TY  - JOUR
AU  - Prokić, Danijela
AU  - Vukcević, Marija
AU  - Mitrović, Angelina
AU  - Maletić, Marina
AU  - Kalijadis, Ana
AU  - Janković-Častvan, Ivona
AU  - Durkić, Tatjana
PY  - 2022
UR  - https://ritnms.itnms.ac.rs/handle/123456789/642
AB  - Carbon materials of different structural and textural properties (multi-walled carbon nanotubes, carbon cryogel, and carbonized hydrothermal carbon) were used as adsorbents for the removal of estrone, 17 beta-estradiol, and 17 alpha-ethinylestradiol from aqueous solutions. Chemical modification and/or activation were applied to alter surface characteristics and to increase the adsorption and desorption efficiency of carbon materials. Surfaces of treated and untreated carbon materials were characterized through the examination of the textural properties, the nature of surface functional groups, and surface acidity. It was found that the adsorption capacity of tested carbon materials is not directly proportional to the specific surface area and the content of surface oxygen groups. However, a high ratio of surface mesoporosity affected the adsorption process most prominently, by increasing adsorption capacity and the rate of the adsorption process. Adsorption of estrone, 17 beta-estradiol, and 17 alpha-ethinylestradiol followed pseudo-second-order kinetic model, while the equilibrium adsorption data were best fitted with the Langmuir isotherm model. Calculated mean adsorption energy values, along with the thermodynamic parameters, indicated that removal of selected hormones was dominated by the physisorption mechanism. High values of adsorption efficiency (88-100 %) and Langmuir adsorption capacities (29.45-194.7 mg/g) imply that examined materials, especially mesoporous carbon cryogel and multi-walled carbon nanotubes, can be used as powerful adsorbents for relatively fast removal of estrogen hormones from water.
PB  - Springer Heidelberg, Heidelberg
T2  - Environmental science and pollution research
T1  - Adsorption of estrone, 17 beta-estradiol, and 17 alpha-ethinylestradiol from water onto modified multi-walled carbon nanotubes, carbon cryogel, and carbonized hydrothermal carbon
EP  - 4445
IS  - 3
SP  - 4431
VL  - 29
DO  - 10.1007/s11356-021-15970-4
UR  - conv_913
ER  - 

@article{
author = "Prokić, Danijela and Vukcević, Marija and Mitrović, Angelina and Maletić, Marina and Kalijadis, Ana and Janković-Častvan, Ivona and Durkić, Tatjana",
year = "2022",
abstract = "Carbon materials of different structural and textural properties (multi-walled carbon nanotubes, carbon cryogel, and carbonized hydrothermal carbon) were used as adsorbents for the removal of estrone, 17 beta-estradiol, and 17 alpha-ethinylestradiol from aqueous solutions. Chemical modification and/or activation were applied to alter surface characteristics and to increase the adsorption and desorption efficiency of carbon materials. Surfaces of treated and untreated carbon materials were characterized through the examination of the textural properties, the nature of surface functional groups, and surface acidity. It was found that the adsorption capacity of tested carbon materials is not directly proportional to the specific surface area and the content of surface oxygen groups. However, a high ratio of surface mesoporosity affected the adsorption process most prominently, by increasing adsorption capacity and the rate of the adsorption process. Adsorption of estrone, 17 beta-estradiol, and 17 alpha-ethinylestradiol followed pseudo-second-order kinetic model, while the equilibrium adsorption data were best fitted with the Langmuir isotherm model. Calculated mean adsorption energy values, along with the thermodynamic parameters, indicated that removal of selected hormones was dominated by the physisorption mechanism. High values of adsorption efficiency (88-100 %) and Langmuir adsorption capacities (29.45-194.7 mg/g) imply that examined materials, especially mesoporous carbon cryogel and multi-walled carbon nanotubes, can be used as powerful adsorbents for relatively fast removal of estrogen hormones from water.",
publisher = "Springer Heidelberg, Heidelberg",
journal = "Environmental science and pollution research",
title = "Adsorption of estrone, 17 beta-estradiol, and 17 alpha-ethinylestradiol from water onto modified multi-walled carbon nanotubes, carbon cryogel, and carbonized hydrothermal carbon",
pages = "4445-4431",
number = "3",
volume = "29",
doi = "10.1007/s11356-021-15970-4",
url = "conv_913"
}

Prokić, D., Vukcević, M., Mitrović, A., Maletić, M., Kalijadis, A., Janković-Častvan, I.,& Durkić, T.. (2022). Adsorption of estrone, 17 beta-estradiol, and 17 alpha-ethinylestradiol from water onto modified multi-walled carbon nanotubes, carbon cryogel, and carbonized hydrothermal carbon. in Environmental science and pollution research
Springer Heidelberg, Heidelberg., 29(3), 4431-4445.
https://doi.org/10.1007/s11356-021-15970-4
conv_913

Prokić D, Vukcević M, Mitrović A, Maletić M, Kalijadis A, Janković-Častvan I, Durkić T. Adsorption of estrone, 17 beta-estradiol, and 17 alpha-ethinylestradiol from water onto modified multi-walled carbon nanotubes, carbon cryogel, and carbonized hydrothermal carbon. in Environmental science and pollution research. 2022;29(3):4431-4445.
doi:10.1007/s11356-021-15970-4
conv_913 .

Prokić, Danijela, Vukcević, Marija, Mitrović, Angelina, Maletić, Marina, Kalijadis, Ana, Janković-Častvan, Ivona, Durkić, Tatjana, "Adsorption of estrone, 17 beta-estradiol, and 17 alpha-ethinylestradiol from water onto modified multi-walled carbon nanotubes, carbon cryogel, and carbonized hydrothermal carbon" in Environmental science and pollution research, 29, no. 3 (2022):4431-4445,
https://doi.org/10.1007/s11356-021-15970-4 .,
conv_913 .