Preparation of glass-ceramic in Li2O-Al2O3-GeO2-P2O5 system
2013
Autori
Nikolić, JelenaSmiljanić, Sonja
Matijašević, Srđan
Živanović, Vladimir D.
Tošič, Mihajlo B.
Grujić, Snežana R.
Stojanović, Jovica
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
The results of preparation and structural characterization of glass-ceramics from the system Li2O-Al2O3-GeO2-P2O5 are shown in this paper. The crystallization behaviour of the selected glass was examined under non-isothermal and isothermal crystallization conditions. DTA, XRD and SEM methods were employed for analyses. It was confirmed that this glass crystallizes by the volume crystallization mechanism. The results also showed that the glass crystallize by primary crystallization. As a primary phase the LiGe2(PO4)3 is formed and the traces of GeO2 as a secondary one is present. The crystallization process occurred at a high homogeneous nucleation rate and the spherical morphology of crystal growth. By applying the Kissinger relation the activation energy of crystal growth Ea = 462 kJ/mol was determined.
Ključne reči:
kinetics / germanium phosphate glass / crystallization / crystal growthIzvor:
Processing and Application of Ceramics, 2013, 7, 4, 147-151Izdavač:
- Univerzitet u Novom Sadu - Tehnološki fakultet, Novi Sad
Finansiranje / projekti:
- Razvoj stakala sa kontrolisanim otpuštanjem jona za primenu u poljoprivredi i medicini (RS-MESTD-Technological Development (TD or TR)-34001)
- Fenomeni i procesi sinteze novih staklastih i nanostrukturnih staklo-keramičkih materijala (RS-MESTD-Basic Research (BR or ON)-172004)
Institucija/grupa
Institut za tehnologiju nuklearnih i drugih mineralnih sirovinaTY - JOUR AU - Nikolić, Jelena AU - Smiljanić, Sonja AU - Matijašević, Srđan AU - Živanović, Vladimir D. AU - Tošič, Mihajlo B. AU - Grujić, Snežana R. AU - Stojanović, Jovica PY - 2013 UR - https://ritnms.itnms.ac.rs/handle/123456789/266 AB - The results of preparation and structural characterization of glass-ceramics from the system Li2O-Al2O3-GeO2-P2O5 are shown in this paper. The crystallization behaviour of the selected glass was examined under non-isothermal and isothermal crystallization conditions. DTA, XRD and SEM methods were employed for analyses. It was confirmed that this glass crystallizes by the volume crystallization mechanism. The results also showed that the glass crystallize by primary crystallization. As a primary phase the LiGe2(PO4)3 is formed and the traces of GeO2 as a secondary one is present. The crystallization process occurred at a high homogeneous nucleation rate and the spherical morphology of crystal growth. By applying the Kissinger relation the activation energy of crystal growth Ea = 462 kJ/mol was determined. PB - Univerzitet u Novom Sadu - Tehnološki fakultet, Novi Sad T2 - Processing and Application of Ceramics T1 - Preparation of glass-ceramic in Li2O-Al2O3-GeO2-P2O5 system EP - 151 IS - 4 SP - 147 VL - 7 DO - 10.2298/PAC1304147N UR - https://hdl.handle.net/21.15107/rcub_technorep_2333 UR - conv_474 ER -
@article{ author = "Nikolić, Jelena and Smiljanić, Sonja and Matijašević, Srđan and Živanović, Vladimir D. and Tošič, Mihajlo B. and Grujić, Snežana R. and Stojanović, Jovica", year = "2013", abstract = "The results of preparation and structural characterization of glass-ceramics from the system Li2O-Al2O3-GeO2-P2O5 are shown in this paper. The crystallization behaviour of the selected glass was examined under non-isothermal and isothermal crystallization conditions. DTA, XRD and SEM methods were employed for analyses. It was confirmed that this glass crystallizes by the volume crystallization mechanism. The results also showed that the glass crystallize by primary crystallization. As a primary phase the LiGe2(PO4)3 is formed and the traces of GeO2 as a secondary one is present. The crystallization process occurred at a high homogeneous nucleation rate and the spherical morphology of crystal growth. By applying the Kissinger relation the activation energy of crystal growth Ea = 462 kJ/mol was determined.", publisher = "Univerzitet u Novom Sadu - Tehnološki fakultet, Novi Sad", journal = "Processing and Application of Ceramics", title = "Preparation of glass-ceramic in Li2O-Al2O3-GeO2-P2O5 system", pages = "151-147", number = "4", volume = "7", doi = "10.2298/PAC1304147N", url = "https://hdl.handle.net/21.15107/rcub_technorep_2333, conv_474" }
Nikolić, J., Smiljanić, S., Matijašević, S., Živanović, V. D., Tošič, M. B., Grujić, S. R.,& Stojanović, J.. (2013). Preparation of glass-ceramic in Li2O-Al2O3-GeO2-P2O5 system. in Processing and Application of Ceramics Univerzitet u Novom Sadu - Tehnološki fakultet, Novi Sad., 7(4), 147-151. https://doi.org/10.2298/PAC1304147N https://hdl.handle.net/21.15107/rcub_technorep_2333
Nikolić J, Smiljanić S, Matijašević S, Živanović VD, Tošič MB, Grujić SR, Stojanović J. Preparation of glass-ceramic in Li2O-Al2O3-GeO2-P2O5 system. in Processing and Application of Ceramics. 2013;7(4):147-151. doi:10.2298/PAC1304147N https://hdl.handle.net/21.15107/rcub_technorep_2333 .
Nikolić, Jelena, Smiljanić, Sonja, Matijašević, Srđan, Živanović, Vladimir D., Tošič, Mihajlo B., Grujić, Snežana R., Stojanović, Jovica, "Preparation of glass-ceramic in Li2O-Al2O3-GeO2-P2O5 system" in Processing and Application of Ceramics, 7, no. 4 (2013):147-151, https://doi.org/10.2298/PAC1304147N ., https://hdl.handle.net/21.15107/rcub_technorep_2333 .