Removal of lead from aqueous solutions by using the natural and Fe(III)-modified zeolite
Нема приказа
Аутори
Kragović, Milan![](/themes/Mirageritnms/images/orcid.png)
Daković, Aleksandra
![](/themes/Mirageritnms/images/orcid.png)
Sekulić, Živko
Trgo, Marina
![](/themes/Mirageritnms/images/orcid.png)
Ugrina, Marin
![](/themes/Mirageritnms/images/orcid.png)
Perić, Jelena
Gatta, G. Diego
![](/themes/Mirageritnms/images/orcid.png)
Чланак у часопису (Објављена верзија)
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Метаподаци
Приказ свих података о документуАпстракт
In the present study, the sorption of lead by the natural and Fe(III)-modified zeolite (clinoptilolite) is described. The characterization of the natural zeolite-rich rock and the Fe(III)-modified form was performed by chemical analysis, point of the zero charge (pHpzc), X-ray powder diffraction, applying the Rietveld/RIR method for the quantitative phase analysis, and scanning electron microscopy. The effects of sorbents dose and the initial lead concentrations on its sorption by two sorbents were investigated. For both sorbents, it was determined that at lower initial concentrations of lead, ion exchange of inorganic cations in zeolites with lead, together with uptake of hydrogen dominated, while at higher initial lead concentrations beside these processes, chemisorption of lead occurred. Significantly higher sorption of lead was achieved with Fe(III)-modified zeolite. From sorption isotherms, maximum sorbed amounts of lead, under the applied experimental conditions, were 66 mg/g for... the natural and 133 mg/g for Fe(III)modified zeolite. The best fit of experimental data was achieved with the Freundlich model (R-2 >= 0.94).
Кључне речи:
Sorption / Natural zeolite / Lead / Heavy metals / Fe(III)-modified zeoliteИзвор:
Applied Surface Science, 2012, 258, 8, 3667-3673Издавач:
- Elsevier, Amsterdam
Финансирање / пројекти:
- Порозни материјали на бази оксида у заштити животне средине од генотоксичних супстанци (RS-MESTD-Basic Research (BR or ON)-172018)
- Освајање технолошких поступака добијања еколошких материјала на бази неметаличних минералних сировина (RS-MESTD-Technological Development (TD or TR)-34013)
DOI: 10.1016/j.apsusc.2011.12.002
ISSN: 0169-4332
WoS: 000300185800052
Scopus: 2-s2.0-84856228819
Институција/група
Institut za tehnologiju nuklearnih i drugih mineralnih sirovinaTY - JOUR AU - Kragović, Milan AU - Daković, Aleksandra AU - Sekulić, Živko AU - Trgo, Marina AU - Ugrina, Marin AU - Perić, Jelena AU - Gatta, G. Diego PY - 2012 UR - https://ritnms.itnms.ac.rs/handle/123456789/204 AB - In the present study, the sorption of lead by the natural and Fe(III)-modified zeolite (clinoptilolite) is described. The characterization of the natural zeolite-rich rock and the Fe(III)-modified form was performed by chemical analysis, point of the zero charge (pHpzc), X-ray powder diffraction, applying the Rietveld/RIR method for the quantitative phase analysis, and scanning electron microscopy. The effects of sorbents dose and the initial lead concentrations on its sorption by two sorbents were investigated. For both sorbents, it was determined that at lower initial concentrations of lead, ion exchange of inorganic cations in zeolites with lead, together with uptake of hydrogen dominated, while at higher initial lead concentrations beside these processes, chemisorption of lead occurred. Significantly higher sorption of lead was achieved with Fe(III)-modified zeolite. From sorption isotherms, maximum sorbed amounts of lead, under the applied experimental conditions, were 66 mg/g for the natural and 133 mg/g for Fe(III)modified zeolite. The best fit of experimental data was achieved with the Freundlich model (R-2 >= 0.94). PB - Elsevier, Amsterdam T2 - Applied Surface Science T1 - Removal of lead from aqueous solutions by using the natural and Fe(III)-modified zeolite EP - 3673 IS - 8 SP - 3667 VL - 258 DO - 10.1016/j.apsusc.2011.12.002 UR - conv_609 ER -
@article{ author = "Kragović, Milan and Daković, Aleksandra and Sekulić, Živko and Trgo, Marina and Ugrina, Marin and Perić, Jelena and Gatta, G. Diego", year = "2012", abstract = "In the present study, the sorption of lead by the natural and Fe(III)-modified zeolite (clinoptilolite) is described. The characterization of the natural zeolite-rich rock and the Fe(III)-modified form was performed by chemical analysis, point of the zero charge (pHpzc), X-ray powder diffraction, applying the Rietveld/RIR method for the quantitative phase analysis, and scanning electron microscopy. The effects of sorbents dose and the initial lead concentrations on its sorption by two sorbents were investigated. For both sorbents, it was determined that at lower initial concentrations of lead, ion exchange of inorganic cations in zeolites with lead, together with uptake of hydrogen dominated, while at higher initial lead concentrations beside these processes, chemisorption of lead occurred. Significantly higher sorption of lead was achieved with Fe(III)-modified zeolite. From sorption isotherms, maximum sorbed amounts of lead, under the applied experimental conditions, were 66 mg/g for the natural and 133 mg/g for Fe(III)modified zeolite. The best fit of experimental data was achieved with the Freundlich model (R-2 >= 0.94).", publisher = "Elsevier, Amsterdam", journal = "Applied Surface Science", title = "Removal of lead from aqueous solutions by using the natural and Fe(III)-modified zeolite", pages = "3673-3667", number = "8", volume = "258", doi = "10.1016/j.apsusc.2011.12.002", url = "conv_609" }
Kragović, M., Daković, A., Sekulić, Ž., Trgo, M., Ugrina, M., Perić, J.,& Gatta, G. D.. (2012). Removal of lead from aqueous solutions by using the natural and Fe(III)-modified zeolite. in Applied Surface Science Elsevier, Amsterdam., 258(8), 3667-3673. https://doi.org/10.1016/j.apsusc.2011.12.002 conv_609
Kragović M, Daković A, Sekulić Ž, Trgo M, Ugrina M, Perić J, Gatta GD. Removal of lead from aqueous solutions by using the natural and Fe(III)-modified zeolite. in Applied Surface Science. 2012;258(8):3667-3673. doi:10.1016/j.apsusc.2011.12.002 conv_609 .
Kragović, Milan, Daković, Aleksandra, Sekulić, Živko, Trgo, Marina, Ugrina, Marin, Perić, Jelena, Gatta, G. Diego, "Removal of lead from aqueous solutions by using the natural and Fe(III)-modified zeolite" in Applied Surface Science, 258, no. 8 (2012):3667-3673, https://doi.org/10.1016/j.apsusc.2011.12.002 ., conv_609 .