Tošović, Radule

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002a8c5b-ec79-47ad-80eb-8bb86f0f9f85
  • Tošović, Radule (2)
  • Tošović, Radule D. (2)
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Author's Bibliography

A review of the Pb-Zn-Cu-Ag-Bi-W polymetallic ore from the Rudnik orefield, Central Serbia

Stojanović, Jovica; Radosavljević, Slobodan; Tošović, Radule; Pačevski, Aleksandar; Radosavljević-Mihajlović, Ana; Kašić, Vladan; Vuković, Nikola

(Belgrade : University of Belgrade, Faculty of Mining and Geology, 2018)

TY  - JOUR
AU  - Stojanović, Jovica
AU  - Radosavljević, Slobodan
AU  - Tošović, Radule
AU  - Pačevski, Aleksandar
AU  - Radosavljević-Mihajlović, Ana
AU  - Kašić, Vladan
AU  - Vuković, Nikola
PY  - 2018
UR  - https://ritnms.itnms.ac.rs/handle/123456789/1029
AB  - The  Rudnik  orefield  is  one  of  the  well-known  skarn-replacement  and  high-temperature
hydrothermal Pb-Zn-Cu-Ag-Bi-W polymetallic sulfide deposits, and is a part of the Šumadija Metallogenic
District, Serbia. It comprises ore bodies grouped into several major ore zones. The pseudostratified and plate-
like ore bodies have relatively high content of valuable metals. The average content varies in wide ranges: Pb
(0.94–5.66 wt%), Zn (0.49–4.49 wt%), Cu (0.08–2.18 wt%), Ag (50–297 ppm), Bi (~100–150 ppm), and Cd
(~100–150 ppm). Generally, a complex mineral association has been determined. Iron sulfides, arsenopyrite,
chalcopyrite, sphalerite, galena and sulfosalts are abundant minerals in the ore. Carrier minerals of Bi and Ag
are Bi-sulfosalts, such as galenobismutite, cosalite, Ag-bearing aschamalmite, vikingite, schirmerite and gus-
tavite.  Copper,  Ag  and  Pb-Sb  sulfosalts  have  been  found  only  locally.  Complex  Ni-minerals  (sulfides,
arsenides and sulfoarsenidеs) with Fe, Co and Ag were formed under to the influence of present serpentine
rocks and their yield of Ni, Co and Cr in the hydrothermal ore-bearing solutions. Significant scheelite mine-
ralizations have been found in the Nova Jama, Gušavi Potok and Azna ore zones. The presence of Bi-sulfo-
salts and argentopentlandite suggests formation temperatures higher than 350, and lower than 445°C, respecti-
vely. Therefore, the mineralization was formed in the temperature range 350 to 400°C. The continuity of py-
rite, pyrrhotite and siderite colloform bands in relic aggregates shows frequent changes of 
f
S
2
and 
f
O
2
in hy-
drothermal solutions. Isotopic composition of sulfur also confirms that the source of the ore-bearing fluids
was magmatic. In addition, the enrichment of Bi and Ag indicates a magmatic origin. The appearance of Bi-
minerals represents a significant genetic indicator for detection of increased Ag concentrations within the ore
mineralizations. Typical gangue minerals are quartz, silicates, carbonates, oxides and different oxy-hydroxi-
des. Special attention is given to the paragenetic relationships and the genetic significance of mineral associ-
ations as indicators of ore-forming conditions.
PB  - Belgrade : University of Belgrade, Faculty of Mining and Geology
T2  - Geoloski Anali Balkanskog Poluostrava
T1  - A review of the Pb-Zn-Cu-Ag-Bi-W polymetallic ore from the Rudnik orefield, Central Serbia
EP  - 69
IS  - 1
SP  - 47
VL  - 79
DO  - 10.2298/GABP1879047S
ER  - 
@article{
author = "Stojanović, Jovica and Radosavljević, Slobodan and Tošović, Radule and Pačevski, Aleksandar and Radosavljević-Mihajlović, Ana and Kašić, Vladan and Vuković, Nikola",
year = "2018",
abstract = "The  Rudnik  orefield  is  one  of  the  well-known  skarn-replacement  and  high-temperature
hydrothermal Pb-Zn-Cu-Ag-Bi-W polymetallic sulfide deposits, and is a part of the Šumadija Metallogenic
District, Serbia. It comprises ore bodies grouped into several major ore zones. The pseudostratified and plate-
like ore bodies have relatively high content of valuable metals. The average content varies in wide ranges: Pb
(0.94–5.66 wt%), Zn (0.49–4.49 wt%), Cu (0.08–2.18 wt%), Ag (50–297 ppm), Bi (~100–150 ppm), and Cd
(~100–150 ppm). Generally, a complex mineral association has been determined. Iron sulfides, arsenopyrite,
chalcopyrite, sphalerite, galena and sulfosalts are abundant minerals in the ore. Carrier minerals of Bi and Ag
are Bi-sulfosalts, such as galenobismutite, cosalite, Ag-bearing aschamalmite, vikingite, schirmerite and gus-
tavite.  Copper,  Ag  and  Pb-Sb  sulfosalts  have  been  found  only  locally.  Complex  Ni-minerals  (sulfides,
arsenides and sulfoarsenidеs) with Fe, Co and Ag were formed under to the influence of present serpentine
rocks and their yield of Ni, Co and Cr in the hydrothermal ore-bearing solutions. Significant scheelite mine-
ralizations have been found in the Nova Jama, Gušavi Potok and Azna ore zones. The presence of Bi-sulfo-
salts and argentopentlandite suggests formation temperatures higher than 350, and lower than 445°C, respecti-
vely. Therefore, the mineralization was formed in the temperature range 350 to 400°C. The continuity of py-
rite, pyrrhotite and siderite colloform bands in relic aggregates shows frequent changes of 
f
S
2
and 
f
O
2
in hy-
drothermal solutions. Isotopic composition of sulfur also confirms that the source of the ore-bearing fluids
was magmatic. In addition, the enrichment of Bi and Ag indicates a magmatic origin. The appearance of Bi-
minerals represents a significant genetic indicator for detection of increased Ag concentrations within the ore
mineralizations. Typical gangue minerals are quartz, silicates, carbonates, oxides and different oxy-hydroxi-
des. Special attention is given to the paragenetic relationships and the genetic significance of mineral associ-
ations as indicators of ore-forming conditions.",
publisher = "Belgrade : University of Belgrade, Faculty of Mining and Geology",
journal = "Geoloski Anali Balkanskog Poluostrava",
title = "A review of the Pb-Zn-Cu-Ag-Bi-W polymetallic ore from the Rudnik orefield, Central Serbia",
pages = "69-47",
number = "1",
volume = "79",
doi = "10.2298/GABP1879047S"
}
Stojanović, J., Radosavljević, S., Tošović, R., Pačevski, A., Radosavljević-Mihajlović, A., Kašić, V.,& Vuković, N.. (2018). A review of the Pb-Zn-Cu-Ag-Bi-W polymetallic ore from the Rudnik orefield, Central Serbia. in Geoloski Anali Balkanskog Poluostrava
Belgrade : University of Belgrade, Faculty of Mining and Geology., 79(1), 47-69.
https://doi.org/10.2298/GABP1879047S
Stojanović J, Radosavljević S, Tošović R, Pačevski A, Radosavljević-Mihajlović A, Kašić V, Vuković N. A review of the Pb-Zn-Cu-Ag-Bi-W polymetallic ore from the Rudnik orefield, Central Serbia. in Geoloski Anali Balkanskog Poluostrava. 2018;79(1):47-69.
doi:10.2298/GABP1879047S .
Stojanović, Jovica, Radosavljević, Slobodan, Tošović, Radule, Pačevski, Aleksandar, Radosavljević-Mihajlović, Ana, Kašić, Vladan, Vuković, Nikola, "A review of the Pb-Zn-Cu-Ag-Bi-W polymetallic ore from the Rudnik orefield, Central Serbia" in Geoloski Anali Balkanskog Poluostrava, 79, no. 1 (2018):47-69,
https://doi.org/10.2298/GABP1879047S . .
2

A review of the Pb-Zn-Cu-Ag-Bi-W polymetallic ore from the Rudnik orefield, Central Serbia

Stojanović, Jovica; Radosavljević, Slobodan; Tošović, Radule D.; Pačevski, Aleksandar M.; Radosavljević-Mihajlović, Ana; Kašić, Vladan; Vuković, Nikola

(Univerzitet u Beogradu - Rudarsko-geološki fakultet, Beograd, 2018)

TY  - JOUR
AU  - Stojanović, Jovica
AU  - Radosavljević, Slobodan
AU  - Tošović, Radule D.
AU  - Pačevski, Aleksandar M.
AU  - Radosavljević-Mihajlović, Ana
AU  - Kašić, Vladan
AU  - Vuković, Nikola
PY  - 2018
UR  - https://ritnms.itnms.ac.rs/handle/123456789/470
AB  - The Rudnik orefield is one of the well-known skarn-replacement and
   high-temperature hydrothermal Pb-Zn-Cu-Ag-Bi-W polymetallic sulfide
   deposits, and is a part of the Šumadija Metallogenic District, Serbia. It
   comprises ore bodies grouped into several major ore zones. The
   pseudostratified and platelike ore bodies have relatively high content of
   valuable metals. The average content varies in wide ranges: Pb (0.94-5.66
   wt%), Zn (0.49-4.49 wt%), Cu (0.08-2.18 wt%), Ag (50-297 ppm), Bi (~100-150
   ppm), and Cd (~100-150 ppm). Generally, a complex mineral association has
   been determined. Iron sulfides, arsenopyrite, chalcopyrite, sphalerite,
   galena and sulfosalts are abundant minerals in the ore. Carrier minerals of
   Bi and Ag are Bi-sulfosalts, such as galenobismutite, cosalite, Ag-bearing
   aschamalmite, vikingite, schirmerite and gustavite. Copper, Ag and Pb-Sb
   sulfosalts have been found only locally. Complex Ni-minerals (sulfides,
   arsenides and sulfoarsenidеs) with Fe, Co and Ag were formed under to the
   influence of present serpentine rocks and their yield of Ni, Co and Cr in
   the hydrothermal ore-bearing solutions. Significant scheelite
   mineralizations have been found in the Nova Jama, Gušavi Potok and Azna ore
   zones. The presence of Bi-sulfosalts and argentopentlandite suggests
   formation temperatures higher than 350, and lower than 445°C, respectively.
   Therefore, the mineralization was formed in the temperature range 350 to
   400°C. The continuity of pyrite, pyrrhotite and siderite colloform bands in
   relic aggregates shows frequent changes of fS2 and fO2 in hydrothermal
   solutions. Isotopic composition of sulfur also confirms that the source of
   the ore-bearing fluids was magmatic. In addition, the enrichment of Bi and
   Ag indicates a magmatic origin. The appearance of Biminerals represents a
   significant genetic indicator for detection of increased Ag concentrations
   within the ore mineralizations. Typical gangue minerals are quartz,
   silicates, carbonates, oxides and different oxy-hydroxides. Special
   attention is given to the paragenetic relationships and the genetic
   significance of mineral associations as indicators of ore-forming conditions.
PB  - Univerzitet u Beogradu - Rudarsko-geološki fakultet, Beograd
T2  - Geološki Anali Balkanskoga Poluostrva
T1  - A review of the Pb-Zn-Cu-Ag-Bi-W polymetallic ore from the Rudnik orefield, Central Serbia
EP  - 69
EP  - 
IS  - 1
SP  - 47
VL  - 79
DO  - 10.2298/GABP1879047S
UR  - conv_1203
ER  - 
@article{
author = "Stojanović, Jovica and Radosavljević, Slobodan and Tošović, Radule D. and Pačevski, Aleksandar M. and Radosavljević-Mihajlović, Ana and Kašić, Vladan and Vuković, Nikola",
year = "2018",
abstract = "The Rudnik orefield is one of the well-known skarn-replacement and
   high-temperature hydrothermal Pb-Zn-Cu-Ag-Bi-W polymetallic sulfide
   deposits, and is a part of the Šumadija Metallogenic District, Serbia. It
   comprises ore bodies grouped into several major ore zones. The
   pseudostratified and platelike ore bodies have relatively high content of
   valuable metals. The average content varies in wide ranges: Pb (0.94-5.66
   wt%), Zn (0.49-4.49 wt%), Cu (0.08-2.18 wt%), Ag (50-297 ppm), Bi (~100-150
   ppm), and Cd (~100-150 ppm). Generally, a complex mineral association has
   been determined. Iron sulfides, arsenopyrite, chalcopyrite, sphalerite,
   galena and sulfosalts are abundant minerals in the ore. Carrier minerals of
   Bi and Ag are Bi-sulfosalts, such as galenobismutite, cosalite, Ag-bearing
   aschamalmite, vikingite, schirmerite and gustavite. Copper, Ag and Pb-Sb
   sulfosalts have been found only locally. Complex Ni-minerals (sulfides,
   arsenides and sulfoarsenidеs) with Fe, Co and Ag were formed under to the
   influence of present serpentine rocks and their yield of Ni, Co and Cr in
   the hydrothermal ore-bearing solutions. Significant scheelite
   mineralizations have been found in the Nova Jama, Gušavi Potok and Azna ore
   zones. The presence of Bi-sulfosalts and argentopentlandite suggests
   formation temperatures higher than 350, and lower than 445°C, respectively.
   Therefore, the mineralization was formed in the temperature range 350 to
   400°C. The continuity of pyrite, pyrrhotite and siderite colloform bands in
   relic aggregates shows frequent changes of fS2 and fO2 in hydrothermal
   solutions. Isotopic composition of sulfur also confirms that the source of
   the ore-bearing fluids was magmatic. In addition, the enrichment of Bi and
   Ag indicates a magmatic origin. The appearance of Biminerals represents a
   significant genetic indicator for detection of increased Ag concentrations
   within the ore mineralizations. Typical gangue minerals are quartz,
   silicates, carbonates, oxides and different oxy-hydroxides. Special
   attention is given to the paragenetic relationships and the genetic
   significance of mineral associations as indicators of ore-forming conditions.",
publisher = "Univerzitet u Beogradu - Rudarsko-geološki fakultet, Beograd",
journal = "Geološki Anali Balkanskoga Poluostrva",
title = "A review of the Pb-Zn-Cu-Ag-Bi-W polymetallic ore from the Rudnik orefield, Central Serbia",
pages = "69--47",
number = "1",
volume = "79",
doi = "10.2298/GABP1879047S",
url = "conv_1203"
}
Stojanović, J., Radosavljević, S., Tošović, R. D., Pačevski, A. M., Radosavljević-Mihajlović, A., Kašić, V.,& Vuković, N.. (2018). A review of the Pb-Zn-Cu-Ag-Bi-W polymetallic ore from the Rudnik orefield, Central Serbia. in Geološki Anali Balkanskoga Poluostrva
Univerzitet u Beogradu - Rudarsko-geološki fakultet, Beograd., 79(1), 47-69.
https://doi.org/10.2298/GABP1879047S
conv_1203
Stojanović J, Radosavljević S, Tošović RD, Pačevski AM, Radosavljević-Mihajlović A, Kašić V, Vuković N. A review of the Pb-Zn-Cu-Ag-Bi-W polymetallic ore from the Rudnik orefield, Central Serbia. in Geološki Anali Balkanskoga Poluostrva. 2018;79(1):47-69.
doi:10.2298/GABP1879047S
conv_1203 .
Stojanović, Jovica, Radosavljević, Slobodan, Tošović, Radule D., Pačevski, Aleksandar M., Radosavljević-Mihajlović, Ana, Kašić, Vladan, Vuković, Nikola, "A review of the Pb-Zn-Cu-Ag-Bi-W polymetallic ore from the Rudnik orefield, Central Serbia" in Geološki Anali Balkanskoga Poluostrva, 79, no. 1 (2018):47-69,
https://doi.org/10.2298/GABP1879047S .,
conv_1203 .
2

Mineralogy and genetic features of the Cu-As-Ni-Sb-Pb mineralization from the Mlakva polymetallic deposit (Serbia) - New occurrence of (Ni-Sb)-bearing Cu-arsenides

Radosavljević-Mihajlović, Ana; Stojanović, Jovica; Radosavljević, Slobodan; Pačevski, Aleksandar M.; Vuković, Nikola; Tošović, Radule D.

(Elsevier Science Bv, Amsterdam, 2017)

TY  - JOUR
AU  - Radosavljević-Mihajlović, Ana
AU  - Stojanović, Jovica
AU  - Radosavljević, Slobodan
AU  - Pačevski, Aleksandar M.
AU  - Vuković, Nikola
AU  - Tošović, Radule D.
PY  - 2017
UR  - https://ritnms.itnms.ac.rs/handle/123456789/426
AB  - (Ni-Sb)-bearing Cu-arsenides are rare minerals within the Mlakva and Kram mining sectors (Boranja ore field) one of the less-known Serbian Cu deposits. (Ni-Sb)-bearing Cu-arsenides were collected from the Mlakva skarn-replacement Cu(Ag,Bi)-FeS polymetallic deposit. The identified phases include/3-domeykite, Ni-bearing koutekite and (Ni-Sb)-bearing alpha-domeykite. (Ni-Sb)-bearing Cu-arsenides are associated with nickeline, arsenical breithauptite, chalcocite, native Ag, native Pb and litharge. Pyrrhotite, pyrite, chalcopyrite, cubanite, bismuthinite, molybdenite, sphalerite, galena, Pb(Cu)-Bi sulfosalts and native Bi, as well as minor magnetite, scheelite and powellite are associated with the sulfide paragenesis. The electron microprobe analyses of the (Ni-Sb)-bearing Cu-arsenides yielded the following average formulae: (Cu-2.73,Ni-0.17,Fe-0.03,Ag-0.01)(Sigma 2.94)(-AS(0.98)Sb(0.05)S(0.02))(Sigma) (1.06-)beta-domeykite (simplified formula ( CU2.7,Ni-0,Ni-2)(Sigma 2.9)AS(1.1)); (Cu-3.40,Ni-1.40,Fe-0.11)(Sigma 4.91)(-AS(1.94)Sb(0.13)S(0.02))(Sigma 2.08)-Ni-bearing koutekite (simplified formula (Cu3.4Ni1.5)Sigma As-4.9(2.1)); and Cu-1.97(Ni-0.98,Fe-0.03)Sigma(1.01)(As-0.81,Sb-0.22)Sigma(1.03)-(Ni-Sb)-bearing alpha-domeykite (simplified formula Cu2NiAs). The Rietveld refinement yielded the following unit-cell parameters for beta-domeyldte and Ni-bearing koutekite: a = 7.1331(4); c = 7.3042(5) A; V = 321.86(2) A(3), and a = 5.922(4); b = 11.447(9); c = 5.480(4) A; V = 371.48(5) A(3), respectively. Ore geology, paragenetic assemblages and genesis of the Mlakva deposit are discussed in detail and the Cu-As-Ni-Sb-Pb mineralization has been compared with similar well-known global deposits.
PB  - Elsevier Science Bv, Amsterdam
T2  - Ore Geology Reviews
T1  - Mineralogy and genetic features of the Cu-As-Ni-Sb-Pb mineralization from the Mlakva polymetallic deposit (Serbia) - New occurrence of (Ni-Sb)-bearing Cu-arsenides
EP  - 1258
SP  - 1245
VL  - 80
DO  - 10.1016/j.oregeorev.2016.08.036
UR  - conv_776
ER  - 
@article{
author = "Radosavljević-Mihajlović, Ana and Stojanović, Jovica and Radosavljević, Slobodan and Pačevski, Aleksandar M. and Vuković, Nikola and Tošović, Radule D.",
year = "2017",
abstract = "(Ni-Sb)-bearing Cu-arsenides are rare minerals within the Mlakva and Kram mining sectors (Boranja ore field) one of the less-known Serbian Cu deposits. (Ni-Sb)-bearing Cu-arsenides were collected from the Mlakva skarn-replacement Cu(Ag,Bi)-FeS polymetallic deposit. The identified phases include/3-domeykite, Ni-bearing koutekite and (Ni-Sb)-bearing alpha-domeykite. (Ni-Sb)-bearing Cu-arsenides are associated with nickeline, arsenical breithauptite, chalcocite, native Ag, native Pb and litharge. Pyrrhotite, pyrite, chalcopyrite, cubanite, bismuthinite, molybdenite, sphalerite, galena, Pb(Cu)-Bi sulfosalts and native Bi, as well as minor magnetite, scheelite and powellite are associated with the sulfide paragenesis. The electron microprobe analyses of the (Ni-Sb)-bearing Cu-arsenides yielded the following average formulae: (Cu-2.73,Ni-0.17,Fe-0.03,Ag-0.01)(Sigma 2.94)(-AS(0.98)Sb(0.05)S(0.02))(Sigma) (1.06-)beta-domeykite (simplified formula ( CU2.7,Ni-0,Ni-2)(Sigma 2.9)AS(1.1)); (Cu-3.40,Ni-1.40,Fe-0.11)(Sigma 4.91)(-AS(1.94)Sb(0.13)S(0.02))(Sigma 2.08)-Ni-bearing koutekite (simplified formula (Cu3.4Ni1.5)Sigma As-4.9(2.1)); and Cu-1.97(Ni-0.98,Fe-0.03)Sigma(1.01)(As-0.81,Sb-0.22)Sigma(1.03)-(Ni-Sb)-bearing alpha-domeykite (simplified formula Cu2NiAs). The Rietveld refinement yielded the following unit-cell parameters for beta-domeyldte and Ni-bearing koutekite: a = 7.1331(4); c = 7.3042(5) A; V = 321.86(2) A(3), and a = 5.922(4); b = 11.447(9); c = 5.480(4) A; V = 371.48(5) A(3), respectively. Ore geology, paragenetic assemblages and genesis of the Mlakva deposit are discussed in detail and the Cu-As-Ni-Sb-Pb mineralization has been compared with similar well-known global deposits.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Ore Geology Reviews",
title = "Mineralogy and genetic features of the Cu-As-Ni-Sb-Pb mineralization from the Mlakva polymetallic deposit (Serbia) - New occurrence of (Ni-Sb)-bearing Cu-arsenides",
pages = "1258-1245",
volume = "80",
doi = "10.1016/j.oregeorev.2016.08.036",
url = "conv_776"
}
Radosavljević-Mihajlović, A., Stojanović, J., Radosavljević, S., Pačevski, A. M., Vuković, N.,& Tošović, R. D.. (2017). Mineralogy and genetic features of the Cu-As-Ni-Sb-Pb mineralization from the Mlakva polymetallic deposit (Serbia) - New occurrence of (Ni-Sb)-bearing Cu-arsenides. in Ore Geology Reviews
Elsevier Science Bv, Amsterdam., 80, 1245-1258.
https://doi.org/10.1016/j.oregeorev.2016.08.036
conv_776
Radosavljević-Mihajlović A, Stojanović J, Radosavljević S, Pačevski AM, Vuković N, Tošović RD. Mineralogy and genetic features of the Cu-As-Ni-Sb-Pb mineralization from the Mlakva polymetallic deposit (Serbia) - New occurrence of (Ni-Sb)-bearing Cu-arsenides. in Ore Geology Reviews. 2017;80:1245-1258.
doi:10.1016/j.oregeorev.2016.08.036
conv_776 .
Radosavljević-Mihajlović, Ana, Stojanović, Jovica, Radosavljević, Slobodan, Pačevski, Aleksandar M., Vuković, Nikola, Tošović, Radule D., "Mineralogy and genetic features of the Cu-As-Ni-Sb-Pb mineralization from the Mlakva polymetallic deposit (Serbia) - New occurrence of (Ni-Sb)-bearing Cu-arsenides" in Ore Geology Reviews, 80 (2017):1245-1258,
https://doi.org/10.1016/j.oregeorev.2016.08.036 .,
conv_776 .
5
1
7

Mineralogy and genetic features of the Cu-As-Ni-Sb-Pb mineralization from the Mlakva polymetallic deposit (Serbia) — New occurrence of (Ni-Sb)-bearing Cu-arsenides

Radosavljević-Mihajlović, Ana; Stojanović, Jovica; Radosavljević, Slobodan; Pačevski, Aleksandar; Vuković, Nikola; Tošović, Radule

(Elsevier, 2016)

TY  - JOUR
AU  - Radosavljević-Mihajlović, Ana
AU  - Stojanović, Jovica
AU  - Radosavljević, Slobodan
AU  - Pačevski, Aleksandar
AU  - Vuković, Nikola
AU  - Tošović, Radule
PY  - 2016
UR  - https://ritnms.itnms.ac.rs/handle/123456789/1003
AB  - (Ni-Sb)-bearing Cu-arsenides are rare minerals within the Mlakva and Kram mining sectors (Boranja ore field) one of the less-known Serbian Cu deposits. (Ni-Sb)-bearing Cu-arsenides were collected from the Mlakva skarn-replacement Cu(Ag,Bi)-FeS polymetallic deposit. The identified phases include β-domeykite, Ni-bearing koutekite and (Ni-Sb)-bearing α-domeykite. (Ni-Sb)-bearing Cu-arsenides are associated with nickeline, arsenical breithauptite, chalcocite, native Ag, native Pb and litharge. Pyrrhotite, pyrite, chalcopyrite, cubanite, bismuthinite, molybdenite, sphalerite, galena, Pb(Cu)-Bi sulfosalts and native Bi, as well as minor magnetite, scheelite and powellite are associated with the sulfide paragenesis. The electron microprobe analyses of the (Ni-Sb)-bearing Cu-arsenides yielded the following average formulae: (Cu2.73,Ni0.17,Fe0.03,Ag0.01)∑ 2.94(As0.98,Sb0.05,S0.02)∑ 1.06–β-domeykite (simplified formula (Cu2.7,Ni0.2)∑ 2.9As1.1); (Cu3.40,Ni1.40,Fe0.11)∑ 4.91(As1.94,Sb0.13,S0.02)∑ 2.08–Ni-bearing koutekite (simplified formula (Cu3.4Ni1.5)∑ 4.9As2.1); and Cu1.97(Ni0.98,Fe0.03)∑ 1.01(As0.81,Sb0.22)∑ 1.03–(Ni–Sb)-bearing α-domeykite (simplified formula Cu2NiAs). The Rietveld refinement yielded the following unit-cell parameters for β-domeykite and Ni–bearing koutekite: a = 7.1331(4); c = 7.3042(5) Å; V = 321.86(2) Å3, and a = 5.922(4); b = 11.447(9); c = 5.480(4) Å; V = 371.48(5) Å3, respectively. Ore geology, paragenetic assemblages and genesis of the Mlakva deposit are discussed in detail and the Cu-As-Ni-Sb-Pb mineralization has been compared with similar well-known global deposits.
PB  - Elsevier
T2  - Ore Geology Reviews
T1  - Mineralogy and genetic features of the Cu-As-Ni-Sb-Pb mineralization from the Mlakva polymetallic deposit (Serbia) — New occurrence of (Ni-Sb)-bearing Cu-arsenides
EP  - 1258
SP  - 1245
VL  - 80
DO  - 10.1016/j.oregeorev.2016.08.036
ER  - 
@article{
author = "Radosavljević-Mihajlović, Ana and Stojanović, Jovica and Radosavljević, Slobodan and Pačevski, Aleksandar and Vuković, Nikola and Tošović, Radule",
year = "2016",
abstract = "(Ni-Sb)-bearing Cu-arsenides are rare minerals within the Mlakva and Kram mining sectors (Boranja ore field) one of the less-known Serbian Cu deposits. (Ni-Sb)-bearing Cu-arsenides were collected from the Mlakva skarn-replacement Cu(Ag,Bi)-FeS polymetallic deposit. The identified phases include β-domeykite, Ni-bearing koutekite and (Ni-Sb)-bearing α-domeykite. (Ni-Sb)-bearing Cu-arsenides are associated with nickeline, arsenical breithauptite, chalcocite, native Ag, native Pb and litharge. Pyrrhotite, pyrite, chalcopyrite, cubanite, bismuthinite, molybdenite, sphalerite, galena, Pb(Cu)-Bi sulfosalts and native Bi, as well as minor magnetite, scheelite and powellite are associated with the sulfide paragenesis. The electron microprobe analyses of the (Ni-Sb)-bearing Cu-arsenides yielded the following average formulae: (Cu2.73,Ni0.17,Fe0.03,Ag0.01)∑ 2.94(As0.98,Sb0.05,S0.02)∑ 1.06–β-domeykite (simplified formula (Cu2.7,Ni0.2)∑ 2.9As1.1); (Cu3.40,Ni1.40,Fe0.11)∑ 4.91(As1.94,Sb0.13,S0.02)∑ 2.08–Ni-bearing koutekite (simplified formula (Cu3.4Ni1.5)∑ 4.9As2.1); and Cu1.97(Ni0.98,Fe0.03)∑ 1.01(As0.81,Sb0.22)∑ 1.03–(Ni–Sb)-bearing α-domeykite (simplified formula Cu2NiAs). The Rietveld refinement yielded the following unit-cell parameters for β-domeykite and Ni–bearing koutekite: a = 7.1331(4); c = 7.3042(5) Å; V = 321.86(2) Å3, and a = 5.922(4); b = 11.447(9); c = 5.480(4) Å; V = 371.48(5) Å3, respectively. Ore geology, paragenetic assemblages and genesis of the Mlakva deposit are discussed in detail and the Cu-As-Ni-Sb-Pb mineralization has been compared with similar well-known global deposits.",
publisher = "Elsevier",
journal = "Ore Geology Reviews",
title = "Mineralogy and genetic features of the Cu-As-Ni-Sb-Pb mineralization from the Mlakva polymetallic deposit (Serbia) — New occurrence of (Ni-Sb)-bearing Cu-arsenides",
pages = "1258-1245",
volume = "80",
doi = "10.1016/j.oregeorev.2016.08.036"
}
Radosavljević-Mihajlović, A., Stojanović, J., Radosavljević, S., Pačevski, A., Vuković, N.,& Tošović, R.. (2016). Mineralogy and genetic features of the Cu-As-Ni-Sb-Pb mineralization from the Mlakva polymetallic deposit (Serbia) — New occurrence of (Ni-Sb)-bearing Cu-arsenides. in Ore Geology Reviews
Elsevier., 80, 1245-1258.
https://doi.org/10.1016/j.oregeorev.2016.08.036
Radosavljević-Mihajlović A, Stojanović J, Radosavljević S, Pačevski A, Vuković N, Tošović R. Mineralogy and genetic features of the Cu-As-Ni-Sb-Pb mineralization from the Mlakva polymetallic deposit (Serbia) — New occurrence of (Ni-Sb)-bearing Cu-arsenides. in Ore Geology Reviews. 2016;80:1245-1258.
doi:10.1016/j.oregeorev.2016.08.036 .
Radosavljević-Mihajlović, Ana, Stojanović, Jovica, Radosavljević, Slobodan, Pačevski, Aleksandar, Vuković, Nikola, Tošović, Radule, "Mineralogy and genetic features of the Cu-As-Ni-Sb-Pb mineralization from the Mlakva polymetallic deposit (Serbia) — New occurrence of (Ni-Sb)-bearing Cu-arsenides" in Ore Geology Reviews, 80 (2016):1245-1258,
https://doi.org/10.1016/j.oregeorev.2016.08.036 . .
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