Ileš, Deana

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  • Ileš, Deana (8)
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Author's Bibliography

Phytotoxic Effect of the Uranium on the Growing Up and Development the Plant of Corn

Stojanović, Mirjana; Stevanović, Dragi; Milojković, Jelena; Grubišić, Mirko; Ileš, Deana

(Springer International Publishing Ag, Cham, 2010)

TY  - JOUR
AU  - Stojanović, Mirjana
AU  - Stevanović, Dragi
AU  - Milojković, Jelena
AU  - Grubišić, Mirko
AU  - Ileš, Deana
PY  - 2010
UR  - https://ritnms.itnms.ac.rs/handle/123456789/183
AB  - The aim of this article is the determination of uranium accumulation in plants tissue in shoots and roots of corn-maize (Zea mays), grown on two types of soils, pseudogley and chernozem, together with its phytotoxic effect on the plant growth and development. The soils was contaminated with different rates (10 to 1,000 mg U(VI) kg(-1)) of uranyl nitrate (UO2(NO3)(2)center dot 6H(2)O). Vegetative tests performed with maize indicated uranium phytotoxic effect on plant height, yield, and germination of seeds. This effect was stronger on the plants grown on pseudogley in comparison with those grown on chernozem. Soil properties determined the tolerance and accumulation of U in plants. A linear dependence between the content of uranium in soil and in plants tissue, including maximal content of 1,000 mg U kg(-1), indicates that maize could be used for phytoremediation of uranium-contaminated soils.
PB  - Springer International Publishing Ag, Cham
T2  - Water Air and Soil Pollution
T1  - Phytotoxic Effect of the Uranium on the Growing Up and Development the Plant of Corn
EP  - 410
IS  - 1-4
SP  - 401
VL  - 209
DO  - 10.1007/s11270-009-0208-4
UR  - conv_582
ER  - 
@article{
author = "Stojanović, Mirjana and Stevanović, Dragi and Milojković, Jelena and Grubišić, Mirko and Ileš, Deana",
year = "2010",
abstract = "The aim of this article is the determination of uranium accumulation in plants tissue in shoots and roots of corn-maize (Zea mays), grown on two types of soils, pseudogley and chernozem, together with its phytotoxic effect on the plant growth and development. The soils was contaminated with different rates (10 to 1,000 mg U(VI) kg(-1)) of uranyl nitrate (UO2(NO3)(2)center dot 6H(2)O). Vegetative tests performed with maize indicated uranium phytotoxic effect on plant height, yield, and germination of seeds. This effect was stronger on the plants grown on pseudogley in comparison with those grown on chernozem. Soil properties determined the tolerance and accumulation of U in plants. A linear dependence between the content of uranium in soil and in plants tissue, including maximal content of 1,000 mg U kg(-1), indicates that maize could be used for phytoremediation of uranium-contaminated soils.",
publisher = "Springer International Publishing Ag, Cham",
journal = "Water Air and Soil Pollution",
title = "Phytotoxic Effect of the Uranium on the Growing Up and Development the Plant of Corn",
pages = "410-401",
number = "1-4",
volume = "209",
doi = "10.1007/s11270-009-0208-4",
url = "conv_582"
}
Stojanović, M., Stevanović, D., Milojković, J., Grubišić, M.,& Ileš, D.. (2010). Phytotoxic Effect of the Uranium on the Growing Up and Development the Plant of Corn. in Water Air and Soil Pollution
Springer International Publishing Ag, Cham., 209(1-4), 401-410.
https://doi.org/10.1007/s11270-009-0208-4
conv_582
Stojanović M, Stevanović D, Milojković J, Grubišić M, Ileš D. Phytotoxic Effect of the Uranium on the Growing Up and Development the Plant of Corn. in Water Air and Soil Pollution. 2010;209(1-4):401-410.
doi:10.1007/s11270-009-0208-4
conv_582 .
Stojanović, Mirjana, Stevanović, Dragi, Milojković, Jelena, Grubišić, Mirko, Ileš, Deana, "Phytotoxic Effect of the Uranium on the Growing Up and Development the Plant of Corn" in Water Air and Soil Pollution, 209, no. 1-4 (2010):401-410,
https://doi.org/10.1007/s11270-009-0208-4 .,
conv_582 .
31
11
35

Adsorpcija uranil-jona na modifikovanim klinoptilolitima

Matijašević, Srđan; Daković, Aleksandra; Ileš, Deana; Milićević, Sonja

(Savez hemijskih inženjera, Beograd, 2009)

TY  - JOUR
AU  - Matijašević, Srđan
AU  - Daković, Aleksandra
AU  - Ileš, Deana
AU  - Milićević, Sonja
PY  - 2009
UR  - https://ritnms.itnms.ac.rs/handle/123456789/162
AB  - U ovom radu prikazani su rezultati ispitivanja adsorpcije uranil-jona na zeolitskom mineralu klinoptilolitu modifikovanom tretmanom kiselinama. Adsorpcija je praćena pri različitim količinama čvrste faze u suspenziji kao i na različitim pH. Modifikacija je izvršena tretiranjem klinoptilolita sa kiselinama: hlorovodoničnom, oksalnom i limunskom. Polazni i modifikovani klinoptiloliti su okarakterisani termičkom analizom (DTA/TGA), određivanjem hemijskog sastava i određivanjem sadržaja izmenljivih katjona, dok su polazne kao i neadsorbovane količine uranil-jona određivane fluorimetrijskom metodom. Određeno je da je adsorpcija niska na prirodnom zeolitskom mineralu, dok kiselinski tretman značajno povećava adsorpciju uranil-jona. Kod kiselinski tretiranih klinoptilolita najviši indeksi adsorpcije uranil-jona su postignuti na uzorku dobijenom modifikacijom sa hlorovodoničnom kiselinom.
AB  - In this paper, the results of adsorption of uranyl ion on acid-modified zeolitic mineral clinoptilolite are presented. Adsorption was investigated at different amounts of solid phase in suspension, as well as at different pH values. The modified clinoptilolite samples were obtained by treatment of clinoptilolite with acids: hydrochloric, oxalyc and citric. Starting and modified clinoptilolites were characterized by chemical analysis, thermal (DT/TG) analysis and by determination of cation exchange capacity, while starting and nonadsorbed amounts of uranyl ion were determined by fluorometric method. Uranyl ion adsorption experiments on natural unmodified zeolitic mineral showed that uranyl ion adsorption was low (29.2%) and that treatment of clinoptilolite with acids significantly increases the adsorption of uranyl ion (>90%). In the case of acid treated clinoptilolites, the highest adsorption of uranyl ion was achieved on clinoptilolite modified with hydrochloric acid. Kinetics of adsorption showed that adsorption of uranyl ion begins very fast and that the most of uranyl ion was adsorbed in first 30 min. Practically, there were no changes in uranyl ion adsorption within next 72 h.
PB  - Savez hemijskih inženjera, Beograd
T2  - Hemijska industrija
T1  - Adsorpcija uranil-jona na modifikovanim klinoptilolitima
T1  - Adsorption of uranyl ion on acid-modified zeolitic mineral clinoptilolite
EP  - 414
IS  - 5
SP  - 407
VL  - 63
DO  - 10.2298/HEMIND0905407M
UR  - conv_294
ER  - 
@article{
author = "Matijašević, Srđan and Daković, Aleksandra and Ileš, Deana and Milićević, Sonja",
year = "2009",
abstract = "U ovom radu prikazani su rezultati ispitivanja adsorpcije uranil-jona na zeolitskom mineralu klinoptilolitu modifikovanom tretmanom kiselinama. Adsorpcija je praćena pri različitim količinama čvrste faze u suspenziji kao i na različitim pH. Modifikacija je izvršena tretiranjem klinoptilolita sa kiselinama: hlorovodoničnom, oksalnom i limunskom. Polazni i modifikovani klinoptiloliti su okarakterisani termičkom analizom (DTA/TGA), određivanjem hemijskog sastava i određivanjem sadržaja izmenljivih katjona, dok su polazne kao i neadsorbovane količine uranil-jona određivane fluorimetrijskom metodom. Određeno je da je adsorpcija niska na prirodnom zeolitskom mineralu, dok kiselinski tretman značajno povećava adsorpciju uranil-jona. Kod kiselinski tretiranih klinoptilolita najviši indeksi adsorpcije uranil-jona su postignuti na uzorku dobijenom modifikacijom sa hlorovodoničnom kiselinom., In this paper, the results of adsorption of uranyl ion on acid-modified zeolitic mineral clinoptilolite are presented. Adsorption was investigated at different amounts of solid phase in suspension, as well as at different pH values. The modified clinoptilolite samples were obtained by treatment of clinoptilolite with acids: hydrochloric, oxalyc and citric. Starting and modified clinoptilolites were characterized by chemical analysis, thermal (DT/TG) analysis and by determination of cation exchange capacity, while starting and nonadsorbed amounts of uranyl ion were determined by fluorometric method. Uranyl ion adsorption experiments on natural unmodified zeolitic mineral showed that uranyl ion adsorption was low (29.2%) and that treatment of clinoptilolite with acids significantly increases the adsorption of uranyl ion (>90%). In the case of acid treated clinoptilolites, the highest adsorption of uranyl ion was achieved on clinoptilolite modified with hydrochloric acid. Kinetics of adsorption showed that adsorption of uranyl ion begins very fast and that the most of uranyl ion was adsorbed in first 30 min. Practically, there were no changes in uranyl ion adsorption within next 72 h.",
publisher = "Savez hemijskih inženjera, Beograd",
journal = "Hemijska industrija",
title = "Adsorpcija uranil-jona na modifikovanim klinoptilolitima, Adsorption of uranyl ion on acid-modified zeolitic mineral clinoptilolite",
pages = "414-407",
number = "5",
volume = "63",
doi = "10.2298/HEMIND0905407M",
url = "conv_294"
}
Matijašević, S., Daković, A., Ileš, D.,& Milićević, S.. (2009). Adsorpcija uranil-jona na modifikovanim klinoptilolitima. in Hemijska industrija
Savez hemijskih inženjera, Beograd., 63(5), 407-414.
https://doi.org/10.2298/HEMIND0905407M
conv_294
Matijašević S, Daković A, Ileš D, Milićević S. Adsorpcija uranil-jona na modifikovanim klinoptilolitima. in Hemijska industrija. 2009;63(5):407-414.
doi:10.2298/HEMIND0905407M
conv_294 .
Matijašević, Srđan, Daković, Aleksandra, Ileš, Deana, Milićević, Sonja, "Adsorpcija uranil-jona na modifikovanim klinoptilolitima" in Hemijska industrija, 63, no. 5 (2009):407-414,
https://doi.org/10.2298/HEMIND0905407M .,
conv_294 .
2
3
4

Površinska adsorpcija stearinske kiseline na prirodnom kalcitu

Mihajlović, Slavica; Daković, Aleksandra; Sekulić, Živko; Ileš, Deana; Kragović, Milan

(Savez hemijskih inženjera, Beograd, 2009)

TY  - JOUR
AU  - Mihajlović, Slavica
AU  - Daković, Aleksandra
AU  - Sekulić, Živko
AU  - Ileš, Deana
AU  - Kragović, Milan
PY  - 2009
UR  - https://ritnms.itnms.ac.rs/handle/123456789/160
AB  - U radu su prikazani rezultati modifikovanja površine kalcita suvim i mokrim postupkom. Kalcit je glavni i najzastupljeniji mineral kod prirodnog krečnjaka (>95%). Ispitivanja su vršena na seriji uzoraka sa sadržajem stearinske kiseline , kao površinski aktivne materije, od 0,5, 1, 1.5, 2, 3 i 4%. Na proizvodima dobijenim suvim i mokrim postupkom modifikovanja urađena je diferencijalno termijska analiza (DTA), termo-gravimetrijska analiza (TG) i skenirajuća elektronska mikroskopija (SEM). Stepen hidrofobnosti uzoraka praćen je određivanjem indeksa obloženosti. Rezultati pokazuju da je kod mokrog postupka najveći indeks obloženosti od 99,9% dobijen je na uzorku sa sadržajem stearinske kiseline od 1,5%, a kod suvog postupka kod uzorka sa sadržajem stearinske kiseline od 3%. Rezultati termičke analize pokazuju da se osnovni egzotermni maksimum kod oba postupka javlja na približno istim temperaturama (>310°C) što ukazuje na postojanje istih aktivnih mesta na površini kalcita na kojima može biti hemisorbovana stearinska kiselina. Položaj i intenzitet ostalih egzotermnih pikova ukazuje na različito vezivanje stearinske kiseline za površinu kalcita kod mokrog i suvog postupka.
AB  - In order to obtain hydrophobic material, the surface of natural limestone with the high content of calcite (>95%), was treated with 0.5, 1, 1.5, 2, 3 and 4% of stearic acid. Two methods were used for modification: the solution method and the dry coating. The obtained products were characterized using the thermal analysis (DT/TG), X-ray powder diffraction analysis (XRPD), scanning electron microscopy (SEM) and by the evaluation of floating test. Results of floating test showed that when the solution method was applied, the hydrophobicity arrived at above 99% when the amount of stearic acid was 1.5%, while with the dry coating the same hydrophobicity was achieved with 3% of stearic acid. From the position of the principal exothermic peak (> 310°C) at DTA curves, for calcites modified with dry coating and with the solution method, it can be concluded that with both modification processes, the same active sites exist at the calcite surface onto which stearic acid may be chemisorbed. However, the position and the intensity of the other exothermic peaks, indicate the differences in bonding of stearic acid at the calcite surface during the solution method and the dry coating.
PB  - Savez hemijskih inženjera, Beograd
T2  - Hemijska industrija
T1  - Površinska adsorpcija stearinske kiseline na prirodnom kalcitu
T1  - Surface adsorption of stearic acid by natural calcite
EP  - 106
IS  - 2
SP  - 101
VL  - 63
DO  - 10.2298/HEMIND0902101M
UR  - conv_292
ER  - 
@article{
author = "Mihajlović, Slavica and Daković, Aleksandra and Sekulić, Živko and Ileš, Deana and Kragović, Milan",
year = "2009",
abstract = "U radu su prikazani rezultati modifikovanja površine kalcita suvim i mokrim postupkom. Kalcit je glavni i najzastupljeniji mineral kod prirodnog krečnjaka (>95%). Ispitivanja su vršena na seriji uzoraka sa sadržajem stearinske kiseline , kao površinski aktivne materije, od 0,5, 1, 1.5, 2, 3 i 4%. Na proizvodima dobijenim suvim i mokrim postupkom modifikovanja urađena je diferencijalno termijska analiza (DTA), termo-gravimetrijska analiza (TG) i skenirajuća elektronska mikroskopija (SEM). Stepen hidrofobnosti uzoraka praćen je određivanjem indeksa obloženosti. Rezultati pokazuju da je kod mokrog postupka najveći indeks obloženosti od 99,9% dobijen je na uzorku sa sadržajem stearinske kiseline od 1,5%, a kod suvog postupka kod uzorka sa sadržajem stearinske kiseline od 3%. Rezultati termičke analize pokazuju da se osnovni egzotermni maksimum kod oba postupka javlja na približno istim temperaturama (>310°C) što ukazuje na postojanje istih aktivnih mesta na površini kalcita na kojima može biti hemisorbovana stearinska kiselina. Položaj i intenzitet ostalih egzotermnih pikova ukazuje na različito vezivanje stearinske kiseline za površinu kalcita kod mokrog i suvog postupka., In order to obtain hydrophobic material, the surface of natural limestone with the high content of calcite (>95%), was treated with 0.5, 1, 1.5, 2, 3 and 4% of stearic acid. Two methods were used for modification: the solution method and the dry coating. The obtained products were characterized using the thermal analysis (DT/TG), X-ray powder diffraction analysis (XRPD), scanning electron microscopy (SEM) and by the evaluation of floating test. Results of floating test showed that when the solution method was applied, the hydrophobicity arrived at above 99% when the amount of stearic acid was 1.5%, while with the dry coating the same hydrophobicity was achieved with 3% of stearic acid. From the position of the principal exothermic peak (> 310°C) at DTA curves, for calcites modified with dry coating and with the solution method, it can be concluded that with both modification processes, the same active sites exist at the calcite surface onto which stearic acid may be chemisorbed. However, the position and the intensity of the other exothermic peaks, indicate the differences in bonding of stearic acid at the calcite surface during the solution method and the dry coating.",
publisher = "Savez hemijskih inženjera, Beograd",
journal = "Hemijska industrija",
title = "Površinska adsorpcija stearinske kiseline na prirodnom kalcitu, Surface adsorption of stearic acid by natural calcite",
pages = "106-101",
number = "2",
volume = "63",
doi = "10.2298/HEMIND0902101M",
url = "conv_292"
}
Mihajlović, S., Daković, A., Sekulić, Ž., Ileš, D.,& Kragović, M.. (2009). Površinska adsorpcija stearinske kiseline na prirodnom kalcitu. in Hemijska industrija
Savez hemijskih inženjera, Beograd., 63(2), 101-106.
https://doi.org/10.2298/HEMIND0902101M
conv_292
Mihajlović S, Daković A, Sekulić Ž, Ileš D, Kragović M. Površinska adsorpcija stearinske kiseline na prirodnom kalcitu. in Hemijska industrija. 2009;63(2):101-106.
doi:10.2298/HEMIND0902101M
conv_292 .
Mihajlović, Slavica, Daković, Aleksandra, Sekulić, Živko, Ileš, Deana, Kragović, Milan, "Površinska adsorpcija stearinske kiseline na prirodnom kalcitu" in Hemijska industrija, 63, no. 2 (2009):101-106,
https://doi.org/10.2298/HEMIND0902101M .,
conv_292 .
2
1
3

The Effect of the Uranium Content in the Tailings on Some Cultivated Plants

Stojanović, Mirjana; Stevanović, Dragi; Ileš, Deana; Grubišić, Mirko; Milojković, Jelena

(Springer International Publishing Ag, Cham, 2009)

TY  - JOUR
AU  - Stojanović, Mirjana
AU  - Stevanović, Dragi
AU  - Ileš, Deana
AU  - Grubišić, Mirko
AU  - Milojković, Jelena
PY  - 2009
UR  - https://ritnms.itnms.ac.rs/handle/123456789/151
AB  - Uranium is a radiotoxic and chemotoxic heavy metal. Uptake and accumulation of U has been studied in plants native to uranium mine sites, but not in cultivated plants which are commonly consumed by humans. The objective of this study was better understanding of U uptake and accumulation in cultivated plants and whether different contents of uranium (U) in the substrate affect its concentration in plants and their dry matter mass. Two substrate variants for growing plants, which differed in the uranium content: solid wastes (tailings) and tailings mixed with sand (w/w 1:1). Large amounts of solid wastes (tailings) resulting from the exploitation and treatment of uranium ore from the closed uranium mine Gabrovnica-Kalna, on southeast of Serbia, contained generally 15.33 mg U/kg. In the experiment, three plant species (corn NSSC 231, sunflower N.S. Dukat, and green peas Smederevska Palanka) were grown in pots on the four substrate variants during 40 days. Substrate was suffused by drinking water (DW) and "uranium water" (UW), which issue out from the mine, contained 0,053 mg U/ dm(3). Obtained results show that when UW was added to tailing concentration of U in plants increased. When the content of U in the substrate was lowered by adding sand, the concentration of U in plants decreased, though was significantly higher in comparison to the variants to which DW was added. Dry matter mass was higher in variants where UW was used. Concentration of U was significantly higher in root than in above-ground parts.
PB  - Springer International Publishing Ag, Cham
T2  - Water Air and Soil Pollution
T1  - The Effect of the Uranium Content in the Tailings on Some Cultivated Plants
EP  - 108
IS  - 1-4
SP  - 101
VL  - 200
DO  - 10.1007/s11270-008-9896-4
UR  - conv_562
ER  - 
@article{
author = "Stojanović, Mirjana and Stevanović, Dragi and Ileš, Deana and Grubišić, Mirko and Milojković, Jelena",
year = "2009",
abstract = "Uranium is a radiotoxic and chemotoxic heavy metal. Uptake and accumulation of U has been studied in plants native to uranium mine sites, but not in cultivated plants which are commonly consumed by humans. The objective of this study was better understanding of U uptake and accumulation in cultivated plants and whether different contents of uranium (U) in the substrate affect its concentration in plants and their dry matter mass. Two substrate variants for growing plants, which differed in the uranium content: solid wastes (tailings) and tailings mixed with sand (w/w 1:1). Large amounts of solid wastes (tailings) resulting from the exploitation and treatment of uranium ore from the closed uranium mine Gabrovnica-Kalna, on southeast of Serbia, contained generally 15.33 mg U/kg. In the experiment, three plant species (corn NSSC 231, sunflower N.S. Dukat, and green peas Smederevska Palanka) were grown in pots on the four substrate variants during 40 days. Substrate was suffused by drinking water (DW) and "uranium water" (UW), which issue out from the mine, contained 0,053 mg U/ dm(3). Obtained results show that when UW was added to tailing concentration of U in plants increased. When the content of U in the substrate was lowered by adding sand, the concentration of U in plants decreased, though was significantly higher in comparison to the variants to which DW was added. Dry matter mass was higher in variants where UW was used. Concentration of U was significantly higher in root than in above-ground parts.",
publisher = "Springer International Publishing Ag, Cham",
journal = "Water Air and Soil Pollution",
title = "The Effect of the Uranium Content in the Tailings on Some Cultivated Plants",
pages = "108-101",
number = "1-4",
volume = "200",
doi = "10.1007/s11270-008-9896-4",
url = "conv_562"
}
Stojanović, M., Stevanović, D., Ileš, D., Grubišić, M.,& Milojković, J.. (2009). The Effect of the Uranium Content in the Tailings on Some Cultivated Plants. in Water Air and Soil Pollution
Springer International Publishing Ag, Cham., 200(1-4), 101-108.
https://doi.org/10.1007/s11270-008-9896-4
conv_562
Stojanović M, Stevanović D, Ileš D, Grubišić M, Milojković J. The Effect of the Uranium Content in the Tailings on Some Cultivated Plants. in Water Air and Soil Pollution. 2009;200(1-4):101-108.
doi:10.1007/s11270-008-9896-4
conv_562 .
Stojanović, Mirjana, Stevanović, Dragi, Ileš, Deana, Grubišić, Mirko, Milojković, Jelena, "The Effect of the Uranium Content in the Tailings on Some Cultivated Plants" in Water Air and Soil Pollution, 200, no. 1-4 (2009):101-108,
https://doi.org/10.1007/s11270-008-9896-4 .,
conv_562 .
19
19
25

Remediation of the Serbian soils contaminated by radionuclides in the function of the sustainable development

Stojanović, Mirjana; Grubišić, Mirko; Stevanović, Dragi; Milojković, Jelena; Ileš, Deana

(Savez hemijskih inženjera, Beograd, 2008)

TY  - JOUR
AU  - Stojanović, Mirjana
AU  - Grubišić, Mirko
AU  - Stevanović, Dragi
AU  - Milojković, Jelena
AU  - Ileš, Deana
PY  - 2008
UR  - https://ritnms.itnms.ac.rs/handle/123456789/141
AB  - Phosphate-induced metal stabilization (PIMS) using apatite stabilizes uranium in situ, by chemically binding it into the new low-solubility (Ksp=10-49) phase. Uranium-phosphate-autunite is stable across a wide range of geological conditions for millions of years. A large area of contaminated soil is suitable for in situ remediation that involves minimizing the mobility of the uranium. Laboratory study was conducted to quantify different forms of apatite sequestration of uranium contaminant. The experiment was done with natural phosphate from Lisina deposit (14.43 % P2O5), with non-treated samples, phosphate concentrate samples with 34.95 % P2O5 and mechanochemically activated of natural apatite. Different concentration of P2O5 in apatite, pH, reaction time, solid/liquid ratio was investigated. The concentrate at pH 5.5 for 7 days sorbed around 93,64 % and nature apatite, with 14,43 % P2O5, for 30 days sorbed 94.54 % of the uranium from the water solution, concentration 100 µg U/ml. The results show that mineral apatite 'Lisina' is very effective for the treatment of contaminated soils in situ immobilization of U. Mechanochemical activation of natural apatite in vibration mill immobilized 85.37 % of uranium in the 7-day period of acting. This research on natural apatite from the deposit 'Lisina' for immobilization of uranium was the first one of this type in our country.
PB  - Savez hemijskih inženjera, Beograd
T2  - Chemical Industry and Chemical Engineering Quarterly / CICEQ
T1  - Remediation of the Serbian soils contaminated by radionuclides in the function of the sustainable development
EP  - 267
IS  - 4
SP  - 265
VL  - 14
DO  - 10.2298/CICEQ0804265S
UR  - conv_385
ER  - 
@article{
author = "Stojanović, Mirjana and Grubišić, Mirko and Stevanović, Dragi and Milojković, Jelena and Ileš, Deana",
year = "2008",
abstract = "Phosphate-induced metal stabilization (PIMS) using apatite stabilizes uranium in situ, by chemically binding it into the new low-solubility (Ksp=10-49) phase. Uranium-phosphate-autunite is stable across a wide range of geological conditions for millions of years. A large area of contaminated soil is suitable for in situ remediation that involves minimizing the mobility of the uranium. Laboratory study was conducted to quantify different forms of apatite sequestration of uranium contaminant. The experiment was done with natural phosphate from Lisina deposit (14.43 % P2O5), with non-treated samples, phosphate concentrate samples with 34.95 % P2O5 and mechanochemically activated of natural apatite. Different concentration of P2O5 in apatite, pH, reaction time, solid/liquid ratio was investigated. The concentrate at pH 5.5 for 7 days sorbed around 93,64 % and nature apatite, with 14,43 % P2O5, for 30 days sorbed 94.54 % of the uranium from the water solution, concentration 100 µg U/ml. The results show that mineral apatite 'Lisina' is very effective for the treatment of contaminated soils in situ immobilization of U. Mechanochemical activation of natural apatite in vibration mill immobilized 85.37 % of uranium in the 7-day period of acting. This research on natural apatite from the deposit 'Lisina' for immobilization of uranium was the first one of this type in our country.",
publisher = "Savez hemijskih inženjera, Beograd",
journal = "Chemical Industry and Chemical Engineering Quarterly / CICEQ",
title = "Remediation of the Serbian soils contaminated by radionuclides in the function of the sustainable development",
pages = "267-265",
number = "4",
volume = "14",
doi = "10.2298/CICEQ0804265S",
url = "conv_385"
}
Stojanović, M., Grubišić, M., Stevanović, D., Milojković, J.,& Ileš, D.. (2008). Remediation of the Serbian soils contaminated by radionuclides in the function of the sustainable development. in Chemical Industry and Chemical Engineering Quarterly / CICEQ
Savez hemijskih inženjera, Beograd., 14(4), 265-267.
https://doi.org/10.2298/CICEQ0804265S
conv_385
Stojanović M, Grubišić M, Stevanović D, Milojković J, Ileš D. Remediation of the Serbian soils contaminated by radionuclides in the function of the sustainable development. in Chemical Industry and Chemical Engineering Quarterly / CICEQ. 2008;14(4):265-267.
doi:10.2298/CICEQ0804265S
conv_385 .
Stojanović, Mirjana, Grubišić, Mirko, Stevanović, Dragi, Milojković, Jelena, Ileš, Deana, "Remediation of the Serbian soils contaminated by radionuclides in the function of the sustainable development" in Chemical Industry and Chemical Engineering Quarterly / CICEQ, 14, no. 4 (2008):265-267,
https://doi.org/10.2298/CICEQ0804265S .,
conv_385 .
3
3

Određivanje arsena u rudama i jalovinama

Branković, Anđelka; Tešmanović, Ljiljana; Zildžović, Snežana; Kovačević, Dragana; Ileš, Deana

(Naučno-stručno društvo za zaštitu životne sredine Srbije - Ecologica, Beograd, 2007)

TY  - JOUR
AU  - Branković, Anđelka
AU  - Tešmanović, Ljiljana
AU  - Zildžović, Snežana
AU  - Kovačević, Dragana
AU  - Ileš, Deana
PY  - 2007
UR  - https://ritnms.itnms.ac.rs/handle/123456789/111
AB  - Arsen se pojavljuje kao prateći element sulfidnih ruda ležišta gvožđa, olova i drugih metala. Njegovo prisustvo u rudama je katkad u dovoljnim količinama da je ekonomski opravdano razmišljati o njegovoj eksploataciji. Kao toksičan element i u veoma malim količinama degradira kvalitet rude, na primer olovo-cinkane rude ili rude zeolita. U mnogim geološko-geohemijskim sistemima je prisutan arsen, koji predstavlja rizik za kvalitet životne sredine. Ispitivan je uticaj različitih postupaka hemijskog razlaganja uzorka mineralne sirovine na određivanje arsena, metodom AAS-MHS, sa ciljem da se na bazi eksperimentalnih rezultata, odabere najoptimalniji. Postupak treba da omogući efikasno hemijsko razlaganje uzorka, odnosno transformaciju iz čvrstog u tečno i potpunu jonizaciju migrirajućeg atoma ili jona arsena, što predstavlja osnovu za njegovo kvantitativno određivanje. U eksperimentima je korišćen prirodni zeolit i njemu identična po hemijskom sastavu napravljena smeša (kao referentni materijal) sa određenom koncentracijom arsena. Najoptimalniji način hemijskog razlaganja može, prioritetno i uspešnije, da se primeni i na druge mineralne sirovine i jalovine u koji ma se određuje arsen.
AB  - Arsenic occurs as a concomitant element of sulfide iron, lead and other metallic ores. The presence of arsenic in ores is sometimes in the quantities sufficient to be economically feasible. As a toxic element, even in the small quantities, arsenic degrades the quality of the ore, for example the lead-zinc or zeolite ore. Moreover, the arsenic is present in many geological-geochemical systems, representing the considerable risk for the quality of the environment. The objective of this paper is to present the results of the investigation aimed to evaluate the influence of different procedures applied for chemical destruction of mineral raw material on arsenic determination, using AAS-MHS method and selection of the optimal sample preparation procedure. The selected procedure should provide the efficient destruction of the sample, meaning transformation from solids to liquid, and total ionization of migrating atom or ion of arsenic, which is the basis for its quantitative determination. Natural zeolite ore and chemically identical zeolite mixture (reference material), with the adequate concentration of arsenic were used in the experimental work. The most appropriate procedure for chemical destruction can be preferentially and successfully applied also to the other mineral materials and tailings in which arsenic should be determined.
PB  - Naučno-stručno društvo za zaštitu životne sredine Srbije - Ecologica, Beograd
T2  - Ecologica
T1  - Određivanje arsena u rudama i jalovinama
T1  - The determination of arsenic in ores and tailings
EP  - 14
IS  - 49
SP  - 11
VL  - 14
UR  - conv_239
ER  - 
@article{
author = "Branković, Anđelka and Tešmanović, Ljiljana and Zildžović, Snežana and Kovačević, Dragana and Ileš, Deana",
year = "2007",
abstract = "Arsen se pojavljuje kao prateći element sulfidnih ruda ležišta gvožđa, olova i drugih metala. Njegovo prisustvo u rudama je katkad u dovoljnim količinama da je ekonomski opravdano razmišljati o njegovoj eksploataciji. Kao toksičan element i u veoma malim količinama degradira kvalitet rude, na primer olovo-cinkane rude ili rude zeolita. U mnogim geološko-geohemijskim sistemima je prisutan arsen, koji predstavlja rizik za kvalitet životne sredine. Ispitivan je uticaj različitih postupaka hemijskog razlaganja uzorka mineralne sirovine na određivanje arsena, metodom AAS-MHS, sa ciljem da se na bazi eksperimentalnih rezultata, odabere najoptimalniji. Postupak treba da omogući efikasno hemijsko razlaganje uzorka, odnosno transformaciju iz čvrstog u tečno i potpunu jonizaciju migrirajućeg atoma ili jona arsena, što predstavlja osnovu za njegovo kvantitativno određivanje. U eksperimentima je korišćen prirodni zeolit i njemu identična po hemijskom sastavu napravljena smeša (kao referentni materijal) sa određenom koncentracijom arsena. Najoptimalniji način hemijskog razlaganja može, prioritetno i uspešnije, da se primeni i na druge mineralne sirovine i jalovine u koji ma se određuje arsen., Arsenic occurs as a concomitant element of sulfide iron, lead and other metallic ores. The presence of arsenic in ores is sometimes in the quantities sufficient to be economically feasible. As a toxic element, even in the small quantities, arsenic degrades the quality of the ore, for example the lead-zinc or zeolite ore. Moreover, the arsenic is present in many geological-geochemical systems, representing the considerable risk for the quality of the environment. The objective of this paper is to present the results of the investigation aimed to evaluate the influence of different procedures applied for chemical destruction of mineral raw material on arsenic determination, using AAS-MHS method and selection of the optimal sample preparation procedure. The selected procedure should provide the efficient destruction of the sample, meaning transformation from solids to liquid, and total ionization of migrating atom or ion of arsenic, which is the basis for its quantitative determination. Natural zeolite ore and chemically identical zeolite mixture (reference material), with the adequate concentration of arsenic were used in the experimental work. The most appropriate procedure for chemical destruction can be preferentially and successfully applied also to the other mineral materials and tailings in which arsenic should be determined.",
publisher = "Naučno-stručno društvo za zaštitu životne sredine Srbije - Ecologica, Beograd",
journal = "Ecologica",
title = "Određivanje arsena u rudama i jalovinama, The determination of arsenic in ores and tailings",
pages = "14-11",
number = "49",
volume = "14",
url = "conv_239"
}
Branković, A., Tešmanović, L., Zildžović, S., Kovačević, D.,& Ileš, D.. (2007). Određivanje arsena u rudama i jalovinama. in Ecologica
Naučno-stručno društvo za zaštitu životne sredine Srbije - Ecologica, Beograd., 14(49), 11-14.
conv_239
Branković A, Tešmanović L, Zildžović S, Kovačević D, Ileš D. Određivanje arsena u rudama i jalovinama. in Ecologica. 2007;14(49):11-14.
conv_239 .
Branković, Anđelka, Tešmanović, Ljiljana, Zildžović, Snežana, Kovačević, Dragana, Ileš, Deana, "Određivanje arsena u rudama i jalovinama" in Ecologica, 14, no. 49 (2007):11-14,
conv_239 .

Adsorpcija uranijum(VI)-jona na modifikovanom hejlanditsko/klinoptilolitskom zeolitskom tufu

Matijašević, Srđan; Daković, Aleksandra; Tomašević-Čanović, Magdalena; Stojanović, Mirjana; Ileš, Deana

(Srpsko hemijsko društvo, Beograd, 2006)

TY  - JOUR
AU  - Matijašević, Srđan
AU  - Daković, Aleksandra
AU  - Tomašević-Čanović, Magdalena
AU  - Stojanović, Mirjana
AU  - Ileš, Deana
PY  - 2006
UR  - https://ritnms.itnms.ac.rs/handle/123456789/103
AB  - U radu je ispitivana adsorpcija uranijum(VI)-jona na površinski modifikovanom hejlanditsko/klinoptilolitskom zeolitskom tufu (organozeolitu). Organozeoliti su dobijeni jonskom izmenom neorganskih katjona sa površine zeolita sa heksadecil trimetil amonijum (HDTMA) jonima. Dobijeni rezultati su pokazali da je adsorpcija uranijum(VI)-jona na nemodifikovanom zeolitskom tufu niska (indeks adsorpcije 35% odnosno 0,34 mg uranijum(VI)-jona/g adsorbenta), dok kod organozeolita, adsorpcija uranijum(VI)-jona raste sa porastom sadržaja HDTMA na površini hejlandita/klinoptilolita. Najviši indeksi adsorpcije su dobijeni na organozeolitu od kojeg su svi katjoni sa spoljašnje površine zamenjeni sa HDTMA(OA.-10). Ispitivanja adsorpcije uranijum(VI)-jona na organozeolitu OA-10, na različitim pH su pokazala da adsorpcija raste sa porastom sadržaja adsorbenta u suspenziji. Kako oblik uranijum(VI)-jona u rastvoru, zavisi od pH sredine, isti oblik adsorpcionih izotermi na pH 6 i 8 (Langmuir-ov tip izoterme), ukazuje da se uranijum(VI)-jon u istom obliku apsorbuje na površini zeolitskog tufa. Adsorpcija uranijum(VI)-jona pri pH 3 odgovara Tipu III adsorpcione izoterme.
AB  - The adsorption of uranium(VI) on heulandite/clinoptilolite rich zeolitic tuff modified with different amounts (2, 5 and 10 meq/100 g) of hexadecyltrimethyl ammonium (HDTMA) ion was investigated. The organozeolites were prepared by ion exchange of inorganic cations at the zeolite surface with HDTMA ions, and the three prepared samples were denoted as OA-2, OA-5 and OA-10. The maximal amount of HDTMAin the organozeolite OA-10 (10 meq/100 g) was equal to the external cation exchange capacity of the starting material. The results showed that uranium( VI) adsorption on unmodified zeolitic tuff was low (0.34 mg uranium(VI)/g adsorbent), while for the organozeolites, the adsorption increased with increasing amount of HDTMA at the zeolitic surface. The highest adsorption indexes were achieved for the organozeolite OA-10, in which all the surface inorganic cations had been replaced with HDTMA. An investigation of the adsorption of uranium(VI) ions onto organozeolite OA-10 at different pH values (3, 6 and 8) showed that the adsorption index increased with increasing amount of adsorbent in the suspension. Since uranium(VI) speciation is highly dependent on pH, from the adsorption isotherms, it can be seen that uranium(VI) adsorption on organozeolite OA-10 at pH 6 and 8 is well described by a Langmuir type of isotherm, while at pH 3, it corresponds to a Type III isotherm.
PB  - Srpsko hemijsko društvo, Beograd
T2  - Journal of the Serbian Chemical Society
T1  - Adsorpcija uranijum(VI)-jona na modifikovanom hejlanditsko/klinoptilolitskom zeolitskom tufu
T1  - Uranium(VI) adsorption on surfactant modified heulandite/clinoptilolite rich tuff
EP  - 1331
IS  - 12
SP  - 1323
VL  - 71
DO  - 10.2298/JSC0612323M
UR  - conv_520
ER  - 
@article{
author = "Matijašević, Srđan and Daković, Aleksandra and Tomašević-Čanović, Magdalena and Stojanović, Mirjana and Ileš, Deana",
year = "2006",
abstract = "U radu je ispitivana adsorpcija uranijum(VI)-jona na površinski modifikovanom hejlanditsko/klinoptilolitskom zeolitskom tufu (organozeolitu). Organozeoliti su dobijeni jonskom izmenom neorganskih katjona sa površine zeolita sa heksadecil trimetil amonijum (HDTMA) jonima. Dobijeni rezultati su pokazali da je adsorpcija uranijum(VI)-jona na nemodifikovanom zeolitskom tufu niska (indeks adsorpcije 35% odnosno 0,34 mg uranijum(VI)-jona/g adsorbenta), dok kod organozeolita, adsorpcija uranijum(VI)-jona raste sa porastom sadržaja HDTMA na površini hejlandita/klinoptilolita. Najviši indeksi adsorpcije su dobijeni na organozeolitu od kojeg su svi katjoni sa spoljašnje površine zamenjeni sa HDTMA(OA.-10). Ispitivanja adsorpcije uranijum(VI)-jona na organozeolitu OA-10, na različitim pH su pokazala da adsorpcija raste sa porastom sadržaja adsorbenta u suspenziji. Kako oblik uranijum(VI)-jona u rastvoru, zavisi od pH sredine, isti oblik adsorpcionih izotermi na pH 6 i 8 (Langmuir-ov tip izoterme), ukazuje da se uranijum(VI)-jon u istom obliku apsorbuje na površini zeolitskog tufa. Adsorpcija uranijum(VI)-jona pri pH 3 odgovara Tipu III adsorpcione izoterme., The adsorption of uranium(VI) on heulandite/clinoptilolite rich zeolitic tuff modified with different amounts (2, 5 and 10 meq/100 g) of hexadecyltrimethyl ammonium (HDTMA) ion was investigated. The organozeolites were prepared by ion exchange of inorganic cations at the zeolite surface with HDTMA ions, and the three prepared samples were denoted as OA-2, OA-5 and OA-10. The maximal amount of HDTMAin the organozeolite OA-10 (10 meq/100 g) was equal to the external cation exchange capacity of the starting material. The results showed that uranium( VI) adsorption on unmodified zeolitic tuff was low (0.34 mg uranium(VI)/g adsorbent), while for the organozeolites, the adsorption increased with increasing amount of HDTMA at the zeolitic surface. The highest adsorption indexes were achieved for the organozeolite OA-10, in which all the surface inorganic cations had been replaced with HDTMA. An investigation of the adsorption of uranium(VI) ions onto organozeolite OA-10 at different pH values (3, 6 and 8) showed that the adsorption index increased with increasing amount of adsorbent in the suspension. Since uranium(VI) speciation is highly dependent on pH, from the adsorption isotherms, it can be seen that uranium(VI) adsorption on organozeolite OA-10 at pH 6 and 8 is well described by a Langmuir type of isotherm, while at pH 3, it corresponds to a Type III isotherm.",
publisher = "Srpsko hemijsko društvo, Beograd",
journal = "Journal of the Serbian Chemical Society",
title = "Adsorpcija uranijum(VI)-jona na modifikovanom hejlanditsko/klinoptilolitskom zeolitskom tufu, Uranium(VI) adsorption on surfactant modified heulandite/clinoptilolite rich tuff",
pages = "1331-1323",
number = "12",
volume = "71",
doi = "10.2298/JSC0612323M",
url = "conv_520"
}
Matijašević, S., Daković, A., Tomašević-Čanović, M., Stojanović, M.,& Ileš, D.. (2006). Adsorpcija uranijum(VI)-jona na modifikovanom hejlanditsko/klinoptilolitskom zeolitskom tufu. in Journal of the Serbian Chemical Society
Srpsko hemijsko društvo, Beograd., 71(12), 1323-1331.
https://doi.org/10.2298/JSC0612323M
conv_520
Matijašević S, Daković A, Tomašević-Čanović M, Stojanović M, Ileš D. Adsorpcija uranijum(VI)-jona na modifikovanom hejlanditsko/klinoptilolitskom zeolitskom tufu. in Journal of the Serbian Chemical Society. 2006;71(12):1323-1331.
doi:10.2298/JSC0612323M
conv_520 .
Matijašević, Srđan, Daković, Aleksandra, Tomašević-Čanović, Magdalena, Stojanović, Mirjana, Ileš, Deana, "Adsorpcija uranijum(VI)-jona na modifikovanom hejlanditsko/klinoptilolitskom zeolitskom tufu" in Journal of the Serbian Chemical Society, 71, no. 12 (2006):1323-1331,
https://doi.org/10.2298/JSC0612323M .,
conv_520 .
22
24
29

The influence of detergents and active components of detergent on bioproduction of organic matters and enzymatic activity of some species of fungi

Stojanović, J; Stojanović, Mirjana; Ileš, Deana; Mijusković, Z

(Casa Editrice Tilgher-Genova sas, 2004)

TY  - JOUR
AU  - Stojanović, J
AU  - Stojanović, Mirjana
AU  - Ileš, Deana
AU  - Mijusković, Z
PY  - 2004
UR  - https://ritnms.itnms.ac.rs/handle/123456789/62
AB  - Detergent (Merix, "Merima" Krusevac) applied in concentration of 1 % vol. showed specific influence on the bioproduction of some 15 different amino acids and on the enzyme activity of the species of fungi A. niger, A. alternata and T. roseum. Detergent has significantly stimulated the production of 15 analyzed amino acids of the fungi species A. niger. The same applied concentration of detergent has decreased or considerably decreased the production of some 14 of totally 15 analyzed amino acids of investigated fungi species A. alternata and T. roseum. The enzyme activity of the fungi A. niger was more intensive in relation to species A. alternata and T. roseum during the experimental period or in the species some phases of the experimental period. The detergent component, ethoxyled oleyl-cetyl alcohol, in concentration of 0.01 %, 0.1 % and 1 % showed an inhibitory effect, or significant inhibitory effect on the enzyme activity of the examined species of fungi (A. niger, A. alternata and T. roseum).
PB  - Casa Editrice Tilgher-Genova sas
T2  - Rivista di Biologia - Biology Forum
T1  - The influence of detergents and active components of detergent on bioproduction of organic matters and enzymatic activity of some species of fungi
EP  - 350
IS  - 2
SP  - 341
VL  - 97
UR  - conv_1134
ER  - 
@article{
author = "Stojanović, J and Stojanović, Mirjana and Ileš, Deana and Mijusković, Z",
year = "2004",
abstract = "Detergent (Merix, "Merima" Krusevac) applied in concentration of 1 % vol. showed specific influence on the bioproduction of some 15 different amino acids and on the enzyme activity of the species of fungi A. niger, A. alternata and T. roseum. Detergent has significantly stimulated the production of 15 analyzed amino acids of the fungi species A. niger. The same applied concentration of detergent has decreased or considerably decreased the production of some 14 of totally 15 analyzed amino acids of investigated fungi species A. alternata and T. roseum. The enzyme activity of the fungi A. niger was more intensive in relation to species A. alternata and T. roseum during the experimental period or in the species some phases of the experimental period. The detergent component, ethoxyled oleyl-cetyl alcohol, in concentration of 0.01 %, 0.1 % and 1 % showed an inhibitory effect, or significant inhibitory effect on the enzyme activity of the examined species of fungi (A. niger, A. alternata and T. roseum).",
publisher = "Casa Editrice Tilgher-Genova sas",
journal = "Rivista di Biologia - Biology Forum",
title = "The influence of detergents and active components of detergent on bioproduction of organic matters and enzymatic activity of some species of fungi",
pages = "350-341",
number = "2",
volume = "97",
url = "conv_1134"
}
Stojanović, J., Stojanović, M., Ileš, D.,& Mijusković, Z.. (2004). The influence of detergents and active components of detergent on bioproduction of organic matters and enzymatic activity of some species of fungi. in Rivista di Biologia - Biology Forum
Casa Editrice Tilgher-Genova sas., 97(2), 341-350.
conv_1134
Stojanović J, Stojanović M, Ileš D, Mijusković Z. The influence of detergents and active components of detergent on bioproduction of organic matters and enzymatic activity of some species of fungi. in Rivista di Biologia - Biology Forum. 2004;97(2):341-350.
conv_1134 .
Stojanović, J, Stojanović, Mirjana, Ileš, Deana, Mijusković, Z, "The influence of detergents and active components of detergent on bioproduction of organic matters and enzymatic activity of some species of fungi" in Rivista di Biologia - Biology Forum, 97, no. 2 (2004):341-350,
conv_1134 .