TY  - CONF
AU  - Grubišić, Mirko
AU  - Bošković-Rakočević, Ljiljana
AU  - Dugalić, Goran
AU  - Petrović, Jelena
AU  - Petrović, Marija
AU  - Milojković, Jelena
AU  - Kojić, Marija
PY  - 2019
UR  - https://ritnms.itnms.ac.rs/handle/123456789/1213
AB  - Knowledge of the mobility of heavy metals and radionuclides, such as Pb, Cd, Zn and U, represents one of the goals of protection, regulation, rational use and irrigation of agricultural soils from the aspect of safe food production. The aim of this work was investigation of efficiency of natural mineral materials based on zeolite and apatite from domestic deposits in the mobility of heavy metals and radionuclides in the waters and soils of the different physico-chemical characteristics (pseudogley and chemozem). The affinity, efficiency, zeolite adsorption mechanisms and apatite adsorption precipitation were determined in a constant- pressure column system at 300 mg 1 for different pH values (5.00 and 7.00) of the basic contaminated solution (Pb, Cd, Zn, U) at time intervals of 30, 60, 90, 120, 180 minutes. In all experiments, significant changes in the pH of the filtrate occurred. The most significant changes in the pH of the filtrate, minimal fluctuations in the time interval, at pH = 5.00, recorded the basic solutions of Pb (7.69-7.87) and U (7.77-7.93) during leakage through the column with apatite, while slightly lower changes for Cd and Zn were observed. Changes also occurred in the column with the zeolite, but with a much lower intensity compared to the column of apatite, and with the trend of changes U> Pb Cd Zn. The trend of changes between apatite and zeolite also occurred in the basic contaminated solution with initial pH-7.00. Zeolite and apatite adsorption/precipitation processes successfully immobilized Pb at both tested pH values of stock solution. Our investigation showed that in colonies, apatite better immobilized U, zeolite is better for immobilization of the Cd, while for the Zn both materials showed a very similar affinity. Zeolite and apatite were added in amount of 20 gkg soil to reduce the content of water-soluble and easily accessible forms of Pb, Cd and Zn in uncontaminated and contaminated soil.
PB  - East Sarajevo : University of East Sarajevo, Faculty of Agriculture, Republic of Srpska
C3  - X International Scientific Agriculture Symposium “Agrosym 2019”
T1  - Efficiency and the possibility of using zeolite and apatite purifying water for irrigation and remedation of contaminated soil
EP  - 884
SP  - 879
ER  - 

@conference{
author = "Grubišić, Mirko and Bošković-Rakočević, Ljiljana and Dugalić, Goran and Petrović, Jelena and Petrović, Marija and Milojković, Jelena and Kojić, Marija",
year = "2019",
abstract = "Knowledge of the mobility of heavy metals and radionuclides, such as Pb, Cd, Zn and U, represents one of the goals of protection, regulation, rational use and irrigation of agricultural soils from the aspect of safe food production. The aim of this work was investigation of efficiency of natural mineral materials based on zeolite and apatite from domestic deposits in the mobility of heavy metals and radionuclides in the waters and soils of the different physico-chemical characteristics (pseudogley and chemozem). The affinity, efficiency, zeolite adsorption mechanisms and apatite adsorption precipitation were determined in a constant- pressure column system at 300 mg 1 for different pH values (5.00 and 7.00) of the basic contaminated solution (Pb, Cd, Zn, U) at time intervals of 30, 60, 90, 120, 180 minutes. In all experiments, significant changes in the pH of the filtrate occurred. The most significant changes in the pH of the filtrate, minimal fluctuations in the time interval, at pH = 5.00, recorded the basic solutions of Pb (7.69-7.87) and U (7.77-7.93) during leakage through the column with apatite, while slightly lower changes for Cd and Zn were observed. Changes also occurred in the column with the zeolite, but with a much lower intensity compared to the column of apatite, and with the trend of changes U> Pb Cd Zn. The trend of changes between apatite and zeolite also occurred in the basic contaminated solution with initial pH-7.00. Zeolite and apatite adsorption/precipitation processes successfully immobilized Pb at both tested pH values of stock solution. Our investigation showed that in colonies, apatite better immobilized U, zeolite is better for immobilization of the Cd, while for the Zn both materials showed a very similar affinity. Zeolite and apatite were added in amount of 20 gkg soil to reduce the content of water-soluble and easily accessible forms of Pb, Cd and Zn in uncontaminated and contaminated soil.",
publisher = "East Sarajevo : University of East Sarajevo, Faculty of Agriculture, Republic of Srpska",
journal = "X International Scientific Agriculture Symposium “Agrosym 2019”",
title = "Efficiency and the possibility of using zeolite and apatite purifying water for irrigation and remedation of contaminated soil",
pages = "884-879"
}

Grubišić, M., Bošković-Rakočević, L., Dugalić, G., Petrović, J., Petrović, M., Milojković, J.,& Kojić, M.. (2019). Efficiency and the possibility of using zeolite and apatite purifying water for irrigation and remedation of contaminated soil. in X International Scientific Agriculture Symposium “Agrosym 2019”
East Sarajevo : University of East Sarajevo, Faculty of Agriculture, Republic of Srpska., 879-884.

Grubišić M, Bošković-Rakočević L, Dugalić G, Petrović J, Petrović M, Milojković J, Kojić M. Efficiency and the possibility of using zeolite and apatite purifying water for irrigation and remedation of contaminated soil. in X International Scientific Agriculture Symposium “Agrosym 2019”. 2019;:879-884..

Grubišić, Mirko, Bošković-Rakočević, Ljiljana, Dugalić, Goran, Petrović, Jelena, Petrović, Marija, Milojković, Jelena, Kojić, Marija, "Efficiency and the possibility of using zeolite and apatite purifying water for irrigation and remedation of contaminated soil" in X International Scientific Agriculture Symposium “Agrosym 2019” (2019):879-884.

TY  - JOUR
AU  - Grubišić, Mirko
AU  - Dugalić, Goran
PY  - 2004
UR  - https://ritnms.itnms.ac.rs/handle/123456789/70
AB  - U radu su prikazani rezultati određivanja sadržaja, sastava i osobina humusa Kraljevačkog pseudogleja u pet profila koji reprezentuju tri različita varijeteta prema načinu njegovog korišćenja i to pod šumom (1), livadom (1) i njivom (3), pri čemu je otvaranje izvršeno na neđubrenoj, đubrenoj sa NPK (120:120:80) i đubrenoj sa NPK+5000 kg/ha-1 Ca đubrivom. Na osnovu dobijenih rezultata konstatovano je da se najvećim sadržajem humusa (5.83 %) karakteriše šumski varijetet, potom livadski sa 3.00 %, dok u njivskom neđubrenom varijetetu sadržaj humusa iznosi samo 1.79 %. Tendencija opadanja sadržaja humusa u varijantama njivskog varijeteta đubrenim sa NPK (1.57 %) i NPK+Ca đubrivom (1.52 %) se nastavlja, ukazujući na poboljšanje uslova za mineralizaciju organske materije, kao i na potrebu da se pri đubrenju mineralnim đubrivima i kalcifikacijom pseudoglejnih zemljišta radi održavanja i poboljšanja njihovog adsorptivnog kompleksa, istovremeno sprovodi i humizacija. Bitna karakteristika frakcionog sastava humusa ispitivanih varijeteta izuzimajuši njivski varijetet sa unetim Ca đubrivom, je preovlađivanje fulvo nad humiskim kiselinama, što se vidi iz odnosa Chk/Cfk, koji varira u širokom intervalu od 0.35 do 0.98, sa najvećom zastupljenošću fulvo kiselina u njivskom neđubrenom varijetetu. U njivskom varijetetu sa unetim Ca đubrivom taj odnos se drastično menja do 45 cm dubine, varirajući u intervalu od 1.5 do 2.8, što ukazuje na stabilizujuc'i karakter procesa izazvan unetim Ca i smanjivanje mobilnosti huminskih kiselina obrazovanjem odgovarajućih humata. Na osnovu odnosa ekstinkcija E4:En, konstatovano je daje najmanji stepen kondenzovanosti huminskih kiselina, odnosno njihovih aromatskih jezgara, prisutan u šumskom varijetetu (5.67), a najpovoljniji (4.64) u livadskom varijetetu. Određivanje praga koagulacije, odnosno izoelektrične tačke, huminskih kiselina ukazuje na visok stepen njihove disperznosti i uniformnosti u tom pogledu, imajući u vidu da je potpuna koagulacija postignuta angažovanjem 16-20 m.eqv-CaCh na l litar humata.
AB  - In the work are showed the results of determination the content, composition and characteristics of humus from Kraljevo pseudogley in five profiles which represent three different varieties according the way of using and that is the forest soil (1), meadow soil (1) and arable field soil type (3), and the opening is done on the unfertilized, fertilized with NPK and fertilized with NPK+Ca variety. The forest soil type has the biggest content of humus 5,83 %, after that meadow soil type with 3,00 %, unfertilized arable field soil type 1,79 %, fertilized 1,57 % and fertilized +Ca 1,52 %. Obtaining fulvous under the humic acids in the wide interval with the except of the arable field soil type fertilized +Ca is important characteristic of the fraction composition of humus of the examined varieties of pseudogley. According the relation of extinctions E4:E6 the smallest condensation of aromatic nucleuses of the humic acids has forest soil (5,67), better (5,00-5,17) arable field soil type and the best (4,64) meadow variety of pseudogley. The values of the threshold of coagulation, respectively isoelectric point, humic acids (16-20meq CaCh on 1/1 of humate shows the high degree of its dispersion and uniformity characteristics.
PB  - Unija bioloških naučnih društava Jugoslavije, Beograd
T2  - Zemljište i biljka
T1  - Sadržaj, sastav i osobine humusa pseudogleja pod različitim načinom korišćenja
T1  - Content, composition and characteristics of humus in pseudogley under the different ways of using
EP  - 10
IS  - 1
SP  - 1
VL  - 53
UR  - conv_307
ER  - 

@article{
author = "Grubišić, Mirko and Dugalić, Goran",
year = "2004",
abstract = "U radu su prikazani rezultati određivanja sadržaja, sastava i osobina humusa Kraljevačkog pseudogleja u pet profila koji reprezentuju tri različita varijeteta prema načinu njegovog korišćenja i to pod šumom (1), livadom (1) i njivom (3), pri čemu je otvaranje izvršeno na neđubrenoj, đubrenoj sa NPK (120:120:80) i đubrenoj sa NPK+5000 kg/ha-1 Ca đubrivom. Na osnovu dobijenih rezultata konstatovano je da se najvećim sadržajem humusa (5.83 %) karakteriše šumski varijetet, potom livadski sa 3.00 %, dok u njivskom neđubrenom varijetetu sadržaj humusa iznosi samo 1.79 %. Tendencija opadanja sadržaja humusa u varijantama njivskog varijeteta đubrenim sa NPK (1.57 %) i NPK+Ca đubrivom (1.52 %) se nastavlja, ukazujući na poboljšanje uslova za mineralizaciju organske materije, kao i na potrebu da se pri đubrenju mineralnim đubrivima i kalcifikacijom pseudoglejnih zemljišta radi održavanja i poboljšanja njihovog adsorptivnog kompleksa, istovremeno sprovodi i humizacija. Bitna karakteristika frakcionog sastava humusa ispitivanih varijeteta izuzimajuši njivski varijetet sa unetim Ca đubrivom, je preovlađivanje fulvo nad humiskim kiselinama, što se vidi iz odnosa Chk/Cfk, koji varira u širokom intervalu od 0.35 do 0.98, sa najvećom zastupljenošću fulvo kiselina u njivskom neđubrenom varijetetu. U njivskom varijetetu sa unetim Ca đubrivom taj odnos se drastično menja do 45 cm dubine, varirajući u intervalu od 1.5 do 2.8, što ukazuje na stabilizujuc'i karakter procesa izazvan unetim Ca i smanjivanje mobilnosti huminskih kiselina obrazovanjem odgovarajućih humata. Na osnovu odnosa ekstinkcija E4:En, konstatovano je daje najmanji stepen kondenzovanosti huminskih kiselina, odnosno njihovih aromatskih jezgara, prisutan u šumskom varijetetu (5.67), a najpovoljniji (4.64) u livadskom varijetetu. Određivanje praga koagulacije, odnosno izoelektrične tačke, huminskih kiselina ukazuje na visok stepen njihove disperznosti i uniformnosti u tom pogledu, imajući u vidu da je potpuna koagulacija postignuta angažovanjem 16-20 m.eqv-CaCh na l litar humata., In the work are showed the results of determination the content, composition and characteristics of humus from Kraljevo pseudogley in five profiles which represent three different varieties according the way of using and that is the forest soil (1), meadow soil (1) and arable field soil type (3), and the opening is done on the unfertilized, fertilized with NPK and fertilized with NPK+Ca variety. The forest soil type has the biggest content of humus 5,83 %, after that meadow soil type with 3,00 %, unfertilized arable field soil type 1,79 %, fertilized 1,57 % and fertilized +Ca 1,52 %. Obtaining fulvous under the humic acids in the wide interval with the except of the arable field soil type fertilized +Ca is important characteristic of the fraction composition of humus of the examined varieties of pseudogley. According the relation of extinctions E4:E6 the smallest condensation of aromatic nucleuses of the humic acids has forest soil (5,67), better (5,00-5,17) arable field soil type and the best (4,64) meadow variety of pseudogley. The values of the threshold of coagulation, respectively isoelectric point, humic acids (16-20meq CaCh on 1/1 of humate shows the high degree of its dispersion and uniformity characteristics.",
publisher = "Unija bioloških naučnih društava Jugoslavije, Beograd",
journal = "Zemljište i biljka",
title = "Sadržaj, sastav i osobine humusa pseudogleja pod različitim načinom korišćenja, Content, composition and characteristics of humus in pseudogley under the different ways of using",
pages = "10-1",
number = "1",
volume = "53",
url = "conv_307"
}

Grubišić, M.,& Dugalić, G.. (2004). Sadržaj, sastav i osobine humusa pseudogleja pod različitim načinom korišćenja. in Zemljište i biljka
Unija bioloških naučnih društava Jugoslavije, Beograd., 53(1), 1-10.
conv_307

Grubišić M, Dugalić G. Sadržaj, sastav i osobine humusa pseudogleja pod različitim načinom korišćenja. in Zemljište i biljka. 2004;53(1):1-10.
conv_307 .

Grubišić, Mirko, Dugalić, Goran, "Sadržaj, sastav i osobine humusa pseudogleja pod različitim načinom korišćenja" in Zemljište i biljka, 53, no. 1 (2004):1-10,
conv_307 .