures may be used but only together with previous separation techniques. That
approach would increase overall leaching with oxidizing agents and enable leaching of
noble metals.
PB  - Split : University of Split, Faculty of Chemistry and Technology
C3  - 3rd International Convention of Scientists, Specialist Employees and Students on the Topic of Environmental Protection in the Republic of Croatia - 3rd ZORH CONVENTION
T1  - Approach on recycling of printed circuit boards (PCB) via hydrometallurgical procedures: Principle and methodology
EP  - 8
SP  - 8
ER  - 
@conference{
author = "Bugarčić, Mladen and Jovanović, Gvozden and Petronijević, Nela and Marković, Branislav and Stopić, Srećko and Friedrich, Bernd and Sokić, Miroslav",
year = "2022",
abstract = "Recent mankind demand for electronic devices is in constant upgrowth, those devices
always contain printed circuit boards (PCB) which are mainly constructed of plastics, semiconductors
and decent content of various metals. Hence, in the end-of-life of those
products, it is highly recommended to recover those materials or functionalize those waste
into other products or feed materials, in order to lessen their harmful impact on the
environment. One of the promising processing procedures is hydrometallurgical treatment,
since it is cost-effective and simple. In order to recover metals as aqueous soluble salts,
crushed and milled PCB is air-pyrolyzed and obtained powder is processed as start material
in leaching experiments. The use of concentrated aqua regia led to the passivation of solid
material and consequently impede the leaching process. Dry-digestion leaching using
concentrated sulfuric acid partially leached some metals. The highest leaching rate (≥70 %)
has been achieved using diluted sulfuric acid (for Al, Ni, Fe, Co, and rare-earth) and copper
yield was highest utilizing 2 M H2SO4 + 3 M H2O2; S/L = 0.1 g/ml. While sulfuric acid has
accomplished some results for enumerated leachates, it achieved limited success for
leaching Ba, Pb, Ag, Au, Pt and Pd. Overall findings imply that hydrometallurgical
procedures may be used but only together with previous separation techniques. That
approach would increase overall leaching with oxidizing agents and enable leaching of
noble metals.",
publisher = "Split : University of Split, Faculty of Chemistry and Technology",
journal = "3rd International Convention of Scientists, Specialist Employees and Students on the Topic of Environmental Protection in the Republic of Croatia - 3rd ZORH CONVENTION",
title = "Approach on recycling of printed circuit boards (PCB) via hydrometallurgical procedures: Principle and methodology",
pages = "8-8"
}
Bugarčić, M., Jovanović, G., Petronijević, N., Marković, B., Stopić, S., Friedrich, B.,& Sokić, M.. (2022). Approach on recycling of printed circuit boards (PCB) via hydrometallurgical procedures: Principle and methodology. in 3rd International Convention of Scientists, Specialist Employees and Students on the Topic of Environmental Protection in the Republic of Croatia - 3rd ZORH CONVENTION
Split : University of Split, Faculty of Chemistry and Technology., 8-8.
Bugarčić M, Jovanović G, Petronijević N, Marković B, Stopić S, Friedrich B, Sokić M. Approach on recycling of printed circuit boards (PCB) via hydrometallurgical procedures: Principle and methodology. in 3rd International Convention of Scientists, Specialist Employees and Students on the Topic of Environmental Protection in the Republic of Croatia - 3rd ZORH CONVENTION. 2022;:8-8..
Bugarčić, Mladen, Jovanović, Gvozden, Petronijević, Nela, Marković, Branislav, Stopić, Srećko, Friedrich, Bernd, Sokić, Miroslav, "Approach on recycling of printed circuit boards (PCB) via hydrometallurgical procedures: Principle and methodology" in 3rd International Convention of Scientists, Specialist Employees and Students on the Topic of Environmental Protection in the Republic of Croatia - 3rd ZORH CONVENTION (2022):8-8.

Simulation of the impact of preheating temperature on railway aluminothermic welding

Jovanović, Gvozden; Manojlović, Vaso; Sokić, Miroslav; Delić, Alen; Gavrilovski, Milorad

(Banja Luka : University in Banja Luka, Faculty of Technology, 2022)

TY  - CONF
AU  - Jovanović, Gvozden
AU  - Manojlović, Vaso
AU  - Sokić, Miroslav
AU  - Delić, Alen
AU  - Gavrilovski, Milorad
PY  - 2022
UR  - https://ritnms.itnms.ac.rs/handle/123456789/944
AB  - For more than a century, railway rails have been joined using the aluminothermic welding process. The flexibility, compactness of the weld, and ease of execution are all advantages of this process. It is not necessary to use external energy to finish the operation. It is provided by the exothermic effect of the chemical reactions of the elements of the aluminothermic combination. The design of the mold
with the pouring system, which should ensure even pouring of thermal steel, without turbulence, then even heat dissipation or cooling in order to obtain an appropriate micro and macro structure of steel, free of internal and external defects, is an important factor in producing a welded joint of the required quality. As a result, the design of the mold was continually developing, necessitating the adoption of expensive experimental approaches in industrial settings. To eliminate costly and time-consuming industrial experiments, software applications are being employed to imitate aditional casting methods that can be used in the casting of thermite steel during the fabrication of welded railway connections. This study presents a simulation of casting thermite steel in the mold cavity, i.e., in the weld joint, for the 49E1 rail using the NovaFlow & Solid CV software package.
PB  - Banja Luka : University in Banja Luka, Faculty of Technology
C3  - XIV Conference of Chemists, Technologists and Environmentalists of Republic of Srpska
T1  - Simulation of the impact of preheating temperature on railway aluminothermic welding
EP  - 290
SP  - 284
ER  - 
@conference{
author = "Jovanović, Gvozden and Manojlović, Vaso and Sokić, Miroslav and Delić, Alen and Gavrilovski, Milorad",
year = "2022",
abstract = "For more than a century, railway rails have been joined using the aluminothermic welding process. The flexibility, compactness of the weld, and ease of execution are all advantages of this process. It is not necessary to use external energy to finish the operation. It is provided by the exothermic effect of the chemical reactions of the elements of the aluminothermic combination. The design of the mold
with the pouring system, which should ensure even pouring of thermal steel, without turbulence, then even heat dissipation or cooling in order to obtain an appropriate micro and macro structure of steel, free of internal and external defects, is an important factor in producing a welded joint of the required quality. As a result, the design of the mold was continually developing, necessitating the adoption of expensive experimental approaches in industrial settings. To eliminate costly and time-consuming industrial experiments, software applications are being employed to imitate aditional casting methods that can be used in the casting of thermite steel during the fabrication of welded railway connections. This study presents a simulation of casting thermite steel in the mold cavity, i.e., in the weld joint, for the 49E1 rail using the NovaFlow & Solid CV software package.",
publisher = "Banja Luka : University in Banja Luka, Faculty of Technology",
journal = "XIV Conference of Chemists, Technologists and Environmentalists of Republic of Srpska",
title = "Simulation of the impact of preheating temperature on railway aluminothermic welding",
pages = "290-284"
}
Jovanović, G., Manojlović, V., Sokić, M., Delić, A.,& Gavrilovski, M.. (2022). Simulation of the impact of preheating temperature on railway aluminothermic welding. in XIV Conference of Chemists, Technologists and Environmentalists of Republic of Srpska
Banja Luka : University in Banja Luka, Faculty of Technology., 284-290.
Jovanović G, Manojlović V, Sokić M, Delić A, Gavrilovski M. Simulation of the impact of preheating temperature on railway aluminothermic welding. in XIV Conference of Chemists, Technologists and Environmentalists of Republic of Srpska. 2022;:284-290..
Jovanović, Gvozden, Manojlović, Vaso, Sokić, Miroslav, Delić, Alen, Gavrilovski, Milorad, "Simulation of the impact of preheating temperature on railway aluminothermic welding" in XIV Conference of Chemists, Technologists and Environmentalists of Republic of Srpska (2022):284-290.

Sustainable mining and acid mine water treatment

Petronijević, Nela; Jovanović, Gvozden; Sokić, Miroslav; Jovanović, Aleksandar; Radovanović, Dragana; Kamberović, Željko; Stanković, Srđan

(Ljubljana : University of Ljubljana Press, 2022)

TY  - CONF
AU  - Petronijević, Nela
AU  - Jovanović, Gvozden
AU  - Sokić, Miroslav
AU  - Jovanović, Aleksandar
AU  - Radovanović, Dragana
AU  - Kamberović, Željko
AU  - Stanković, Srđan
PY  - 2022
UR  - https://ritnms.itnms.ac.rs/handle/123456789/1026
AB  - The mining sector, nowadays, faces rising
challenges to find suitable practice that are
sustainable for already disposed waste streams
(AMD, flotation tailings and fly ash) [1]. There is a
growing tendency globally to use waste from
various industries to neutralize AMD, which has
both economic and environmental benefits. In
attempt to connect mining waste with concept of
sustainable development in the Republic of Serbia,
several experiments were taken into consideration:
neutralisation of AMD from Bor’s mine with a)
flotation tailings from copper mine Majdanpek
(FJM) b) fly ash (FA) from thermal power Nikola
Tesla (EF) and Kostolac (KOST). All three samples
of alternative product are voluminous, hazardous
waste products, difficult and expensive for safe
deposition, causes environmental pollution (by
spontaneous leaching of useful components, which
causes additional investment in the rehabilitation of
that or reversibly lost compounds that pollutes the
environment, or its dispersion by wind in
surrounding streams and groundwater resources of
drinking water, air or soil and also degradation by
soil erosion) and can affects human health’s if are
not regularly discharged. But its benefits are that
there are free of charge alkaline wastes, suitable to
neutralize the AMD by altering pH, which leads to
precipitation of valuable metal which can be reused,
such as Fe or Cu. The chemical and mineralogical
composition of the initial samples of FJM and FA
was evaluated two standard leaching tests: TCLP
and EN 12457-4, as well as Acid Neutralization
Capacity test. These base materials were shown to
have a large capacity to neutralize acid, making
them a highly effective alternative material for
neutralizing acid mine drainage and eliminating
metals, even better than results of neutralisation
with NaOH, as conventional reagent. According to
the findings the FJM and FA neutralization
experiments precipitated more than 99 % of Al, Fe,
and Cu, 90 % of Pb, and 92 % of Zn. Leaching of
these metals from FJM and FA raises Cd and Mn
concentrations. Additional treatment was
undertaken using hydrated lime to boost the pH to
10 and so offer circumstances for its removal, in
order to reduce the concentration of Mn below the
authorized limits by Serbian legislation. At the end,
as a result of utilizing alternative materials such as
FJM and two FA purified water, safe for release into
the environment was obtained. In this way,
resources are preserved for the future generation,
and the treatment of already disposed amounts of
waste reduces the contamination of the
environment, the emission of toxic metals and the
formation of acidic mine waters.
PB  - Ljubljana : University of Ljubljana Press
C3  - 22nd European Meeting on Environmental Chemistry EMEC22
T1  - Sustainable mining and acid mine water treatment
EP  - 62
SP  - 62
DO  - 10.55295/9789612970352
ER  - 
@conference{
author = "Petronijević, Nela and Jovanović, Gvozden and Sokić, Miroslav and Jovanović, Aleksandar and Radovanović, Dragana and Kamberović, Željko and Stanković, Srđan",
year = "2022",
abstract = "The mining sector, nowadays, faces rising
challenges to find suitable practice that are
sustainable for already disposed waste streams
(AMD, flotation tailings and fly ash) [1]. There is a
growing tendency globally to use waste from
various industries to neutralize AMD, which has
both economic and environmental benefits. In
attempt to connect mining waste with concept of
sustainable development in the Republic of Serbia,
several experiments were taken into consideration:
neutralisation of AMD from Bor’s mine with a)
flotation tailings from copper mine Majdanpek
(FJM) b) fly ash (FA) from thermal power Nikola
Tesla (EF) and Kostolac (KOST). All three samples
of alternative product are voluminous, hazardous
waste products, difficult and expensive for safe
deposition, causes environmental pollution (by
spontaneous leaching of useful components, which
causes additional investment in the rehabilitation of
that or reversibly lost compounds that pollutes the
environment, or its dispersion by wind in
surrounding streams and groundwater resources of
drinking water, air or soil and also degradation by
soil erosion) and can affects human health’s if are
not regularly discharged. But its benefits are that
there are free of charge alkaline wastes, suitable to
neutralize the AMD by altering pH, which leads to
precipitation of valuable metal which can be reused,
such as Fe or Cu. The chemical and mineralogical
composition of the initial samples of FJM and FA
was evaluated two standard leaching tests: TCLP
and EN 12457-4, as well as Acid Neutralization
Capacity test. These base materials were shown to
have a large capacity to neutralize acid, making
them a highly effective alternative material for
neutralizing acid mine drainage and eliminating
metals, even better than results of neutralisation
with NaOH, as conventional reagent. According to
the findings the FJM and FA neutralization
experiments precipitated more than 99 % of Al, Fe,
and Cu, 90 % of Pb, and 92 % of Zn. Leaching of
these metals from FJM and FA raises Cd and Mn
concentrations. Additional treatment was
undertaken using hydrated lime to boost the pH to
10 and so offer circumstances for its removal, in
order to reduce the concentration of Mn below the
authorized limits by Serbian legislation. At the end,
as a result of utilizing alternative materials such as
FJM and two FA purified water, safe for release into
the environment was obtained. In this way,
resources are preserved for the future generation,
and the treatment of already disposed amounts of
waste reduces the contamination of the
environment, the emission of toxic metals and the
formation of acidic mine waters.",
publisher = "Ljubljana : University of Ljubljana Press",
journal = "22nd European Meeting on Environmental Chemistry EMEC22",
title = "Sustainable mining and acid mine water treatment",
pages = "62-62",
doi = "10.55295/9789612970352"
}
Petronijević, N., Jovanović, G., Sokić, M., Jovanović, A., Radovanović, D., Kamberović, Ž.,& Stanković, S.. (2022). Sustainable mining and acid mine water treatment. in 22nd European Meeting on Environmental Chemistry EMEC22
Ljubljana : University of Ljubljana Press., 62-62.
https://doi.org/10.55295/9789612970352
Petronijević N, Jovanović G, Sokić M, Jovanović A, Radovanović D, Kamberović Ž, Stanković S. Sustainable mining and acid mine water treatment. in 22nd European Meeting on Environmental Chemistry EMEC22. 2022;:62-62.
doi:10.55295/9789612970352 .
Petronijević, Nela, Jovanović, Gvozden, Sokić, Miroslav, Jovanović, Aleksandar, Radovanović, Dragana, Kamberović, Željko, Stanković, Srđan, "Sustainable mining and acid mine water treatment" in 22nd European Meeting on Environmental Chemistry EMEC22 (2022):62-62,
https://doi.org/10.55295/9789612970352 . .

A Multifocal Study Investigation of Pyrolyzed Printed Circuit Board Leaching

Jovanović, Gvozden; Bugarčić, Mladen; Petronijević, Nela; Stopić, Srećko; Friedrich, Bernd; Marković, Branislav; Stanković, Srđan; Sokić, Miroslav

(MDPI, Basel, 2022)

TY  - JOUR
AU  - Jovanović, Gvozden
AU  - Bugarčić, Mladen
AU  - Petronijević, Nela
AU  - Stopić, Srećko
AU  - Friedrich, Bernd
AU  - Marković, Branislav
AU  - Stanković, Srđan
AU  - Sokić, Miroslav
PY  - 2022
UR  - https://ritnms.itnms.ac.rs/handle/123456789/621
AB  - Electric waste from numerous devices that are put out of use every day has some form of printed circuit board that contains precious and valuable metals in their components. In order to extract these metals, the printed circuit boards were crushed and pyrolyzed into powder. The fine pyrolyzed printed circuit board (PPCB) powder was separated into fractions, and the fine metallic fraction was used as a raw material for metal leaching extraction. In order to better understand how various metal species react in leaching media, several leaching agents were used (sulfuric acid, nitric acid, glycine, and acid mine drainage-AMD) alone, and with the addition of hydrogen peroxide. Additionally, the influence of the S/L ratio and leaching temperature were investigated in sulfuric acid leaching solutions, as this is the one most widely used. In one case, the reactor was heated in a thermal bath, while in the other, it was heated in an ultrasonic bath. Lastly, several experiments were conducted with a (consecutive) two-pronged leaching approach, with and without applied pretreatment. The aim of this paper is to give a multifocal and detailed approach to how metals such as Al, Cu, Co, Zn, Sn, and Ca behave when extracted from fine PPCB powder. However, some attention is given to Nd, Pd, Pb, and Ba as well. One of the main findings is that regardless of the pretreatment or the sequence of leaching media applied, consecutive two-pronged leaching cannot be used for selective metal extraction. However, AMD was found to be suitable for selective leaching with very limited applications.
PB  - MDPI, Basel
T2  - Metals
T1  - A Multifocal Study Investigation of Pyrolyzed Printed Circuit Board Leaching
IS  - 12
VL  - 12
DO  - 10.3390/met12122021
UR  - conv_961
ER  - 
@article{
author = "Jovanović, Gvozden and Bugarčić, Mladen and Petronijević, Nela and Stopić, Srećko and Friedrich, Bernd and Marković, Branislav and Stanković, Srđan and Sokić, Miroslav",
year = "2022",
abstract = "Electric waste from numerous devices that are put out of use every day has some form of printed circuit board that contains precious and valuable metals in their components. In order to extract these metals, the printed circuit boards were crushed and pyrolyzed into powder. The fine pyrolyzed printed circuit board (PPCB) powder was separated into fractions, and the fine metallic fraction was used as a raw material for metal leaching extraction. In order to better understand how various metal species react in leaching media, several leaching agents were used (sulfuric acid, nitric acid, glycine, and acid mine drainage-AMD) alone, and with the addition of hydrogen peroxide. Additionally, the influence of the S/L ratio and leaching temperature were investigated in sulfuric acid leaching solutions, as this is the one most widely used. In one case, the reactor was heated in a thermal bath, while in the other, it was heated in an ultrasonic bath. Lastly, several experiments were conducted with a (consecutive) two-pronged leaching approach, with and without applied pretreatment. The aim of this paper is to give a multifocal and detailed approach to how metals such as Al, Cu, Co, Zn, Sn, and Ca behave when extracted from fine PPCB powder. However, some attention is given to Nd, Pd, Pb, and Ba as well. One of the main findings is that regardless of the pretreatment or the sequence of leaching media applied, consecutive two-pronged leaching cannot be used for selective metal extraction. However, AMD was found to be suitable for selective leaching with very limited applications.",
publisher = "MDPI, Basel",
journal = "Metals",
title = "A Multifocal Study Investigation of Pyrolyzed Printed Circuit Board Leaching",
number = "12",
volume = "12",
doi = "10.3390/met12122021",
url = "conv_961"
}
Jovanović, G., Bugarčić, M., Petronijević, N., Stopić, S., Friedrich, B., Marković, B., Stanković, S.,& Sokić, M.. (2022). A Multifocal Study Investigation of Pyrolyzed Printed Circuit Board Leaching. in Metals
MDPI, Basel., 12(12).
https://doi.org/10.3390/met12122021
conv_961
Jovanović G, Bugarčić M, Petronijević N, Stopić S, Friedrich B, Marković B, Stanković S, Sokić M. A Multifocal Study Investigation of Pyrolyzed Printed Circuit Board Leaching. in Metals. 2022;12(12).
doi:10.3390/met12122021
conv_961 .
Jovanović, Gvozden, Bugarčić, Mladen, Petronijević, Nela, Stopić, Srećko, Friedrich, Bernd, Marković, Branislav, Stanković, Srđan, Sokić, Miroslav, "A Multifocal Study Investigation of Pyrolyzed Printed Circuit Board Leaching" in Metals, 12, no. 12 (2022),
https://doi.org/10.3390/met12122021 .,
conv_961 .
1
1

Physical simulation of finish rolling of microalloyed steels in isothermal conditions

Dikić, Stefan; Glišić, Dragomir; Fadel, Abdunaser; Jovanović, Gvozden; Radović, Nenad

(Savez hemijskih inženjera, Beograd, 2022)

TY  - JOUR
AU  - Dikić, Stefan
AU  - Glišić, Dragomir
AU  - Fadel, Abdunaser
AU  - Jovanović, Gvozden
AU  - Radović, Nenad
PY  - 2022
UR  - https://ritnms.itnms.ac.rs/handle/123456789/625
AB  - The aim of this work was to establish a temperature of finish rolling stage of Nb/Ti microalloyed steel containing 0.06 wt.% C, 0.77 wt.% Mn, 0.039 wt.% Nb and 0.015 wt.% Ti, using physical simulation. Samples were subjected to laboratory simulation at a twist plastometer at high temperatures, i.e. between 825 and 950 degrees C. Five pass deformation and interpass times were selected in accordance with a processing parameters at five stand finishing hot strip mill. Restoration (recovery and/or recrystallization) behavior was evaluated by calculation of Fraction Softening (FS) and Area Softening Parameter (ASP) values. At 950 degrees C all individual pass stress-strain curves, FS and ASP show full recrystallization in all interpass intervals. On the other hand, with a decrease in temperature to the interval of 875-825 degrees C, the extent of restoration is decreasing, leading to recovery as a sole softening mechanism at 825 degrees C, which was confirmed by the stress-strain curve shape, and values of FS and ASP. It is assumed that, due to high supersaturation, strain-induced precipitation promoted pinning of grain and subgrain boundaries and suppressed recrystallization. Therefore, the critical temperature for finish rolling was estimated to be 825 degrees C.
PB  - Savez hemijskih inženjera, Beograd
T2  - Hemijska industrija
T1  - Physical simulation of finish rolling of microalloyed steels in isothermal conditions
EP  - 236
IS  - 4
SP  - 227
VL  - 76
DO  - 10.2298/HEMIND220816018D
UR  - conv_962
ER  - 
@article{
author = "Dikić, Stefan and Glišić, Dragomir and Fadel, Abdunaser and Jovanović, Gvozden and Radović, Nenad",
year = "2022",
abstract = "The aim of this work was to establish a temperature of finish rolling stage of Nb/Ti microalloyed steel containing 0.06 wt.% C, 0.77 wt.% Mn, 0.039 wt.% Nb and 0.015 wt.% Ti, using physical simulation. Samples were subjected to laboratory simulation at a twist plastometer at high temperatures, i.e. between 825 and 950 degrees C. Five pass deformation and interpass times were selected in accordance with a processing parameters at five stand finishing hot strip mill. Restoration (recovery and/or recrystallization) behavior was evaluated by calculation of Fraction Softening (FS) and Area Softening Parameter (ASP) values. At 950 degrees C all individual pass stress-strain curves, FS and ASP show full recrystallization in all interpass intervals. On the other hand, with a decrease in temperature to the interval of 875-825 degrees C, the extent of restoration is decreasing, leading to recovery as a sole softening mechanism at 825 degrees C, which was confirmed by the stress-strain curve shape, and values of FS and ASP. It is assumed that, due to high supersaturation, strain-induced precipitation promoted pinning of grain and subgrain boundaries and suppressed recrystallization. Therefore, the critical temperature for finish rolling was estimated to be 825 degrees C.",
publisher = "Savez hemijskih inženjera, Beograd",
journal = "Hemijska industrija",
title = "Physical simulation of finish rolling of microalloyed steels in isothermal conditions",
pages = "236-227",
number = "4",
volume = "76",
doi = "10.2298/HEMIND220816018D",
url = "conv_962"
}
Dikić, S., Glišić, D., Fadel, A., Jovanović, G.,& Radović, N.. (2022). Physical simulation of finish rolling of microalloyed steels in isothermal conditions. in Hemijska industrija
Savez hemijskih inženjera, Beograd., 76(4), 227-236.
https://doi.org/10.2298/HEMIND220816018D
conv_962
Dikić S, Glišić D, Fadel A, Jovanović G, Radović N. Physical simulation of finish rolling of microalloyed steels in isothermal conditions. in Hemijska industrija. 2022;76(4):227-236.
doi:10.2298/HEMIND220816018D
conv_962 .
Dikić, Stefan, Glišić, Dragomir, Fadel, Abdunaser, Jovanović, Gvozden, Radović, Nenad, "Physical simulation of finish rolling of microalloyed steels in isothermal conditions" in Hemijska industrija, 76, no. 4 (2022):227-236,
https://doi.org/10.2298/HEMIND220816018D .,
conv_962 .
1
1

Cleavage Fracture of the Air Cooled Medium Carbon Microalloyed Forging Steels with Heterogeneous Microstructures

Jovanović, Gvozden; Glišić, Dragomir; Dikić, Stefan; Radović, Nenad; Patarić, Aleksandra

(MDPI, Basel, 2022)

TY  - JOUR
AU  - Jovanović, Gvozden
AU  - Glišić, Dragomir
AU  - Dikić, Stefan
AU  - Radović, Nenad
AU  - Patarić, Aleksandra
PY  - 2022
UR  - https://ritnms.itnms.ac.rs/handle/123456789/634
AB  - Cleavage fracture of the V and Ti-V microalloyed forging steels was investigated by the four-point bending testing of the notched specimens of Griffith-Owen's type at -196 degrees C, in conjunction with the finite element analysis and the fractographic examination by scanning electron microscopy. To assess the mixed microstructure consisting mostly of the acicular ferrite, alongside proeutectoid ferrite grains and pearlite, the samples were held at 1250 degrees C for 30 min and subsequently cooled instill air. Cleavage fracture was initiated in the matrix under the high plastic strains near the notch root of the four-point bending specimens without the participation of the second phase particles in the process. Estimated values of the effective surface energy for the V and the Ti-V microalloyed steel of 37 Jm(-2) and 74 Jm(-2), respectively, and the related increase of local critical fracture stress were attributed to the increased content of the acicular ferrite. It was concluded that the observed increase of the local stress for cleavage crack propagation through the matrix was due to the increased number of the high angle boundaries, but also that the acicular ferrite affects the cleavage fracture mechanism by its characteristic stress-strain response with relatively low yield strength and considerable ductility at -196 degrees C.
PB  - MDPI, Basel
T2  - Materials
T1  - Cleavage Fracture of the Air Cooled Medium Carbon Microalloyed Forging Steels with Heterogeneous Microstructures
IS  - 5
VL  - 15
DO  - 10.3390/ma15051760
UR  - conv_938
ER  - 
@article{
author = "Jovanović, Gvozden and Glišić, Dragomir and Dikić, Stefan and Radović, Nenad and Patarić, Aleksandra",
year = "2022",
abstract = "Cleavage fracture of the V and Ti-V microalloyed forging steels was investigated by the four-point bending testing of the notched specimens of Griffith-Owen's type at -196 degrees C, in conjunction with the finite element analysis and the fractographic examination by scanning electron microscopy. To assess the mixed microstructure consisting mostly of the acicular ferrite, alongside proeutectoid ferrite grains and pearlite, the samples were held at 1250 degrees C for 30 min and subsequently cooled instill air. Cleavage fracture was initiated in the matrix under the high plastic strains near the notch root of the four-point bending specimens without the participation of the second phase particles in the process. Estimated values of the effective surface energy for the V and the Ti-V microalloyed steel of 37 Jm(-2) and 74 Jm(-2), respectively, and the related increase of local critical fracture stress were attributed to the increased content of the acicular ferrite. It was concluded that the observed increase of the local stress for cleavage crack propagation through the matrix was due to the increased number of the high angle boundaries, but also that the acicular ferrite affects the cleavage fracture mechanism by its characteristic stress-strain response with relatively low yield strength and considerable ductility at -196 degrees C.",
publisher = "MDPI, Basel",
journal = "Materials",
title = "Cleavage Fracture of the Air Cooled Medium Carbon Microalloyed Forging Steels with Heterogeneous Microstructures",
number = "5",
volume = "15",
doi = "10.3390/ma15051760",
url = "conv_938"
}
Jovanović, G., Glišić, D., Dikić, S., Radović, N.,& Patarić, A.. (2022). Cleavage Fracture of the Air Cooled Medium Carbon Microalloyed Forging Steels with Heterogeneous Microstructures. in Materials
MDPI, Basel., 15(5).
https://doi.org/10.3390/ma15051760
conv_938
Jovanović G, Glišić D, Dikić S, Radović N, Patarić A. Cleavage Fracture of the Air Cooled Medium Carbon Microalloyed Forging Steels with Heterogeneous Microstructures. in Materials. 2022;15(5).
doi:10.3390/ma15051760
conv_938 .
Jovanović, Gvozden, Glišić, Dragomir, Dikić, Stefan, Radović, Nenad, Patarić, Aleksandra, "Cleavage Fracture of the Air Cooled Medium Carbon Microalloyed Forging Steels with Heterogeneous Microstructures" in Materials, 15, no. 5 (2022),
https://doi.org/10.3390/ma15051760 .,
conv_938 .
6
6

Pregled tehnologija za ekstrakciju Zn iz biljaka hiperakumulatora - trenutna istraživanja i budući pravci

Jovanović, Gvozden; Ranđelović, Dragana; Marković, Branislav; Sokić, Miroslav

(Univerzitet u Beogradu - Tehnički fakultet u Boru, Beograd, 2022)

TY  - JOUR
AU  - Jovanović, Gvozden
AU  - Ranđelović, Dragana
AU  - Marković, Branislav
AU  - Sokić, Miroslav
PY  - 2022
UR  - https://ritnms.itnms.ac.rs/handle/123456789/617
AB  - Iako u ranoj fazi istraživanja fitorudarenje je podstaklo interesovanje u ispitivanju metala poput Ni, Au i retkih zemalja (REE). Međutim zagađenje cinkom iz rudničkog otpada, topionica, letećeg pepela i drugih antropogenih izvora postalo je ekološki problem. Fitoremedijacija hiperakumulirajućim biljkama pokazala se kao jedno od rešenja za smanjenje tog zagađenja. Stoga se pojavila i potreba za korišćenjem ili odlaganjem biljaka-hiperakumulatora cinka. Pošto su ranije sprovedena ispitivanja određenih hiperakumulatora za ekstrakciju metala, slični hidrometalurški i pirometalurški postupci ispitani su i za Zn. Hidrometalurški pravac ispitivanja fokusiran je na proizvodnju grubih eko katalizatora za potrebe organske hemije ili separaciju metalnih hidroksida cementacijom. Ovo je postignuto kiselim luženjem pepela dobijenog sagorevanjem nadzemne biomase. S druge strane, pirometalurški pravac više je fokusiran na bezbedno i ekološki prihvatljivo odlaganje proizvoda sagorevanja poput pepela i biočađi, uz postizanje nulte emisije toksičnih gasova pri pirolizi biomase. Bez obzira na pristup, potrebna su dalja istraživanja kako bi se ispitala stabilizacija metala koji zaostaju u čvrstoj frakciji tokom sagorevanja kao i smanjenje sadržaja metala u emitovanim gasovima. Do sada nijedna od ovih tehnologija nije dovedena do poluindustrijskih razmera u ispitivanjima, mada postoji potencijal u povezivanju ova dva pristupa.
AB  - Phytomining, although predominantly in its early stages on the broader scientific scope of investigation, has garnered interest in metals such as Ni, Au, or rare earth elements (REE). However, Zn pollution from mine wastes, smelters, coal ash and other anthropogenic sources has become an environmental problem. Phytoremediation by hyperaccumulating plants is one of the proposed solutions to mitigate the pollution. Therefore, a need to utilize or dispose Zn hyperaccumulating plants occurred. Since studies of certain hyperaccumulating plant species have been previously conducted in order to extract metal products, similar hydrometallurgical and pyrometallurgical techniques were tried with Zn. The hydrometallurgical route was more focused on producing crude eco catalysts for organic chemistry or separating metal hydroxides by cementation. This was achieved with acid leaching of the ash which was obtained by calcinating the aboveground plant biomass. On the other hand, the pyrometallurgical route was more focused on safe and eco-friendly disposal of combustion products such as ash or biochar, while achieving zero toxic gaseous emissions from biomass pyrolysis. Regardless of the approach further research is needed to investigate the stabilization of metals that remain in the solid fraction during combustion and lowering the metal content in produced gases. So far, none of these technologies have been brought to a semi industrial scale and there is the potential of linking those two approaches together.
PB  - Univerzitet u Beogradu - Tehnički fakultet u Boru, Beograd
T2  - Journal of Mining and Metallurgy A: Mining
T1  - Pregled tehnologija za ekstrakciju Zn iz biljaka hiperakumulatora - trenutna istraživanja i budući pravci
T1  - Overview of technologies for Zn extraction from hyperaccumulating plants: Current state of research and future directions
EP  - 38
IS  - 1
SP  - 29
VL  - 58
DO  - 10.5937/JMMA2201029J
UR  - conv_340
ER  - 
@article{
author = "Jovanović, Gvozden and Ranđelović, Dragana and Marković, Branislav and Sokić, Miroslav",
year = "2022",
abstract = "Iako u ranoj fazi istraživanja fitorudarenje je podstaklo interesovanje u ispitivanju metala poput Ni, Au i retkih zemalja (REE). Međutim zagađenje cinkom iz rudničkog otpada, topionica, letećeg pepela i drugih antropogenih izvora postalo je ekološki problem. Fitoremedijacija hiperakumulirajućim biljkama pokazala se kao jedno od rešenja za smanjenje tog zagađenja. Stoga se pojavila i potreba za korišćenjem ili odlaganjem biljaka-hiperakumulatora cinka. Pošto su ranije sprovedena ispitivanja određenih hiperakumulatora za ekstrakciju metala, slični hidrometalurški i pirometalurški postupci ispitani su i za Zn. Hidrometalurški pravac ispitivanja fokusiran je na proizvodnju grubih eko katalizatora za potrebe organske hemije ili separaciju metalnih hidroksida cementacijom. Ovo je postignuto kiselim luženjem pepela dobijenog sagorevanjem nadzemne biomase. S druge strane, pirometalurški pravac više je fokusiran na bezbedno i ekološki prihvatljivo odlaganje proizvoda sagorevanja poput pepela i biočađi, uz postizanje nulte emisije toksičnih gasova pri pirolizi biomase. Bez obzira na pristup, potrebna su dalja istraživanja kako bi se ispitala stabilizacija metala koji zaostaju u čvrstoj frakciji tokom sagorevanja kao i smanjenje sadržaja metala u emitovanim gasovima. Do sada nijedna od ovih tehnologija nije dovedena do poluindustrijskih razmera u ispitivanjima, mada postoji potencijal u povezivanju ova dva pristupa., Phytomining, although predominantly in its early stages on the broader scientific scope of investigation, has garnered interest in metals such as Ni, Au, or rare earth elements (REE). However, Zn pollution from mine wastes, smelters, coal ash and other anthropogenic sources has become an environmental problem. Phytoremediation by hyperaccumulating plants is one of the proposed solutions to mitigate the pollution. Therefore, a need to utilize or dispose Zn hyperaccumulating plants occurred. Since studies of certain hyperaccumulating plant species have been previously conducted in order to extract metal products, similar hydrometallurgical and pyrometallurgical techniques were tried with Zn. The hydrometallurgical route was more focused on producing crude eco catalysts for organic chemistry or separating metal hydroxides by cementation. This was achieved with acid leaching of the ash which was obtained by calcinating the aboveground plant biomass. On the other hand, the pyrometallurgical route was more focused on safe and eco-friendly disposal of combustion products such as ash or biochar, while achieving zero toxic gaseous emissions from biomass pyrolysis. Regardless of the approach further research is needed to investigate the stabilization of metals that remain in the solid fraction during combustion and lowering the metal content in produced gases. So far, none of these technologies have been brought to a semi industrial scale and there is the potential of linking those two approaches together.",
publisher = "Univerzitet u Beogradu - Tehnički fakultet u Boru, Beograd",
journal = "Journal of Mining and Metallurgy A: Mining",
title = "Pregled tehnologija za ekstrakciju Zn iz biljaka hiperakumulatora - trenutna istraživanja i budući pravci, Overview of technologies for Zn extraction from hyperaccumulating plants: Current state of research and future directions",
pages = "38-29",
number = "1",
volume = "58",
doi = "10.5937/JMMA2201029J",
url = "conv_340"
}
Jovanović, G., Ranđelović, D., Marković, B.,& Sokić, M.. (2022). Pregled tehnologija za ekstrakciju Zn iz biljaka hiperakumulatora - trenutna istraživanja i budući pravci. in Journal of Mining and Metallurgy A: Mining
Univerzitet u Beogradu - Tehnički fakultet u Boru, Beograd., 58(1), 29-38.
https://doi.org/10.5937/JMMA2201029J
conv_340
Jovanović G, Ranđelović D, Marković B, Sokić M. Pregled tehnologija za ekstrakciju Zn iz biljaka hiperakumulatora - trenutna istraživanja i budući pravci. in Journal of Mining and Metallurgy A: Mining. 2022;58(1):29-38.
doi:10.5937/JMMA2201029J
conv_340 .
Jovanović, Gvozden, Ranđelović, Dragana, Marković, Branislav, Sokić, Miroslav, "Pregled tehnologija za ekstrakciju Zn iz biljaka hiperakumulatora - trenutna istraživanja i budući pravci" in Journal of Mining and Metallurgy A: Mining, 58, no. 1 (2022):29-38,
https://doi.org/10.5937/JMMA2201029J .,
conv_340 .
1

Analysis of the Mechanism of Acid Mine Drainage Neutralization Using Fly Ash as an Alternative Material: A Case Study of the Extremely Acidic Lake Robule in Eastern Serbia

Petronijević, Nela; Radovanović, Dragana; Stulović, Marija; Sokić, Miroslav; Jovanović, Gvozden; Kamberović, Željko; Stanković, Srđan; Stopić, Srećko; Onjia, Antonije

(MDPI, Basel, 2022)

TY  - JOUR
AU  - Petronijević, Nela
AU  - Radovanović, Dragana
AU  - Stulović, Marija
AU  - Sokić, Miroslav
AU  - Jovanović, Gvozden
AU  - Kamberović, Željko
AU  - Stanković, Srđan
AU  - Stopić, Srećko
AU  - Onjia, Antonije
PY  - 2022
UR  - https://ritnms.itnms.ac.rs/handle/123456789/616
AB  - Acid mine drainage (AMD) is a waste from mining sites, usually acidic, with high concentrations of sulfates and heavy metal ions. This study investigates the AMD neutralization process using fly ash (FA) as an alternative material. Samples of FA from coal-fired power plants in Serbia ("Nikola Tesla" (EF) and "Kostolac" (KOST)) were analyzed and used. The results were compared with the treatment efficiency of commercial neutralization agent (NaOH). The alkaline nature of FA was the basis for use in the treatment process of the extremely acid Lake Robule (pH 2.46), located in the mining areas of eastern Serbia. The optimal S/L ratio for the AMD neutralization process determined for EF was 25 wt.%, and for KOST it was 20 wt.%. The mechanism of the neutralization process was analyzed using the ANC test and PHREEQC program. The element concentrations and pH values in solutions indicated that FA samples could neutralize Lake Robule with more than 99% of Al, Fe, Cu, Zn, and more than 89% of Pb precipitated. Formation of insoluble (oxy)hydroxide forms (Fe3+ and Al3+ ions) creates favorable conditions for co-precipitation of other trace metals (Cu, Zn, Ni, Pb, and Cd) from AMD, which is further enhanced by cation adsorption on FA particles. FA proved to be a more effective neutralization agent than NaOH due to its adsorption effect, while among the FA samples, KOST was more effective due to the aging process through the carbonization reaction. Using FA as an alternative material is a promising and sustainable method for treating AMD, with economic and environmental benefits.
PB  - MDPI, Basel
T2  - Water
T1  - Analysis of the Mechanism of Acid Mine Drainage Neutralization Using Fly Ash as an Alternative Material: A Case Study of the Extremely Acidic Lake Robule in Eastern Serbia
IS  - 20
VL  - 14
DO  - 10.3390/w14203244
UR  - conv_955
ER  - 
@article{
author = "Petronijević, Nela and Radovanović, Dragana and Stulović, Marija and Sokić, Miroslav and Jovanović, Gvozden and Kamberović, Željko and Stanković, Srđan and Stopić, Srećko and Onjia, Antonije",
year = "2022",
abstract = "Acid mine drainage (AMD) is a waste from mining sites, usually acidic, with high concentrations of sulfates and heavy metal ions. This study investigates the AMD neutralization process using fly ash (FA) as an alternative material. Samples of FA from coal-fired power plants in Serbia ("Nikola Tesla" (EF) and "Kostolac" (KOST)) were analyzed and used. The results were compared with the treatment efficiency of commercial neutralization agent (NaOH). The alkaline nature of FA was the basis for use in the treatment process of the extremely acid Lake Robule (pH 2.46), located in the mining areas of eastern Serbia. The optimal S/L ratio for the AMD neutralization process determined for EF was 25 wt.%, and for KOST it was 20 wt.%. The mechanism of the neutralization process was analyzed using the ANC test and PHREEQC program. The element concentrations and pH values in solutions indicated that FA samples could neutralize Lake Robule with more than 99% of Al, Fe, Cu, Zn, and more than 89% of Pb precipitated. Formation of insoluble (oxy)hydroxide forms (Fe3+ and Al3+ ions) creates favorable conditions for co-precipitation of other trace metals (Cu, Zn, Ni, Pb, and Cd) from AMD, which is further enhanced by cation adsorption on FA particles. FA proved to be a more effective neutralization agent than NaOH due to its adsorption effect, while among the FA samples, KOST was more effective due to the aging process through the carbonization reaction. Using FA as an alternative material is a promising and sustainable method for treating AMD, with economic and environmental benefits.",
publisher = "MDPI, Basel",
journal = "Water",
title = "Analysis of the Mechanism of Acid Mine Drainage Neutralization Using Fly Ash as an Alternative Material: A Case Study of the Extremely Acidic Lake Robule in Eastern Serbia",
number = "20",
volume = "14",
doi = "10.3390/w14203244",
url = "conv_955"
}
Petronijević, N., Radovanović, D., Stulović, M., Sokić, M., Jovanović, G., Kamberović, Ž., Stanković, S., Stopić, S.,& Onjia, A.. (2022). Analysis of the Mechanism of Acid Mine Drainage Neutralization Using Fly Ash as an Alternative Material: A Case Study of the Extremely Acidic Lake Robule in Eastern Serbia. in Water
MDPI, Basel., 14(20).
https://doi.org/10.3390/w14203244
conv_955
Petronijević N, Radovanović D, Stulović M, Sokić M, Jovanović G, Kamberović Ž, Stanković S, Stopić S, Onjia A. Analysis of the Mechanism of Acid Mine Drainage Neutralization Using Fly Ash as an Alternative Material: A Case Study of the Extremely Acidic Lake Robule in Eastern Serbia. in Water. 2022;14(20).
doi:10.3390/w14203244
conv_955 .
Petronijević, Nela, Radovanović, Dragana, Stulović, Marija, Sokić, Miroslav, Jovanović, Gvozden, Kamberović, Željko, Stanković, Srđan, Stopić, Srećko, Onjia, Antonije, "Analysis of the Mechanism of Acid Mine Drainage Neutralization Using Fly Ash as an Alternative Material: A Case Study of the Extremely Acidic Lake Robule in Eastern Serbia" in Water, 14, no. 20 (2022),
https://doi.org/10.3390/w14203244 .,
conv_955 .
5
5

Pregled tehnologija ekstrakcije i mogućnosti primene na metale iz hiperakumulatora Balkana

Jovanović, Gvozden; Ranđelović, Dragana; Marković, Branislav; Sokić, Miroslav

(Savez inženjera i tehničara Srbije, Beograd, 2022)

TY  - JOUR
AU  - Jovanović, Gvozden
AU  - Ranđelović, Dragana
AU  - Marković, Branislav
AU  - Sokić, Miroslav
PY  - 2022
UR  - https://ritnms.itnms.ac.rs/handle/123456789/613
AB  - Fitorudarenje je aktuelna biotehnologija u razvoju kojom se ekstrahuju retki i dragoceni metali iz prirodno obogaćenih ili zagađenih zemljišta uz pomoć biljaka hiperakumulatora. Na teritoriji Balkana hiperakumulatorske vrste usvajaju prevashodno nikl, cink, talijum, bakar i arsen. U ovom radu dat je pregled do sada ispitanih tehnologija za ekstrakciju ovih elemenata iz biomase hiperakumulatorskih vrsta širom sveta, kao i područja potencijalne primene dobijenih produkata. Na teritoriji Srbije fitorudarenje ima perspektivu, i potrebno je vršiti ispitivanja u pravcu pronalaženja upotrebne vrednosti dostupnih hiperakumulatora, kao i razvoja tehnologija za ekstrakciju metala iz njihove biomase.
AB  - Phytomining is a currently developing biotechnology aiming to extract rare and precious metals from naturally enriched or polluted soils with the help of hyperaccumulator plants. On the territory of the Balkans, hyperaccumulating species mainly accumulate elements such as nickel, zinc, thallium, copper and arsenic. This paper provides an overview of the studied technologies around the world for the extraction of these elements from hyperaccumulator's biomass, as well as the areas of potential application of the obtained products. Phytomining has a potential for development in Serbia, and for this purpose it is necessary to utilitized available hyperaccumulators, as well as to investigate technologies for the extraction of metals from their biomass.
PB  - Savez inženjera i tehničara Srbije, Beograd
T2  - Tehnika
T1  - Pregled tehnologija ekstrakcije i mogućnosti primene na metale iz hiperakumulatora Balkana
T1  - Overview of extraction technologies and applications for metals from Balkan hyperaccumulators
EP  - 549
IS  - 5
SP  - 543
VL  - 77
DO  - 10.5937/tehnika2205543J
UR  - conv_38
ER  - 
@article{
author = "Jovanović, Gvozden and Ranđelović, Dragana and Marković, Branislav and Sokić, Miroslav",
year = "2022",
abstract = "Fitorudarenje je aktuelna biotehnologija u razvoju kojom se ekstrahuju retki i dragoceni metali iz prirodno obogaćenih ili zagađenih zemljišta uz pomoć biljaka hiperakumulatora. Na teritoriji Balkana hiperakumulatorske vrste usvajaju prevashodno nikl, cink, talijum, bakar i arsen. U ovom radu dat je pregled do sada ispitanih tehnologija za ekstrakciju ovih elemenata iz biomase hiperakumulatorskih vrsta širom sveta, kao i područja potencijalne primene dobijenih produkata. Na teritoriji Srbije fitorudarenje ima perspektivu, i potrebno je vršiti ispitivanja u pravcu pronalaženja upotrebne vrednosti dostupnih hiperakumulatora, kao i razvoja tehnologija za ekstrakciju metala iz njihove biomase., Phytomining is a currently developing biotechnology aiming to extract rare and precious metals from naturally enriched or polluted soils with the help of hyperaccumulator plants. On the territory of the Balkans, hyperaccumulating species mainly accumulate elements such as nickel, zinc, thallium, copper and arsenic. This paper provides an overview of the studied technologies around the world for the extraction of these elements from hyperaccumulator's biomass, as well as the areas of potential application of the obtained products. Phytomining has a potential for development in Serbia, and for this purpose it is necessary to utilitized available hyperaccumulators, as well as to investigate technologies for the extraction of metals from their biomass.",
publisher = "Savez inženjera i tehničara Srbije, Beograd",
journal = "Tehnika",
title = "Pregled tehnologija ekstrakcije i mogućnosti primene na metale iz hiperakumulatora Balkana, Overview of extraction technologies and applications for metals from Balkan hyperaccumulators",
pages = "549-543",
number = "5",
volume = "77",
doi = "10.5937/tehnika2205543J",
url = "conv_38"
}
Jovanović, G., Ranđelović, D., Marković, B.,& Sokić, M.. (2022). Pregled tehnologija ekstrakcije i mogućnosti primene na metale iz hiperakumulatora Balkana. in Tehnika
Savez inženjera i tehničara Srbije, Beograd., 77(5), 543-549.
https://doi.org/10.5937/tehnika2205543J
conv_38
Jovanović G, Ranđelović D, Marković B, Sokić M. Pregled tehnologija ekstrakcije i mogućnosti primene na metale iz hiperakumulatora Balkana. in Tehnika. 2022;77(5):543-549.
doi:10.5937/tehnika2205543J
conv_38 .
Jovanović, Gvozden, Ranđelović, Dragana, Marković, Branislav, Sokić, Miroslav, "Pregled tehnologija ekstrakcije i mogućnosti primene na metale iz hiperakumulatora Balkana" in Tehnika, 77, no. 5 (2022):543-549,
https://doi.org/10.5937/tehnika2205543J .,
conv_38 .

A review of coal demineralization and desulphurization by chemical leaching

Pantović Spajić, Katarina; Marković, Branislav; Sokić, Miroslav; Jovanović, Gvozden; Stojanović, Ksenija

(Belgrade : Innovation Center of Faculty of Mechanical Engineering, 2021)

TY  - CONF
AU  - Pantović Spajić, Katarina
AU  - Marković, Branislav
AU  - Sokić, Miroslav
AU  - Jovanović, Gvozden
AU  - Stojanović, Ksenija
PY  - 2021
UR  - https://ritnms.itnms.ac.rs/handle/123456789/1124
AB  - Coal is a well-known fossil fuel. It was used as a non-renewable energy source for several centuries. Nowadays it is mainly used for electricity generation in power plants or heat generation for industrial and home utilization.
There are many types of coal that differ in composition and calorific value, as well as in the amounts of undesired hazard substances produced by combustion. Depending on the coal composition, environmental impact can be reduced by its treatment before combustion. One of the cheap and effective methods is the chemical leaching of coal that reduces sulfur content and the amount of mineral matter (ash). Lowering the ash amount increases the calorific value of coal, reduces its transportation cost, and reduces the negative environmental impact of toxic elements, which are usually present in ash. Another benefit of coal leaching, that results from lowering the sulfur content is reduced emission of toxic gases (SO2 and SO3) during combustion. In order to determine the optimal leaching conditions for the treatment of different types of coal, numerous studies have been done, investigating various chemical reagents, including inorganic and organic acids, alkalis, oxidative reagents, and their combinations [1, 2]. The key parameters that effect leaching efficiency are type and concentration of reagent, reaction temperature, the mass ratio between coal and leaching reagent, coal particle size, and reaction time. The degree of leaching efficiency is measured by the level of demineralization and desulphurization [3]. The current review summarises recent results and further plans for the development of an efficient and environmentally friendly method for the chemical leaching of Serbian sub-bituminous coal.
PB  - Belgrade : Innovation Center of Faculty of Mechanical Engineering
C3  - International Conference of Experimental and Numerical Investigations and New Technologies
T1  - A review of coal demineralization and desulphurization by chemical leaching
EP  - 99
SP  - 99
ER  - 
@conference{
author = "Pantović Spajić, Katarina and Marković, Branislav and Sokić, Miroslav and Jovanović, Gvozden and Stojanović, Ksenija",
year = "2021",
abstract = "Coal is a well-known fossil fuel. It was used as a non-renewable energy source for several centuries. Nowadays it is mainly used for electricity generation in power plants or heat generation for industrial and home utilization.
There are many types of coal that differ in composition and calorific value, as well as in the amounts of undesired hazard substances produced by combustion. Depending on the coal composition, environmental impact can be reduced by its treatment before combustion. One of the cheap and effective methods is the chemical leaching of coal that reduces sulfur content and the amount of mineral matter (ash). Lowering the ash amount increases the calorific value of coal, reduces its transportation cost, and reduces the negative environmental impact of toxic elements, which are usually present in ash. Another benefit of coal leaching, that results from lowering the sulfur content is reduced emission of toxic gases (SO2 and SO3) during combustion. In order to determine the optimal leaching conditions for the treatment of different types of coal, numerous studies have been done, investigating various chemical reagents, including inorganic and organic acids, alkalis, oxidative reagents, and their combinations [1, 2]. The key parameters that effect leaching efficiency are type and concentration of reagent, reaction temperature, the mass ratio between coal and leaching reagent, coal particle size, and reaction time. The degree of leaching efficiency is measured by the level of demineralization and desulphurization [3]. The current review summarises recent results and further plans for the development of an efficient and environmentally friendly method for the chemical leaching of Serbian sub-bituminous coal.",
publisher = "Belgrade : Innovation Center of Faculty of Mechanical Engineering",
journal = "International Conference of Experimental and Numerical Investigations and New Technologies",
title = "A review of coal demineralization and desulphurization by chemical leaching",
pages = "99-99"
}
Pantović Spajić, K., Marković, B., Sokić, M., Jovanović, G.,& Stojanović, K.. (2021). A review of coal demineralization and desulphurization by chemical leaching. in International Conference of Experimental and Numerical Investigations and New Technologies
Belgrade : Innovation Center of Faculty of Mechanical Engineering., 99-99.
Pantović Spajić K, Marković B, Sokić M, Jovanović G, Stojanović K. A review of coal demineralization and desulphurization by chemical leaching. in International Conference of Experimental and Numerical Investigations and New Technologies. 2021;:99-99..
Pantović Spajić, Katarina, Marković, Branislav, Sokić, Miroslav, Jovanović, Gvozden, Stojanović, Ksenija, "A review of coal demineralization and desulphurization by chemical leaching" in International Conference of Experimental and Numerical Investigations and New Technologies (2021):99-99.

"Chemical leaching of subbituminous coal from the Bogovina - East field (Bogovina basin, Serbia) using hydrochloric acid"

Pantović Spajić, Katarina; Marković, Branislav; Sokić, Miroslav; Bugarčić, Mladen; Jovanović, Gvozden; Manojlović, Vaso; Stojanović, Ksenija

(Sisak : Univerzitet u Zagrebu, Metalurški Fakultet, 2021)

TY  - CONF
AU  - Pantović Spajić, Katarina
AU  - Marković, Branislav
AU  - Sokić, Miroslav
AU  - Bugarčić, Mladen
AU  - Jovanović, Gvozden
AU  - Manojlović, Vaso
AU  - Stojanović, Ksenija
PY  - 2021
UR  - https://ritnms.itnms.ac.rs/handle/123456789/1122
AB  - All over the world, huge amounts of coal are available and it is utilized in large quantities for different
purposes. The coal combustion causes environmental problems, such as the release of toxic metals
and other pollutants into wastewaters, emission of noxious gases, produce of ash dumps, etc. One of
the solutions for the reduction of environment pollution, caused by coal combustion, is
demineralization and desulphurization of coal. In that sense, treatment of coal by different chemical
reagents becomes important. A subbituminous coal, used in this study was taken from the Bogovina -
East field (Lower Miocene » 20-16 Ma) of the Bogovina Basin, which is located in Eastern Serbia. The
sample was selected based on the previous studies of Bogovina - East field which indicated a high
amount of sulphur, relatively high percent of mineral matter and considerably amount of liptinites
for humic coal, which represent the most reactive maceral group. The aim of the study was an
attempt to reduce the amount of ash and sulphur in coal, keeping the organic matter unaltered as
possible, using simple and cheap method e.g. treatment with hydrochloric acid (HCl). Ash and total
sulphur content was determined before and after HCl leaching. In addition characteristics of initial
and treated coal were tracked by X-ray diffraction (XRD) analysis and Fourier-transform infrared
(FTIR) spectroscopy. The obtained results showed that the high percentage of deashing (» 80 %) was
achieved with cheap hydrochloric acid. XRD analysis of ash before and after sample treatment
provides more information about mineral phases in coal and effects of chemical leaching. FTIR
analysis indicates almost no changes in structure of coal organic matter after treatment by HCl,
which is important for further coal usage (e.g. combustion). On the other hand, the applied chemical
leaching with HCl had low impact on the sulphur content in Bogovina coal (desulphurization
percentage » 8 %). Therefore, in future research other reagents for efficient desulphurization should
be investigated.
PB  - Sisak : Univerzitet u Zagrebu, Metalurški Fakultet
C3  - 19th INTERNATIONAL FOUNDRYMEN CONFERENCE
T1  - "Chemical leaching of subbituminous coal from the Bogovina - East field (Bogovina basin, Serbia) using hydrochloric acid"
EP  - 440
SP  - 435
ER  - 
@conference{
author = "Pantović Spajić, Katarina and Marković, Branislav and Sokić, Miroslav and Bugarčić, Mladen and Jovanović, Gvozden and Manojlović, Vaso and Stojanović, Ksenija",
year = "2021",
abstract = "All over the world, huge amounts of coal are available and it is utilized in large quantities for different
purposes. The coal combustion causes environmental problems, such as the release of toxic metals
and other pollutants into wastewaters, emission of noxious gases, produce of ash dumps, etc. One of
the solutions for the reduction of environment pollution, caused by coal combustion, is
demineralization and desulphurization of coal. In that sense, treatment of coal by different chemical
reagents becomes important. A subbituminous coal, used in this study was taken from the Bogovina -
East field (Lower Miocene » 20-16 Ma) of the Bogovina Basin, which is located in Eastern Serbia. The
sample was selected based on the previous studies of Bogovina - East field which indicated a high
amount of sulphur, relatively high percent of mineral matter and considerably amount of liptinites
for humic coal, which represent the most reactive maceral group. The aim of the study was an
attempt to reduce the amount of ash and sulphur in coal, keeping the organic matter unaltered as
possible, using simple and cheap method e.g. treatment with hydrochloric acid (HCl). Ash and total
sulphur content was determined before and after HCl leaching. In addition characteristics of initial
and treated coal were tracked by X-ray diffraction (XRD) analysis and Fourier-transform infrared
(FTIR) spectroscopy. The obtained results showed that the high percentage of deashing (» 80 %) was
achieved with cheap hydrochloric acid. XRD analysis of ash before and after sample treatment
provides more information about mineral phases in coal and effects of chemical leaching. FTIR
analysis indicates almost no changes in structure of coal organic matter after treatment by HCl,
which is important for further coal usage (e.g. combustion). On the other hand, the applied chemical
leaching with HCl had low impact on the sulphur content in Bogovina coal (desulphurization
percentage » 8 %). Therefore, in future research other reagents for efficient desulphurization should
be investigated.",
publisher = "Sisak : Univerzitet u Zagrebu, Metalurški Fakultet",
journal = "19th INTERNATIONAL FOUNDRYMEN CONFERENCE",
title = ""Chemical leaching of subbituminous coal from the Bogovina - East field (Bogovina basin, Serbia) using hydrochloric acid"",
pages = "440-435"
}
Pantović Spajić, K., Marković, B., Sokić, M., Bugarčić, M., Jovanović, G., Manojlović, V.,& Stojanović, K.. (2021). "Chemical leaching of subbituminous coal from the Bogovina - East field (Bogovina basin, Serbia) using hydrochloric acid". in 19th INTERNATIONAL FOUNDRYMEN CONFERENCE
Sisak : Univerzitet u Zagrebu, Metalurški Fakultet., 435-440.
Pantović Spajić K, Marković B, Sokić M, Bugarčić M, Jovanović G, Manojlović V, Stojanović K. "Chemical leaching of subbituminous coal from the Bogovina - East field (Bogovina basin, Serbia) using hydrochloric acid". in 19th INTERNATIONAL FOUNDRYMEN CONFERENCE. 2021;:435-440..
Pantović Spajić, Katarina, Marković, Branislav, Sokić, Miroslav, Bugarčić, Mladen, Jovanović, Gvozden, Manojlović, Vaso, Stojanović, Ksenija, ""Chemical leaching of subbituminous coal from the Bogovina - East field (Bogovina basin, Serbia) using hydrochloric acid"" in 19th INTERNATIONAL FOUNDRYMEN CONFERENCE (2021):435-440.