Radovanović, Dragana

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orcid::0000-0002-2935-7711
  • Radovanović, Dragana (9)

Author's Bibliography

Stability of solid residue after integral treatment of acid mine drainage

Petronijević, Nela; Radovanović, Dragana; Stanković, Srđan; Sokić, Miroslav; Kamberović, Željko; Onjia, Antonije; Jovanović, Gvozden

(Belgrade : Association of Metallurgical Engineers of Serbia, 2023)

TY  - JOUR
AU  - Petronijević, Nela
AU  - Radovanović, Dragana
AU  - Stanković, Srđan
AU  - Sokić, Miroslav
AU  - Kamberović, Željko
AU  - Onjia, Antonije
AU  - Jovanović, Gvozden
PY  - 2023
UR  - https://ritnms.itnms.ac.rs/handle/123456789/1208
AB  - Acid mine drainage is a challenging environmental problem caused by mining activities. Long-term  copper  ore  exploitation  and  vast  amounts  of  mining  waste  lead  to  severe  soil  contamination as well as river and groundwater pollution. In this paper, research is focused on utilizing waste mine waters and off-balance parts of the mine deposit (such as flotation tailings) and converting their negative characteristics to an environmentally friendly one. In the  authors’  previous  work,  acid  mine  water  from  Robule,  which  is  part  of  the  Bor  copper  mining and smelting complex in Serbia, was successfully treated using flotation tailings, and the resulting solution was suitable for safe discharge. This paper investigates the characteristics of the solid residue that remained after the treatment of the modified flotation tailings in order to  evaluate  the  possibility  of  its  safe  disposal  back  into  the  environment.  The  solid  residue  was subjected to TCLP and EN 12457-4 tests as standard procedures that assess the leaching characteristics  of  a  material.  The  solid  residue  was  also  exposed  to  long-term  leaching  with  melted  snow  to  simulate  environmental  conditions  for  one  year.  This  drainage  water  was  analyzed and compared with the results of the standard leaching procedures. The investigated treatments lead to improved economic and environmental effects, while the process itself is adjusted to preserve the environment.
PB  - Belgrade : Association of Metallurgical Engineers of Serbia
T2  - Metallurgical and Materials Data
T1  - Stability of solid residue after integral treatment of acid mine drainage
EP  - 63
IS  - 2
SP  - 57
VL  - 1
DO  - 10.30544/MMD6
ER  - 
@article{
author = "Petronijević, Nela and Radovanović, Dragana and Stanković, Srđan and Sokić, Miroslav and Kamberović, Željko and Onjia, Antonije and Jovanović, Gvozden",
year = "2023",
abstract = "Acid mine drainage is a challenging environmental problem caused by mining activities. Long-term  copper  ore  exploitation  and  vast  amounts  of  mining  waste  lead  to  severe  soil  contamination as well as river and groundwater pollution. In this paper, research is focused on utilizing waste mine waters and off-balance parts of the mine deposit (such as flotation tailings) and converting their negative characteristics to an environmentally friendly one. In the  authors’  previous  work,  acid  mine  water  from  Robule,  which  is  part  of  the  Bor  copper  mining and smelting complex in Serbia, was successfully treated using flotation tailings, and the resulting solution was suitable for safe discharge. This paper investigates the characteristics of the solid residue that remained after the treatment of the modified flotation tailings in order to  evaluate  the  possibility  of  its  safe  disposal  back  into  the  environment.  The  solid  residue  was subjected to TCLP and EN 12457-4 tests as standard procedures that assess the leaching characteristics  of  a  material.  The  solid  residue  was  also  exposed  to  long-term  leaching  with  melted  snow  to  simulate  environmental  conditions  for  one  year.  This  drainage  water  was  analyzed and compared with the results of the standard leaching procedures. The investigated treatments lead to improved economic and environmental effects, while the process itself is adjusted to preserve the environment.",
publisher = "Belgrade : Association of Metallurgical Engineers of Serbia",
journal = "Metallurgical and Materials Data",
title = "Stability of solid residue after integral treatment of acid mine drainage",
pages = "63-57",
number = "2",
volume = "1",
doi = "10.30544/MMD6"
}
Petronijević, N., Radovanović, D., Stanković, S., Sokić, M., Kamberović, Ž., Onjia, A.,& Jovanović, G.. (2023). Stability of solid residue after integral treatment of acid mine drainage. in Metallurgical and Materials Data
Belgrade : Association of Metallurgical Engineers of Serbia., 1(2), 57-63.
https://doi.org/10.30544/MMD6
Petronijević N, Radovanović D, Stanković S, Sokić M, Kamberović Ž, Onjia A, Jovanović G. Stability of solid residue after integral treatment of acid mine drainage. in Metallurgical and Materials Data. 2023;1(2):57-63.
doi:10.30544/MMD6 .
Petronijević, Nela, Radovanović, Dragana, Stanković, Srđan, Sokić, Miroslav, Kamberović, Željko, Onjia, Antonije, Jovanović, Gvozden, "Stability of solid residue after integral treatment of acid mine drainage" in Metallurgical and Materials Data, 1, no. 2 (2023):57-63,
https://doi.org/10.30544/MMD6 . .

Sustainable mining and acid mine water treatment

Petronijević, Nela; Jovanović, Gvozden; Sokić, Miroslav; Jovanović, Aleksandar; Radovanović, Dragana; Kamberović, Željko; Stanković, Srđan

(Ljubljana : University of Ljubljana Press, 2022)

TY  - CONF
AU  - Petronijević, Nela
AU  - Jovanović, Gvozden
AU  - Sokić, Miroslav
AU  - Jovanović, Aleksandar
AU  - Radovanović, Dragana
AU  - Kamberović, Željko
AU  - Stanković, Srđan
PY  - 2022
UR  - https://ritnms.itnms.ac.rs/handle/123456789/1026
AB  - The mining sector, nowadays, faces rising
challenges to find suitable practice that are
sustainable for already disposed waste streams
(AMD, flotation tailings and fly ash) [1]. There is a
growing tendency globally to use waste from
various industries to neutralize AMD, which has
both economic and environmental benefits. In
attempt to connect mining waste with concept of
sustainable development in the Republic of Serbia,
several experiments were taken into consideration:
neutralisation of AMD from Bor’s mine with a)
flotation tailings from copper mine Majdanpek
(FJM) b) fly ash (FA) from thermal power Nikola
Tesla (EF) and Kostolac (KOST). All three samples
of alternative product are voluminous, hazardous
waste products, difficult and expensive for safe
deposition, causes environmental pollution (by
spontaneous leaching of useful components, which
causes additional investment in the rehabilitation of
that or reversibly lost compounds that pollutes the
environment, or its dispersion by wind in
surrounding streams and groundwater resources of
drinking water, air or soil and also degradation by
soil erosion) and can affects human health’s if are
not regularly discharged. But its benefits are that
there are free of charge alkaline wastes, suitable to
neutralize the AMD by altering pH, which leads to
precipitation of valuable metal which can be reused,
such as Fe or Cu. The chemical and mineralogical
composition of the initial samples of FJM and FA
was evaluated two standard leaching tests: TCLP
and EN 12457-4, as well as Acid Neutralization
Capacity test. These base materials were shown to
have a large capacity to neutralize acid, making
them a highly effective alternative material for
neutralizing acid mine drainage and eliminating
metals, even better than results of neutralisation
with NaOH, as conventional reagent. According to
the findings the FJM and FA neutralization
experiments precipitated more than 99 % of Al, Fe,
and Cu, 90 % of Pb, and 92 % of Zn. Leaching of
these metals from FJM and FA raises Cd and Mn
concentrations. Additional treatment was
undertaken using hydrated lime to boost the pH to
10 and so offer circumstances for its removal, in
order to reduce the concentration of Mn below the
authorized limits by Serbian legislation. At the end,
as a result of utilizing alternative materials such as
FJM and two FA purified water, safe for release into
the environment was obtained. In this way,
resources are preserved for the future generation,
and the treatment of already disposed amounts of
waste reduces the contamination of the
environment, the emission of toxic metals and the
formation of acidic mine waters.
PB  - Ljubljana : University of Ljubljana Press
C3  - 22nd European Meeting on Environmental Chemistry EMEC22
T1  - Sustainable mining and acid mine water treatment
EP  - 62
SP  - 62
DO  - 10.55295/9789612970352
ER  - 
@conference{
author = "Petronijević, Nela and Jovanović, Gvozden and Sokić, Miroslav and Jovanović, Aleksandar and Radovanović, Dragana and Kamberović, Željko and Stanković, Srđan",
year = "2022",
abstract = "The mining sector, nowadays, faces rising
challenges to find suitable practice that are
sustainable for already disposed waste streams
(AMD, flotation tailings and fly ash) [1]. There is a
growing tendency globally to use waste from
various industries to neutralize AMD, which has
both economic and environmental benefits. In
attempt to connect mining waste with concept of
sustainable development in the Republic of Serbia,
several experiments were taken into consideration:
neutralisation of AMD from Bor’s mine with a)
flotation tailings from copper mine Majdanpek
(FJM) b) fly ash (FA) from thermal power Nikola
Tesla (EF) and Kostolac (KOST). All three samples
of alternative product are voluminous, hazardous
waste products, difficult and expensive for safe
deposition, causes environmental pollution (by
spontaneous leaching of useful components, which
causes additional investment in the rehabilitation of
that or reversibly lost compounds that pollutes the
environment, or its dispersion by wind in
surrounding streams and groundwater resources of
drinking water, air or soil and also degradation by
soil erosion) and can affects human health’s if are
not regularly discharged. But its benefits are that
there are free of charge alkaline wastes, suitable to
neutralize the AMD by altering pH, which leads to
precipitation of valuable metal which can be reused,
such as Fe or Cu. The chemical and mineralogical
composition of the initial samples of FJM and FA
was evaluated two standard leaching tests: TCLP
and EN 12457-4, as well as Acid Neutralization
Capacity test. These base materials were shown to
have a large capacity to neutralize acid, making
them a highly effective alternative material for
neutralizing acid mine drainage and eliminating
metals, even better than results of neutralisation
with NaOH, as conventional reagent. According to
the findings the FJM and FA neutralization
experiments precipitated more than 99 % of Al, Fe,
and Cu, 90 % of Pb, and 92 % of Zn. Leaching of
these metals from FJM and FA raises Cd and Mn
concentrations. Additional treatment was
undertaken using hydrated lime to boost the pH to
10 and so offer circumstances for its removal, in
order to reduce the concentration of Mn below the
authorized limits by Serbian legislation. At the end,
as a result of utilizing alternative materials such as
FJM and two FA purified water, safe for release into
the environment was obtained. In this way,
resources are preserved for the future generation,
and the treatment of already disposed amounts of
waste reduces the contamination of the
environment, the emission of toxic metals and the
formation of acidic mine waters.",
publisher = "Ljubljana : University of Ljubljana Press",
journal = "22nd European Meeting on Environmental Chemistry EMEC22",
title = "Sustainable mining and acid mine water treatment",
pages = "62-62",
doi = "10.55295/9789612970352"
}
Petronijević, N., Jovanović, G., Sokić, M., Jovanović, A., Radovanović, D., Kamberović, Ž.,& Stanković, S.. (2022). Sustainable mining and acid mine water treatment. in 22nd European Meeting on Environmental Chemistry EMEC22
Ljubljana : University of Ljubljana Press., 62-62.
https://doi.org/10.55295/9789612970352
Petronijević N, Jovanović G, Sokić M, Jovanović A, Radovanović D, Kamberović Ž, Stanković S. Sustainable mining and acid mine water treatment. in 22nd European Meeting on Environmental Chemistry EMEC22. 2022;:62-62.
doi:10.55295/9789612970352 .
Petronijević, Nela, Jovanović, Gvozden, Sokić, Miroslav, Jovanović, Aleksandar, Radovanović, Dragana, Kamberović, Željko, Stanković, Srđan, "Sustainable mining and acid mine water treatment" in 22nd European Meeting on Environmental Chemistry EMEC22 (2022):62-62,
https://doi.org/10.55295/9789612970352 . .

Analysis of the Mechanism of Acid Mine Drainage Neutralization Using Fly Ash as an Alternative Material: A Case Study of the Extremely Acidic Lake Robule in Eastern Serbia

Petronijević, Nela; Radovanović, Dragana; Stulović, Marija; Sokić, Miroslav; Jovanović, Gvozden; Kamberović, Željko; Stanković, Srđan; Stopić, Srećko; Onjia, Antonije

(MDPI, Basel, 2022)

TY  - JOUR
AU  - Petronijević, Nela
AU  - Radovanović, Dragana
AU  - Stulović, Marija
AU  - Sokić, Miroslav
AU  - Jovanović, Gvozden
AU  - Kamberović, Željko
AU  - Stanković, Srđan
AU  - Stopić, Srećko
AU  - Onjia, Antonije
PY  - 2022
UR  - https://ritnms.itnms.ac.rs/handle/123456789/616
AB  - Acid mine drainage (AMD) is a waste from mining sites, usually acidic, with high concentrations of sulfates and heavy metal ions. This study investigates the AMD neutralization process using fly ash (FA) as an alternative material. Samples of FA from coal-fired power plants in Serbia ("Nikola Tesla" (EF) and "Kostolac" (KOST)) were analyzed and used. The results were compared with the treatment efficiency of commercial neutralization agent (NaOH). The alkaline nature of FA was the basis for use in the treatment process of the extremely acid Lake Robule (pH 2.46), located in the mining areas of eastern Serbia. The optimal S/L ratio for the AMD neutralization process determined for EF was 25 wt.%, and for KOST it was 20 wt.%. The mechanism of the neutralization process was analyzed using the ANC test and PHREEQC program. The element concentrations and pH values in solutions indicated that FA samples could neutralize Lake Robule with more than 99% of Al, Fe, Cu, Zn, and more than 89% of Pb precipitated. Formation of insoluble (oxy)hydroxide forms (Fe3+ and Al3+ ions) creates favorable conditions for co-precipitation of other trace metals (Cu, Zn, Ni, Pb, and Cd) from AMD, which is further enhanced by cation adsorption on FA particles. FA proved to be a more effective neutralization agent than NaOH due to its adsorption effect, while among the FA samples, KOST was more effective due to the aging process through the carbonization reaction. Using FA as an alternative material is a promising and sustainable method for treating AMD, with economic and environmental benefits.
PB  - MDPI, Basel
T2  - Water
T1  - Analysis of the Mechanism of Acid Mine Drainage Neutralization Using Fly Ash as an Alternative Material: A Case Study of the Extremely Acidic Lake Robule in Eastern Serbia
IS  - 20
VL  - 14
DO  - 10.3390/w14203244
UR  - conv_955
ER  - 
@article{
author = "Petronijević, Nela and Radovanović, Dragana and Stulović, Marija and Sokić, Miroslav and Jovanović, Gvozden and Kamberović, Željko and Stanković, Srđan and Stopić, Srećko and Onjia, Antonije",
year = "2022",
abstract = "Acid mine drainage (AMD) is a waste from mining sites, usually acidic, with high concentrations of sulfates and heavy metal ions. This study investigates the AMD neutralization process using fly ash (FA) as an alternative material. Samples of FA from coal-fired power plants in Serbia ("Nikola Tesla" (EF) and "Kostolac" (KOST)) were analyzed and used. The results were compared with the treatment efficiency of commercial neutralization agent (NaOH). The alkaline nature of FA was the basis for use in the treatment process of the extremely acid Lake Robule (pH 2.46), located in the mining areas of eastern Serbia. The optimal S/L ratio for the AMD neutralization process determined for EF was 25 wt.%, and for KOST it was 20 wt.%. The mechanism of the neutralization process was analyzed using the ANC test and PHREEQC program. The element concentrations and pH values in solutions indicated that FA samples could neutralize Lake Robule with more than 99% of Al, Fe, Cu, Zn, and more than 89% of Pb precipitated. Formation of insoluble (oxy)hydroxide forms (Fe3+ and Al3+ ions) creates favorable conditions for co-precipitation of other trace metals (Cu, Zn, Ni, Pb, and Cd) from AMD, which is further enhanced by cation adsorption on FA particles. FA proved to be a more effective neutralization agent than NaOH due to its adsorption effect, while among the FA samples, KOST was more effective due to the aging process through the carbonization reaction. Using FA as an alternative material is a promising and sustainable method for treating AMD, with economic and environmental benefits.",
publisher = "MDPI, Basel",
journal = "Water",
title = "Analysis of the Mechanism of Acid Mine Drainage Neutralization Using Fly Ash as an Alternative Material: A Case Study of the Extremely Acidic Lake Robule in Eastern Serbia",
number = "20",
volume = "14",
doi = "10.3390/w14203244",
url = "conv_955"
}
Petronijević, N., Radovanović, D., Stulović, M., Sokić, M., Jovanović, G., Kamberović, Ž., Stanković, S., Stopić, S.,& Onjia, A.. (2022). Analysis of the Mechanism of Acid Mine Drainage Neutralization Using Fly Ash as an Alternative Material: A Case Study of the Extremely Acidic Lake Robule in Eastern Serbia. in Water
MDPI, Basel., 14(20).
https://doi.org/10.3390/w14203244
conv_955
Petronijević N, Radovanović D, Stulović M, Sokić M, Jovanović G, Kamberović Ž, Stanković S, Stopić S, Onjia A. Analysis of the Mechanism of Acid Mine Drainage Neutralization Using Fly Ash as an Alternative Material: A Case Study of the Extremely Acidic Lake Robule in Eastern Serbia. in Water. 2022;14(20).
doi:10.3390/w14203244
conv_955 .
Petronijević, Nela, Radovanović, Dragana, Stulović, Marija, Sokić, Miroslav, Jovanović, Gvozden, Kamberović, Željko, Stanković, Srđan, Stopić, Srećko, Onjia, Antonije, "Analysis of the Mechanism of Acid Mine Drainage Neutralization Using Fly Ash as an Alternative Material: A Case Study of the Extremely Acidic Lake Robule in Eastern Serbia" in Water, 14, no. 20 (2022),
https://doi.org/10.3390/w14203244 .,
conv_955 .
5
5

Sustainable mining towards accoplisihng circular economy principles

Petronijević, Nela; Alivojvodić, Vesna; Sokić, Miroslav; Marković, Branislav; Stanković, Srđan; Radovanović, Dragana

(Beograd : Institut za istraživanja i projektovanja u privredi, 2020)

TY  - CONF
AU  - Petronijević, Nela
AU  - Alivojvodić, Vesna
AU  - Sokić, Miroslav
AU  - Marković, Branislav
AU  - Stanković, Srđan
AU  - Radovanović, Dragana
PY  - 2020
UR  - https://ritnms.itnms.ac.rs/handle/123456789/957
AB  - Today human society is already witnessing rapid depletion of non-renewable ore resources. As the distribution of raw material resources globally is very off-balance, and preassure on environment as the consequence of ore exploatation is not negligible, reutilization and recycling of industrial side-streams gaining on importance. Finding new potentially anthropogenic resources of material (at first place critical raw materials) are inline with sustainable waste management goals, and in correlation with boundaries given by the circular economy principles. Side-streams from mines can become source for recovery of these materials. The aim of this paper was to analyze position of mining waste in correlation with circular economy principles, as well potential for implementation of them within extraction industry in the Republic of Serbia.
PB  - Beograd : Institut za istraživanja i projektovanja u privredi
C3  - YOUng ResearcherS Conference 2020
T1  - Sustainable mining towards accoplisihng circular economy principles
EP  - 24
SP  - 24
ER  - 
@conference{
author = "Petronijević, Nela and Alivojvodić, Vesna and Sokić, Miroslav and Marković, Branislav and Stanković, Srđan and Radovanović, Dragana",
year = "2020",
abstract = "Today human society is already witnessing rapid depletion of non-renewable ore resources. As the distribution of raw material resources globally is very off-balance, and preassure on environment as the consequence of ore exploatation is not negligible, reutilization and recycling of industrial side-streams gaining on importance. Finding new potentially anthropogenic resources of material (at first place critical raw materials) are inline with sustainable waste management goals, and in correlation with boundaries given by the circular economy principles. Side-streams from mines can become source for recovery of these materials. The aim of this paper was to analyze position of mining waste in correlation with circular economy principles, as well potential for implementation of them within extraction industry in the Republic of Serbia.",
publisher = "Beograd : Institut za istraživanja i projektovanja u privredi",
journal = "YOUng ResearcherS Conference 2020",
title = "Sustainable mining towards accoplisihng circular economy principles",
pages = "24-24"
}
Petronijević, N., Alivojvodić, V., Sokić, M., Marković, B., Stanković, S.,& Radovanović, D.. (2020). Sustainable mining towards accoplisihng circular economy principles. in YOUng ResearcherS Conference 2020
Beograd : Institut za istraživanja i projektovanja u privredi., 24-24.
Petronijević N, Alivojvodić V, Sokić M, Marković B, Stanković S, Radovanović D. Sustainable mining towards accoplisihng circular economy principles. in YOUng ResearcherS Conference 2020. 2020;:24-24..
Petronijević, Nela, Alivojvodić, Vesna, Sokić, Miroslav, Marković, Branislav, Stanković, Srđan, Radovanović, Dragana, "Sustainable mining towards accoplisihng circular economy principles" in YOUng ResearcherS Conference 2020 (2020):24-24.

Atmosfersko luženje bakra iz oksidno-sulfidne rude rastvorom sumporne kiseline

Ranitović, Milisav; Kamberović, Željko; Korać, Marija S.; Radovanović, Dragana; Sokić, Miroslav

(Savez inženjera i tehničara Srbije, Beograd, 2020)

TY  - JOUR
AU  - Ranitović, Milisav
AU  - Kamberović, Željko
AU  - Korać, Marija S.
AU  - Radovanović, Dragana
AU  - Sokić, Miroslav
PY  - 2020
UR  - https://ritnms.itnms.ac.rs/handle/123456789/548
AB  - Visoka fleksibilnost, ekonomičnost i ekološka prihvatljivost hidrometalurških operacija nude mogućnost za selektivno dobijanje metala u ranim fazama tehnološkog procesa. To omogućava primenu hidrometalurških operacija u preradi ruda koje, zbog kompleksnog sastava ili niskog sadržaja metala, nisu pogodne za pirometalurški tretman. Nasuprot sulfidnim mineralima, za luženje oksidnih ruda nije potrebno prisustvo oksidansa. U ovom radu prikazani su rezultati ispitivanja uticaja temperature na stepen izluženja bakra iz piritno-halkopiritnog koncentrata rastvorom sumporne kiseline pri atmosferskom pritisku. Na osnovu dobijenih rezultata utvrđeno je da povećanje temperature luženja značajno doprinosi povećanju efikasnosti izluženja pri čemu nakon 6 sati luženja na 40°C postignuta efikasnost je iznosila 90,6%.
AB  - High flexibility of hydrometallurgical operations as well as economic and environmental acceptability, offer the opportunity to selectively obtain metals in the early stages of the processing. This enables the application of hydrometallurgical operations in processing of ores which, due to their complex composition or low copper content, are not suitable for pyrometallurgical treatment. In contrast to sulfide minerals, leaching of oxide ores does not requires presence of oxidizing agent. This paper presents the results of influence of temperature on the leaching degree of copper from pyritechalcopyrite concentrate by sulfuric acid solution at atmospheric pressure. According to the obtained results, it was found that an increase in the leaching temperature significantly contributes to the increase in the leaching efficiency, where after 6 hours of leaching at 40°C achieved efficiency was 90.6%.
PB  - Savez inženjera i tehničara Srbije, Beograd
T2  - Tehnika
T1  - Atmosfersko luženje bakra iz oksidno-sulfidne rude rastvorom sumporne kiseline
T1  - Atmospheric leaching of copper from oxide-sulfide ore using sulfuric acid
EP  - 175
IS  - 2
SP  - 172
VL  - 75
DO  - 10.5937/tehnika2002172R
UR  - conv_28
ER  - 
@article{
author = "Ranitović, Milisav and Kamberović, Željko and Korać, Marija S. and Radovanović, Dragana and Sokić, Miroslav",
year = "2020",
abstract = "Visoka fleksibilnost, ekonomičnost i ekološka prihvatljivost hidrometalurških operacija nude mogućnost za selektivno dobijanje metala u ranim fazama tehnološkog procesa. To omogućava primenu hidrometalurških operacija u preradi ruda koje, zbog kompleksnog sastava ili niskog sadržaja metala, nisu pogodne za pirometalurški tretman. Nasuprot sulfidnim mineralima, za luženje oksidnih ruda nije potrebno prisustvo oksidansa. U ovom radu prikazani su rezultati ispitivanja uticaja temperature na stepen izluženja bakra iz piritno-halkopiritnog koncentrata rastvorom sumporne kiseline pri atmosferskom pritisku. Na osnovu dobijenih rezultata utvrđeno je da povećanje temperature luženja značajno doprinosi povećanju efikasnosti izluženja pri čemu nakon 6 sati luženja na 40°C postignuta efikasnost je iznosila 90,6%., High flexibility of hydrometallurgical operations as well as economic and environmental acceptability, offer the opportunity to selectively obtain metals in the early stages of the processing. This enables the application of hydrometallurgical operations in processing of ores which, due to their complex composition or low copper content, are not suitable for pyrometallurgical treatment. In contrast to sulfide minerals, leaching of oxide ores does not requires presence of oxidizing agent. This paper presents the results of influence of temperature on the leaching degree of copper from pyritechalcopyrite concentrate by sulfuric acid solution at atmospheric pressure. According to the obtained results, it was found that an increase in the leaching temperature significantly contributes to the increase in the leaching efficiency, where after 6 hours of leaching at 40°C achieved efficiency was 90.6%.",
publisher = "Savez inženjera i tehničara Srbije, Beograd",
journal = "Tehnika",
title = "Atmosfersko luženje bakra iz oksidno-sulfidne rude rastvorom sumporne kiseline, Atmospheric leaching of copper from oxide-sulfide ore using sulfuric acid",
pages = "175-172",
number = "2",
volume = "75",
doi = "10.5937/tehnika2002172R",
url = "conv_28"
}
Ranitović, M., Kamberović, Ž., Korać, M. S., Radovanović, D.,& Sokić, M.. (2020). Atmosfersko luženje bakra iz oksidno-sulfidne rude rastvorom sumporne kiseline. in Tehnika
Savez inženjera i tehničara Srbije, Beograd., 75(2), 172-175.
https://doi.org/10.5937/tehnika2002172R
conv_28
Ranitović M, Kamberović Ž, Korać MS, Radovanović D, Sokić M. Atmosfersko luženje bakra iz oksidno-sulfidne rude rastvorom sumporne kiseline. in Tehnika. 2020;75(2):172-175.
doi:10.5937/tehnika2002172R
conv_28 .
Ranitović, Milisav, Kamberović, Željko, Korać, Marija S., Radovanović, Dragana, Sokić, Miroslav, "Atmosfersko luženje bakra iz oksidno-sulfidne rude rastvorom sumporne kiseline" in Tehnika, 75, no. 2 (2020):172-175,
https://doi.org/10.5937/tehnika2002172R .,
conv_28 .

Application of the Flotation Tailings as an Alternative Material for an Acid Mine Drainage Remediation: A Case Study of the Extremely Acidic Lake Robule (Serbia)

Petronijević, Nela; Stanković, Srđan; Radovanović, Dragana; Sokić, Miroslav; Marković, Branislav; Stopić, Srećko; Kamberović, Željko

(MDPI, Basel, 2020)

TY  - JOUR
AU  - Petronijević, Nela
AU  - Stanković, Srđan
AU  - Radovanović, Dragana
AU  - Sokić, Miroslav
AU  - Marković, Branislav
AU  - Stopić, Srećko
AU  - Kamberović, Željko
PY  - 2020
UR  - https://ritnms.itnms.ac.rs/handle/123456789/546
AB  - Flotation tailings rich in carbonate minerals from the tailings deposit of the copper mine Majdanpek (Serbia) were applied for neutralization of the water taken from the extremely acidic Lake Robule (Bor, Serbia). Tests conducted in Erlenmeyer flasks showed that after neutralization of the lake water to pH 7, over 99% of aluminum (Al), iron (Fe), and copper (Cu) precipitated, as well as 92% of Zn and 98% of Pb. In order to remove residual Mn and Ag, the water was further treated with NaOH. After treatment with NaOH, all concentrations of the metals in the lake water samples were below discharge limits for municipal wastewater according to the national legislation of the Republic of Serbia. The results of this work suggest that mining waste could be used for active neutralization of the acid mine drainage. The use of the mining waste instead of lime could reduce the costs of the active treatment of the acid mine drainage.
PB  - MDPI, Basel
T2  - Metals
T1  - Application of the Flotation Tailings as an Alternative Material for an Acid Mine Drainage Remediation: A Case Study of the Extremely Acidic Lake Robule (Serbia)
IS  - 1
VL  - 10
DO  - 10.3390/met10010016
UR  - conv_875
ER  - 
@article{
author = "Petronijević, Nela and Stanković, Srđan and Radovanović, Dragana and Sokić, Miroslav and Marković, Branislav and Stopić, Srećko and Kamberović, Željko",
year = "2020",
abstract = "Flotation tailings rich in carbonate minerals from the tailings deposit of the copper mine Majdanpek (Serbia) were applied for neutralization of the water taken from the extremely acidic Lake Robule (Bor, Serbia). Tests conducted in Erlenmeyer flasks showed that after neutralization of the lake water to pH 7, over 99% of aluminum (Al), iron (Fe), and copper (Cu) precipitated, as well as 92% of Zn and 98% of Pb. In order to remove residual Mn and Ag, the water was further treated with NaOH. After treatment with NaOH, all concentrations of the metals in the lake water samples were below discharge limits for municipal wastewater according to the national legislation of the Republic of Serbia. The results of this work suggest that mining waste could be used for active neutralization of the acid mine drainage. The use of the mining waste instead of lime could reduce the costs of the active treatment of the acid mine drainage.",
publisher = "MDPI, Basel",
journal = "Metals",
title = "Application of the Flotation Tailings as an Alternative Material for an Acid Mine Drainage Remediation: A Case Study of the Extremely Acidic Lake Robule (Serbia)",
number = "1",
volume = "10",
doi = "10.3390/met10010016",
url = "conv_875"
}
Petronijević, N., Stanković, S., Radovanović, D., Sokić, M., Marković, B., Stopić, S.,& Kamberović, Ž.. (2020). Application of the Flotation Tailings as an Alternative Material for an Acid Mine Drainage Remediation: A Case Study of the Extremely Acidic Lake Robule (Serbia). in Metals
MDPI, Basel., 10(1).
https://doi.org/10.3390/met10010016
conv_875
Petronijević N, Stanković S, Radovanović D, Sokić M, Marković B, Stopić S, Kamberović Ž. Application of the Flotation Tailings as an Alternative Material for an Acid Mine Drainage Remediation: A Case Study of the Extremely Acidic Lake Robule (Serbia). in Metals. 2020;10(1).
doi:10.3390/met10010016
conv_875 .
Petronijević, Nela, Stanković, Srđan, Radovanović, Dragana, Sokić, Miroslav, Marković, Branislav, Stopić, Srećko, Kamberović, Željko, "Application of the Flotation Tailings as an Alternative Material for an Acid Mine Drainage Remediation: A Case Study of the Extremely Acidic Lake Robule (Serbia)" in Metals, 10, no. 1 (2020),
https://doi.org/10.3390/met10010016 .,
conv_875 .
10
5
11

Sustainable mining towards accomplishing circular economy principles

Petronijević, Nela; Alivojvodić, Vesna; Sokić, Miroslav; Marković, Branislav; Stanković, Srđan; Radovanović, Dragana

(Institut za istraživanja i projektovanja u privredi, Beograd, 2020)

TY  - JOUR
AU  - Petronijević, Nela
AU  - Alivojvodić, Vesna
AU  - Sokić, Miroslav
AU  - Marković, Branislav
AU  - Stanković, Srđan
AU  - Radovanović, Dragana
PY  - 2020
UR  - https://ritnms.itnms.ac.rs/handle/123456789/531
AB  - Today human society is already witnessing rapid depletion of non-renewable ore resources. As the distribution of raw material resources globally is very off-balance, and preassure on environment as the consequence of ore exploatation is not negligible, re-utilization and recycling of industrial side-streams gaining on importance. Finding new potentially anthropogenic resources of material (at first place critical raw materials) are inline with sustainable waste management goals, and in correlation with boundaries given by the circular economy principles. Side-streams from mines can become source for recovery of these materials. The aim of this paper was to analyze position of mining waste in correlation with circular economy principles, as well potential for implementation of them within extraction industry in the Republic of Serbia.
PB  - Institut za istraživanja i projektovanja u privredi, Beograd
T2  - Journal of Applied Engineering Science
T1  - Sustainable mining towards accomplishing circular economy principles
EP  - 499
IS  - 4
SP  - 493
VL  - 18
DO  - 10.5937/jaes0-27460
UR  - conv_380
ER  - 
@article{
author = "Petronijević, Nela and Alivojvodić, Vesna and Sokić, Miroslav and Marković, Branislav and Stanković, Srđan and Radovanović, Dragana",
year = "2020",
abstract = "Today human society is already witnessing rapid depletion of non-renewable ore resources. As the distribution of raw material resources globally is very off-balance, and preassure on environment as the consequence of ore exploatation is not negligible, re-utilization and recycling of industrial side-streams gaining on importance. Finding new potentially anthropogenic resources of material (at first place critical raw materials) are inline with sustainable waste management goals, and in correlation with boundaries given by the circular economy principles. Side-streams from mines can become source for recovery of these materials. The aim of this paper was to analyze position of mining waste in correlation with circular economy principles, as well potential for implementation of them within extraction industry in the Republic of Serbia.",
publisher = "Institut za istraživanja i projektovanja u privredi, Beograd",
journal = "Journal of Applied Engineering Science",
title = "Sustainable mining towards accomplishing circular economy principles",
pages = "499-493",
number = "4",
volume = "18",
doi = "10.5937/jaes0-27460",
url = "conv_380"
}
Petronijević, N., Alivojvodić, V., Sokić, M., Marković, B., Stanković, S.,& Radovanović, D.. (2020). Sustainable mining towards accomplishing circular economy principles. in Journal of Applied Engineering Science
Institut za istraživanja i projektovanja u privredi, Beograd., 18(4), 493-499.
https://doi.org/10.5937/jaes0-27460
conv_380
Petronijević N, Alivojvodić V, Sokić M, Marković B, Stanković S, Radovanović D. Sustainable mining towards accomplishing circular economy principles. in Journal of Applied Engineering Science. 2020;18(4):493-499.
doi:10.5937/jaes0-27460
conv_380 .
Petronijević, Nela, Alivojvodić, Vesna, Sokić, Miroslav, Marković, Branislav, Stanković, Srđan, Radovanović, Dragana, "Sustainable mining towards accomplishing circular economy principles" in Journal of Applied Engineering Science, 18, no. 4 (2020):493-499,
https://doi.org/10.5937/jaes0-27460 .,
conv_380 .
3
3

Treatment of the acidic effluent from a copper smelter by flotation tailings

Sokić, Miroslav; Radovanović, Dragana; Marković, Branislav; Stojanović, Jovica; Kamberović, Željko; Petronijević, Nela; Stanković, Srđan

(Savez hemijskih inženjera, Beograd, 2019)

TY  - JOUR
AU  - Sokić, Miroslav
AU  - Radovanović, Dragana
AU  - Marković, Branislav
AU  - Stojanović, Jovica
AU  - Kamberović, Željko
AU  - Petronijević, Nela
AU  - Stanković, Srđan
PY  - 2019
UR  - https://ritnms.itnms.ac.rs/handle/123456789/508
AB  - Since commissioning in 1961, the copper mine Majdanpek, a part of the Mining and Smelting Complex Bor (RTB Bor), produced approximately 378 million tons of flotation tailings. Semiquantitative mineralogical analysis of the flotation tailings revealed significant content of carbonate minerals (approximately 20-25 %), indicating high acid neutralization capacity. Also, approximately 70 % of copper is in the form of the oxide mineral cuprite (Cu2O). Copper can be easily leached from cuprite by using sulphuric acid. The RTB Bor copper smelter generates 8.7 m(3)h(-1) of extremely acidic waste effluent (142.4 kgm(-3) of sulphuric acid, pH - 0.464) with relatively high concentrations of dissolved metals and metalloids (Cu, Fe, Zn, Pb and As). The effluent is currently treated with hydrated lime. The present study focused on application of flotation tailings as a neutralizing agent for acidic effluents. Laboratory experiments followed by computer simulation of the industrial process showed that 99% of the acid can be neutralized with flotation tailings in a series of six reactors resulting in the final copper concentration of 1.55 gL(-1). Benefits of the proposed process are: lower environmental impact of the process and reduced costs of neutralization of the acidic effluent from the copper smelter.
PB  - Savez hemijskih inženjera, Beograd
T2  - Hemijska industrija
T1  - Treatment of the acidic effluent from a copper smelter by flotation tailings
EP  - 124
IS  - 2
SP  - 115
VL  - 73
DO  - 10.2298/HEMIND181009010S
UR  - conv_850
ER  - 
@article{
author = "Sokić, Miroslav and Radovanović, Dragana and Marković, Branislav and Stojanović, Jovica and Kamberović, Željko and Petronijević, Nela and Stanković, Srđan",
year = "2019",
abstract = "Since commissioning in 1961, the copper mine Majdanpek, a part of the Mining and Smelting Complex Bor (RTB Bor), produced approximately 378 million tons of flotation tailings. Semiquantitative mineralogical analysis of the flotation tailings revealed significant content of carbonate minerals (approximately 20-25 %), indicating high acid neutralization capacity. Also, approximately 70 % of copper is in the form of the oxide mineral cuprite (Cu2O). Copper can be easily leached from cuprite by using sulphuric acid. The RTB Bor copper smelter generates 8.7 m(3)h(-1) of extremely acidic waste effluent (142.4 kgm(-3) of sulphuric acid, pH - 0.464) with relatively high concentrations of dissolved metals and metalloids (Cu, Fe, Zn, Pb and As). The effluent is currently treated with hydrated lime. The present study focused on application of flotation tailings as a neutralizing agent for acidic effluents. Laboratory experiments followed by computer simulation of the industrial process showed that 99% of the acid can be neutralized with flotation tailings in a series of six reactors resulting in the final copper concentration of 1.55 gL(-1). Benefits of the proposed process are: lower environmental impact of the process and reduced costs of neutralization of the acidic effluent from the copper smelter.",
publisher = "Savez hemijskih inženjera, Beograd",
journal = "Hemijska industrija",
title = "Treatment of the acidic effluent from a copper smelter by flotation tailings",
pages = "124-115",
number = "2",
volume = "73",
doi = "10.2298/HEMIND181009010S",
url = "conv_850"
}
Sokić, M., Radovanović, D., Marković, B., Stojanović, J., Kamberović, Ž., Petronijević, N.,& Stanković, S.. (2019). Treatment of the acidic effluent from a copper smelter by flotation tailings. in Hemijska industrija
Savez hemijskih inženjera, Beograd., 73(2), 115-124.
https://doi.org/10.2298/HEMIND181009010S
conv_850
Sokić M, Radovanović D, Marković B, Stojanović J, Kamberović Ž, Petronijević N, Stanković S. Treatment of the acidic effluent from a copper smelter by flotation tailings. in Hemijska industrija. 2019;73(2):115-124.
doi:10.2298/HEMIND181009010S
conv_850 .
Sokić, Miroslav, Radovanović, Dragana, Marković, Branislav, Stojanović, Jovica, Kamberović, Željko, Petronijević, Nela, Stanković, Srđan, "Treatment of the acidic effluent from a copper smelter by flotation tailings" in Hemijska industrija, 73, no. 2 (2019):115-124,
https://doi.org/10.2298/HEMIND181009010S .,
conv_850 .
3
1
3

The effect of CaO and MgO addition and cooling rate on stability of slag obtained after jarosite and neutral leaching residue treatment in the Waelz process

Radovanović, Dragana; Kamberović, Željko; Anđić, Zoran; Ranitović, Milisav; Marković, Branislav

(Oficyna Wydawnicza Politechniki Wroclawskiej, Wroclaw, 2018)

TY  - JOUR
AU  - Radovanović, Dragana
AU  - Kamberović, Željko
AU  - Anđić, Zoran
AU  - Ranitović, Milisav
AU  - Marković, Branislav
PY  - 2018
UR  - https://ritnms.itnms.ac.rs/handle/123456789/479
AB  - Jarosite and neutral leaching residue (NLR) are the greatest environmental problems of hydrometallurgical zinc production due to their high quantity and hazardous content. Pyrometallurgical processes, such as the Waelz process, could be applied to recover valuable metals present in this waste. The paper investigates the possibility of forming environmentally stable Waelz slag after the Waelz process of jarosite and NLR. Waelz slag, obtained using CaO as a conventional alkaline additive in the Waelz process, showed high As and Sb release after the EN 12457-4 standard leaching test. Multiphase equilibrium composition calculations indicated that As and Sb were present as volatile and migratory species in the slag. In order to obtain Waelz slag with more stable matrices that would encapsulate and immobilize pollutants, MgO additions to CaO and different cooling conditions of the slag were further investigated. The efficiency of modification in additives composition and cooling conditions was assessed by EN 12457-4 leaching test and chemical and microstructural characterization (XRF and SEM-EDS analyses) of the Waelz slags. The results show that addition of MgO does not reduce the efficiency of the process, even more it increases leaching resistance of the slags. Concentrations of all investigated metals (As, Ba, Cu, Mo, Pb, Sb, Zn) after the leaching test were below defined limits for non-hazardous waste. Microstructural analyses revealed that MgO remained inert during Waelz process, and thus favoring the formation of amorphous stable structure, which was enhanced by increased cooling rate. All investigated Waelz slags with MgO additions are suitable for further use or safe disposal.
PB  - Oficyna Wydawnicza Politechniki Wroclawskiej, Wroclaw
T2  - Physicochemical Problems of Mineral Processing
T1  - The effect of CaO and MgO addition and cooling rate on stability of slag obtained after jarosite and neutral leaching residue treatment in the Waelz process
EP  - 495
IS  - 2
SP  - 484
VL  - 54
DO  - 10.5277/ppmp1842
UR  - conv_827
ER  - 
@article{
author = "Radovanović, Dragana and Kamberović, Željko and Anđić, Zoran and Ranitović, Milisav and Marković, Branislav",
year = "2018",
abstract = "Jarosite and neutral leaching residue (NLR) are the greatest environmental problems of hydrometallurgical zinc production due to their high quantity and hazardous content. Pyrometallurgical processes, such as the Waelz process, could be applied to recover valuable metals present in this waste. The paper investigates the possibility of forming environmentally stable Waelz slag after the Waelz process of jarosite and NLR. Waelz slag, obtained using CaO as a conventional alkaline additive in the Waelz process, showed high As and Sb release after the EN 12457-4 standard leaching test. Multiphase equilibrium composition calculations indicated that As and Sb were present as volatile and migratory species in the slag. In order to obtain Waelz slag with more stable matrices that would encapsulate and immobilize pollutants, MgO additions to CaO and different cooling conditions of the slag were further investigated. The efficiency of modification in additives composition and cooling conditions was assessed by EN 12457-4 leaching test and chemical and microstructural characterization (XRF and SEM-EDS analyses) of the Waelz slags. The results show that addition of MgO does not reduce the efficiency of the process, even more it increases leaching resistance of the slags. Concentrations of all investigated metals (As, Ba, Cu, Mo, Pb, Sb, Zn) after the leaching test were below defined limits for non-hazardous waste. Microstructural analyses revealed that MgO remained inert during Waelz process, and thus favoring the formation of amorphous stable structure, which was enhanced by increased cooling rate. All investigated Waelz slags with MgO additions are suitable for further use or safe disposal.",
publisher = "Oficyna Wydawnicza Politechniki Wroclawskiej, Wroclaw",
journal = "Physicochemical Problems of Mineral Processing",
title = "The effect of CaO and MgO addition and cooling rate on stability of slag obtained after jarosite and neutral leaching residue treatment in the Waelz process",
pages = "495-484",
number = "2",
volume = "54",
doi = "10.5277/ppmp1842",
url = "conv_827"
}
Radovanović, D., Kamberović, Ž., Anđić, Z., Ranitović, M.,& Marković, B.. (2018). The effect of CaO and MgO addition and cooling rate on stability of slag obtained after jarosite and neutral leaching residue treatment in the Waelz process. in Physicochemical Problems of Mineral Processing
Oficyna Wydawnicza Politechniki Wroclawskiej, Wroclaw., 54(2), 484-495.
https://doi.org/10.5277/ppmp1842
conv_827
Radovanović D, Kamberović Ž, Anđić Z, Ranitović M, Marković B. The effect of CaO and MgO addition and cooling rate on stability of slag obtained after jarosite and neutral leaching residue treatment in the Waelz process. in Physicochemical Problems of Mineral Processing. 2018;54(2):484-495.
doi:10.5277/ppmp1842
conv_827 .
Radovanović, Dragana, Kamberović, Željko, Anđić, Zoran, Ranitović, Milisav, Marković, Branislav, "The effect of CaO and MgO addition and cooling rate on stability of slag obtained after jarosite and neutral leaching residue treatment in the Waelz process" in Physicochemical Problems of Mineral Processing, 54, no. 2 (2018):484-495,
https://doi.org/10.5277/ppmp1842 .,
conv_827 .
2
4